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At least 37 records · Page 2

Biochar from Biomass and its Potential Agronomic and Environmental Use in Washington: A Promising Alternative to Drawdown Carbon from the Atmosphere and Develop a New Industry

Climate change is one of the most serious issues facing the world today. Increasing concentrations of carbon dioxide (CO 2 ) and other long-lived greenhouse gases (GHGs) in the atmosphere continue to warm the planet and destabilize the climate. It has been estimated that the impact from this warming could cost the state 10 billion per year by 2020, and 16 billion per year by 2040. Long-term solutions to the climate problem likely will require that large quantities of CO 2 be removed from the atmosphere. In fact, massive CO 2 drawdowns from the atmosphere have occurred in earth’s recent past from events occurring in our hemisphere. Studies of those analogs provide insight into the potential magnitude for specific actions to drawdown significant CO 2 from the atmosphere. One of these potential actions is the large-scale production of biochar from abundant woody biomass waste and its storage in soils, where it remains stable for hundreds to thousands of years. Moreover, for the carbon emission intensity of Washington’s fuel mix, biochar production from biomass is twice as effective in offsetting GHG emissions as complete biomass combustion of the same biomass. Washington State has large quantities of wood waste biomass that could be purposed for production of combined heat/power/biochar (CHPB) through existing biomass boilers. We propose to 1) evaluate the quantities of Washington wood waste biomass, 2) inventory existing boiler capacity and assess the technical merits and challenges to repurpose the boilers to CHPB, and 3) apply literature values and analog biochar examples to better quantify the extent of CO 2 drawdown that could be achieved in Washington State over the next century using engineered biochar. This white paper explores the potential to replicate the historical drawdowns of atmospheric CO 2 , a topic the authors think should be part of current climate-change mitigation discussions. This document is a companion to a white paper titled Biochar from Wood Biomass and Agricultural Residues and its Potential Agronomic Use in Washington: A Tool to Improve Irrigation Water Use Efficiency, Energy Efficiency and Sequester Carbon (Amonette, et al., 2016, in preparation).

09 BIOMASS FUELS↗

Advanced Methods for Modeling Water-Levels and Estimating Drawdowns with SeriesSEE, an Excel Add-In

Water-level modeling is used for multiple-well aquifer tests to reliably differentiate pumping responses from natural water-level changes in wells, or environmental fluctuations. Synthetic water levels are created during water-level modeling and represent the summation of multiple component fluctuations, including those caused by environmental forcing and pumping. Pumping signals are modeled by transforming step-wise pumping records into water-level changes by using superimposed Theis functions. Water-levels can be modeled robustly with this Theis-transform approach because environmental fluctuations and pumping signals are simulated simultaneously. Water-level modeling with Theis transforms has been implemented in the program SeriesSEE, which is a Microsoft® Excel add-in. Moving average, Theis, pneumatic-lag, and gamma functions transform time series of measured values into water-level model components in SeriesSEE. Earth tides and step transforms are additional computed water-level model components. Water-level models are calibrated by minimizing a sum-of-squares objective function where singular value decomposition and Tikhonov regularization stabilize results. Drawdown estimates from a water-level model are the summation of all Theis transforms minus residual differences between synthetic and measured water levels. The accuracy of drawdown estimates is limited primarily by noise in the data sets, not the Theis-transform approach. Drawdowns much smaller than environmental fluctuations have been detected across major fault structures, at distances of more than 1 mile from the pumping well, and with limited pre-pumping and recovery data at sites across the United States. In addition to water-level modeling, utilities exist in SeriesSEE for viewing, cleaning, manipulating, and analyzing time-series data.

58 GEOSCIENCES↗

Supplementary Data for "Evaluation of the Economic Implications of Varied Pressure Drawdown Strategies Generated Using a Real-time, Rapid Predictive, Multi-fidelity Model for Unconventional Oil and Gas Wells" by Bello, K., Vikara, D., Sheriff, A., Viswanathan, H., Carr, T., Sweeney, M., O'Malley, D., Marquis, M., Vactor, R.T., and Cunha, L.

The Bello et al. study evaluates the impact of contrasting pressure drawdown on gas productivity and the resulting economics of a well in the Marcellus Shale of the Appalachian Basin. This research applies a techno-economic analysis approach to help identify potential ways pressure management strategies can be used to improve cumulative recovery of hydraulically fractured horizontal wells while maintaining project profitability. Gas production forecast outlook scenarios of the Marcellus Shale Energy and Environment Laboratory Laboratory's MIP-3H well were generated under varying pressure drawdowns using two approaches: 1) a novel physics-informed machine learning (PIML) workflow and 2) via traditional reservoir simulation in Computer Modeling Group’s (CMG) GEM Compositional & Unconventional Simulator. Cash flow and other economic metrics of interest were compiled on the production outlook using the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) Unconventional Shale Well Economic Model (UShWEM).The sheets within this Microsoft ExcelTM workbook provide the economic metric outputs for the baseline condition and the one-at-a-time (OAT) sensitivity analysis of UShWEM's input parameters for each of the production scenarios evaluated.

