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At least 37 records · Page 2

High performance thermoplastics - A review of neat resin and composite properties

A review was made of the principal thermoplastics used to fabricate high performance composites. Neat resin tensile and fracture toughness properties, glass transition temperatures (Tg), crystalline melt temperatures (Tm) and approximate processing conditions are presented. Mechanical properties of carbon fiber composites made from many of these thermoplastics are given, including flexural, longitudinal tensile, transverse tensile and in-plane shear properties as well as short beam shear and compressive strengths and interlaminar fracture toughness.

Johnston, Norman J.↗

The Effect of Molecular Weight on the Composite Properties of Cured Phenylethynyl Terminated Imide Oligomers

As part of a program to develop high temperature/high performance structural resins for aeronautical applications, imide oligomers containing terminal phenylethynyl groups with calculated number average molecular weights of 1250, 2500 and 5000 g/mol were prepared, characterized, and evaluated as adhesives and composite matrix resins. The goal of this work was to develop resin systems that are processable using conventional processing equipment into void free composites that exhibit high mechanical properties with long term high temperature durability, and are not affected by exposure to common aircraft fluids. The imide oligomers containing terminal phenylethynyl groups were fabricated into titanium adhesive specimens and IM-7 carbon fiber laminates under 0.1 - 1.4 MPa for 1 hr at 350-371 C. The lower molecular weight oligomers exhibited higher cured Tg, better processability, and better retention of mechanical properties at elevated temperature without significantly sacrificing toughness or damage tolerance than the higher molecular weight oligomer. The neat resin, adhesive and composite properties of the cured polymers will be presented.

Smith, J. G., Jr.↗

Novel Hourly-Resolved Global Cloud Property Composite from Operational Satellites Imagers

Numerous applications in satellite remote sensing of surface properties, atmospheric state, composition, and radiation require accurate knowledge of the location and characteristics of clouds. Operational satellite imager radiances are valuable for cloud detection and for deriving many different physical parameters that can be used for a variety of weather, aviation, and energy applications. The NASA Satellite ClOud and Radiation Property retrieval System (SatCORPS) applies a suite of algorithms to meteorological satellite data to provide cloud properties, radiative fluxes and other parameters on a global scale. This paper describes a new global high-resolution dataset of cloud properties made available for community use that is constructed from analyses of a constellation of meteorological satellite imagers. Data taken from Meteosat-8/9 and -11, Himawari-8/9, GOES-16, and -17/-18, Aqua, Terra, Suomi-NPP and NOAA-20 are processed and composited on a 3-km grid to provide hourly global coverage. A historical multi-year dataset is available to serve various needs including modeling challenges related to cloud evaluations and parameterizations. Near real-time data products are also currently available between 60N and 60S. Efforts are underway to operationalize polar orbiting satellite cloud detection methods for low-latency applications over polar regions. The cloud detection and retrieval algorithms have been developed over many years to support NASA weather and climate programs such as the Clouds and Earth’s Radiant Energy System (CERES). To improve the utility of the data products, machine learning and other innovative methods are applied in various ways to help minimize data product uncertainties under the most challenging conditions and to improve their consistency at all times of day. A brief description of the methods highlighting the unique aspects of the SatCORPS data products will be presented along with information on their status and availability.

SatCORPS↗

Interfacial effects on the behavior of partially bonded metal matrix composite properties

A novel computational method developed at NASA-Lewis in order to predict the behavior of unidirectional composites has been used to explore the effects of partial debonding and fiber fracture on the behavior of room temperature and high temperature metal-matrix composites. Attention is presently given to the influence of disbonding, which occurs with fractured fibers, on the ply properties of metal-matrix composites with orthotropic fibers, in the case of a graphite fiber-reinforced copper-matrix composite. It is shown that, for small amounts of partial bonding on fractured fibers, composite material properties are not significantly affected.

Caruso, J. J.↗

Dust from Mars-Analog Plains (Iceland): Physico-Compositional Properties as a Function of Grain-Size Fraction

Dust is a key component of the geological and climatic systems of Earth and Mars. On Mars, dust is ubiquitous. It coats rocks and soils, and, in the atmosphere, it interacts strongly with solar and thermal radiation. Yet, key questions remain about the genesis and fate of martian dust, as well as its sources, composition, and properties. We collected wind-blown dust from basaltic plains in SW Iceland at Skjaldbreiðauhraun that represent a geologic Mars-analog environment. Icelandic dust differs from the typical continental sources (e.g. Sahara, Asia) because of its basaltic volcanogenic origin, which is similar to Mars. Dust collection took place in July of 2019 as a complementary project to the SAND-E: Semi-Autonomous Navigation for Detrital Environments project. Here we report preliminary analyses of this Mars-analog dust material, with the goal of understanding the processes that control the physico-chemical proper-ties of the different grain-size fractions.

