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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Calculated hydroxyl A2 sigma --> X2 pi (0, 0) band emission rate factors applicable to atmospheric spectroscopy

A calculation of the A2 sigma --> X2 pi (0, 0) band emission rate factors and line center absorption cross sections of OH applicable to its measurement using solar resonant fluorescence in the terrestrial atmosphere is presented in this paper. The most accurate available line parameters have been used. Special consideration has been given to the solar input flux because of its highly structured Fraunhofer spectrum. The calculation for the OH atmospheric emission rate factor in the solar resonant fluorescent case is described in detail with examples and intermediate results. Results of this calculation of OH emission rate factors for individual rotational lines are on average 30% lower than the values obtained in an earlier work.

NASA Discipline Exobiology↗
NASA NTRS1980

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for calcium and nickel ions in low-density high-temperature plasmas

The total dielectronic recombination rates for Ca and Ni ions were calculated taking into account autoionization to excited states of the recombining ion and stabilizing radiative transitions of the recombining electron. Radiative transitions of the recombining ion are found to be the dominant stabilizing processes, and the relative importance of Delta n = 0 and Delta n not equal to 0 transitions in the relevant temperature region is determined for each ion. The relative importance of the Delta n = 0 and Delta n not equal to 0 contributions is significantly altered for some ions by the inclusion of autoionization to excited levels. The relative abundance of the various ionization stages has been determined by using a corona equilibrium model in which collisional ionization and inner-shell excitation followed by autoionization are balanced by direct radiative and dielectronic recombination.

Jacobs, V. L.↗
NASA NTRS1990

Auroral modeling of the 3371 A emission rate - Dependence on characteristic electron energy

An efficient two-stream auroral electron model is used to study the deposition of auroral energy and the dependence of auroral emission rates on characteristic energy. This model incorporates the concept of average energy loss to reduce the computation time. This simple two-stream model produces integrated emission rates that are in excellent agreement with the much more complex multistream model of Strickland et al. (1983) but disagrees with a recent study by Rees and Lummerzheim (1989) that indicates that the N2 second positive emission rate is a strongly decreasing function of the characteristic energy of the precipitating flux. These calculations reveal that a 10 keV electron will undergo approximately 160 ionizing collisions, with an average energy loss per collision of 62 eV before thermalizing. The secondary electrons are created with an average energy of 42 eV. When all processes including the backscattered escape fluxes are taken into account, the average energy loss per electron-ion pair is 35 eV in good agreement with laboratory results.

Richards, P. G.↗
NASA NTRS1991

Inversion techniques for recovering two-dimensional distributions of auroral emission rates from tomographic rocket photometer measurements

This paper demonstrates how the spatial distribution of optical emission rates within an auroral arc may be recovered from rocket photometer measurements made in a tomographic spin scan mode. The tomographic inversion procedures required to recover this information and the implementation of two inversion algorithms that are particularly well suited for dealing with the problem of noise in the observational data are described. The performance of the inversion algorithms and the limitations of the rocket tomography technique are assessed using various sets of simulated rocket measurements that were generated from 'known' auroral emission-rate distributions. The simulations are used to investigate how the quality of the tomographic recovery may be influenced by various factors such as noise in the data, rocket penetration of the auroral form, background sources of emission, smearing due to the photometer field of view, and temporal variations in the auroral form.

Mcdade, Ian. C.↗
DOE OSTI2024

Consequential Analysis of the Greenhouse Gas Emissions Impacts of Actions That Influence the Electric Grid: The Theory and Practice of Using Marginal Emissions Rates

This paper discusses consequential greenhouse gas emissions analysis for actions that influence the electric grid that is, the analytical approach of estimating how such actions change greenhouse gas emissions, relative to what they otherwise would have been without the action. Although the paper starts with general considerations, it ultimately focuses on consequential analysis with marginal emissions rates as an option likely more scalable than others.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Planning for the Evolution of the Electric Grid with a Long-Run Marginal Emission Rate [Slides]

NREL Webinar slide deck that summarizes the findings of a recent article published in iScience, "Planning for the evolution of the grid with a long-run marginal emission rate". The webinar focuses on a study of how well three different types of emissions factors can anticipate the electric-sector carbon emissions induced by different types of interventions.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

Long-run Marginal Emission Rates for Electricity - Workbooks for 2023 Cambium Data

These workbooks contain modeled estimates of long-run marginal emission rates (LRMER) for the contiguous United States' electric sector. A LRMER is an estimate of the rate of emissions that would be either induced or avoided by a change in electric demand, taking into account how the change could influence both the operation as well as the structure of the grid (i.e., the building and retiring of capital assets, such as generators and transmission lines). These workbooks provide data for 18 GEA regions covering the contiguous United States. Mappings of these regions to ZIP codes and counties is given in this workbook in the corresponding tabs. For more data underlying these emissions factors, see the Cambium 2023 project at https://scenarioviewer.nrel.gov/. For more details on input assumptions and methodology see the associated report (Cambium 2023 Scenario Descriptions and Documentation, https://www.nrel.gov/docs/fy24osti/88507.pdf). Users are advised to review section 4 of the report, which discusses limitations and caveats of the data. This data is planned to be updated annually. Information on the latest versions can be found at https://www.nrel.gov/analysis/cambium.html.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