Fracture Network Model↗

Annual Report of Available Drawdowns for Each Oil Storage Cavern in the Strategic Petroleum Reserve

DOE maintains an up-to-date documentation of the number of available full drawdowns of each of the caverns at the U.S. Strategic Petroleum Reserve (SPR). This information is important for assessing the SPR’s ability to deliver oil to domestic oil companies expeditiously if national or world events dictate a rapid sale and deployment of the oil reserves. This report is the latest in a series of annual reports, and it includes the baseline available drawdowns for each cavern.

02 PETROLEUM↗

Thermal Drawdown-Induced Flow Channeling in Fractured Geothermal Reservoirs

In this paper, we investigate the flow-channeling phenomenon caused by thermal drawdown in fractured geothermal reservoirs. A discrete fracture network-based, fully coupled thermal–hydrological–mechanical simulator is used to study the interactions between fluid flow, temperature change, and the associated rock deformation. The responses of a number of randomly generated 2D fracture networks that represent a variety of reservoir characteristics are simulated with various injection-production well distances. We find that flow channeling, namely flow concentration in cooled zones, is the inevitable fate of all the scenarios evaluated. We also identify a secondary geomechanical mechanism caused by the anisotropy in thermal stress that counteracts the primary mechanism of flow channeling. This new mechanism tends, to some extent, to result in a more diffuse flow distribution, although it is generally not strong enough to completely reverse flow channeling. We find that fracture intensity substantially affects the overall hydraulic impedance of the reservoir but increasing fracture intensity generally does not improve heat production performance. Finally, increasing the injection-production well separation appears to be an effective means to prolong the production life of a reservoir.

15 GEOTHERMAL ENERGY↗

Soil phosphorus drawdown by perennial bioenergy cropping systems in the Midwestern US

Abstract Without fertilization, harvest of perennial bioenergy cropping systems diminishes soil nutrient stocks, yet the time course of nutrient drawdown has not often been investigated. We analyzed phosphorus (P) inputs (fertilization and atmospheric deposition) and outputs (harvest and leaching losses) over 7 years in three representative biomass crops—switchgrass ( Panicum virgatum L.), miscanthus ( Miscanthus × giganteus ) and hybrid poplar trees ( Populus nigra × P. maximowiczii )—as well as in no‐till corn (maize; Zea mays L.) for comparison, all planted on former cropland in SW Michigan, USA. Only corn received P fertilizer. Corn (grain and stover), switchgrass, and miscanthus were harvested annually, while poplar was harvested after 6 years. Soil test P (STP; Bray‐1 method) was measured in the upper 25 cm of soil annually. Harvest P removal was calculated from tissue P concentration and harvest yield (or annual woody biomass accrual in poplar). Leaching was estimated as total dissolved P concentration in soil solutions sampled beneath the rooting depth (1.25 m), combined with hydrological modeling. Fertilization and harvest were by far the dominant P budget terms for corn, and harvest P removal dominated the P budgets in switchgrass, miscanthus, and poplar, while atmospheric deposition and leaching losses were comparatively insignificant. Because of significant P removal by harvest, the P balances of switchgrass, miscanthus, and poplar were negative and corresponded with decreasing STP, whereas P fertilization compensated for the harvest P removal in corn, resulting in a positive P balance. Results indicate that perennial crop harvest without P fertilization removed legacy P from soils, and continued harvest will soon draw P down to limiting levels, even in soils once heavily P‐fertilized. Widespread cultivation of bioenergy crops may, therefore, alter P balances in agricultural landscapes, eventually requiring P fertilization, which could be supplied by P recovery from harvested biomass.

