Discovery of a 〈2 1 0〉-fiber texture in medical-grade metastable beta titanium wire
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Directed energy deposition (DED) with a coaxial wire-laser configuration has gained significant attention in recent years for the production of large-scale metallic components because of its low directional dependence, fast deposition rate, high feedstock efficiency, and low manufacturing costs. This work studies the coaxial wire-laser DED process of Inconel 718 alloy under a stable deposition condition with a relatively low input volumetric energy density (55.5J/mm 3 ). Post characterization reveals a cluster of refined grains at the center-bottom region of the as-printed track. Operando high-energy synchrotron X-ray experiments and multi-physics modeling are applied innovatively to study the fundamental mechanism responsible for the formation of this microstructure. The X-ray diffraction experiment provides direct evidence, which is supported by the simulation, that the feeding wire can reach the melt pool bottom and release solid particles (primarily carbides) near the mushy zone owing to insufficient melting. Consequently, these sub-micron sized particles suppress the growth of large columnar grains and cause the formation of unique microstructural heterogeneity. In conclusion, this discovery offers new opportunities for tailoring the solidification microstructure by controlling the melting state of the feedstock wire in DED process, in addition to commonly known factors such as the thermal gradient and solidification velocity.
Imploding wire arrays on the 20 MA Z generator have recently provided some of the most powerful and energetic laboratory sources of multi-keV photons, including ∼375 kJ of Al K-shell emission (hν ∼ 1–2 keV), ∼80 kJ of stainless steel K-shell emission (hν ∼ 5–9 keV) and a kJ-level of Mo K-shell emission (hν ∼ 17 keV). While the global implosion dynamics of these different wire arrays are very similar, the physical process that dominates the emission from these x-ray sources fall into three broad categories. Al wire arrays produce a column of plasma with densities up to ∼3 × 10{sup 21} ions/cm{sup 3}, where opacity inhibits the escape of K-shell photons. Significant structure from instabilities can reduce the density and increase the surface area, therefore increase the K-shell emission. In contrast, stainless steel wire arrays operate in a regime where achieving a high pinch temperature (achieved by thermalizing a high implosion kinetic energy) is critical and, while opacity is present, it has less impact on the pinch emissivity. At higher photon energies, line emission associated with inner shell ionization due to energetic electrons becomes important.
Copper-carbon composites are a group of materials with excellent mechanical, electrical, thermal, and tribological properties. However, bulk size copper-carbon composites made by the traditional manufacturing processes, like rolling or extrusion, fall short of reaching some of these properties predicted by theory or demonstrated only by samples at centimeter scale or smaller. The two main challenges to the successful scaling-up are: 1) to uniformly disperse carbon in the metal matrix; 2) to avoid degradation due to oxidation or reaction from overheating. In this work, we first demonstrate friction extrusion as a new method to make bulk-size void-free copper-carbon composite wires with homogenized carbon dispersion. Three different carbon varieties, graphite powder, graphene nanopowder, and carbon nanotubes, were added to the copper matrix with the concentration ranging from 0.5 wt% to 15 wt%. Special tooling, processing parameters, and procedures were developed, especially for high carbon content samples. Ten-fold reductions of both copper grain size and carbon particle size were achieved and attributed to the high shear deformation. Energy dispersive X-ray spectrometry indicates the carbon powder was refined to a sub-micron level and uniformly dispersed in the copper matrix. Compared with that of pure copper, the thermal capacity of the composite wire increases by 30 % while density reduces by 29 %.
The term photonic wire laser is now widely used for lasers with transverse dimensions much smaller than the wavelength. As a result, a large fraction of the mode propagates outside the solid core. In this paper, we propose and demonstrate a scheme to form a coupled cavity by taking advantage of this unique feature of photonic wire lasers. In this scheme, we used quantum cascade lasers with antenna-coupled third-order distributed feedback grating as the platform. Inspired by the chemistry of hybridization, our scheme phase-locks multiple such lasers by π coupling. With the coupled-cavity laser, we demonstrated several performance metrics that are important for various applications in sensing and imaging: a continuous electrical tuning of ~10 GHz at ~3.8 THz (fractional tuning of ~0.26%), a good level of output power (~50–90 mW of continuous-wave power) and tight beam patterns (~10 0 of beam divergence).
