Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “activity relationship”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

Extragalactic Radio Jets and Intergalactic Medium 2

During the mid 1990s, the ROSAT satellite provided the highest resolution X-ray imaging, with useful X-ray spectroscopy, and excellent sensitivity. ROSAT"s PSPC and HRI instruments gave us our first high-quality data on the AGN phenomenon in nearby galaxies - the central theme of this research project. Initially this project concentrated on separating the AGN-related component of the X-ray emission from thermal radiation from the surrounding atmospheres in radio galaxies. There was ample reason to believe that this separation would be possible, although earlier work had taken the view that the X-ray emission from radio galaxies is either wholly AGN-related (and hence of sub-arcsec scale), or wholly from the galaxy and cluster atmospheres (and hence of scales - 10 arcsec or more in the low-redshift radio galaxies that we chose to study). First with the PSPC, and then with the HRI, we proved that a wide range of AGN core X ray emissivities could be found, and that the generic radio galaxy produces both AGN-related and atmosphere-related X-radiation. We demonstrated that there is a close relationship between the core X-ray power and the core radio power, and found instances in which the hot atmospheres of the galaxies must be participating in cooling flows, and other cases where those atmospheres are relatively stable. In some cases, there is a clear active relationship between the extended radio emission and the X-ray atmospheres: thus in NGC 326, we interpret the distorted radio structure as evidence of buoyancy as the radio plasma rises through the cluster atmosphere. In 3C 449, we can see that the radio plasma is displacing the X-ray emitting gas. In a further case (NGC 1265), we hoped that the motion of a radio galaxy through a cluster atmosphere would be apparent though the wake that it might establish - unfortunately, other structure in the atmosphere of the Perseus cluster tends to dominate our X-ray image, and no useful limits could be placed on the strength of the wake. In the light of so-called "unified" models of AGN, it is expected that the low-power radio galaxies studied under these programmes are the unbeamed counterparts of BL Lac objects. Accordingly, we predicted that BL Lac objects, as a class, should show X-ray halos from atmospheres similar to those associated with radio galaxies. The difficulty with studying this is that BL Lac objects tend to be X-ray bright, and the halos then vanish under the wings of the point response function. We found a BL Lac with less of a dynamic range problem, mapped it with the ROSAT HRI, and duly found an atmosphere (Hardcastle et al. 1999). Unfortunately for unification models, this atmosphere is exceptionally dense, so that it must be participating in an intense cooling flow. The implications of this for unification models are far from clear, and further work is under way.

Birkinshaw, Mark↗

IUE and Einstein survey of late-type giant and supergiant stars and the dividing line

Results are presented on an IUE UV survey of 255 late-type G, K, and M stars, complementing the Maggio et al. (1990) Einstein X-ray survey of 380 late-type stars. The large data sample of X-ray and UV detections make it possible to examine the activity relationship between the X-ray and the UV emissions. The results confirm previous finding of a trend involving a steeply-dropping upper envelope of the transition region line fluxes, f(line)/f(V), as the dividing line is approached. This suggests that a sharp decrease in maximum activity accompanies the advancing spectral type, with the dividing line corresponding to this steep gradient region. The results confirm the rotation-activity connection for stars in this region of the H-R diagram.

Haisch, Bernhard M.↗

Development and Application of Computational/In Vitro Toxicological Methods for Chemical Hazard Risk Reduction of New Materials for Advanced Weapon Systems

The development of quantitative structure-activity relationship (QSAR) is essential for reducing the chemical hazards of new weapon systems. The current collaboration between HEST (toxicology research and testing), MLPJ (computational chemistry) and PRS (computational chemistry, new propellant synthesis) is focusing R&D efforts on basic research goals that will rapidly transition to useful products for propellant development. Computational methods are being investigated that will assist in forecasting cellular toxicological end-points. Models developed from these chemical structure-toxicity relationships are useful for the prediction of the toxicological endpoints of new related compounds. Research is focusing on the evaluation tools to be used for the discovery of such relationships and the development of models of the mechanisms of action. Combinations of computational chemistry techniques, in vitro toxicity methods, and statistical correlations, will be employed to develop and explore potential predictive relationships; results for series of molecular systems that demonstrate the viability of this approach are reported. A number of hydrazine salts have been synthesized for evaluation. Computational chemistry methods are being used to elucidate the mechanism of action of these salts. Toxicity endpoints such as viability (LDH) and changes in enzyme activity (glutahoione peroxidase and catalase) are being experimentally measured as indicators of cellular damage. Extrapolation from computational/in vitro studies to human toxicity, is the ultimate goal. The product of this program will be a predictive tool to assist in the development of new, less toxic propellants.

