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At least 37 records · Page 2

Glass particle resuspension from a contaminated (dirty) glass surface

A wealth of adhesion force measurements between a variety of particle/surface pairs have been gathered via Atomic Force Microscopy (AFM) in the past years. However, these measurements deal mostly with clean surfaces and particles for reproducibility. It is therefore up for debate whether particle resuspension could be calculated using these measurements as surrogates for real outdoor particles and surfaces, which often carry both organic and inorganic contaminants (“urban grime”). Two components are necessary to investigate this question: (1) adhesion force measurements on both clean and contaminated surfaces and (2) estimation of particle resuspension from both surface types. In this work, AFM was used to measure the distribution of the adhesion force between a 5-µm clean glass particle and two glass surfaces: the first cleaned according to conventional laboratory standards and a second one left outdoors for six weeks in Albuquerque (New Mexico). The Rock ‘n' Roll model was modified to use experimental adhesion force distributions of arbitrary shape and number of modes instead of a lognormal distribution, as in the original work Reeks & Hall (2001). The results of this analysis showed that the differences in the fraction of particles resuspended were small for a friction velocity of 0.5 m/s but increased for 1 and 2 m/s. For instance, for a friction velocity of 3 m/s, 71% of the original deposit was still on the surface after a day for the clean glass, while only 33% remained on the contaminated glass.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The Mechanical Performance of Subscale Candidate Elastomer Docking Seals

The National Aeronautics and Space Administration is developing a Low Impact Docking System (LIDS) for future exploration missions. The mechanism is a new state-of-the-art device for in-space assembly of structures and rendezvous of vehicles. At the interface between two pressurized modules, each with a version of the LIDS attached, a composite elastomer-metal seal assembly prevents the breathable air from escaping into the vacuum of space. Attached to the active LIDS, this seal mates against the passive LIDS during docking operation. The main interface seal assembly must exhibit low leak and outgas values, must be able to withstand various harsh space environments, must remain operational over a range of temperatures from -50 C to 75 C, and perform after numerous docking cycles. This paper presents results from a comprehensive study of the mechanical performance of four candidate subscale seal assembly designs at -50, 23, 50, and 75 C test temperatures. In particular, the force required to fully compress the seal during docking, and that which is required for separation during the undocking operation were measured. The height of subscale main interface seal bulbs, as well as the test temperature, were shown to have a significant effect on the forces the main interface seal of the LIDS may experience during docking and undocking operations. The average force values required to fully compress each of the seal assemblies were shown to increase with test temperature by approximately 50% from -50 to 75 C. Also, the required compression forces were shown to increase as the height of the seal bulb was increased. The seal design with the tallest elastomer seal bulb, which was 31% taller than that with the shortest bulb, required force values approximately 45% higher than those for the shortest bulb, independent of the test temperature. The force required to separate the seal was shown to increase with decreasing temperature after 15 hours of simulated docking. No adhesion force was observed at 75 C, while magnitudes of up to 235 lbf were recorded at the refrigerated temperature. In addition, the adhesion force was observed to increase with bulb height. When compared with the LIDS program requirements, the measured compression force values were found to be below the maximum allowable load allotted to the main interface seal. However, the measured adhesion force values at the refrigerated test temperature were found to exceed the program limits.

Bastrzyk, Marta B.↗

Measurement of Cohesion in Asteroid Regolith Materials

A study has been initiated to examine cohesive forces in asteroid materials to contribute to a better understanding of low density bodies such as asteroids and Phobos, and assist in exploration missions involving interaction with their surface material. The test specimen used in this study was a lightly weathered CM2 meteorite which is spectroscopically similar to Type C (carbonaceous) asteroids, and thought to have representative surface chemistry. To account for sample heterogeneity, adhesion forces were measured between the CM2 sample and its five primary mineral phase components. These adhesive forces bound the range of cohesive force that can be expected for the bulk material. All materials were characterized using a variety of optical and spectroscopic methods. Adhesive forces on the order of 50 to 400 μN were measured using a torsion balance in an ultrahigh vacuum chamber. The mineral samples exhibited clearly different adhesive strengths in the following hierarchy: Serpentine > Siderite > Bronzite > Olivine ≈ Fe-Ni.

