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At least 37 records · Page 2

Parameter Reduction of Composite Load Model Using Active Subspace Method

Over the past decades, the increasing penetration of distributed energy resources (DERs) has dramatically changed the power load composition in the distribution networks. The traditional static and dynamic load models can hardly capture the dynamic behavior of modern loads especially for fault-induced delayed voltage recovery (FIDVR) events. Thus, a more comprehensive composite load model with combination of static load, different types of induction motors, single-phase A/C motor, electronic load and DERs has been proposed by Western Electricity Coordinating Council (WECC). However, due to the large number of parameters and model complexity, the WECC composite load model (WECC CMLD) raises new challenges to power system studies. To overcome these challenges, in this paper, a cutting-edge parameter reduction (PR) approach for WECC CMLD based on active subspace method (ASM) is proposed. Firstly, the WECC CMLD is parameterized in a discrete-time manner for the application of the proposed method. Then, parameter sensitivities are calculated by discovering the active subspace, which is a lower-dimensional linear subspace of the parameter space of WECC CMLD in which the dynamic response is most sensitive. The interdependency among parameters can be taken into consideration by our approach. Finally, the numerical experiments validate the effectiveness and advantages of the proposed approach for WECC CMLD model.

active subspace↗

Autonomous Ion Mass Spectrometer Sentry (AIMSS)

Satellite measurements of plasma density and temperature help predict the intensity of geomagnetic storms, which can impact satellites, communications, and power systems. Accurate forecasting requires knowledge of plasma composition. However, typical orbital mass spectrometers have difficulty distinguishing between nitrogen (N+) and oxygen (O+) ions due to their similar masses. This limitation makes it difficult to validate modern space weather models, which depend on accurate knowledge of ion composition in near-Earth space. N+ and O+ ions behave differently in space due to differences in their origin, transport, and loss mechanisms. Improving our ability to distinguish between these ions is critical for understanding and predicting space weather.

47 OTHER INSTRUMENTATION↗

Exploiting Chemistry and Molecular Systems for Quantum Information Science

The power of chemistry to prepare new compositions of matter has driven the quest for new approaches to solve problems having global societal impact, such as renewable energy, healthcare, and information science. In the latter case, the intrinsic quantum nature of molecules offers intriguing new possibilities to advance the emerging field of Quantum Information Science (QIS). In this Perspective, we discuss how chemical systems and reactions can impact quantum computing, communication, and sensing. Hierarchical molecular design and synthesis, from small molecules to supramolecular assemblies, combined with new spectroscopic probes of quantum coherence and theoretical modeling of complex systems, offer a broad range of possibilities to realize practical QIS applications.

quantum computing, Spectrocopy, computational chem↗

Softwarized Federations of Science Instruments with Edge-Continuum Containers

Significant expansion of capabilities of DOE science complex of supercomputers, instruments and networks is expected as powerful experimental facilities, exascale computers and terabit networks are added. Combined with the advances in edge and cloud computing technologies, DOE science users now have the promise of unprecedented execution of complex, continuum workflows, namely, small and latency-sensitive computations at the edge and site, massive computations at remote HPC systems, and everything in between on the cloud. But, bringing this capability to the science user requires overcoming the overwhelming complexity of forming the federations of systems, and efficiently and effectively orchestrating the workflows while ensuring high utilization of the expensive facilities. Current manual configuration of the federated systems simply will not scale, since the coordination across sites may take weeks to months, often leading to under-utilized and hard-to-diagnose compositions. A powerful, composable software stack will be developed to (i) wrap the systems so that federations can be composed fast in software, and (ii) containerize computations to be orchestrated across the edge, site, cloud and HPC resources.

Rao, Nageswara S.↗

Multilayered Cu-Carbon Nanotube Composites for Advanced Conductors

Improving the efficiency of electrical components is critical in reducing energy consumption for various industrial and residential applications, ranging from rotating machinery to all electric devices and electric vehicle (EV) components to power grid systems. Substituting Cu wires with reduced resistance conductors that incorporate carbon nanotubes (CNTs) into Cu─ultraconductive Cu (UCC) composites─has recently been considered a promising strategy to improve energy efficiency, power density, and/or performance across various applications. Here, in this study, we created stable material formulations [CNT-containing polyvinylpyrrolidone (PVP) in dimethylformamide (DMF) solution] and utilized commercially viable fabrication approaches (electrospinning and magnetron sputtering) that produced high-performance multilayered tape-based UCC composite architectures. Increasing the CNT volume fraction by sequential layering of the structure with additional Cu-CNT layers showed a nearly stepwise improved performance in electrical and mechanical properties. This study also provides valuable insight into the effectiveness of nitrogen doping in modifying the conductivity of the CNT matrix. Fabricated prototypes demonstrated a >10% increase in current carrying capacity and >10% improvement in mechanical strength compared to those obtained on pure Cu. We believe that the properties demonstrated here, combined with the scalable manufacturing pathway of our approach, pave the way in designing future advanced conductors for diverse energy efficient and high-performance electrical systems and applications.