Frazier, John M.↗

NASA Langley Research Center outreach in astronautical education

The Langley Research Center has traditionally maintained an active relationship with the academic community, especially at the graduate level, to promote the Center's research program and to make graduate education available to its staff. Two new institutes at the Center - the Joint Institute for Acoustics and Flight Sciences, and the Institute for Computer Applications - are discussed. Both provide for research activity at the Center by university faculties. The American Society of Engineering Education Summer Faculty Fellowship Program and the NASA-NRC Postdoctoral Resident Research Associateship Program are also discussed.

Duberg, J. E.↗

Possible relationships between solar activity and meteorological phenomena

A symposium was conducted in which the following questions were discussed: (1) the evidence concerning possible relationships between solar activity and meteorological phenomena; (2) plausible physical mechanisms to explain these relationships; and (3) kinds of critical measurements needed to determine the nature of solar/meteorological relationships and/or the mechanisms to explain them, and which of these measurements can be accomplished best from space.

Bandeen, W. R.↗

Microorganisms, Organic Carbon, and Their Relationship with Oxidant Activity in Hyper-Arid Mars-Like Soils: Implications for Soil Habitability

Soil samples from the hyper-arid region in the Atacama 23 Desert in Southern Peru (La Joya Desert) were analyzed for total and labile organic carbon (TOC & LOC), phospholipid fatty acids analysis (PLFA), quantitative real time polymerase chain reaction (qRT-PCR), 4',6- diamidino-2-phenylindole (DAPI)-fluorescent microscopy, culturable microorganisms, and oxidant activity, in order to understand the relationship between the presence of organic matter and microorganisms in these types of soils. TOC content levels were similar to the labile pool of carbon suggesting the absence of recalcitrant carbon in these soils. The range of LOC was from 2 to 60 micro-g/g of soil. PLFA analysis indicated a maximum of 2.3 x 10(exp 5) cell equivalents/g. Culturing of soil extracts yielded 1.1 x 10(exp 2)-3.7 x 10(exp 3) CFU/g. qRT-PCR showed between 1.0 x 10(exp 2) and 8 x 10(exp 3) cells/g; and DAPI fluorescent staining indicated bacteria counts up to 5 x 104 cells/g. Arid and semiarid samples (controls) showed values between 10(exp 7) and 10(exp 11) cells/g with all of the methods used. Importantly, the concentration of microorganisms in hyper-arid soils did not show any correlation with the organic carbon content; however, there was a significant dependence on the oxidant activity present in these soil samples evaluated as the capacity to decompose sodium formate in 10 hours. We suggest that the analysis of oxidant activity could be a useful indicator of the microbial habitability in hyper-arid soils, obviating the need to measure water activity over time. This approach could be useful in astrobiological studies on other worlds.

Mars-like soils↗

27-day recurrence and long term modulation of cosmic ray intensity.

Previous work by Balasubrahmanyan and Venkatesan (1970) on the general problem of the solar activity relationship with the 27-day recurrence and long term modulation of cosmic ray intensity, and Lockwood's (1971) comments thereon are discussed in the light of some further work. A possible explanation proposed for the absence of any time lag in both short and long term cosmic ray intensity changes views the long term variation as a result of a superposition of a number of short term decreases.

