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At least 37 records · Page 2

Column amounts of trace gases from ground based FTIR measurements in the late north polar winters 1990 and 1991

Two FTIR spectrometers were employed in the late winters 1990 and 1991 in Esrange, North Sweden, and in Ny Aalesund, Spitsbergen to detect zenith column amounts of several trace gases. Time series of column amounts of the trace gases O3, N2O, CH4, HNO3, NO2, CHl, and HF have been derived from the measured spectra. Additionally, some information on the vertical distribution of HCl could be obtained by analyzing the spectral line shapes. The results are interpreted in terms of dynamical and chemical processes.

Adrian, Gabriele

The determination of HNO3 column amounts from tunable diode laser heterodyne spectrometer spectra taken at Jungfruajoch, Switzerland

In May of 1991 a tunable diode laser heterodyne spectrometer built by the National Physical Laboratory was operated at the International Scientific Station of the Jungfraujoch (46.5 deg N, 8.0 deg E, altitude 3.56 km). Nitric acid spectra in the region of 868 wavenumbers were recorded at sunset and sunrise on two separate days at a resolution of 0.0013 wavenumbers with a signal-to-noise ratio of approximately 130:1. A vertical column amount of HNO3 of 1.61 x 10(exp 16) molecules/sq cm was determined using an atmospheric transmission model developed at the University of Denver. The mean of a number of mid-latitude, northern hemisphere profiles was used as the initial profile for the inversion. A comparison of different initial profiles provides information on the sensitivity of the retrieved column amount of 1.61 x 10(exp 16) molecules/sq cm lies within the range of values published in the World Meteorological Organization Report no. 16 (1986), but is considerably larger than the value of (0.99 - 1.29) x 10(exp 16) reported by Rinsland et al. (1991) for June during the period 1986 to 1990.

Fogal, P. F.

Expert system shell to reason on large amounts of data

The current data base management systems (DBMS's) do not provide a sophisticated environment to develop rule based expert systems applications. Some of the new DBMS's come with some sort of rule mechanism; these are active and deductive database systems. However, both of these are not featured enough to support full implementation based on rules. On the other hand, current expert system shells do not provide any link with external databases. That is, all the data are kept in the system working memory. Such working memory is maintained in main memory. For some applications the reduced size of the available working memory could represent a constraint for the development. Typically these are applications which require reasoning on huge amounts of data. All these data do not fit into the computer main memory. Moreover, in some cases these data can be already available in some database systems and continuously updated while the expert system is running. This paper proposes an architecture which employs knowledge discovering techniques to reduce the amount of data to be stored in the main memory; in this architecture a standard DBMS is coupled with a rule-based language. The data are stored into the DBMS. An interface between the two systems is responsible for inducing knowledge from the set of relations. Such induced knowledge is then transferred to the rule-based language working memory.

Giuffrida, Gionanni

MM-Wave Radiometric Measurements of Low Amounts of Precipitable Water Vapor

An experiment was conducted during March, 1999 to study ways in which to improve techniques for measuring low amounts of total-column precipitable water vapor (PWV). The experiment was conducted at the DOE's ARM program's North Slope of Alaska/Adjacent Arctic Ocean Cloud and Radiation Testbed site (DoE ARM NSA/AAO CaRT) located just outside Barrow, Alaska. NASA and NOAA deployed a suite of radiometers covering 25 channels in the frequency range of 20 GHz up to 340 GHz including 8 channels around the 183 GHz water vapor absorption line. In addition to the usual CaRT site instrumentation the NOAA Depolarization and Backscatter Unattended Lidar (DABUL), the SUNY Rotating Shadowband Spectroradiometer (RSS) and other surface based meteorological instrumentation were deployed during the intensive observation period. Vaisala RS80 radiosondes were launched daily as well as nearby National Weather Service VIZ sondes. Atmospheric conditions ranged from clear calm skies to blowing snow and heavy multi-layer cloud coverage. Measurements made by the radiosondes indicate the PWV varied from approx. 1 to approx. 5 mm during the experiment. The near-surface temperature varied between about -40 C to - 15 C. In this presentation, an overview of the experiment with examples of data collected will be presented. Application of the data for assessing the potential and limitations of millimeter-wave radiometry for retrieving very low amounts of PWV will be discussed.

Racette, P.

