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NASA NTRS1986

Possible Mars brines - Equilibrium and kinetic considerations

To determine the fate of postulated near surface brines on Mars, the rate of H2O mass loss from subsurface brines was calculated as a function of latitude, depth, regolith porosity, eutectic temperature, and pore size. A model for a chemically reasonable brine that could reproduce Martian radar results was developed, and the escape rate of H2O molecules from such a brine was estimated. It is suggested that the presence of a low-permeability duricrust may be required to preserve such a brine for reasonable periods, and to prevent detection of an extensive subsurface system by the Viking MAWD instrument.

Zent, A. P.↗

NASA NTRS1988

Atmospheric H2O and the search for Martian brines

Abundant martian brines would have important implication for current theories of volatile migration on Mars, since, although the presence of metastable brines is quite plausible, any brine in the reasonably near-surface should be completely depleted on a timescale short in relation to the age of Mars. It is important to determine whether brines exist in the martian subsurface, for the current paradigm for understanding martian volatile regime requires substantial alteration if they are found to exist. It is determined, however, that the prospect for detection of a subsurface brine via atmospheric water vapor measurements is marginal. Four reasons are given for this conclusion.

Zent, Aaron P.↗

NASA NTRS2003

Investigating the Martian Gullies for Possible Brine Origin: A Preliminary Search for Evaporite Minerals Using THEMIS Data

Photographs taken by both the Mars Orbiter Camera (MOC) aboard the Mars Global Surveyor (MGS) spacecraft and the Thermal Emission Imaging System (THEMIS) aboard the Mars Odyssey (MO) spacecraft have shown the presence of young gullies on Mars. These gullies occur at middle and high latitudes (predominantly in the southern hemisphere) in the walls of both impact craters and canyons. They are thought possibly to be formed by the melting of ground ice, groundwater seepage (possibly as brines), surface runoff, or even liquid CO2, activated sporadically as a result of oscillations in Mars orbit. For this work, the hypothesis of gully formation being related to the outflow of brines will be investigated through the observation and study of spacecraft data. Brine rich fluids expunged from underground onto the walls of canyons and craters would either evaporate or freeze and sublimate. Removal of water from a brine by evaporation or sublimation would cause the solutes to precipitate as evaporite minerals on the canyon and crater walls or at the base of the walls, and possibly on the canyon and crater floors. Hence, the gully sites are ideal target areas to search for evaporites using THEMIS data. The objective of this work is to survey the recently acquired THEMIS data for spectral evidence of evaporite minerals, with a focus on areas of gully formation. Identifying salt mineral residues could provide chemical evidence in support of the brine origin of the Martian gullies.

Lane, M. D.↗

NASA NTRS1992

Scanning electron microscope observations of brine shrimp larvae from space shuttle experiments

Brine shrimp are encysted as gastrula stage embryos, and may remain dehydrated and encysted for years without compromising their viability. This aspect of brine shrimp biology is desirable for studying development of animals during space shuttle flight, as cysts placed aboard a spacecraft may be rehydrated at the convenience of an astronaut, guaranteeing that subsequent brine shrimp development occurs only on orbit and not on the pad during launch delays. Brine shrimp cysts placed in 5 ml syringes were rehydrated with salt water and hatched during a 9 day space shuttle mission. Subsequent larvae developed to the 8th larval stage in the sealed syringes. We studied the morphogenesis of the brine shrimp larvae and found the larvae from the space shuttle experiments similar in rate of growth and extent of development, to larvae grown in sealed syringes on the ground. Extensive differentiation and development of embryos and larvae can occur in a microgravity environment.

short duration↗

NASA NTRS2014

Advances in Spacecraft Brine Water Recovery: Development of a Radial Vaned Capillary Drying Tray

Technology improvements in the recovery of water from brine are critical to establishing closed-loop water recovery systems, enabling long-duration missions, and achieving a sustained human presence in space. A genre of 'in-place drying' brine water recovery concepts, collectively referred to herein as Brine Residual In-Containment, are under development. These brine water recovery concepts aim to increase the overall robustness and reliability of the brine recovery process by performing drying inside the container used for final disposal of the solid residual waste. Implementation of in-place drying techniques have been demonstrated for applications where gravity is present and phase separation occurs naturally by buoyancy-induced effects. In this work, a microgravity-compatible analogue of the gravity-driven phase separation process is considered by exploiting capillarity in the form of surface wetting, surface tension, and container geometry. The proposed design consists of a series of planar radial vanes aligned about a central slotted core. Preliminary testing of the fundamental geometry in a reduced gravity environment has shown the device to spontaneously fill and saturate rapidly, thereby creating a free surface from which evaporation and phase separation can occur similar to a terrestrial-like 'cylindrical pool' of fluid. Mathematical modeling and analysis of the design suggest predictable rates of filling and stability of fluid containment as a function of relevant system dimensions; e.g., number of vanes, vane length, width, and thickness. A description of the proposed capillary design solution is presented along with preliminary results from testing, modeling, and analysis of the system.