Asteroids↗

Solution-derived monolithic thin films with low adhesion surface

Nanostructured thin films were synthesized using a silica-based sol-gel method. The morphology of the films was tailored by controlling the hydrolysis and crosslinking mechanisms of the tetraethyl orthosilicate precursor. Silica nanoparticle self-assembled structures and linear silica chains were crosslinked and formed monolithic nanostructured films. The self-assembly mechanism was investigated using coarse-grained molecular dynamic simulation. Three nanostructured configurations were synthesized and studied to optimize the surface features of the films and minimize the adhesion of sand particles. Surface microscopy imaging and adhesion force measurements using atomic force microscopy with an attached silica particle on the cantilever tip were performed to correlate the adhesion force and the surface structure. The solar specular reflectance of coated solar mirror samples was measured across the solar spectrum before and after the soiling test of the samples. The mechanical properties of the thin films were evaluated using nanoindentation measurements on coated substrates. Here, the solution-derived thin film coatings can provide anti-soiling protection of solar glass in desert environments and increase the efficiency of photovoltaic and concentrated solar power installations.

42 ENGINEERING↗

Adhesion of metals to a clean iron surface studied with LEED and Auger emission spectroscopy.

Discussion of the results of adhesion experiments conducted with various metals contacting a clean iron surface. The metals included gold, silver, nickel, platinum, lead, tantalum, aluminum, and cobalt. Some of the metals were examined with oxygen present on their surface as well as in the clean state. The results indicate that, with the various metals contacting iron, the cohesively weaker will adhere and transfer to the cohesively stronger. The chemical activity of the metal also influenced the adhesive forces measured. With oxygen present on the metal surface, the adhesive forces measured could be correlated with the binding energy of the metal to oxygen.

Buckley, D. H.↗

Measuring Work of Adhesion of Polystyrene Microspheres

Particle adhesion is relevant in fields ranging from aerospace and energy to civil engineering and medicine. The functions of aerodynamic surfaces, heat exchangers, solar panels, ventilation systems, and blood vessels are affected by the buildup of particulates on their surfaces. Direct measurement of the adhesive force between a particle and a surface is key to understanding and mitigating particle fouling. Approaches such as the Johnson-Kendall-Roberts (JKR) and Derjaguin-Muller-Toporov (DMT) models offer a first approximation of the forces involved but do not account for non-idealities like roughness or plastic deformation. Experimental measurements of adhesive forces often deviate significantly from predictions. One approach to measure adhesion is the colloidal probe technique, which uses a particle attached to the tip of an atomic force microscope (AFM) cantilever. The particle is touched to a surface and then withdrawn and a pull-off force (FPO) determined by cantilever deflection. FPO can be used to estimate work of adhesion (Wa) and other properties from existing models. We describe a new method for producing colloidal probes using wax as an adhesive to attach micrometer-scale spheres to AFM tips. This method can be used with a range of particles and minimizes the potential for changes to the particle surface chemistry or geometry from exposure to heat, chemicals, radiation, or external forces. Particle attachment to AFM tips is robust and reversible, allowing old particles to be replaced with new ones in a few minutes. Pull-off measurements using polystyrene (PS) particles, pristine and modified with myristyltrimethylammonium bromide (14-TAB), were collected from various substrates to demonstrate the viability of this technique and investigate the impact of particle surface modification.

Schmitz, Russell C.↗

Development of a Semi-autonomous Miniature Rover for Inspection of Double Shell Tank Floors - 19575

Leaks in the primary liner of double-shell tank (DST) 241-AY-102 at Hanford have prompted the need for the development of inspection tools that are able to access confined spaces around and underneath the tanks. Last year, Florida International University (FIU) has continued to improve inspection tools that were developed in the previous years, to ensure that the resultant tools are able to overcome the challenges posed by the DSTs. Experimental testing conducted last year at the full-scale sectional mock-up of the DST's refractory slots revealed some shortcomings of the miniature rover, particularly in traversing over weld seams of different heights. The weld seams are the results of welded steel plate-joints for the DST. It was advised by the site engineers that the weld seams height could range from 6.35 mm - 9.525 mm (1/4 to 3/8 inches), and with 12.7 mm (1/2 inches) width. As the rover traverses over a weld seam, the gap between the rover's magnets and tank surface increases, causing the adhesive force to drop. The rover loses its surface contact if this adhesive force drops below its weight, jeopardizing the inspection tasks. In this paper, we present the numerical studies to calculate the minimum magnetic force required for the miniature rover to traverse over weld seams with different heights and the corresponding modifications to the rover design. Initial bench scale tests were conducted using a steel bar with 5 welds of varying heights. The testing validated the results from the simulation studies and established the rover's capability in traversing weld seams. Another challenge for the miniature rover is the use of a joystick or keypad for manual control. Utilizing these controls will likely be difficult for the operators due to the tight channels underneath the tank. Having a semi-autonomous navigational capability would alleviate the complexity of the inspection tasks and allow the operator to focus on the channel inspection. The goal is to implement lane-keeping capability, akin to that of a driverless car, for the inspection tool, so that it will maintain its relative position with respect to the wall of the channels. Am image processing pipeline has been developed using both the Robot Operating System (ROS) and OpenCV to process the image stream coming from the onboard camera, for the purpose of lane identification. Additionally, a PID controller has been implemented to navigate the miniature rover along the central location of the detected lane, while allowing the operator to control the tool's forward and backward motion. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Measuring Adhesion And Friction Forces