Balasubrahmanyan, V. K.↗

The moisture budget in relation to convection

An evaluation of the moisture budget in the environment of convective storms is presented by using the unique 3- to 6-h rawinsonde data. Net horizontal and vertical boundary fluxes accounted for most of the large amounts of moisture which were concentrated into convective regions associated with two squall lines that moved through the area during the experiment. The largest values of moisture accumulations were located slightly downwind of the most intense convective activity. Relationships between computed moisture quantities of the moisture budget and radar-observed convection improved when lagging the radar data by 3 h. The residual of moisture which represents all sources and sinks of moisture in the budget equation was largely accounted for by measurements of precipitation.

Scott, R. W.↗

The MINE project: Minority Involvement in NASA Engineering

The Mine Project developed by Lewis Research Center (LRC) along with Tennessee State University and Tuskegee Institute, is described. The project calls for LRC to assemble on-going NASA university affairs programs aimed at benefiting the school, its faculty, and its student body. The schools receive grants to pursue research and technology projects that are relevant to NASA's missions. Upon request from the universities, LRC furnishes instructors and lecturers. The schools have use of surplus government equipment and access to NASA research facilities for certain projects. Both the faculty and students of the universities are eligible for summer employment at LRC through special programs. The MINE Project is designed to establish a continuing active relationship of 3 to 5 years between NASA and the universities, and will afford LRC with an opportunity to increase its recruitment of minority and women employees.

Allen, H., Jr.↗

Structure-activity correlations for organophosphorus ester anticholinesterases. Part 2: CNDO/2 calculations applied to ester hydrolysis rates

Quantitative structure-activity relationships are presented for the hydrolysis of organophosphorus esters, RR'P(O)X, where R and R' are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. CNDO/2 calculations provide values for molecular parameters that correlate with alkaline hydrolysis rates. For each subset of esters with the same leaving group, X, the CNDO-derived net atomic charge at the central phosphorus atom correlates well with the alkaline hydrolysis rate constants. For the whole set of esters with different leaving groups, equations are derived that relate charge, orbital energy and bond order to the hydrolysis rate constants.

Johnson, H.↗

The X-ray spectra and the rotation-activity connection of RS CVN binaries

Results from a survey of RS CVn binaries which were observed with the Imaging Proportional Counter (IPC) on board the Einstein Observatory are presented. Spectral analyses of the IPC pulse height spectra show that the coronae of RS CVn binaries always contain hot gas with temperatures 10 million K, similar to active late-type main sequence stars, and that at least 2 temperature components are necessary to account for the higher quality IPC spectra (when absorption is unimportant). It is argued that these bimodal temperature distributions indicate true distributions of emission measure vs temperature that are continuous (just as is the case for magnetically-confined coronal plasma loops observed on the Sun). It is shown that none of the derivable X-ray characteristics of RS CVn binaries depend on rotation period, implying that claims of period-activity relationships in RS CVn binaries are unfounded.

Majer, P.↗

X-ray spectra and the rotation-activity connection of RS Canum Venaticorum binaries

Results are presented from a survey of RS CVn binaries which were observed with the imaging proportional counter (IPC) on board the Einstein Observatory. Spectral analyses of the IPC pulse height spectra show that the coronae of RS CVn binaries always contain hot gas with temperatures in excess of 10 to the 7th K, similar to active late-type main-sequence stars, and that at least two temperature components are necessary to account for the higher quality IPC spectra (when absorption is unimportant). It is argued that these bimodal temperature distributions found by the IPC are indicative of true distributions of emission measure versus temperature that are continuous (just as is the case of magnetically confined coronal plasma loops observed on the sun). It is further shown that none of the derivable X-ray characteristics of RS CVn binaries depend on rotation period, implying that previous claims of period-activity relationships in RS CVn binaries were unfounded.

Majer, P.↗

QSAR for cholinesterase inhibition by organophosphorus esters and CNDO/2 calculations for organophosphorus ester hydrolysis

Quantitative structure-activity relationships were derived for acetyl- and butyrylcholinesterase inhibition by various organophosphorus esters. Bimolecular inhibition rate constants correlate well with hydrophobic substituent constants, and with the presence or absence of catonic groups on the inhibitor, but not with steric substituent constants. CNDO/2 calculations were performed on a separate set of organophosphorus esters, RR'P(O)X, where R and R' are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. For each subset with the same X, the CNDO-derived net atomic charge at the central phosphorus atom in the ester correlates well with the alkaline hydrolysis rate constant. For the whole set of esters with different X, two equations were derived that relate either charge and leaving group steric bulk, or orbital energy and bond order to the hydrogen hydrolysis rate constant.