Evaluation of Flush-Mounted, S-Duct Inlets With Large Amounts of Boundary Layer Ingestion

A new high Reynolds number test capability for boundary layer ingesting inlets has been developed for the NASA Langley Research Center 0.3-Meter Transonic Cryogenic Tunnel. Using this new capability, an experimental investigation of four S-duct inlet configurations with large amounts of boundary layer ingestion (nominal boundary layer thickness of about 40% of inlet height) was conducted at realistic operating conditions (high subsonic Mach numbers and full-scale Reynolds numbers). The objectives of this investigation were to 1) develop a new high Reynolds number, boundary-layer ingesting inlet test capability, 2) evaluate the performance of several boundary layer ingesting S-duct inlets, 3) provide a database for CFD tool validation, and 4) provide a baseline inlet for future inlet flow-control studies. Tests were conducted at Mach numbers from 0.25 to 0.83, Reynolds numbers (based on duct exit diameter) from 5.1 million to a fullscale value of 13.9 million, and inlet mass-flow ratios from 0.39 to 1.58 depending on Mach number. Results of this investigation indicate that inlet pressure recovery generally decreased and inlet distortion generally increased with increasing Mach number. Except at low Mach numbers, increasing inlet mass-flow increased pressure recovery and increased distortion. Increasing the amount of boundary layer ingestion (by decreasing inlet throat height and increasing inlet throat width) or ingesting a boundary layer with a distorted profile decreased pressure recovery and increased distortion. Finally, increasing Reynolds number had almost no effect on inlet distortion but increased inlet recovery by about one-half percent at a Mach number near cruise.

Berrier, Bobby L.

Evaluation of Flush-Mounted, S-Duct Inlets with Large Amounts of Boundary Layer Ingestion

A new high Reynolds number test capability for boundary layer ingesting inlets has been developed for the NASA Langley Research Center 0.3-Meter Transonic Cryogenic Tunnel. Using this new capability, an experimental investigation of four S-duct inlet configurations with large amounts of boundary layer ingestion (nominal boundary layer thickness of about 40% of inlet height) was conducted at realistic operating conditions (high subsonic Mach numbers and full-scale Reynolds numbers). The objectives of this investigation were to 1) provide a database for CFD tool validation on boundary layer ingesting inlets operating at realistic conditions and 2) provide a baseline inlet for future inlet flow-control studies. Tests were conducted at Mach numbers from 0.25 to 0.83, Reynolds numbers (based on duct exit diameter) from 5.1 million to a full-scale value of 13.9 million, and inlet mass-flow ratios from 0.39 to 1.58 depending on Mach number. Results of this investigation indicate that inlet pressure recovery generally decreased and inlet distortion generally increased with increasing Mach number. Except at low Mach numbers, increasing inlet mass-flow increased pressure recovery and increased distortion. Increasing the amount of boundary layer ingestion (by decreasing inlet throat height) or ingesting a boundary layer with a distorted (adverse) profile decreased pressure recovery and increased distortion. Finally, increasing Reynolds number had almost no effect on inlet distortion but increased inlet recovery by about one-half percent at a Mach number near cruise.

Berrier, Bobby L.

The locations and amounts of endogenous ions and elements in the cap and elongating zone of horizontally oriented roots of Zea mays L.: an electron-probe EDS study

We used quantitative electron-probe energy-dispersive x-ray microanalysis to localize endogenous Na, Cl, K, P, S, Mg and Ca in cryofixed and freeze-dried cryosections of the cap (i.e. the putative site of graviperception) and elongating zone (i.e. site of gravicurvature) of horizontally oriented roots of Zea mays. Ca, Na, Cl, K and Mg accumulate along the lower side of caps of horizontally oriented roots. The most dramatic asymmetries of these ions occur in the apoplast, especially the mucilage. We could not detect any significant differences in the concentrations of these ions in the central cytoplasm of columella cells along the upper and lower sides of caps of horizontally-oriented roots. However, the increased amounts of Na, Cl, K and Mg in the longitudinal walls of columella cells along the lower side of the cap suggest that these ions may move down through the columella tissue of horizontally-oriented roots. Ca also accumulates (largely in the mucilage) along the lower side of the elongating zone of horizontally-oriented roots, while Na, P, Cl and K tend to accumulate along the upper side of the elongating zone. Of these ions, only K increases in concentration in the cytoplasm and longitudinal walls of cortical cells in the upper vs lower sides of the elongating zone. These results indicate that (1) gravity-induced asymmetries of ions differ significantly in the cap and elongating zone of graviresponding roots, (2) Ca accumulates along the lower side of the cap and elongating zone of graviresponding roots, (3) increased growth of the upper side of the elongating zone of horizontally-oriented roots correlates positively with increased amounts of K in the cytoplasm and longitudinal walls of cortical cells, and (4) the apoplast (especially the mucilage) may be an important component of the pathway via which ions move in graviresponding rots of Zea mays. These results are discussed relative to mechanisms for graviperception and gravicurvature of roots.

