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At least 37 records · Page 2

Exploring Afro-Asian water fluxes in CMIP5 and CMIP6 models: Present-day evaluation and future projections

Accurate representation and projection of water fluxes are vital, particularly in monsoon regions where seasonal variability and changes significantly impact water resources, agriculture, hydroelectric power generation, and the economy. This study uses both CMIP5 and CMIP6 models to investigate the present-day representation of key water flux components (including precipitation, evaporation, water vapor, and moisture advection) over the Afro-Asian region during the summer monsoon (JJAS). We also examine future changes under two emission scenarios and assess the underlying physical mechanisms driving these changes while identifying sources of projection uncertainty. Our results show that both models reasonably capture the present-day characteristics of water flux components, although with noticeable biases. Across most regions, we find that CMIP6 models demonstrate slight improvements over CMIP5 in the representation of these components. In a warmer future, a robust intensification of JJAS precipitation (exceeding 0.25 mm/day) is projected across the Afro-Asian region. This increase is largely driven by the vertical thermodynamic term associated with increasing temperature. We find that model uncertainty is the primary source of uncertainty in water flux projections, accounting for over 50 % of the total variance.

Climate change

A More Transparent Infrared Window

The infrared window region (780–1,250 cm –1 , 12.8 to 8.0 μm) is of great importance to Earth's climate due to its high transparency and thermal energy. We present here a new investigation of the transparency of this spectral region based on observations by interferometers of downwelling surface radiance at two DOE Atmospheric Radiation Measurement program sites. We focus on the dominant source of absorption in this region, the water vapor continuum, and derive updated values of spectral absorption coefficients for both the self and foreign continua. Our results show that the self continuum is too strong in the previous version of Mlawer-Tobin_Clough-Kneizys-Davies (MT_CKD) water vapor continuum model, a result that is consistent with other recent analyses, while the foreign continuum is too weak in MT_CKD. In general, the weaker self continuum derived in this study results in an overall increase in atmospheric transparency in the window, although in atmospheres with low amounts of water vapor the transparency may slightly decrease due to the increase in foreign continuum absorption. These continuum changes lead to a significant decrease in downwelling longwave flux at the surface for moist atmospheres and a modest increase in outgoing longwave radiation. The increased fraction of surface-leaving radiation that escapes to space leads to a notable increase (~5–10%) in climate feedback, implying that climate simulations that use the new infrared window continuum will show somewhat less warming than before. This study also points out the possibly important role that aerosol absorption may play in the longwave radiative budget.

58 GEOSCIENCES

Observations of water vapor ions at the lunar surface.

The Apollo 14 Suprathermal Ion Detector Experiment observed a series of bursts of 48.6 eV water vapor ions at the lunar surface during a 14-hr period on Mar. 7, 1971. The maximum flux observed was 100 million ions per sq cm per sec per sr. These ions were also observed at Apollo 12, 183 km to the west. Evaluation of specific artificial sources including the Apollo missions and the Russian Lunokhod leads to the conclusion that the water vapor did not come from a man-made source. Natural sources exogenous to the moon such as comets and the solar wind are also found to be inadequate to explain the observed fluxes. Consequently, these water vapor ions appear to be of lunar origin.-

Freeman, J. W., Jr.

Effect of water vapor on the destruction of ozone in the stratosphere perturbed by ClX or NOx pollutants

Results are presented for a self-consistent one-dimensional coupled flow calculation for Ox, NOx, HOx, ClX, H2O, H2, CH4, H2O2, and N2O densities between 10 and 120 km. The results agree well with observations for the normal midlatitude atmosphere over this altitude range. ClX, NOx, and H2O are varied independently in the model considered. It is shown that the effect of depletion of ozone by ClX is to remove ozone preferentially above 30 km and to lower the altitude of maximum ozone density. This leads to enhanced solar heating of the lower stratosphere and tropopause and suggests the possibility of an increased flux of water into the stratosphere. Increasing water vapor in the stratosphere greatly enhances the rate of destruction of O3 by ClX and also causes an increase in the rate of destruction of O3 in the NOx-perturbed atmosphere.

Liu, S. C.