Callahan, Michael R.↗

NASA NTRS2016

Results of the FY15 Brine Evaporation Bag (BEB) Technology Down-Select Testing

The Brine Evaporation Bag (BEB) recently participated in the Brine Concentrator Technology (BCT) Technology Down-Select (TDS). It was found that the BEB System is able to process ISS (International Space Station) Alternate Pretreat Brine at a rate high enough for ISS application as well as future deep space missions. The BEB System is also capable of processing the brine to a solid residue which will add to the stability and safety of storing the brine residue. The results of the BEB testing for the BCT-TDS will be presented in this paper.

Delzeit, Lance↗

NASA NTRS2020

Impact-driven mobilization of deep crustal brines on dwarf planet Ceres

Ceres, the only dwarf planet in the inner Solar System, appears to be a relict ocean world. Data collected by NASA's Dawn spacecraft provided evidence that global aqueous alteration within Ceres resulted in a chemically evolved body that remains volatile-rich(1). Recent emplacement of bright deposits sourced from brines attests to Ceres being a persistently geologically active world(2,3), but the surprising longevity of this activity at the 92-km Occator crater has yet to be explained. Here, we use new high-resolution Dawn gravity data to study the subsurface architecture of the region surrounding Occator crater, which hosts extensive young bright carbonate deposits (faculae). Gravity data and thermal modelling imply an extensive deep brine reservoir beneath Occator, which we argue could have been mobilized by the heating and deep fracturing associated with the Occator impact, leading to long-lived extrusion of brines and formation of the faculae. Moreover, we find that pre-existing tectonic cracks may provide pathways for deep brines to migrate within the crust, extending the regions affected by impacts and creating compositional heterogeneity. The long-lived hydrological system resulting from the impact might also occur for large impacts in icy moons, with implications for creation of transient habitable niches over time.High-resolution data of Ceres's bright spots (faculae), obtained by Dawn's second extended mission, suggest the existence of a deep brine-rich reservoir that emerged to the surface through long-lived cryovolcanic activity as a consequence of the impact that created Occator crater.

C. A. Raymond↗

NASA NTRSDate not supplied

Evaluation of the Maximum Soluble Water Recovery from Pretreated Urine Brines in Low Earth Orbit

The Urine Processor Assembly (UPA) on the International Space Station recovers water from pretreated urine by thin-film, vacuum compression distillation (VCD). A number of iterative improvements to the distiller assembly (DA) have enabled increases in on-orbit water recovery and improved distillate water quality at on-orbit recoveries up to 87% by volume relative to the volume of pretreated urine. The phosphoric acid-based pretreatment formulation has enabled these higher recoveries on-orbit since May of 2016. Application of simple empirical chemistry models have allowed water recovery of sulfuric-acid pretreated urine from the Russian Orbiting segment to be distilled with phosphoric acid pretreated urine from the U.S. Orbiting Segment. Returned liquid brine from brine filters in the UPA brine loop have enabled empirical measurement of gypsum solubility as a function of recovery, conductivity, or mass density in the real brines of ISS. Calculations of maximum soluble recovery, MSR, are based on preventing the precipitation of gypsum, which is the first mineral to precipitate for both types of pretreated urine. A statistical urine model of urine composition provides an estimate of worst-case urine from a crew of three during one year of operations on ISS. The MSR is defined based on the worst-case concentrations of urinary calcium and urinary sulfate that are pretreated, pooled, and distilled. The potential to increase water recoveries above 87% without gypsum precipitation are evaluated. The potential benefits and costs of the addition of a conductivity sensor or a Coriolis mass flow meter to the brine loop are evaluated.