Cavendish balance adapted to new purpose. Apparatus developed which measures forces of adhesion and friction between specimens of solid materials in vacuum at temperatures from ambient to 900 degrees C. Intended primarily for use in studying adhesion properties of ceramics and metals, including silicon carbide, aluminum oxide, and iron-base amorphous alloys.

Miyoshi, Kazuhisa↗

A study of electroactive polyvinyl chloride (PVC) gel actuators through the use of the electric modulus formalism and cyclic linear voltage sweeps

The conductivity and dielectric properties are integral to the function of polyvinyl chloride (PVC) gel actuators. The frequency-dependent properties of PVC gel actuators are investigated here in terms of their impedance, permittivity, and for the first time, electric modulus. The data shows that PVC gels’ conductive properties are just as, if not more, important as their dielectric properties in electromechanical transduction applications. The electrode polarization (EP) and its impact on the impedance and dielectric spectra of PVC gels, as well as the developed asymmetric space charge at the anode, are discussed. The electric modulus and tan δ spectra are used for the fitting of Cole-Cole (CC) and Debye relaxation models for gels of varying plasticizer content. The electrostatic adhesive force for PVC gels of varying plasticizer is also measured, indicating large electrostatic adhesion (>2 N cm -2 ). A cyclic linear voltage sweep is used to clarify the dynamics of space charge within the gels. The peak current (associated with space charge development) is seen to be concurrent with the onset of mechanical deformation, showing the asymmetric charge as the origin of electromechanical transduction. Additionally, the maximum charge transferred (as measured by the integration of current over time) before space charge development is found to correlate with the electrostatic adhesive force measured for the gels, pointing to a new method of characterizing PVC gels for actuation.

Instruments & Instrumentation↗

Development of a torsion balance for adhesion measurements

A new torsion balance for study of adhesion in ceramics is discussed. A torsion wire and a linear variable differential transformer are used to monitor load and to measure pull-off force (adhesion force). The investigation suggests that this torsion balance is valuable in studying the interfacial properties of ceramics in controlled environments such as in ultrahigh vacuum. The pull-off forces measured in dry, moist, and saturated nitrogen atmosphere demonstrate that the adhesion of silicon nitride contacts remains low at humidities below 80 percent but rises rapidly above that. The adhesion at saturation is 10 times or more greater than that below 80 percent relative humidity. The adhesion in a saturated atmosphere arises primarily from the surface tension effects of a thin film of water adsorbed on the surface. The surface tension of the water film was 58 x 10 to the minus 5 to 65 x 10 to the minus 5 power. The accepted value for water is 72.7 x 10 to the minus 5 power N/cm. Adhesion characteristics of silicon nitride in contact with metals, like the friction characteristics of silicon carbide to metal contacts, can be related to the relative chemical activity of metals in ultrahigh vacuum. The more active the metal, the higher the adhesion.

Miyoshi, Kazuhisa↗

A Study of the Attraction Forces of Lunar Dust Simulant

In previous manned lunar missions little work was done on countermeasures to combat the spread of lunar dust onto equipment and into the habitat because the astronauts were not scheduled to stay on the lunar surface for extended periods of time. However, as NASA prepares to return to the moon for longer durations than before developing materials that can help in the fight against lunar dust is important. The purpose of this project is to examine the attraction forces between lunar dust and various materials in an effort to discover materials which have a low affinity for lunar dust. The adhesion forces present between individual grains of dust and various materials were analyzed using an atomic force microscope (AFM). The AFM probes were calibrated by the added-mass technique to find the spring constant of the cantilever. The probes were modified by attaching a particle of lunar dust stimulant to the cantilever arm. The adhesion force between the dust particle and various materials were determined by analysis of AFM force spectra.