ARM Data-Oriented Metrics and Diagnostics Package for Climate Model Evaluation

A Python-based metrics and diagnostics package is currently being developed by the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Infrastructure Team at Lawrence Livermore National Laboratory (LLNL) to facilitate the use of long-term, high-frequency measurements from the ARM Facility in evaluating the regional climate simulation of clouds, radiation, and precipitation. This metrics and diagnostics package computes climatological means of targeted climate model simulation and generates tables and plots for comparing the model simulation with ARM observational data. The Coupled Model Intercomparison Project (CMIP) model data sets are also included in the package to enable model intercomparison as demonstrated in Zhang et al. (2017). The mean of the CMIP model can serve as a reference for individual models. Basic performance metrics are computed to measure the accuracy of mean state and variability of climate models. The evaluated physical quantities include cloud fraction, temperature, relative humidity, cloud liquid water path, total column water vapor, precipitation, sensible and latent heat fluxes, and radiative fluxes, with plan to extend to more fields, such as aerosol and microphysics properties. Process-oriented diagnostics focusing on individual cloud- and precipitation-related phenomena are also being developed for the evaluation and development of specific model physical parameterizations. The version 1.0 package is designed based on data collected at ARM’s Southern Great Plains (SGP) Research Facility, with the plan to extend to other ARM sites. The metrics and diagnostics package is currently built upon standard Python libraries and additional Python packages developed by DOE (such as CDMS and CDAT). The ARM metrics and diagnostic package is available publicly with the hope that it can serve as an easy entry point for climate modelers to compare their models with ARM data. In this report, we first present the input data, which constitutes the core content of the metrics and diagnostics package in section 2, and a user's guide documenting the workflow/structure of the version 1.0 codes, and including step-by-step instruction for running the package in section 3.

54 ENVIRONMENTAL SCIENCES

Simulating Pyrocumulonimbus Clouds Using a Multiscale Wildfire Simulation Framework

Pyrocumulonimbus (pyroCb) clouds, driven by extreme fires under favorable meteorological conditions, can inject smoke into the stratosphere at magnitudes comparable to those of moderate volcanic eruptions, potentially altering the global radiative balance and atmospheric composition. However, simulating pyroCb is particularly challenging in Earth system models. Using the Energy Exascale Earth System Model (E3SM), we developed a novel global multiscale framework to model pyroCb events in California, which includes a high‐resolution fire radiative power time series, a one‐dimensional plume‐rise parameterization, a fire‐induced vertical water vapor transport scheme, and a surface wildfire sensible heat flux representation. Our simulation successfully reproduces many pyroCb features, including cloud height, spatiotemporal evolution, and convective intensity in comparison with satellite and ground‐based observations. Sensitivity experiments show that realistic pyroCb simulation depends on vertical water vapor transport. These advances provide a basis for future exploration of pyroCb impacts at regional and global scales within climate models.

E3SM

A radiative transfer model for surface radiation budget studies

A high resolution spectral radiative transfer model of the troposphere for computing downwelling radiance and flux density at the surface in the 5-200 micron region has been developed. The model is fast and accurate and takes into consideration all major and minor constituents active in this region, namely, water vapor, carbon dioxide, ozone, nitrous oxide, and methane. It uses the quasi-random band model of absorption for computing atmospheric transmittances due to various bands. Continuum absorption by water vapor in the 8-14 micron region has also been taken into account. The model has been used to examine the sensitivity of downwelling flux to variations of surface water vapor pressure (or surface relative humidity), water vapor scale-height and concentrations of other gaseous constituents of the atmosphere. In addition, sensitivity to changes in a number of cloud parameters, namely, fractional cloud cover, cloud height, and high-cloud emissivity, has also been examined. Results obtained with the present model compare well with those from the empirical and semi-empirical correlations. The present work demonstrates, for the first time, the feasibility of using a high-resolution narrow-band model for computing this flux for a meteorological application.

Gupta, S. K.

Satellite estimates of ocean-air heat fluxes during cold air outbreaks

A method for estimating the heat and moisture fluxes of coastal waters using the cloud free path, the sea surface temperature, and the saturation water vapor mixing ratio is presented. Generalized nomograms for the surface sensible and latent heat fluxes are developed using the Stage and Businger (1981) mixed-layer model. The fluxes are found to be slightly dependent on wind speed. The results are found to be applicable to any path within the cloud-free region, with heat fluxes obtainable by multiplication of the mean heating by the mean wind speed in the boundary layer. Higher stability causes lowered heating. It is shown that the latent heat flux is linear. Applications of the method to lake-effect snowstorms and for verification of boundary-layer models are indicated.