Dean L Muirhead↗

NASA NTRS2015

Design of the Brine Evaporation Bag for Increased Water Recovery in Microgravity

The existing water recovery system on the International Space Station (ISS) is limited to 75% reclamation; consequently, long duration space missions are currently unfeasible due to the large quantity of water necessary to sustain the crew. The Brine Evaporation Bag (BEB) is a proposed system to supplement the existing water recovery system aboard the ISS that can to increase water recovery to 99%. The largest barrier to high water recovery is mineral scaling inside the water recovery equipment, which leads to equipment failure; therefore, some water must remain to keep the minerals dissolved. This waste stream is liquid brine containing salts, acids, organics, and water. The BEB is designed to recover this remaining water while protecting the equipment from scale. The BEB consists of a sealed bag containing a hydrophobic membrane that allows water vapor and gas to pass through. It is operated under vacuum, heated, and continuously filled with brine to boil away the water. The water vapor is recovered and the solids are contained inside the bag for disposal. The BEB can dry the brine to a solid block. Ongoing work includes improving the design of the BEB and the evaporator to prevent leaks, maximize the rate of water removal, and minimize energy use and weight. Additional testing will determine whether designs are heat- or mass-transfer limited and the optimal water recovery rate.

Brine Evaporation Bag↗

NASA NTRS2014

Continued Development of the Brine Evaporation Bag

The Brine Evaporation Bag (BEB) is a membrane-based bag system for the dewatering of brine. Previous studies showed the ability of the BEB to dewater brine at low temperatures with a 96 percent mass reduction. Additionally, a microgravity flight showed the BEB is microgravity compatible. Current work focuses on the effects of temperature, vacuum, purge gas flow rate, membrane area, and membrane permeability on the rate of dewatering within a vacuum oven configured to mimic the Heat Melt Compactor. Within this study, it was found that changing the temperature or level of vacuum would change the rate of dewatering. The purge gas, membrane area, and membrane permeability did not affect the dewater rate. The reason for this behavior may be that the dewatering is heat transfer limited, and out of all the parameters studied, only the temperature and vacuum have an effect on the heat transfer rate. The ISS (International Space Station) produces brine at a rate of 1.2 liters per day. This initial study showed that it is possible to remove water from a BEB at a rate of 1.6 liters per day in this breadboard configuration; even at moderate temperatures. Development of a dedicated BEB Evaporator will be discussed. In addition, it is further postulated that a specifically designed BEB Evaporator would result in an increased dewatering rate allowing for even lower operating temperatures or faster dewatering rates.

Recycling↗

NASA NTRS1994

Development of the brine shrimp Artemia is accelerated during spaceflight

Developmentally arrested brine shrimp cysts have been reactivated during orbital spaceflight on two different Space Shuttle missions (STS-50 and STS-54), and their subsequent development has been compared with that of simultaneously reactivated ground controls. Flight and control brine shrimp do not significantly differ with respect to hatching rates or larval morphology at the scanning and transmission EM levels. A small percentage of the flight larvae had defective nauplier eye development, but the observation was not statistically significant. However, in three different experiments on two different flights, involving a total of 232 larvae that developed in space, a highly significant difference in degree of flight to control development was found. By as early as 2.25 days after reactivation of development, spaceflight brine shrimp were accelerated, by a full instar, over ground control brine shrimp. Although developing more rapidly, flight shrimp grew as long as control shrimp at each developmental instar or stage.

Flight Experiment↗

NASA NTRS2012

Comparison of Four Strong Acids on the Precipitation Potential of Gypsum in Brines During Distillation of Pretreated, Augmented Urine

In this study, three different mineral acids were substituted for sulfuric acid (H2SO4) in the urine stabilizer solution to eliminate the excess of sulfate ions in pretreated urine and assess the impact on maximum water recovery to avoid precipitation of minerals during distillation. The study evaluated replacing 98% sulfuric acid with 85% phosphoric acid (H3PO4), 37% hydrochloric acid (HCl), or 70% nitric acid (HNO3). The effect of lowering the oxidizer concentration in the pretreatment formulation also was studied. This paper summarizes the test results, defines candidate formulations for further study, and specifies the injection masses required to stabilize urine and minimize the risk of mineral precipitation during distillation. In the first test with a brine ersatz acidified with different acids, the solubility of calcium in gypsum saturated solutions was measured. The solubility of gypsum was doubled in the brines acidified with the alternative acids compared to sulfuric acid. In a second series of tests, the alternative acid pretreatment concentrations were effective at preventing precipitation of gypsum and other minerals up to 85% water recovery from 95th-percentile pretreated, augmented urine. Based on test results, phosphoric acid is recommended as the safest alternative to sulfuric acid. It also is recommended that the injected mass concentration of chromium trioxide solution be reduced by 75% to minimize liquid resupply mass by about 50%, reduce toxicity of brines, and reduce the concentration of organic acids in distillate. The new stabilizer solution formulations and required doses to stabilize urine and prevent precipitation of minerals up to 85% water recovery are given. The formulations in this study were tested on a limited number of artificially augmented urine batches collected from employees at the Johnson Space Center (JSC). This study successfully demonstrated that the desired physical and chemical stability of pretreated urine and brines can be achieved using alternate pretreatment formulations under laboratory conditions. Additional testing and hazard assessments will be required to determine the feasibility of utilizing the proposed urine pretreatment formulations on ISS.