Nachon, Marion↗

Polyimide Composites Properties of RTM370 Fabricated by Vacuum Assisted Resins Transfer Molding (VARTM)

RTM370 imide resin based on 2,3,3 ,4 -biphenyl dianhydride ( a-BPDA), 3,4 -oxydianinline (3,4 -ODA) with 4-phenylethynylphthalic (PEPA) endcap has shown to exhibit high Tg (370 C) and low melt viscosity (10-30 poise) at 280 C with a pot-life of 1-2 h. Previously, RTM370 resin has been fabricated into composites with T650-35 carbon fabrics by resin transfer molding (RTM) successfully. RTM370 composites exhibit excellent mechanical properties up to 327 C (620 F), and outstanding property retention after aging at 288 C (550 F) for 1000 hrs. In this presentation, RTM 370 composites will be fabricated by vacuum assisted resins transfer molding (VARTM), using vacuum bags without mold. The mechanical properties of RTM370 composites fabricated by VARTM will be compared to those of RTM370 made by RTM.

Chuang, Kathy C.↗

Composite Properties of RTM370 Polyimide Fabricated by Vacuum Assisted Resin Transfer Molding (VARTM)

RTM370 imide resin based on 2,3,3?,4?-biphenyl dianhydride (a-BPDA), 3,4'-oxydianinline (3,4'-ODA) with the 4-phenylethynylphthalic (PEPA) endcap has been shown to exhibit a high cured T(sub g) (370 C) and low melt viscosity (10-30 poise) at 280 C with a pot-life of 1-2 h. Previously, RTM370 resin has been successfully fabricated into composites reinforced with T650-35 carbon fabrics by resin transfer molding (RTM). RTM370 composites exhibit excellent mechanical properties up to 327?C (620?F), and outstanding property retention after aging at 288?C (550?F) for 1000 h. In this work, RTM370 composites were fabricated by vacuum assisted resin transfer molding (VARTM), using vacuum bags on a steel plate. The mechanical properties of RTM370 composites fabricated by VARTM are compared to those prepared by RTM.

Chuang, Kathy C.↗

PETI-298 Prepared by Microwave Synthesis: Neat Resin and Composite Properties

PETI-298 is a high temperature/high performance matrix resin that is processable into composites by resin transfer molding (RTM), resin infusion and vacuum assisted RTM techniques. It is typically synthesized in a polar aprotic solvent from the reaction of an aromatic anhydride and a combination of diamines and endcapped with phenylethynylphthalic anhydride. Microwave synthesis of PETI-298 was investigated as a means to eliminate solvent and decrease reaction time. The monomers were manually mixed and placed in a microwave oven for various times to determine optimum reaction conditions. The synthetic process was subsequently scaled-up to 330g. Three batches were synthesized and combined to give 1 kg of material that was characterized for thermal and rheological properties and compared to PETI-298 prepared by the classic solution based synthetic method. The microwave synthesized PETI-298 was subsequently used to fabricate flat laminates on T650 carbon fabric by RTM. The composite panels were analyzed and mechanical properties determined and compared with those fabricated from PETI-298 prepared by the classic solution method. The microwave synthesis process and characterization of neat resin and carbon fiber reinforced composites fabricated by RTM will be presented. KEY WORDS: Resin Transfer Molding, High Temperature Polymers, Phenylethynyl Terminated Imides, Microwave Synthesis

Smith, Joseph G.↗

Modeling of Euclidean braided fiber architectures to optimize composite properties

Three-dimensional braided fiber reinforcements are a very effective toughening mechanism for composite materials. The integral yarn path inherent to this fiber architecture allows for effective multidirectional dispersion of strain energy and negates delamination problems. In this paper a geometric model of Euclidean braid fiber architectures is presented. This information is used to determine the degree of geometric isotropy in the braids. This information, when combined with candidate material properties, can be used to quickly generate an estimate of the available load-carrying capacity of Euclidean braids at any arbitrary angle.

Armstrong-Carroll, E.↗

Adhesive and Composite Properties of a New Phenylethynyl Terminated Imide

A relatively new phenylethynyl terminated imide oligomer (PETI) from the reaction of 2,3,',4'- biphenyltetracarboxylic dianhydride, 4,4'-oxydianiline and endcapped with 4- phenylethynylphthalic anhydride at a calculated number average molecular weight of 5000 g/mole was evaluated as an adhesive and composite matrix. The asymmetric dianhydride imparts a low melt viscosity to the oligomer and a high glass transition temperature to the cured resin. Preliminary adhesive work with titanium (6Al-4V) adherend gave good room temperature (RT) tensile shear strengths and excellent retention of RT strength at 260 C. Preliminary composite work using unsized IM7 carbon fiber provided moderate to high mechanical properties. The chemistry, mechanical, and physical properties of the new PETI in neat resin, adhesive and composite form are presented.