Carbon nanotubes↗

Behavior and properties of helium cavities in ductile-phase-toughened tungsten irradiated with He + ions at an elevated temperature

Ductile-phase toughened tungsten (DPT W) composites have demonstrated a great potential for plasma-facing components in fusion power systems. These materials can retain the outstanding thermomechanical properties of W while significantly enhancing the fracture toughness. The DPT W composite in this study consists of W particles (88 wt.%) embedded in a ductile NiFeW (12 wt.%) solution matrix. Irradiation of the composite was performed with 90 keV He + ions to 1.0 × 10 17 He + /cm 2 at 973 K. The He cavities formed in both W and NiFeW phases are examined using convergent-beam scanning transmission electron microscopy (CB-STEM) at an atomic-level resolution. Full-range depth profiles of the He cavity diameters and number densities are analyzed. The results show that the average cavity diameter in NiFeW is ~2.7 times that in W, while the number density is an order of magnitude lower. A quantitative analysis of the He density and pressure in the cavities is also achieved using STEM electron energy loss spectroscopy (STEM-EELS) mapping. The He atoms in the cavities in NiFeW are found to be under-pressurized, while those in similar-sized cavities in W are not detectable. Further, the He energy-loss shift exhibits a linear relationship with the He density in cavities in NiFeW, with the slope comparable to that for martensitic steel.

36 MATERIALS SCIENCE↗

Wet chemistry-synthesized Fe/mixed ferrite soft magnetic composites for high-frequency power conversion

State-of-the-art soft magnetic (SM) alloy systems such as electrical steels and permalloys exhibit large eddy current losses at high-frequency (kHz range and above), limiting their application in fast switching devices. Eddy current losses can be reduced for metallic alloys through a decrease in characteristic length scale or embedding them in an insulation layer. This work proposes the development of fine-scale core materials consisting of metallic SM nano/microparticles with magnetic, inorganic insulation layers, and their synthesis using a wet chemistry-based, scalable method for high frequency and high-power applications. More specifically, a magnetic ferrite coating (Ni 0.5-x Mn x Zn 0.5 Fe 2 O 4 , x = 0.0–0.5) was applied via deposition of ferrite powder produced using a “wet chemistry-based” co-precipitation method; the ferrite was distributed through the Fe micropowder via either ball milling or ultrasonic mixing. Powder cores were prepared by compaction of the synthesized composites. Relative magnetic permeability and core loss were measured at excitation frequencies to 200 kHz. A core loss of 127 kW/m 3 was measured at excitation frequency of 100 kHz and magnetization of 0.02 T. This value improves on the 199.3 kW/m 3 reported in literature at identical excitation conditions for a compact formed from a composite comprising Fe microparticles coated with low-permeability Ni 0.5 Zn 0.5 Fe 2 O 4 . Ultrasonic mixing resulted in slightly lower core loss than ball milling, possibly because ball milling causes loss-increasing deformation of the Fe micropowder. XRD and SEM were used to observe composite composition and core cross-section microstructure.

36 MATERIALS SCIENCE↗

A reactive separation process for pre-combustion CO 2 capture employing oxygen-blown coal gasifier off-gas