NASA Program Space Biology

Direct Retrieval of Sulfur Dioxide Amount and Altitude from Spaceborne Hyperspectral UV Measurements: Theory and Application

We describe the physical processes by which a vertically localized absorber perturbs the top-of-atmosphere solar backscattered ultraviolet (UV) radiance. The distinct spectral responses to perturbations of an absorber in its column amount and layer altitude provide the basis for a practical satellite retrieval technique, the Extended Iterative Spectral Fitting (EISF) algorithm, for the simultaneous retrieval of these quantities of a SO2 plume. In addition, the EISF retrieval provides an improved UV aerosol index for quantifying the spectral contrast of apparent scene reflectance at the bottom of atmosphere bounded by the surface and/or cloud; hence it can be used for detection of the presence or absence of UV absorbing aerosols. We study the performance and characterize the uncertainties of the EISF algorithm using synthetic backscattered UV radiances, retrievals from which can be compared with those used in the simulation. Our findings indicate that the presence of aerosols (both absorbing and nonabsorbing) does not cause large errors in EISF retrievals under most observing conditions when they are located below the SO2 plume. The EISF retrievals assuming a homogeneous field of view can provide accurate column amounts for inhomogeneous scenes, but they always underestimate the plume altitudes. The EISF algorithm reduces systematic errors present in existing linear retrieval algorithms that use prescribed SO2 plume heights. Applying the EISF algorithm to Ozone Monitoring Instrument satellite observations of the recent Kasatochi volcanic eruption, we demonstrate the successful retrieval of effective plume altitude of volcanic SO2, and we also show the improvement in accuracy in the corresponding SO2 columns.

Yang, Kau

An Integrated 0-1 Hour First-Flash Lightning Nowcasting, Lightning Amount and Lightning Jump Warning Capability

Lightning one of the most dangerous weather-related phenomena, especially as many jobs and activities occur outdoors, presenting risk from a lightning strike. Cloud-to-ground (CG) lightning represents a considerable safety threat to people at airfields, marinas, and outdoor facilities-from airfield personnel, to people attending outdoor stadium events, on beaches and golf courses, to mariners, as well as emergency personnel. Holle et al. (2005) show that 90% of lightning deaths occurred outdoors, while 10% occurred indoors despite the perception of safety when inside buildings. Curran et al. (2000) found that nearly half of fatalities due to weather were related to convective weather in the 1992-1994 timeframe, with lightning causing a large component of the fatalities, in addition to tornadoes and flash flooding. Related to the aviation industry, CG lightning represents a considerable hazard to baggage-handlers, aircraft refuelers, food caterers, and emergency personnel, who all become exposed to the risk of being struck within short time periods while convective storm clouds develop. Airport safety protocols require that ramp operations be modified or discontinued when lightning is in the vicinity (typically 16 km), which becomes very costly and disruptive to flight operations. Therefore, much focus has been paid to nowcasting the first-time initiation and extent of lightning, both of CG and of any lightning (e.g, in-cloud, cloud-to-cloud). For this project three lightning nowcasting methodologies will be combined: (1) a GOESbased 0-1 hour lightning initiation (LI) product (Harris et al. 2010; Iskenderian et al. 2012), (2) a High Resolution Rapid Refresh (HRRR) lightning probability and forecasted lightning flash density product, such that a quantitative amount of lightning (QL) can be assigned to a location of expected LI, and (3) an algorithm that relates Pseudo-GLM data (Stano et al. 2012, 2014) to the so-called "lightning jump" (LJ) methodology (Shultz et al. 2011) to monitor lightning trends and to anticipate/forecast severe weather (hail > or =2.5 cm, winds > or =25 m/s, tornadoes). The result will be a time-continuous algorithm that uses GOES satellite, radar fields, and HRRR model fields to nowcast first-flash LI and QL, and subsequently monitors lightning trends on a perstorm basis within the LJ algorithm for possible severe weather occurrence out to > or =3 hours. The LI-QL-LJ product will also help prepare the operational forecast community for Geostationary Lightning Mapper (GLM) data expected in late 2015, as these data are monitored for ongoing convective storms. The LI-QL-LJ product will first predict where new lightning is highly probable using GOES imagery of developing cumulus clouds, followed by n analysis of NWS (dual-polarization) radar indicators (reflectivity at the -10 C altitude) of lightning occurrence, to increase confidence that LI is immanent. Once lightning is observed, time-continuous lightning mapping array and Pseudo-GLM observations will be analyzed to assess trends and the severe weather threat as identified by trends in lightning (i.e. LJs). Additionally, 5- and 15-min GOES imagery will then be evaluated on a per-storm basis for overshooting and other cloud-top features known to be associated with severe storms. For the processing framework, the GOES-R 0-1 hour convective initiation algorithm's output will be developed within the Warning Decision Support System - Integrated Information (WDSS-II) tracking tool, and merged with radar and lightning (LMA/Psuedo-GLM) datasets for active storms. The initial focus of system development will be over North Alabama for select lightning-active days in summer 2014, yet will be formed in an expandable manner. The lightning alert tool will also be developed in concert with National Weather Service (NWS) forecasters to meet their needs for real-time, accurate first-flash LI and timing, as well as anticipated lightning trends, amounts, continuation and cessation, so to provide key situational awareness and decision support information. The NASA Short-term Prediction Research and Transition (SPoRT) Center will provide important logistical and collaborative support and training, involving interactions with the NWS and broader user community.