09 BIOMASS FUELS↗

Data for: Time to anoxia: Observations and predictions of oxygen drawdown following coastal flood events

This dataset contains data and code associated with the paper Patel et al. "Time to anoxia: Observations and predictions of oxygen drawdown following coastal flood events".The coastal terrestrial-aquatic interface (TAI) is a highly dynamic system characterized by strong physical, chemical, and biological gradients. In particular, shifting soil redox conditions and consumption of terminal electron acceptors, due in part to dynamic hydrologic conditions, is a strong driver of carbon availability and transformations across TAIs. However, while redox dynamics are well described, our ability to quantitatively forecast rates of oxic to anoxic shifts in soils with different characteristics and inundation regimes is limited. We integrated field measurements, laboratory incubations, and model simulations to improve mechanistic understanding of oxygen consumption dynamics in coastal soils. Continuous in situ monitoring unexpectedly revealed that flooding caused temporary spikes in subsurface dissolved oxygen followed by rapid consumption in the wetlands. To further investigate these mechanisms in a controlled setting, we performed laboratory incubations using surface and subsurface soils from a TAI gradient (defined here as upland forest to transitional forest to wetland) in Western Lake Erie to measure oxygen consumption rates in TAI soils during flood events. In our experiments, wetland soils reached anoxia the fastest, in ∼ 9 h on average, whereas upland soils turned anoxic in ∼ 18 h. Subsurface upland soils did not turn anoxic even after two weeks of saturation in the lab, and their oxygen consumption patterns suggested carbon and/or nutrient limitation. These results are consistent with in-situ groundwater redox and oxygen measurements in the field, where wetland soils exhibited the highest rates of oxygen consumption along the TAI. Model simulations of oxygen consumption suggested that oxygen consumption had stronger abiotic controls in wetland soils but stronger biotic controls in upland soils, providing a useful framework for future incubation experiments. Microbial activity is a strong driver of oxygen consumption in TAI soils, although it is constrained by the availability of dissolved carbon in subsurface soils.This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/COMPASS-DOE/cmps-time_to_anoxia (DOI: 10.5281/zenodo.10815374).

54 ENVIRONMENTAL SCIENCES↗

Plant-based CO 2 drawdown and storage as SiC

Since the 1950's the Earth's natural carbon cycle has not sufficiently sequestrated excess atmospheric CO 2 contributed by human activities. CO 2 levels rose above 400 ppm in 2013 and are forecasted to exceed 500 ppm by 2070, a level last experienced during the Paleogene period 25–65 MYA. While humanity benefits from the extraction and combustion of carbon from Earth's crust, we have overlooked the impact on global climate change. Here, we present a strategy to mine atmospheric carbon to mitigate CO 2 emissions and create economically lucrative green products. We employ an artificial carbon cycle where agricultural plants capture CO 2 and the carbon is transformed into silicon carbide (SiC), a valuable commercial material. By carefully quantifying the process we show that 14% of plant-sequestered carbon is stored as SiC and estimate the scale needed for this process to have a global impact.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Adding Tree Rings to North America's National Forest Inventories: An Essential Tool to Guide Drawdown of Atmospheric CO 2

Tree-ring time series provide long-term, annually resolved information on the growth of trees. When sampled in a systematic context, tree-ring data can be scaled to estimate the forest carbon capture and storage of landscapes, biomes, and—ultimately—the globe. A systematic effort to sample tree rings in national forest inventories would yield unprecedented temporal and spatial resolution of forest carbon dynamics and help resolve key scientific uncertainties, which we highlight in terms of evidence for forest greening (enhanced growth) versus browning (reduced growth, increased mortality). We describe jump-starting a tree-ring collection across the continent of North America, given the commitments of Canada, the United States, and Mexico to visit forest inventory plots, along with existing legacy collections. Failing to do so would be a missed opportunity to help chart an evidence-based path toward meeting national commitments to reduce net greenhouse gas emissions, urgently needed for climate stabilization and repair.

54 ENVIRONMENTAL SCIENCES↗

Interpolation data transfer between the models before and after a partial drawdown leach in BH

It has been recognized that as cavern operations become more frequent due to oil sales, field conditions may arise which require a faster turnaround time of analysis to address potential cavern impacts. This letter describes attempts to implement a strategy of transferring an intermediate solution of a Big Hill (BH) geomechanical model from a previous finite element mesh with a specified cavern geometry, to a new mesh with a new cavern geometry created by leaching from an oil sale operation.

02 PETROLEUM↗

Data from: Soil phosphorus drawdown by perennial bioenergy cropping systems in the Midwestern US

We analyzed phosphorus (P) inputs (fertilization and atmospheric deposition) and outputs (harvest and leaching losses) over seven years in three representative biomass crops—switchgrass ( Panicum virga­tum L.), miscanthus ( Miscanthus X giganteus ) and hybrid poplar trees ( Populus nigra X P . maximowiczii ) – as well as in no-till corn (maize; Zea mays L.) for comparison, all planted on former cropland in SW Michigan, USA.

corn↗