In this paper, we present an experimental study of a reactive separation system, consisting of a membrane reactor (MR) and an adsorptive reactor (AR) operating in tandem, with the MR’s reject stream serving as the AR’s feed. We investigates the feasibility of applying this MR-AR system for high-purity H 2 production and simultaneous CO 2 capture via the water gas shift (WGS) reaction in the context of Integrated Gas Combined Cycle (IGCC) power generation employing oxygen-blown gasifier syngas from biomass and coal. We previously studied this MR-AR system for the IGCC process employing air-blown gasifier syngas, for which it demonstrated good performance, attaining high conversion exceeding equilibrium, producing ultra-pure H 2 for power generation, and a CO 2 stream ready for sequestration. In this study, we focus on oxygen-blown gasifier off-gas that contains no N 2 , with composition distinctly different from the air-blown gasifier syngas which has a large N 2 content. We employ a carbon molecular sieve membrane (CMSM), a commercial sour-shift WGS catalyst, and a hydrotalcite (HTC) adsorbent. We carried out experiments to determine membrane performance and to identify promising operating conditions in an IGCC-relevant environment. The CMSM proved robust during a long-term (~344 hr run) experimental run under high temperature and pressure maintaining a high He/N 2 selectivity (~170). Multi-cycle runs were carried out during which the MR-AR system displayed superior performance to that of a PBR, by producing a high purity H 2 product directly usable in power generation. Therefore, the findings from this study demonstrate the ability of the MR-AR system to operate stably for a broad range of gasifier off-gas compositions, and indicate its potential for integration into IGCC plants for power generation with CO 2 capture.

01 COAL, LIGNITE, AND PEAT↗

Design-time performance modeling of compositional parallel programs

Performance models are powerful instruments for understanding the performance of parallel systems and uncovering their bottlenecks. Already during system design, performance models can help ponder alternative development options. However, creating a performance model – whether theoretically or empirically – for an entire application that does not exist yet is challenging. In this paper, we propose to generate performance models of full programs from performance models of their components using formal composition operators derived from parallel design patterns. As long as the design of the overall system follows such a pattern, its performance model can be predicted with reasonable accuracy without an actual implementation. In conclusion, we demonstrate our approach with design patterns of varying complexity, including pipeline, task pool, and eventually MapReduce, which is representative of a broad class of data-analytics applications.

97 MATHEMATICS AND COMPUTING↗

Toward the Instrumentation and Data Acquisition of a Tidal Turbine in Real Site Conditions

The National Renewable Energy Laboratory manufactured, instrumented, and deployed thermoplastic composite blades and a data acquisition system (NDAQ) on one of Verdant Power’s Gen5d 5 m diameter tidal turbines in New York’s East River. The thermoplastic blades had internal strain gages, and the NDAQ was a stand-alone system for monitoring and recording the strain and angular position of the blades. The turbine with thermoplastic blades operated and produced power successfully for 3 months, contributing energy to the New York City electric grid. The NDAQ hardware, instrumentation, and structure all survived the deployment and were still functional upon retrieval of the system, but no data were collected. Even though the data retrieval was not a success, data acquisition for deployed subsea marine renewable structures is a new undertaking, and it is critical to share lessons learned from national laboratory experiences. The successful deployment of thermoplastic composite blades marks a significant advancement toward improved materials for subsea components, as well as an advancement in recyclable composite materials. This article outlines the methodology and lessons learned for the instrumentation and data acquisition system.

16 TIDAL AND WAVE POWER↗

4D Printing of Stretchable Supercapacitors via Hybrid Composite Materials

Stretchable supercapacitors (SCs) have attracted significant attention in developing power-independent stretchable electronic systems due to their intrinsic energy storage function and unique mechanical properties. Most current SCs are generally limited by their low stretchability, complicated fabrication process, and insufficient performance and robustness. This study presents a facile method to fabricate arbitrary-shaped stretchable electrodes via 4D printing of conductive composite from reduced graphene oxide, carbon nanotube, and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate. The electrode patterns of an arbitrary shape can be deposited onto prestretched substrates by aerosol-jet printing, then self-organized origami (ridge) patterns are generated after releasing the substrates from holding stretchers due to the mismatched strains. The stretchable electrodes demonstrate superior mechanical robustness and stretchability without sacrificing its outstanding electrochemical performance. The symmetric SC prototype possesses a gravimetric capacitance of ≈21.7 F g -1 at a current density of 0.5 A g -1 and a capacitance retention of ≈85.8% from 0.5 to 5 A g -1 . A SC array with arbitrary-shaped electrodes is also fabricated and connected in series to power light-emitting diode patterns for large-scale applications. Finally, the proposed method paves avenues for scalable manufacturing of future energy-storage devices with controlled extensibility and high electrochemical performance.