The NASA MMS Spin Plane Double Probe (SDP) Deployer utilizes a helical path, rotating Metering Wheel and a spring loaded Wire "Holding" Track to pay out a "fixed end" 57 meter x 1.5 mm diameter Wire Boom stored between concentric storage cylinders. Unlike rotating spool type storage devices, the storage cylinders remain stationary, and the boom wire is uncoiled along the length of the cylinder via the rotation of the Metering Wheel. This uncoiling action avoids the need for slip-ring contacts since the ends of the wire can remain stationary. Conventional fixed electrical connectors (Micro-D type) are used to terminate to operational electronics.
Here, the present work investigates the effect of process parameters on the geometry of wire arc additive manufactured parts. The geometric accuracy of features produced with a weaving strategy is compared to what can be accomplished with a typical overlapping bead strategy. In this work, single-layer and multi-layer geometries were deposited under varying process and path parameters. The wavelength, amplitude, and torch speed of the weaving path were varied, while the power, wire feed speed, and contact tip to work distance remained constant. The geometric deposition efficiencies of several samples produced with a weave strategy are directly compared to samples generated with two parallel overlapping beads with torch speeds defined to match the deposition rate of the weave samples. Feature geometries were characterized using optical microscopy and laser scanning data. The results indicate that implementing a weave path strategy can improve the geometric accuracy of wire arc additive features, thus increasing the effective volumetric deposition rate of the process. It is shown that the most consistent improvements resulted from the combination of low wavelength and high amplitude, which correlate to wider and taller printed layers.
Development of a new type of vibrating wire monitor (VWM), which has two mechanically coupled wires (vibrating and target), is presented. The new monitor has a much larger aperture size than the previous model of the VWM, and thus allows us to measure transverse beam halos more effectively. A prototype of such a large aperture VWM with a target wire length of 60 mm was designed, manufactured, and bench-tested. Initial beam measurements have been performed at the Fermilab High Intensity Neutrino Source facility, and key results are presented.
Californium-252 (Cf-252) has been synthesized on a large scale (mg) since the 1970s for use as a portable neutron source. With a half-life of 2.645 years and a spontaneous fission fraction of 3.09%, Cf-252 emits 2.31 × 10 12 neutrons/gram second. Today most of the Cf-252 produced in the world is made at Oak Ridge National Laboratory (ORNL) using the High Flux Isotope Reactor (HFIR) and the Radiochemical Engineering Development Center (REDC). Because of its highly radioactive nature, all manipulations of Cf-252 need to be performed in hot cell facilities by highly trained personnel. The Cf-252 produced at ORNL is done at the REDC, which is conveniently located next to the HFIR. Cf-252 is sold as bulk wire, which has been described as palladium (Pd) metal incasing californium oxide (Cf 2 O 3 ). The process was developed by Mosley et al. at Savannah River Laboratory (SRL) where it was modeled after the thorium work done by Fuschillo et al. This process has been used since the 1970s to synthesize this unique wire, but its fundamental chemistry and materials characteristics were never openly reported. Here we aim to better understand the chemistry and the materials characteristics of Cf-252 wire production for process improvements and to better our fundamental understanding of the mid-late actinides. Though there are many challenges in working with radioactive elements such as Cf, the isotope Cf-252 is even more complicated due to its neutron emission. One challenge with neutron emission is the ability of neutrons to penetrate much deeper through materials, causing radiation damage. This makes using instrumentation to characterize the chemistry and materials properties of this process difficult. For this reason, this study will first focus on terbium (Tb) as a surrogate for Cf. Currently Tb is used as a carrier or filler in Cf production when small amounts of Cf are being processed. This, along with their similar size and charge, makes Tb a reasonable surrogate for this study.
Capillary tube wire holder provides a mount for fine wires for photomicrographs. The holder is mounted in a stainless steel tube and cast in a transparent casting material. It protects and permits easy location of the wire.