Bradley, Robert Kelley↗

Ductile adhesive elastomers with force-triggered ultra-high adhesion strength

Elastomers play a vital role in many forthcoming advanced technologies in which their adhesive properties determine materials’ interface performance. Despite great success in improving the adhesive properties of elastomers, permanent adhesives tend to stick to the surfaces prematurely or result in poor contact depending on the installation method. Thus, elastomers with on-demand adhesion that is not limited to being triggered by UV light or heat, which may not be practical for scenarios that do not allow an additional external source, provide a solution to various challenges in conventional adhesive elastomers. Herein, we report a novel, ready-to-use, ultra high-strength, ductile adhesive elastomer with an on-demand adhesion feature that can be easily triggered by a compression force. The precursor is mainly composed of a capsule-separated, two-component curing system. After a force-trigger and curing process, the ductile adhesive elastomer exhibits a peel strength and a lap shear strength of 1.2 × 10 4 N m -1 and 7.8 × 10 3 kPa, respectively, which exceed the reported values for advanced ductile adhesive elastomers. The ultra-high adhesion force is attributed to the excellent surface contact of the liquid-like precursor and to the high elastic modulus of the cured elastomer that is reinforced by a two-phase design. In conclusion, incorporation of such on-demand adhesion into an elastomer enables a controlled delay between installation and curing so that these can take place under their individual ideal conditions, effectively reducing the energy cost, preventing failures, and improving installation processes.

36 MATERIALS SCIENCE↗

The anti-soiling performance of highly reflective superhydrophobic nanoparticle-textured mirrors

In this paper, the anti-soiling (AS) performance of solar mirrors coated with a highly transparent, superhydrophobic nanoparticle-textured coating has been characterized. The AS coatings were created on the mirror surface by depositing nano-textured silica nanoparticle layers of ~250 nm thickness using a draw-down coating process, followed by fluorination of the nanoparticles in a molecular vapor deposition process. Highly uniform surface features of the AS-coated mirrors (20 × 30 cm 2 , no measurable loss in specular reflectance, and water contact angle >165°) provided an outstanding AS performance. A 4× reduction in the rate of dust accumulation as determined by gravimetric measurement of the accumulated dust on coated versus uncoated mirrors was observed. Additional evidence of a significant reduction in soiling rate was determined during measurements of specular reflectance in an outdoor environment test. The adhesion force between a model sand particle and nano-textured coatings in the hydrophobic to superhydrophobic range was also studied. A dramatic decrease in adhesive force acting on the particle was observed with increasing surface hydrophobicity. The results align well with the observed dust accumulation on the AS-coated mirrors. Finally, the AS-coated mirror maintains a high reflectivity by shedding dust and resisting dust accumulation, providing a potential benefit when applied to mirrors in the solar field of a concentrated solar power generation plant.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Evaluation of a Robust, In-Situ Surface Treatment for Pipeline Solids Deposition Mitigation in Flowing Systems

Abstract The formation/precipitation and deposition of pipeline solids, such as gas hydrates, asphaltenes, and waxes have long plagued production fields. Given the vast differences in chemistries of these solids, any current prevention or mitigation strategy, particularly for cases where multiple issues are a concern, is likely to involve an extensive assortment of undefined chemical additives that are both costly and add complexity to the system. Surface treatments (coatings), on the other hand, present a relatively new viable option for management strategies. A chemically and physically robust surface treatment with the ability to address deposition issues for multiple pipeline solids could not only decrease the operating expenditures for a field through material cost savings and obviation of downstream separation, but could also simplify produced fluids by eliminating additional chemicals from the mixture. The purpose of this study is to explore the feasibility of a particular surface treatment as part of a solids management strategy. This work utilizes an omniphobic surface treatment to probe its effects on gas hydrate, asphaltene, and wax deposition. Specifically, high pressure rocking cells are employed to study gas hydrate nucleation and deposition. A bench-scale flowloop filled with crude oil and heptane is used to quantify the deposition of crude oil and asphaltenes after a set time period. Lastly, a mechanical shear device measures the adhesion force of wax deposits on untreated/treated surfaces. The gas hydrate rocking cell tests demonstrate an increase in induction time and occasional elimination of hydrate nucleation with the surface treatment. Moreover, the same apparatus indicates that the critical shear to avoid hydrate deposition may be lowered in the presence of the surface treatment compared to untreated pristine carbon steel coupons. A custom-built asphaltene flowloop then establishes that this surface treatment is effective in dramatically reducing the deposition of the aliphatic components of a crude oil, with a moderate reduction in the asphaltene fraction. Finally, mechanical adhesion force measurements for solidified paraffin wax display trends in agreement with the asphaltene results. The surface treatment on both pristine and corroded surfaces is able to reduce the adhesion of wax deposits to values below a pristine, untreated surface.

