Avoiding Cascading Failure in Battery Packs through Thermal Analysis and Considerations for Electric Aviation.
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Hewson, John↗
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Avoiding cascading failure in battery packs through thermal analysis
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Hewson, John C.↗
Ultrasonic Characterization of Lithium Ion Thermal Runaway Conditions for Real-time Ultrasonic Enabled BMS Integration
The demand for energy storage is growing, and lithium-ion batteries are a promising technology to meet this need due to their high power/energy density, high round-trip efficiency, rapid response time, and portability. However, recent catastrophic events caused by thermal runaway have slowed their adoption, highlighting the need for an early warning system for battery failure. In this work, ultrasound is used to detect physical changes in 950 mAh batteries by identifying material property changes independent of voltage and current. [Ultrasound signal features (e.g., time of flight, maximum frequency component) were extracted as the batteries were cycled and subjected to both constant current and constant voltage overcharge and were used to develop two metrics identifying failure: a warning to detect the start of overcharge and an emergency stop (E-stop) to immediately take the battery out of service. The identification method involved locating magnitude differences of several ultrasound features compared to baseline operation considering different currents and temperatures, and the warning/stopping metrics were consistent across all experiments. For an average overcharge time of 140 minutes, the average warning was issued 124 minutes before the failure and the average E-stop was triggered 94 minutes before failure. As a test of using ultrasound for early warning detection, a battery was forced into overcharge and returned to normal cycling conditions based on the previously determined warning metric. Both the voltage profile and the ultrasound measurements returned to their baseline behavior, indicating that ultrasonic detection can not only identify battery failure before a catastrophic event, but can also provide early enough warnings such that overcharges can be detected and corrected quickly enough so the battery does not need to be decommissioned.]
25 ENERGY STORAGE↗
Safety Hazards of Batteries and Hydrogen Storage Systems in Proximity
This report addresses the safety concerns and mitigations for battery failures and their impact on hydrogen storage systems. Through an analysis of failure modes, this report highlights the risks posed by thermal runaway and chemical emissions caused by batteries. Although rare, battery thermal failure events may prompt the opening of the relief valve on the hydrogen tank. Strategies such as battery management systems, thermal management systems, and multiple thermally activated pressure relief devices can mitigate these risks. Potential simulations and experiments to better quantify the unique risks posed by lithium-ion batteries near tanks are suggested. Improving safety standards will enable integration of batteries and hydrogen storage systems in various energy storage technologies.
08 HYDROGEN↗
Development and Validation of a Simulation Tool to Predict the Combined Structural, Electrical, Electrochemical and Thermal Responses of Automotive Batteries
Battery safety is one of the most important design factors of electrified vehicles (EVs) since battery failure may lead to a catastrophic consequence. To improve the safety of battery systems in EVs, battery behaviors under various abuse conditions should be well understood. One way to examine battery response under extreme conditions is to conduct abuse tests in different scenarios. They can provide first-hand pass/fail information on battery safety, but they are usually expensive and time-consuming, which is inconvenient during design iterations and optimization. On the other hand, computational modeling can predict the battery behaviors in a more efficient and cost-effective way, which becomes an important tool to evaluate battery safety. Modeling battery responses and failure is challenging since it involves multiple coupled physical processes, needs to consider complex material properties and is computationally intensive. This project aims to develop a practical simulation tool to predict the combined structural, electrical, electrochemical, and thermal responses of automotive batteries to crash-induced crush and short circuit and validate it for conditions relevant to automotive crash. Advanced material constitutive models will be utilized to capture the mechanical response of cell components. Moreover, methods will be developed to reduce computational complexity of the model and allow battery safety simulations to extend from cell-level to module/pack level with affordable computational resources.
25 ENERGY STORAGE↗
Battery asset management with cycle life prognosis
We report Battery Asset Management problem determines the minimum cost replacement schedules for each individual asset in a group of battery assets that operate in parallel. Battery cycle life varies under different operating conditions including temperature, depth of discharge (DOD), charge rate, etc., and a battery deteriorates due to usage, which cannot be handled by current asset management models. This paper presents a new battery asset management methodology where battery cycle life prognosis is integrated with parallel asset management to reduce lifecycle cost of the Battery Energy Storage Systems (BESS). For the battery failure time prognosis, a nonlinear physics-based battery capacity fade model is developed and incorporated in parallel asset management model to update battery capacity over time. Experiment results have shown that the developed battery asset management methodology can be conveniently used to facilitate BESS asset management decision making thereby decreasing asset lifecycle costs.
25 ENERGY STORAGE↗
Bat492: Machine Learning for Accelerated Life Prediction and Cell Design 2021
This presentation details work in the early prediction, classification and quantification of battery failure modes and life performance.