36 MATERIALS SCIENCE↗

A High-Voltage High-Reliability Scalable Architecture for Electric Vehicle Power Electronics (Final Report)

This project developed and demonstrated new composite converter technologies that lead to high power density (> 20 kW/L) at power levels of 10s of kW, 100s of kW, or possibly higher, with fundamental advances in converter efficiency and Q that lead to substantial increases in mean time to failure (MTTF). These advantages were realized through development of new composite converter topologies that perform buck, boost, or other conversion functions and that are scalable to higher voltage and power levels through sharing of voltage and current stresses among multiple dissimilar partial-power converter modules. The project led to experimental demonstration of a125 kW multifunction electric vehicle power conversion system having in-creased dc bus voltage (950 V nominal, 1200 V peak) that interfaces a 200 V to 400 V battery pack, and that includes integrated level 2 wired charging and wireless charging functions. The project incorporated SiC MOSFET modules having switching frequencies in excess of 100 kHz, planar magnetics, a hierarchical control architecture that enables scaling to higher voltages and powers with additional converter modules, and a high-power density in excess of 20 kW/L. The research demonstrated how a more complex converter approach can increase mean-time-to-failure, even though the number of elements is increased. This is achieved through significant reduction of temperature rise through fundamentally superior converter circuit topologies. The research also demonstrated new high power planar magnetics that increase power density. The technology is appropriate to a variety of applications including EV power trains, EV charging, PV inverters, battery storage, and similar areas. These systems potentially can be manufactured in the U.S.

33 ADVANCED PROPULSION SYSTEMS↗

Operando Neutron Imaging of Reaction Extent and Particle Swelling Informs Limiting Factors for Salt Hydrate Thermochemical Energy Storage

Salt hydrates are a promising thermochemical energy storage medium that stores heat through the reversible uptake (hydration) and release (dehydration) of water vapor. Our study deploys operando neutron imaging to investigate salt hydrate performance with high spatial resolution (42 μm pixels). For flow over a packed bed with diffusion-driven transport, measurements reveal the formation of a solid diffusion layer due to particle swelling for the pure SrBr2 salt. In contrast, the SrBr2–vermiculite composite exhibits significantly less swelling and more than a 2-fold increase in the apparent water vapor diffusivity. For axial flow through a packed bed, neutron imaging confirms theoretically predicted transitions from a moving reaction front to a homogeneous profile with an increase in humid air flow rate. Our study establishes neutron imaging as a powerful technique to advance fundamental understanding of thermochemical systems and help guide composite material design.

Kinzer, Bryan [ORNL] (ORCID:0000000337804910)↗

Preliminary Design of Nuclear Reactor Heat Delivery Systems: Integration with Reference Oil Refinery, Methanol Synthesis, and Hydrogen Production

The Department of Energy’s (DOE) Integrated Energy Systems (IES) program is generating comprehensive analyses validating the opportunity for using nuclear energy in a variety of applications including future clean grids, providing heat for direct use, and providing heat to help reduce emissions in chemical commodities. This work focuses on the preliminary designs of thermal delivery systems that can integrate heat produced from a nuclear core to industrial processes. The key research question that needs to be answered is: what is the prospective method for integrating nuclear generated heat energy into non-electric applications that can facilitate combined heat and power operations by advanced nuclear reactor systems? This research is a composition of case studies showing preliminary conceptual designs for thermal delivery systems integrating advanced nuclear systems with a few industrial systems including high temperature steam electrolysis, a reference oil refinery, and potential future methanol systems that supplant some natural gas use with nuclear energy. Piping and instrumentation diagrams have been developed to show the conceptual integration of nuclear systems with representative industrial systems. Different features of the configurations are dependent on the specific integration requirements including energy source conditions, demand quantity, and require energy application conditions. Design concepts are validated using thermodynamic balance calculations to verify system performance including calculating system losses during transport. Key components: pumps and compressors, heat exchangers, and network piping are reported with key design information and sizing.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Impact of high-temperature annealing on hafnia-silica composite coatings deposited via ion beam sputtering for high-peak power 1064 nm lasers

