Active sites and roles of solid acid base catalysts
A review on both acid and base catalyst with 42 references is presented. Isomerization of butene, H2-D2 exchange reaction, and hydrogenation reactions are discussed.
Iizuka, T.↗
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Results for “active solids”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Tetravalent Chromium (Cr(4+)) as Laser-Active Ion for Tunable Solid-State Lasers
During 10/31/91 - 3/31/92, the following summarizes are major accomplishments: (1) numerical modeling of the four mirror astigmatically compensated, Z-fold cavity was performed; and (2) the simulation revealed several design parameters to be used for the construction of a femtosecond forsterite laser.
Seas, A.↗
Tetravalent Chromium (Cr(4+)) as Laser-Active Ion for Tunable Solid-State Lasers
During 10/31/92 - 3/31/93, the following summarizes our major accomplishments: (1) the self-mode-locked operation of the Cr:forsterite laser was achieved; (2) synchronous pumping was used to mode lock the forsterite laser resulting in picosecond pulses, which in turn provided the starting mechanism for self-mode-locking; and (3) the pulses generated had a FWHW of 105 fs and were tunable between 1230 - 1270 nm.
Seas, A.↗
The Plausibility of Boiling Geysers on Triton
A mechanism is suggested and modeled whereby there may be boiling geysers on Triton. The geysers would be of nitrogen considering that Voyager detected cryovolcanic activity, that solid nitrogen conducts heat much less than water ice, and that there is internal heat on Triton.
Triton planetary geology geysers↗
Micro-Fabricated Solid-State Radiation Detectors for Active Personal Dosimetry
Active radiation dosimetry is important to human health and equipment functionality for space applications outside the protective environment of a space station or vehicle. This is especially true for long duration missions to the moon, where the lack of a magnetic field offers no protection from space radiation to those on extravehicular activities. In order to improve functionality, durability and reliability of radiation dosimeters for future NASA lunar missions, single crystal silicon carbide devices and scintillating fiber detectors are currently being investigated for applications in advanced extravehicular systems. For many years, NASA Glenn Research Center has led significant efforts in silicon carbide semiconductor technology research and instrumentation research for sensor applications under extreme conditions. This report summarizes the technical progress and accomplishments toward characterization of radiation-sensing components for the recommendation of their fitness for advanced dosimetry development.
Wrbanek, John D.↗
Partitioning of transition metals between diopside and coexisting silicate liquids. I - Nickel, cobalt, and manganese
Distribution coefficients have been found for the partitioning of Ni, Co, and Mn between calcium-rich clinopyroxenes and coexisting silicate liquids. Values are found for the 1110-1360 C temperature range. The breakdown of Henry's Law was not observed. The measured clinopyroxene/liquid distribution coefficients ranged from 1.5-14.0 for Ni, 0.5-2.0 for Co, and 0.3-1.2 for Mn. Analyses of pyroxenes grown from charges differing in the amounts of transition metals indicate that Ni and Co occupy the M1 site of diopside and that Mn occupies the M1 and M2 sites. Equilibrium constants were found in terms of the activities of the components in the liquid and solid phases. These activities are based on the mole fractions. An activity/concentration model was used for the liquid phase in order to explain the variations in the clinopyroxene/liquid coefficients due to bulk composition.
Lindstrom, D. J.↗
Activities and phase boundaries in the Cr-Ni system using a solid electrolyte technique
Cr-Ni system activities and phase boundaries determined by solid electrolyte technique
Fitterer, G. R.↗
Carbon wastewater treatment process
A new powdered-carbon treatment process is being developed for the elimination of the present problems, associated with the disposal of biologically active sewage waste solids, and with water reuse. This counter-current flow process produces an activated carbon, which is obtained from the pyrolysis of the sewage solids, and utilizes this material to remove the adulterating materials from the water. Additional advantages of the process are the elimination of odors, the removal of heavy metals, and the potential for energy conservation.
Humphrey, M. F.↗
Toward Full Active Material Utilization in All-Solid-State Lithium-Sulfur Batteries with Sulfide Electrolytes
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solid state batteries↗
Solid State Drive Radiation Assurance With Active Testing
Automotive and industrial grade SSDs were tested for TID and SEE response at the assembly level to investigate radiation tolerance trends and explore radiation hardness assurance best practices in commercial memory devices. SSDs were installed in passive NVMe extenders to place only the drive in the beam line. A digital I/O module connected to the test computer provided inhibit signals to block both facility beam delivery and power while attempting recovery from any device failure conditions (e.g., failed write, failed read, or unresponsive device).
Edward P Wilcox↗
Analysis of solid-rocket effluents for aluminum, silicon, and other trace elements by neutron activation analysis
The sensitivity and reliability of neutron activation analysis in detecting trace elements in solid rocket effluents are discussed. Special attention was given to Al and Si contaminants. The construction and performance of a thermal column irradiation unit was reported.