25 ENERGY STORAGE↗
Fast Diagnosis of Failure Mechanisms and Lifetime Prediction of Li Metal Batteries
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99 GENERAL AND MISCELLANEOUS↗
Interface Aspects in All‐Solid‐State Li‐Based Batteries Reviewed
Abstract Extensive efforts have been made to improve the Li‐ionic conductivity of solid electrolytes (SE) for developing promising all‐solid‐state Li‐based batteries (ASSB). Recent studies suggest that minimizing the existing interface problems is even more important than maximizing the conductivity of SE. Interfaces are essential in ASSB, and their properties significantly influence the battery performance. Interface problems, arising from both physical and (electro)chemical material properties, can significantly inhibit the transport of electrons and Li‐ions in ASSB. Consequently, interface problems may result in interlayer formation, high impedances, immobilization of moveable Li‐ions, loss of active host sites available to accommodate Li‐ions, and Li‐dendrite formation, all causing significant storage capacity losses and ultimately battery failures. The characteristic differences of interfaces between liquid‐ and solid‐type Li‐based batteries are presented here. Interface types, interlayer origin, physical and chemical structures, properties, time evolution, complex interrelations between various factors, and promising interfacial tailoring approaches are reviewed. Furthermore, recent advances in the interface‐sensitive or depth‐resolved analytical tools that can provide mechanistic insights into the interlayer formation and strategies to tailor the interlayer formation, composition, and properties are discussed.
25 ENERGY STORAGE↗
Evaluation of Multi-cell Failure Propagation
Failure propagation testing is of increasing interest to the designers and end users of battery systems. One of the chief difficulties, however, is choosing an appropriate initiation method to perform the test. Single cell abuse testing is typically used to initiate thermal runaway but this can involve a large amount of additional energy injected into the system. It is assumed that this will have some impact on the behavior of a propagating thermal runaway event, but there is little data available as to how significant this would be. Further, it is ultimately difficult to develop viable propagation tests for compliance and public safety activities without better knowledge of how test methods will impact the results. This work looks at propagating battery failure with a variety of chemistries, formats, configurations and initiation methods to determine the level of significance of the chosen initiation method on the test results. We have ultimately found while there is some impact on the detailed results of propagation testing, in most cases other factors, particularly the energy density of the system play a much greater role in the likelihood of a propagation event consuming an entire battery. We have also provided some guidelines for test design to support best practices in testing.
25 ENERGY STORAGE↗
Harnessing Electrochemical‐Mechanical Couplings to Improve the Reliability of Solid‐State Batteries
Abstract One key barrier to using lithium‐metal anode batteries is that metal dendrites can penetrate solid electrolytes, causing short‐circuits and battery failures. It is established that this failure is likely caused by crack propagation due to electrodeposition‐induced stresses from lithium metal. This study explores ways to harness these electrochemical‐mechanical couplings to control dendrite growth and improve battery reliability using a phase‐field model and targeted fracture experiments. The results show that dendrite growth can be effectively mitigated by applying mechanical stresses or tailoring the material's fracture toughness. This study also outlines the requirements for compressive stress to halt or deflect dendrites as a function of the overpotential and discusses the role of microstructure in this process.
Monismith, Scott↗
Fire Protection Engineering Technical Report for Electric Vehicles and Lithium-Ion Batteries
This fire protection engineering technical report discusses and presents the properties, data, and safety of select lithium-ion batteries. Lithium-ion batteries have increased in usage and a fire scenario analysis must be created for each situation where they may be introduced in buildings to determine the risk associated if a battery failure were to occur.
25 ENERGY STORAGE↗
Lithium Metal as an Anode in Electrochemical Energy Storage
The drastic environmental and economic costs of global warming have driven the necessity to reduce, if not eliminate, a dependency on oil and gas for energy applications. Alternative clean energy reliance has been initiated as a global investment for a more sustainable future. Part of this transitional effort is focused on energy storage via a rechargeable battery. High energy density storage is necessary for utilizing non-dispatchable green energy technologies, as well in the electric transition of our vehicle fleet. Further, understanding methods of extracting, manufacturing, and recycling lithium is necessary to lessen environmental impact. Lithium metal is often considered the “Holy Grail” of battery technology, due to its high theoretical capacity (3,860 mAh/g) and low electrochemical potential (-3.04 V vs. SHE). However, parasitic reactions lead to rapid and dangerous battery failure. Therefore, determining methods of stabilizing lithium metal is paramount for the transition to a greener future.