Muirhead, Dean↗

NASA NTRS2013

Advancements in Spacecraft Brine Water Recovery: Development of a Radial Vaned Capillary Drying Tray

Technology improvements in the recovery of water from brine are critical to establishing closedloop water recovery systems, enabling long duration missions, and achieving a sustained human presence in space. A genre of 'in-place drying' brine water recovery concepts, collectively referred to herein as Brine Residual In-Containment (BRIC), are under development which aim to increase the overall robustness and reliability of the brine recovery process by performing drying inside the container used for final disposal of the solid residual waste. Implementation of in-place drying techniques have been demonstrated for applications where gravity is present and phase separation occurs naturally by buoyancy induced effects. In this work, a microgravity compatible analogue of the gravity-driven phase separation process is considered by exploiting capillarity in the form of surface wetting, surface tension, and container geometry. The proposed design consists of a series of planar radial vanes aligned about a central slotted core. Preliminary testing of the fundamental geometry in a reduced gravity environment has shown the device to spontaneously fill and saturate rapidly creating a free surface from which evaporation and phase separation can occur similar to a 1-g like 'cylindrical pool' of fluid. Mathematical modeling and analysis of the design suggest predictable rates of filling and stability of fluid containment as a function of relevant system dimensions, e.g., number of vanes, vane length, width, and thickness. A description of the proposed capillary design solution is presented along with preliminary results from testing, modeling and analysis of the system.

Callahan, Michael R.↗

NASA NTRS2014

NASA TechPort Entry for Coiled Brine Recovery Assembly (CoBRA) CL IR&D Project

The Coiled Brine Recovery Assembly (CoBRA) project will result in a proof-of-concept demonstration for a lightweight, compact, affordable, regenerable and disposable solution to brine water recovery. The heart of CoBRA is an evaporator that produces water vapor from brine. This evaporator leverages a novel design that enables passive transport of brine from place to place within the system. While it will be necessary to build or modify a system for testing the CoBRA concept, the emphasis of this project will be on developing the evaporator itself. This project will utilize a “test early, test often” approach, building at least one trial evaporator to guide the design of the final product.

Pensinger, Stuart↗

NASA NTRS2015

Results of the GCMS Effluent Gas Analysis for the Brine Processing Test

The effluent gas for the Paragon Ionomer Water Processor (IWP), UMPQUA Ultrasonic Brine Dewatering System (UBDS), and the NASA Brine Evaporation Bag (BEB) were analyzed using Headspace GCMS Analysis in the recent AES FY14 Brine Processing Test. The results from the analysis describe the number and general chemical species of the chemicals produced. Comparisons were also made between the different chromatograms for each system, and an explanation of the differences in the results is reported.

GCMS↗

NASA NTRS2016

Ring Resonator for Detection of Melting Brine Under Shallow Subsurface of Mars

Laboratory experimental evidence using Raman spectroscopy has shown that liquid brine may form below the shallow subsurface of Mars. A simpler experimental method to verify the presence of liquid brine or liquid water below Mars surface is needed. In this paper, a ring resonator is used to detect the phase change between frozen water and liquid water below a sandy soil that simulates the Mars surface. Experimental data shows that the ring resonator can detect the melting of thin layers of frozen brine or water up to 15 mm below the surface.

brine↗

NASA NTRS2016

Ring Resonator for Detection of Melting Brine Under Shallow Subsurface of Mars

Mars↗

NASA NTRS1980

Stability of brines on Mars

The detection of high chlorine and sulfate abundances and duricrusts on Mars strongly suggests the occasional presence of brines on the Martian surface. Ternary phase diagrams for the likely chloride and sulfate brines indicate that the minimum temperature at which a brine can be stable is near 210 K with a water concentration of approximately 70 wt % and a high concentration of calcium chloride. The dominance of sulfate over chlorine in the Martian regolith suggests precipitation of salts at temperatures higher than the minimum.

Brass, G. W.↗