Furr, A. K.↗
Free energy of formation of Mo2C and the thermodynamic properties of carbon in solid molybdenum
As part of a study of the thermodynamical properties of interstitial elements in refractory metals, the free energy of formation of Mo2C is determined, and the thermodynamical properties of C in solution in solid Mo evaluated. The activity of C in the two-phase region Mo + Mo2C is obtained from the C content of iron rods equilibrated with metal + carbide powder mixtures. The free energy of formation of alpha-Mo2C is determined from the activity data. The thermodynamic properties of C in the terminal solid solution are calculated from available data on the solid solubility of C in Mo. Lattice distortion due to misfit of the C atoms in the interstitial sites appears to play a significant role in determining the thermodynamic properties of C in solid Mo.
Seigle, L. L.↗
Heterogeneous reactions with NaCl in the El Chichon volcanic aerosols
Previous investigations of the effects of the 1982 eruption of the El Chichon volcano could not explain all the observations of changes in O3, HCl, NO and NO2 simultaneously without proposing unproven chemical reactions. Since reactions between solid NaCl and gaseous ClNO3 and N2O5 rapidly produce photochemically active chlorine species and solid NaNO3 in laboratory experiments, it is suggested that these reactions could have occurred with the NaCl observed to be present in the El Chichon sulfuric acid areosols. As a consequence, it is predicted that HCl should increase substantially, while NO(x) should decrease, in agreement with the measurements after the eruption. Ozone should be only slightly affected by these reactions. Reactions between solid NaCl and the acids H2SO4 and HNO3 might prove to be important, but sufficient evidence regarding their efficiency and the pressure of HNO3 in the aerosols is lacking.
Michelangeli, Diane V.↗
The University of Chicago cosmic ray electrons and nuclei experiment on the H spacecraft
The University of Chicago instrument on the Heliocentric spacecraft (MEH experiment) will measure the energy spectrum of cosmic electrons in the range 5-400 MeV. In addition, the energy spectra and relative abundances of nuclei from protons to the iron group, with energies ranging from 30 MeV/n to 15 GeV/n, will be determined. Primary scientific objectives involve the study of the long and short term variability of these components as a probe of the structure of the heliosphere. Particles are identified by multiparameter analysis using the pulse height analyzed signals from eight active detectors - silicon solid state, plastic and crystal scintillators are solid and gas Cerenkov counters. Data return is optimized by a three level priority logic scheme.
Meyer, P.↗
An idealized model of homogeneous solid propellant combustion
The idealization of solid propellant combustion which consists of a single condensed-phase reaction and a single gas-phase reaction is discussed. A limiting-case solution to the gas-phase conservation equations is developed and tested by comparison with transformed thermocouple data. Closed-form expressions are derived for the burning rate and temperature sensitivity. Both quantities are linked explicitly to the solid and gas activation energies. It is concluded that the combustion phenomenology associated with the above idealization is still not fully understood. It is suggested that a careful study of the various limiting-case solutions tempered by a small set of numerical benchmark calculations might further such understanding.
Miller, M. S.↗
Advanced 3-V semiconductor technology assessment
Components required for extensions of currently planned space communications systems are discussed for large antennas, crosslink systems, single sideband systems, Aerostat systems, and digital signal processing. Systems using advanced modulation concepts and new concepts in communications satellites are included. The current status and trends in materials technology are examined with emphasis on bulk growth of semi-insulating GaAs and InP, epitaxial growth, and ion implantation. Microwave solid state discrete active devices, multigigabit rate GaAs digital integrated circuits, microwave integrated circuits, and the exploratory development of GaInAs devices, heterojunction devices, and quasi-ballistic devices is considered. Competing technologies such as RF power generation, filter structures, and microwave circuit fabrication are discussed. The fundamental limits of semiconductor devices and problems in implementation are explored.
Nowogrodzki, M.↗
Sensors research and technology
Information on sensors research and technology is given in viewgraph form. Information is given on sensing techniques for space science, passive remote sensing techniques and applications, submillimeter coherent sensing, submillimeter mixers and local oscillator sources, non-coherent sensors, active remote sensing, solid state laser development, a low vibration cooler, separation of liquid helium and vapor phase in zero gravity, and future plans.
Cutts, James A.↗
Modeling the effect of water on mantle rheology
To study the thermal history of the Earth we use a parameterized model of mantle convection. This model includes a mathematical description of de- and regassing processes of water from the Earth's mantle. The rates of this processes are considered to be directly proportional to the seafloor spreading rate. The kinematic viscosity of the mantle depends on the temperature/pressure as well as on the volatile content. Dissolved volatiles such as water weaken the minerals by reducing their activation energy for solid state creep. Karato and Toriumi showed a power law dependence between creep rate and water fugacity derived from experimental results. Therefore, we use such flow parameters of diffusion creep in olivine under wet and dry conditions to calculate the mantle viscosity as a function of the water content. Because the creep rate is proportional to the concentration of water-related point deflects we assume that the water fugacity is proportional to the water weight fraction. An equation for the steady-state strain rate under wet conditions is established. To assess the unknown constant K in this equation, we use flow law parameters given by Karato and Wu as well as the results of McGovern and Schubert.
Bounama, CH.↗