03 NATURAL GAS↗

Performance of thermal adhesives in forced convection

Cooling is critical for the life and performance of electronic equipment. In most cases cooling may be achieved by natural convection but forced convection may be necessary for high wattage applications. Use of conventional type heat sinks may not be feasible from the viewpoint of specific applications and the costs involved. In a heat sink, fins can be attached to the well by ultrasonic welding, by soldering, or with a number of industrially available thermal adhesives. In this paper, the author investigates the heat transfer characteristics of several adhesives and compares them with ultrasonic welding and theoretically calculated values. This experiment was conducted in an air flow chamber. Heat was generated by using heaters mounted on the well. Thermstrate foil, Uniset A401, and Aremco 571 adhesives were tested along with an ultrasonically welded sample. Ultrasonic welding performed far better than the adhesives and Thermstrate foil. This type of experiment can be adapted for a laboratory exercise in an upper level heat transfer course. It gives students an exposure to industrial applications that help them appreciate the importance of the course material.

Kundu, Nikhil K.↗

Rational Design of a Multifunctional Binder for High-Capacity Silicon-Based Anodes

Although several principles have been recognized to fabricate a nominal "better" binder, there continues to be a lack of a rational design and synthesis approach that would meet the robust criteria required for silicon (Si) anodes. Herein, we report a synthetic polymer binder, i.e., catechol-functionalized chitosan cross-linked by glutaraldehyde (CS-CG+GA), that serves dual functionalities: (a) wetness-resistant adhesion capability via catechol grafting and (b) mechanical robustness via in situ formation of a three-dimensional (3D) network. A SiNP-based anode with a designed functional polymer network (CS-CG10%+6%GA) exhibits a capacity retention of 91.5% after 100 cycles (2144 +/- 14 mAh/g). Properties that are traditionally considered to be advantageous, including stronger adhesion strength and higher mechanical robustness, do not always improve the binder performance. A clear relationship between these properties and ultimate electrochemical performance is established by assessing the rheological behavior, mechanical property, adhesion force, peel stress, morphology evolution, and semiquantitative evaluation. This study provides a clear path for the rational design of high-performance functional polymer binders for not only Si-based electrodes but also other types of alloy and conversion-based electrodes.

Cao, Peng-Fei↗

Organotypic platform for studying cancer cell metastasis

Highlights: • Liver and brain slices can be stable, realistic in vitro 3D models. • Cell stiffness and adhesion to the tissue play determinant roles in cellular invasion in 3D. • MEK inhibitors can lead to increased cell stiffness and adhesion forces, and consequently reduced cancer cell invasion. • MDA-MB-231 breast cancer cells migrate faster and deeper into brain tissue compared to liver tissue. Metastasis is the leading cause of mortality in cancer patients. To migrate to distant sites, cancer cells would need to adapt their behaviour in response to different tissue environments. Thus, it is essential to study this process in models that can closely replicate the tumour microenvironment. Here, we evaluate the use of organotypic liver and brain slices to study cancer metastasis. Morphological and viability parameters of the slices were monitored daily over 3 days in culture to assess their stability as a realistic 3D tissue platform for in vitro metastatic assays. Using these slices, we evaluated the invasion of MDA-MB-231 breast cancer cells and of a subpopulation that was selected for increased motility. We show that the more aggressive invasion of the selected cells likely resulted not only from their lower stiffness, but also from their lower adhesion to the surrounding tissue. Different invasion patterns in the brain and liver slices were observed for both subpopulations. Cells migrated faster in the brain slices (with an amoeboid-like mode) compared to in the liver slices (where they migrated with mesenchymal or collective migration-like modes). Inhibition of the Ras/MAPK/ERK pathway increased cell stiffness and adhesion forces, which resulted in reduced invasiveness. These results illustrate the potential for organotypic tissue slices to more closely mimic in vivo conditions during cancer cell metastasis than most in vitro models.

60 APPLIED LIFE SCIENCES↗