A systematic comparison of machine learning methods for modeling of dynamic processes applied to combustion emission rate modeling

Ten established, data-driven dynamic algorithms are surveyed and a practical guide for understanding these methods generated. Existing Python programming packages for implementing each algorithm are acknowledged, and the model equations necessary for prediction are presented. A case study on a coal-fired power plant’s NO x emission rates is performed, directly comparing each modeling method’s performance on a mutual system. Each model is evaluated by its root mean squared error (RMSE) on out-of-sample future horizon predictions. Optimal hyperparameters are identified using either an exhaustive search or genetic algorithm. The top five model structures of each method are used to recursively predict future NO x emission rates over a 60-step time horizon. The RMSE at each future timestep is determined, and the recursive output prediction trends compared against measurements in time. The GRU neural network is identified as the best candidate for representing the system, demonstrating accurate and stable predictions across the future horizon by all considered models, while satisfactory performance was observed in several of the ARX/NARX formulations. Finally, these efforts have contributed 1) a concise resource of multiple proven dynamic machine learning methods, 2) a practical guide explaining the use of these methods, effectively lowering the “barrier-to-entry” of deploying such models in control systems, 3) a comparison study evaluating each method’s performance on a mutual system, 4) demonstration of accurate multi-timestep emissions modeling suitable for systems-level control, and 5) generalizable results demonstrating the suitability of each method for prediction over a multi-step future horizon to other complex dynamic systems.

42 ENGINEERING↗
NASA NTRS1989

OH A 2Sigma - X 2Pi (0,0) band rotational line emission rate factors

This paper presents the results of the emission-rate factor (g factor) calculations for the (0,0) band of the OH (A 2Sigma - X 2Pi) system, for the temperatures 200.0, 240.0, 296.0, 300.0, and 500.0 K, as well as for the individual g factors for each rotational line of the band. The derived g factor at 240 K for the entire band is 0.00055 + or - 0.00011 photon/sec. The g factor for the entire band was found to decrease with increasing temperature, but the difference in the change was less than 10 percent for the temperature range studied. The data on the individual rotational line g factors are valuable for future work on determining OH concentration profiles in the atmosphere, through the observation of the UV fluorescence in the OH (A 2Sigma - X 2Pi) (0,0) band using high-resolution spectrometers of a low-scattered-light design.

Fennelly, J. A.↗
NASA NTRS1976

Resolution of the discrepancy between Balmer alpha emission rates, the solar Lyman beta flux, and models of geocoronal hydrogen concentration

New satellite Balmer alpha measurements and solar Lyman beta flux and line profile measurements, together with new measurements of the zodiacal light intensity used in correcting both ground and satellite Balmer alpha measurements for the effects of the Fraunhofer line in the zodiacal light, have been used in a reevaluation of the long-standing discrepancy between ground-based Balmer alpha emission rates and other geocoronal hydrogen parameters. The solar Lyman beta line center flux is found to be (4.1 plus or minus 1.3) billion photons per sq cm per sec per angstrom at S(10.7) equals 110 and, together with a current hydrogen model which has 92,000 atoms per cu cm at 650 km for T(inf) equals 950 K, gives good agreement between calculated Balmer alpha emission rates and the ground-based and satellite measurements.

Levasseur, A.-C.↗
NASA NTRS2009

Storm/Quiet Ratio Comparisons Between TIMED/SABER NO (sup +)(v) Volume Emission Rates and Incoherent Scatter Radar Electron Densities at E-Region Altitudes

Broadband infrared limb emission at 4.3 microns is measured by the TIMED/SABER instrument. At night, these emission observations at E-region altitudes are used to derive the so called NO+(v) Volume Emission Rate (VER). NO+(v) VER can be derived by removing the background CO2(v3) 4.3 microns radiance contribution using SABER-based non-LTE radiation transfer models, and by performing a standard Abel inversion on the residual radiance. SABER observations show that NO+(v) VER is significantly enhanced during magnetic storms in accordance with increased ionization of the neutral atmosphere by auroral electron precipitation, followed by vibrational excitation of NO+ (i.e., NO+(v)) from fast exothermic ion-neutral reactions, and prompt infrared emission at 4.3 m. Due to charge neutrality, the NO+(v) VER enhancements are highly correlated with electron density enhancements, as observed for example by Incoherent Scatter Radar (ISR). In order to characterize the response of the storm-time E-region from both SABER and ISR measurements, a Storm/Quiet ratio (SQR) quantity is defined as a function of altitude. For SABER, the SQR is the ratio of the storm-to-quiet NO+(v) VER. SQR is the storm-to-quiet ratio of electron densities for ISR. In this work, we compare SABER and ISR SQR values between 100 to 120 km. Results indicate good agreement between these measurements. SQR values are intended to be used as a correction factor to be included in an empirical storm-time correction to the International Reference Ionosphere model at E-region altitudes.