The wire spindle section of the wire screening test equipment was redesigned to prevent breakage of small gage magnet wire during testing operations.
The performance of a constant-temperature inclined hot-wire in a supersonic flow is critically examined. It is shown that calibration techniques applicable to subsonic flow, such as the cosine cooling law cannot be used when the flow is supersonic. Calibration and measurement procedures appropriate to supersonic flow are suggested, together with the possible limits on their validity. Experimental results for different wires indicate that the sensitivities do not seem to depend on flow direction according to any simple correlation. When the sensitivity exhibits a strong dependence on flow direction, the wire should be discarded to avoid errors due to nonlinear effects.
The results of a survey, materials test, and analysis study directed toward the development of an inorganic glass-fiber reinforced cement material for use in the construction of space qualified spark wire frames and drift chamber frames are presented. The purpose for this research was to evaluate the feasibility of using glass fiber reinforced cement (GFRC) for large dimensioned structural frames for supporting a number of precisely located spark wires in multiple planes. A survey of the current state of the art in fiber reinforced cement materials was made; material sample mixes were made and tested to determine their laboratory performances. Tests conducted on sample materials showed that compressive and flexural strengths of this material could approach values which would enable fabrication of structural spark wire frames.
In this investigation, we compare crosstalk analysis, simulation, and measurement results for electrically short configurations. Methods include hand calculations, PSPICE simulations, Microstripes transient field solver, and empirical measurement. In total, four representative physical configurations are examined, including a single wire over a ground plane, a twisted pair over a ground plane, generator plus receptor wires inside a cylindrical conduit, and a single receptor wire inside a cylindrical conduit. Part 1 addresses the first two cases, and Part 2 addresses the final two. Agreement between the analysis, simulation, and test data is shown to be very good.
In this investigation, we compare crosstalk analysis, simulation, and measurement results for electrically short configurations. Methods include hand calculations, PSPICE simulations, Microstripes transient field solver, and empirical measurement. In total, four representative physical configurations are examined, including a single wire over a ground plane, a twisted pair over a ground plane, generator plus receptor wires inside a cylindrical conduit, and a single receptor wire inside a cylindrical conduit. Part 1 addresses the first two cases, and Part 2 addresses the final two. Agreement between the analysis methods and test data is shown to be very good.
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Post-polymerization radical bromination of a nanostructured poly(ionic liquid) that selectively introduces a reactive bromo-group onto the polyalkylthiophene backbone is described. Raman and FTIR spectroscopy proves that the bromine is successfully introduced at the 3-methyl position of the thiophene and that the molecular structure of the polymer remains largely intact with only minimal chain scission detected. FT-IR and Vis-NIR spectroscopy indicates that incorporation of the bromine induces twisting (loss of co-planarity) of the polythiophene backbone. WAXS confirms retention of an ordered lamellar structure with minor lattice spacing contraction. Cyclic voltammetry confirms spectroscopic findings that the bromination reaction yields a stable p-doped polymer. The installed bromine is susceptible to nucleophilic displacement permitting the covalent attachment of other functional molecules, such as a dialkylphosphonate. Elemental analysis of such a transformation established that 100% functionalization can be achieved. These results collectively demonstrate that post-modification of a pconjugated polymer can be used to both tune electronic and photonic properties, as well as install a chemoselective attachment point for the covalent wiring of other molecules.
Optimization of electron coupling into small solid angles is of extreme importance to applications, such as Fast Ignition, that require maximum electron energy deposition within a small volume. To optimize this coupling, we use the ultra-high-contrast Trident laser, which remains below intensity of 10 11 W/cm 2 until < 0.1 ns before the main pulse, while still attaining high-energy, 75 J, and peak intensity of 5 x 10 19 W/cm 2 . Using a cone-wire target, we find that the coupling into the 40 μm diameter wire is increased by a factor of 2.7x over the low-contrast Titan laser at similar peak intensity. Full-scale simulations are used to model the laser interaction and quantitatively reproduce the experimental results. These show that increase in coupling is due to both a closer interaction, as well as the reduction of laser filamentation and self-focusing.