Johnson, H.↗

QSAR for cholinesterase inhibition by organophosphorus esters and CNDO/2 calculations for organophosphorus ester hydrolysis

Quantitative structure-activity relationships were derived for acetyl- and butyrylcholinesterase inhibition by various organophosphorus esters. Bimolecular inhibition rate constants correlate well with hydrophobic substituent constants, and with the presence or absence of cationic groups on the inhibitor, but not with steric substituent constants. CNDO/2 calculations were performed on a separate set of organophosphorus esters, RR-primeP(O)X, where R and R-prime are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. For each subset with the same X, the CNDO-derived net atomic charge at the central phosphorus atom in the ester correlates well with the alkaline hydrolysis rate constant. For the whole set of esters with different X, two equations were derived that relate either charge and leaving group steric bulk, or orbital energy and bond order to the hydrolysis rate constant.

Johnson, H.↗

Statistical properties of magnetic field fluctuations in the distant plasmasheet

Short (less than 1 min) and long time (greater than 5 min) variations of the plasmasheet magnetic field have been examined during all intervals when ISEE-3 was at distances x less than -200 earth radii. It is determined that short period magnetic turbulence increases by a factor of about 3 with increasing geomagnetic activity, as indicated by AE. In contrast, long period field variations with North-then-South signatures at plasmasheet entry occur about 2.5 times more frequently than South-then-North signatures. This result, combined with other previous ISEE-3 results, is in agreement with the interpretation that the North-South plasmasheet features are plasmoids propagating tailward. However, a statistical examination of the geomagnetic activity relationship indicates that there does not appear to be any substorm dependence on these North-South events.

Tsurutani, Bruce T.↗

Catalytic methods using molecular oxygen for treatment of PMMS and ECLSS waste streams, volume 2

Catalytic oxidation has proven to be an effective addition to the baseline sorption, ion exchange water reclamation technology which will be used on Space Station Freedom (SSF). Low molecular weight, polar organics such as alcohols, aldehydes, ketones, amides, and thiocarbamides which are poorly removed by the baseline multifiltration (MF) technology can be oxidized to carbon dioxide at low temperature (121 C). The catalytic oxidation process by itself can reduce the Total Organic Carbon (TOC) to below 500 ppb for solutions designed to model these waste waters. Individual challenges by selected contaminants have shown only moderate selectivity towards particular organic species. The combined technology is applicable to the more complex waste water generated in the Process Materials Management System (PMMS) and Environmental Control and Life Support System (ECLSS) aboard SSF. During the phase 3 Core Module Integrated Facility (CMIF) water recovery tests at NASA MSFC, real hygiene waste water and humidity condensate were processed to meet potable specifications by the combined technology. A kinetic study of catalytic oxidation demonstrates that the Langmuir-Hinshelwood rate equation for heterogeneous catalysts accurately represent the kinetic behavior. From this relationship, activation energy and rate constants for acetone were determined.

Akse, James R.↗

Scope and Abstraction: Two Criteria for Localized Planning

Localization is a general-purpose representational technique for partitioning problem requirements into subproblems. Localized search utilizes a partitioning by breaking the overall search space into several smaller search spaces, one for each subproblem. Unlike most methods of partitioning, localization allows for subproblems that overlap -- i.e., multiple search spaces may be involved in constructing shared pieces of the overall plan. In this paper we focus on two criteria for forming localizations: abstraction and scope. Abstraction-based localizations are motivated by activation relationships between problem requirements. In contrast, scope-based localizations are motivated by the relevance of problem requirements to specific portions of the overall plan. This paper also describes a method for automatically generating scope and abstraction-based localizations. Empirical results are provided that contrast their use in an office-building construction planning domain.

Lansky, Amy L.↗