The maximum power handling fluence of high-peak and average power laser systems is often limited by the laser damage of the coatings on optical components. Furthermore, these multilayer dielectric coatings are limited in their maximum power handling due to laser-damage-prone defects in the lower optical bandgap, higher optical index material. Some of these defects can be mitigated by thermal annealing to high temperatures, which can greatly reduce the linear absorbative precursors. Typically, hafnia and silica are the materials of choice for high-peak and average power laser systems in the ultraviolet through infrared spectral range; however, hafnia crystalizes readily when annealed at high temperatures. In this study, we prepare composite HfO 2 -SiO 2 coatings by co-sputtering hafnia and silica in an ion beam sputtering system and compare them to pure hafnia-based coatings. We demonstrate that crystallinity in hafnia can be completely suppressed when it is mixed with silica, such as the composite coatings in this study. High reflectors were fabricated and annealed, demonstrating that the multilayer dielectric stacks can survive high-temperature annealing and exhibit an excellent linear absorption of 0.2 +/- 1 ppm at 1064 nm. Short- and long-pulse laser damage was explored, demonstrating the complex relationship between linear absorption and the non-linear absorption which drives pulsed laser damage. These results provide an excellent route to the creation of very low linear absorption optical coatings, which also utilize low scattering materials that are best suited for high-peak and average power applications.

Harthcock, Colin [Lawrence Livermore National Labo↗

Demand Response Potential from the Bulk Grid Perspective

Gain insight from an exploration of the potential value of demand response (DR) in future power systems. Using hourly DR resource estimates by sub-sector, electrical end-use, and grid service, we incorporate virtual generator models of DR resources into large-scale production cost models, and analyze the grid-level impacts in terms of the ability of DR to reduce system costs and potentially help integrate renewables or reduce system emissions. Additionally, we examine the value of DR, its revenue, and how these change under different system conditions. In this panel session, we will describe our input data and modeling methods, provide an overview of the production cost models used, and summarize key results from analyses in Florida and the western United States. Findings include variations in DR value by end-use and geography, an ability to increase economic PV deployment potential in high penetration systems, and mixed emissions outcomes depending on system composition and fuel prices.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Development of High-Temperature Emissivity Measurement Capabilities for Molten Salts at PNNL

In this study, an emissivity measurement system for a liquid molten salt was developed on the bases on the Stefan Boltzmann Law. A prototype device operating in ambient atmosphere was constructed an initial result compared well with available literature. The diffuse emissivity of NaCl-KCl system (NaCl, 51mol% NaCl – 49mol% KCl and KCl) was measured from 550 to 850 °C at a wavelength of 1.3 µm. The system appears to be relatively invariant with composition but a clear trend of decreasing emissivity values from ~0.9 at 550 °C to 0.75 at 850 °C was observed. A schematic for an enclosed system for inert atmosphere and actinide salts was drafted. Several of the components for fabrication of this device, improved laser system, furnace, nickel for capsule construction, have been purchased and are ready for assembly. The new laser system will have an improved measurement range of 275-1000 °C. The clam shell furnace has a maximum temperature of 1200 °C and will support the hermetically sealed inert encapsulation vessels. Nickel plate and tubing will create a relatively corrosion resistance capsule for testing that can withstand temperature up to 1000 °C. Emissivity measurements are important for a larger effort to understand radiative heat transfer within molten salts at elevated temperatures (600-1000 °C). Literature review of optical salt properties and radiative heat transfer models indicated that systems within elevated temperature regimes could see upwards of 20% or more of their total heat transferred through photonic mechanisms. Ultimately, future work will measure the total thermal conductivity and break down the molecular and radiative portions. Thermal conductivity, along with other thermal properties of molten salts, both coolant and fuel, are fundamental to modeling and simulations that support MSR design. The results presented here and ongoing work at PNNL will be useful in selecting optimal salt compositions, designing reactor systems, and optimizing heat transfer within a MSR power plant.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Computational design of high entropy alloy coating for hydrogen turbine applications

This project aims to develop novel high entropy alloy (HEA)-based coatings to protect critical components in hydrogen-fueled turbine power system. The HEA-coatings will demonstrate superior performance in hydrogen combustion environment to commercial NiCoCrAlY coating in current natural gas turbine system. The HEA coating facilitates the formation of a protective scale of alpha-alumina to slow down the inward diffusion of oxidizing species and the outward diffusion of metal elements, and possesses ultrahigh corrosion and spallation resistance to prolong the service lifetime of critical components in hydrogen turbine power system. Aimed to accelerate the discovery of novel HEA coating compositions, high throughput computational modeling including CALPHAD and density functional theory and machine learning are performed to predict phase stability, oxygen permeability, oxidation rate constant, coefficient of thermal expansion, and mechanical properties. Based on the modeling and machine learning prediction, experimental validation is performed. Preliminary results will be presented and approaches to minimize oxidation will be discussed.

alloy design↗