Fernandez, J. R.↗
NASA NTRS1991

A rocket tomography measurement of the N2(+) 3914 A emission rates within an auroral arc

A rocket tomography experiment designed to measure the two-dimensional distribution of the N2(+) 3914 A volume emission rates within an auroral arc is described. A simple filter photometer on board a sounding rocket, which was launched during the ARIES auroral campaign, was used to measure the 3914 A aruoral brightnesses at elevation angles ranging from 0 to 360 deg in the plane of the rocket trajectory. The measured auroral brightnesses have been tomographically inverted to recover the local 3914 A volume emissioin rates as a function of both altitude and latitude within the arc. The tomographic inversion procedure, which is based upon a maximum probability algebraic reconstruction approach, is described, and the implications of the results for studies of auroral excitation processes are briefly discussed.

Mcdade, I. C.↗
DOE OSTI2021

Bedrock weathering rates, reactive nitrogen influxes and effluxes, and nitrous oxide emissions rates from the Pumphouse Hillslope, East River Watershed, Colorado

Atmospheric nitrous oxide contributes directly to global warming, yet models of the nitrogen cycle do not account for bedrock, the largest pool of terrestrial nitrogen, as a source of nitrous oxide. Although it is known that release rates of nitrogen from bedrock are large, there is an incomplete understanding of the connection between bedrock-hosted nitrogen and atmospheric nitrous oxide. Here, we quantify nitrogen fluxes and mass balances at a hillslope underlain by marine shale. We found that at this site bedrock weathering contributes 78% of the subsurface reactive nitrogen, while atmospheric sources (commonly regarded as the sole sources of reactive nitrogen in pristine environments) account for only the remaining 22%. About 56% of the total subsurface reactive nitrogen denitrifies, including 14% emitted as nitrous oxide. The remaining reactive nitrogen discharges in porewaters to a floodplain where additional denitrification likely occurs. We also found that the release of bedrock nitrogen occurs primarily within the zone of the seasonally fluctuating water table and suggest that the accumulation of nitrate in the vadoes zone, often attributed to fertilization and soil leaching, may also include contributions from weathered nitrogen-rich bedrock. Our hillslope study suggests that under oxygenated and moisture-rich conditions, weathering of deep, nitrogen-rich bedrock makes an important contribution to the nitrogen cycle. The data files are in Excel, which can be accessed using Microsoft Office, and consist of many data sets from the Pumphouse Hillslope PLM (Pumphouse Lower Montane) 1, 2, 3, and 4. They include soil to rock (0-10 meters) solid phase minerals and elements compositions; time- and depth-resolved pore-water chemistry and pore-gas compositions; time- and depth-resolved water table depths and water fluxes; subsurface weathering rates; nitrogen influxes and effluxes and mass balance. The attached paper is in a Word document, which can be accessed using Microsoft Office, and in pdf format.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1994

Mesospheric and lower thermospheric winds, temperatures densities, and volume emission rates

This memo has been written to report on the progress made under grant NAG1-1315 and to request a continuation of funding for this work. Our proposal involved a plan to utilize an existing ground-based chain of optical and radar facilities to assemble a comprehensive, long-term, multi-station base of upper-mesospheric and lower thermospheric measurements of neutral winds, temperatures, and volume emission rates that can be used to make comparisons with data from the HRDI and WINDII instruments that are flying aboard the UARS spacecraft. The ground-based, optical data were to be obtained on a routine basis from five geographically separated observatories at: Thule, Greenland; Sondrestrom, Greenland; Watson Lake, Yukon (replacing Calgary, Alberta); Ann Arbor, Michigan; and Maynooth, Eire. Several different optical instruments are present at these sites: the total array of instruments is comprised of five Fabry-Perot interferometers, two half meter Ebert-Fastie spectrometers, one all-sky CCD imager, and a near infra-red Michelson Fourier transform spectrometer. In addition to these optical instruments, data were to be obtained from the incoherent scatter radar at Sondrestrom, Greenland. These radar measurements are comprised of neutral winds, temperatures, and densities from altitudes between approximately 70 - 120 km. The optical measurements are obtained locally from specific altitudes depending on the emission line studied. For example, red line optical data come from about 220 km. In this report we summarize the progress made in obtaining these data and relate it to the specific tasks outlined in the original grant application. These tasks are discussed in the next section. Progress towards their completion is discussed in section three, while future plans and summary are described in section four.

Killeen, Timothy L.↗