Mecikalski, John

Ultra-Low Amounts of Transition Metals in Carbon-Based Catalysts Improve Their Alkaline OER Performance: A Systematic Study

The pursuit of green hydrogen production highlights a persistent gap in electrocatalyst research: while academic efforts prioritize cost-efficiency via activity enhancement, industrial viability demands greater emphasis on electrochemical stability. Carbon-based electrocatalysts, particularly those incorporating transition metals, have shown promise in alkaline oxygen evolution (OER) due to their high activity, cost-efficiency, and resource-efficiency. However, these catalysts suffer from insufficient stability under oxidizing conditions compared to pure transition metal catalysts due to erosion of the carbon support resulting from carbon corrosion, among other degradation mechanisms. In this systematic study, the influence of ultra-low amounts (<1 wt %) of iron, cobalt, nickel, and their most common combinations on the stability of a hydrothermally derived, N-doped carbon support and the overall catalyst performance during alkaline OER is systematically explored. By identifying critical stability descriptors and correlating them with synthesis conditions and catalyst properties, primary and secondary corrosion pathways are unraveled. Subsequently, through careful adjustment of carbonization temperature and composition of incorporated transition metals, overall catalyst corrosion can be suppressed immensely. Especially, the inclusion of Ni and Fe is paramount for the formation of stable catalyst materials under laboratory conditions (10 mA/cm 2 in 0.1 M KOH), which is surprisingly unconstrained by the degree of graphitization of the carbon support. Mixing this electrochemically stable material with a graphitic carbon powder results in an excellent stability of over 400 h at 100 mA/cm 2 in 1 M KOH, implying great potential for the future improvement of carbon-based electrodes under oxidizing conditions toward industrial application.

N-doped carbon

Biocrust Mosses and Cyanobacteria Exhibit Distinct Carbon Uptake Responses to Variations in Precipitation Amount and Frequency

ABSTRACT Dryland organisms exhibit varied responses to changes in precipitation, including event size, frequency, and soil moisture duration, influencing carbon uptake and reserve management strategies. This principle, central to the pulse‐reserve paradigm, has not been thoroughly evaluated in biological soil crusts (biocrusts), essential primary producers on dryland surfaces. We conducted two experiments to investigate carbon uptake in biocrusts under different precipitation regimes. In the first, we applied a gradient of watering amounts to biocrusts dominated by moss or cyanobacteria, hypothesising distinct pulse‐response strategies. The second experiment extended watering treatments over three months, varying pulse size and frequency. Our results revealed distinct carbon uptake patterns: moss crusts exhibited increased CO 2 uptake with larger, less frequent watering events, whereas cyanobacteria crusts maintained similar carbon uptake across all event sizes. These findings suggest divergent pulse‐response strategies across biocrust types, with implications for modelling dryland carbon dynamics and informing land management under changing precipitation regimes.

Young, Kristina E. [USDA‐ARS Jornada Experimental

Monitor senses amount of contamination deposited on surfaces

Monitoring device detects and indicates directly the amount of contamination deposited on a surface. It uses an optical system in conjunction with a reliable collimated light source and associated electronics. Change in its output signal is proportional to change in the optical absorption characteristics of the sample plate surface.

Sheehy, R. N.