25 ENERGY STORAGE↗
A Cation-Tethered Flowable Polymeric Interface for Enabling Stable Deposition of Metallic Lithium
A fundamental challenge, shared across many energy storage devices, is the complexity of electrochemistry at the electrode–electrolyte interfaces that impacts the Coulombic efficiency, operational rate capability, and lifetime. Specifically, in energy-dense lithium metal batteries, the charging/discharging process results in structural heterogeneities of the metal anode, leading to battery failure by short-circuit and capacity fade. In this work, we take advantage of organic cations with lower reduction potential than lithium to build an electrically responsive polymer interface that not only adapts to morphological perturbations during electrodeposition and stripping but also modulates the lithium ion migration pathways to eliminate surface roughening. As a result, we find that this concept can enable prolonging the long-term cycling of a high-voltage lithium metal battery by at least twofold compared to bare lithium metal.
25 ENERGY STORAGE↗
Decoupling the degradation factors of Ni-rich NMC/Li metal batteries using concentrated electrolytes
Battery degradation results from multiple factors that usually correlate with each other. Electrochemical corrosion of the current collector is one of the main reasons for battery failure, leading to poor internal electrical contact and the dissolution of harmful ions into electrolytes. This phenomenon is especially evident in lithium bistrifluoromethanesulfonimidate (LiTFSI)-based electrolytes, although they have many advantages over conventional lithium hexafluorophosphate (LiPF 6 )-based electrolytes, such as low viscosity, good thermal stability, and stable to water. Recently, highly concentrated electrolytes are found hopeful of inhibiting aluminum's corrosion and boosting new electrolyte development. Here we discuss the solvation structures of liquid electrolytes and decouple the degradation mechanisms of using LiTFSI-based electrolytes in Li(Ni 0.8 Co 0.1 Mn 0.1 )O 2 /Li metal batteries. The results suggest although concentrated electrolytes inhibit the Al corrosion, the growth of lithium dendrites and the protection of the cathode-electrolyte interphase are not significantly improved. Furthermore, this paper provides a paradigm to evaluate the performance of electrolytes comprehensively.
25 ENERGY STORAGE↗
The Effect of Cell Geometry and Trigger Method on the Risks Associated with Thermal Runaway of Lithium-Ion Batteries
Consideration of thermal runaway heat output variability is paramount for the development of safe lithium-ion battery assemblies. This study utilizes data gathered from fractional thermal runaway calorimetry (FTRC) experiments to conduct a comparative analysis of thermal runaway heat output for three cell formats (18650, 21700, and 33600) as a function of trigger method (heaters, internal short-circuiting device, and nail penetration). The analysis is based on comparisons for the calculated total energy yield, fractional energy yield, heat rate, and heat flux. This study reveals that nail penetration tends to result in higher thermal runaway heat output for larger cells (21700 & 33600); these experiments also tended to result in higher fractions of the total energy being released through the cell body. The smaller cells (18650) did not appear to have significant variation in heat output as a function of trigger method. This finding suggests that, for this cell type, worst-case scenario heat output could be achievable in assembly level testing regardless of the utilized trigger method. This study also demonstrates successful translation of FTRC results, as recorded in the Battery Failure Databank, into meaningful analysis that breaks down the influence of specific conditions on thermal runaway heat output.
calorimetry↗
Untapped Potential of Fluoride Ions in Maximizing the Electrochemical Stability of Deep Eutectic Solvents
Advancing the batteries is pivotal to propelling our society toward a sustainable, electrified future. The stability of electrolytes forms the backbone of energy storage systems. This is particularly the case for redox flow batteries (RFBs). Their deployability depends on their longevity and dependability. The presence of unstable electrolytes can trigger undesirable reactions, degrade performance, and lead to battery failure. Aqueous electrolytes, with limited electrochemical stability window (ESW), are prone to hydrogen and oxygen evolution. Conversely, non-aqueous electrolytes offer enhanced stability. In this study, we unveil the ESW of a non-aqueous eutectic solvent, comprising choline fluoride and ethylene glycol—a composition that has eluded experimental investigation until now. Our findings show that the stability window, reduction and oxidation potential limits of deep eutectic solvents, are sensitive to variations in the halide component of the ammonium salt. Furthermore, this work not only highlights the benefits of novel deep eutectic solvents but also sets the stage for their strategic use in future battery electrolytes.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Effect of diffusion constant on the morphology of dendrite growth in lithium metal batteries
Lithium dendrites can lead to a short circuit and battery failure, and developing strategies for their suppression is of considerable importance. In this work, we study the growth of dendrites in a simple model system where the solvent is a continuum and the lithium ions are hard spheres that can deposit by sticking to existing spheres or the electrode surface. Using stochastic dynamics simulations, we investigate the effect of applied voltage and diffusion constant on the growth of dendrites. We find that the diffusion constant is the most significant factor, and the inhomogeneity of the electric field does not play a significant role. Additionally, the growth is most pronounced when the applied voltage and diffusion constant are both low. We observe a structural change from broccoli to cauliflower shape as the diffusion constant is increased. The simulations suggest that a control of electrolyte parameters that impact lithium diffusion might be an attractive route to controlling dendrite growth.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