Thompson, C. M.↗

Modeling of Melt-Infiltrated SiC/SiC Composite Properties

The elastic properties of a two-dimensional five-harness melt-infiltrated silicon carbide fiber reinforced silicon carbide matrix (MI SiC/SiC) ceramic matrix composite (CMC) were predicted using several methods. Methods used in this analysis are multiscale laminate analysis, micromechanics-based woven composite analysis, a hybrid woven composite analysis, and two- and three-dimensional finite element analyses. The elastic properties predicted are in good agreement with each other as well as with the available measured data. However, the various methods differ from each other in three key areas: (1) the fidelity provided, (2) the efforts required for input data preparation, and (3) the computational resources required. Results also indicate that efficient methods are also able to provide a reasonable estimate of local stress fields.

Mital, Subodh K.↗

Remote sensing of potential lunar resources. I - Near-side compositional properties

Using telescopic CCD multispectral images of the lunar near side and the results of 330-870 nm spectroscopy of selected regions, the compositional differences relevant to the locations of potential lunar resources (such as ilmenite, FeTiO3, and solar-wind-implanted He-3 and H) are estimated. The 400/560 nm CCD ratio images were converted to weight percent TiO2, and the values were used to construct a new TiO2 abundance map which can be used to estimate the areas potentially rich in ilmenite. A 950/560 nm CCD ratio mosaic of the full moon provides estimates of relative surface maturity. Since high He-3 concentrations correlate with mature ilmenite-rich soils, a combination of relative surface maturity maps and the TiO2 abundance maps can be used to estimate distributions of He-3 (and possibly H) on local scales.

Johnson, Jeffrey R.↗

Metal matrix composite micromechanics - In situ behavior influence on composite properties

The influence of in situ fiber and matrix properties (such as in situ matrix strength and the interphase degradation) of high-temperature metal matrix composites (HTMMCs) on the unidirectional stress-strain behavior of the composite is examined using results of a numerical investigation of a SiC/Ti-15-3-3-3 unidirectional composite. It is shown that a reduction of the in situ matrix strength substantially decreases the transverse and the longitudinal tensile/compressive strengths, as well as the in-plane shear strength, of the composite. The interphase degradation affects the behavior in transverse tension/compression drastically; both the ultimate strength and strain showed significant reductions. The higher use temperature results in a reduction in the ultimate strength and in the initial tangential modulus for compression and for in-plane shear loading.

Murthy, P. L. N.↗

Satellite Maps and Relevant Compositional Properties of PM2.5 in Difficult Winter Situations and Comparisons to DISCOVER-AQ Airborne Sampling

Mediterranean-climate regions like California's San Joaquin Valley are subject to severe wintertime particulate pollution affecting public health. We present maps of episodes and particulate diagnostics to aid diagnosis and amelioration. For abatement at sources, we require an understanding of sources and transport. Remote sensing should be of aid, but radiance-to-particle relationships are far different from methods which have been of use in the Eastern USA, Northern and Central Europe. Here are the problems: (a) Thin if very polluted mixed layers (MLs) yield optical depths, AOD, near the detection level, (b) bright and quite variegated surfaces (c) Unusual particle composition (e.g., predominance of NH4NO3 and fireplace buning aerosol), which complicate the relationship of AOD to PM2.5. Specialized analysis of MODIS-Aqua data to obtain AOD using the multi-angle (MAIAC) technique employed by Lyapustin and Wang. Meteorological analyses like NOAA's Rapid Analysis Product (RAP, or newer products like HRRR), which are formulated to remain close to observations (e.g. of water), provide useful ML information corroborated by DISCOVER-AQ in-situ and lidar observations. The many PM2.5 measurements allow a calibration of these products and thus maps of aerosol on many successive aerosol buildups. These calibrations also allow insight into compositional information relevant to MODIS retrievals, the product of aerosol density and specific scattering. We have found that the rich in-situ, lidar, and sun-photometer data sets of NASA'S DISCOVER-AQ data set (2013) of great aid. We will highlight the most interesting of many intercomparisons possible with this rich data set. We conclude with a description of new work to extend these insights to similar regions, e.g. the Imperial Valley of California, the Po Valley and maritime Southern Europe, and the litoral regions of Israel.

aerosols↗

Composite Property Dependence on the Fiber, Matrix, and the Interphase

The matrix properties of a difunctional epoxy, Epon 828, were varied. The Hercules type A fiber was also utilized in this investigation. The fiber and the interface between fiber and matrix were examined in terms of shear strength. Micrographs of the epoxy matrix are presented.

Drzal, L. T.↗