Chou, S.-H.

A model for the estimation of the surface fluxes of momentum, heat and moisture of the cloud topped marine atmospheric boundary layer from satellite measurable parameters

A model is developed for the estimation of the surface fluxes of momentum, heat, and moisture of the cloud topped marine atmospheric boundary layer by use of satellite remotely sensed parameters. The parameters chosen for the problem are the integrated liquid water content, q sub li, the integrated water vapor content, q sub vi, the cloud top temperature, and either a measure of the 10 meter neutral wind speed or the friction velocity at the surface. Under the assumption of a horizontally homogeneous, well-mixed boundary layer, the model calculates the equivalent potential temperature and total water profiles of the boundary layer along with the boundary layer height from inputs of q sub li, q sub vi, and cloud top temperature. These values, along with the 10m neutral wind speed or friction velocity and the sea surface temperature are then used to estimate the surface fluxes. The development of a scheme to parameterize the integrated water vapor outside of the boundary layer for the cases of cold air outbreak and California coastal stratus is presented.

Allison, D. E.

Environmental Conditions Affecting Global Mesoscale Convective System Occurrence

Abstract The ERA5 environments of mesoscale convective systems (MCSs), tracked from satellite observations, are assessed over a 20-yr period. The use of a large set of MCS tracks allows us to robustly test the sensitivity of the results to factors such as region, latitude, and diurnal cycle. We aim to provide novel information on environments of observed MCSs for assessments of global atmospheric models and to improve their ability to simulate MCSs. Statistical analysis of all tracked MCSs is performed in two complementary ways. First, we investigate the environments when an MCS has occurred at different spatial scales before and after MCS formation. Several environmental variables are found to show marked changes before MCS initiation, particularly over land. The vertically integrated moisture flux convergence shows a robust signal across different regions and when considering MCS initiation diurnal cycle. We also found spatial scale dependence of the environments between 200 and 500 km, providing new evidence of a natural length scale for use with MCS parameterization. In the second analysis, the likelihood of MCS occurrence for given environmental conditions is evaluated, by considering all environments and determining the probability of being in an MCS core or shield region. These are compared to analogous non-MCS environments, allowing discrimination between conditions suitable for MCS and non-MCS occurrence. Three environmental variables are found to be useful predictors of MCS occurrence: total column water vapor, midlevel relative humidity, and total column moisture flux convergence. Such relations could be used as trigger conditions for the parameterization of MCSs, thereby strengthening the dependence of the MCS scheme on the environment. Significance Statement Large storm systems called mesoscale convective systems form across Earth. These are collections of thunderstorms, with associated high-level clouds that produce substantial, lighter rainfall and modulate Earth’s energy balance. They produce hazardous weather conditions, such as floods and high winds, and are responsible for a high percentage of rainfall in many regions globally. We investigate the environmental conditions under which they form, so that we can understand the spatial extent of the environment which is important for their formation, and also where and when the effects of these storms might be felt. The novel information generated here should help improve the representation of these storms in weather and climate models, improving the prediction of rainfall, thunderclouds, and high-level clouds.

54 ENVIRONMENTAL SCIENCES

Radiation-dominated Snowmelt on Mars

A set of microclimatic conditions conducive to the generation of liquid water is being sought to see whether their requirements are any less stringent than those suggested by the global-climatic models. In particular, the melting of snow and ice in the equatorial zone (where the valley networks are preferentially situated) is investigated with a model that includes detailed infrared radiation transfer between the atmosphere and the snow, penetration of sunlight into the snow, sensible heat transfer to the atmosphere, and water vapor diffusion within the surface boundary layer. IR fluxes are calculated by using pressure and temperature dependent forms for the band absorptances of CO2 and H2O in the spectral range 50 to 2000/cm.

Clow, G. D.

Longwave radiative transfer in the atmosphere

The reported investigation had the objective to develop an accurate radiative transfer model for the thermal infrared region using a quasi-random band model. It is intended to use this model to examine the sensitivity of the outgoing radiance and flux density to the perturbations of such meteorological parameters as the surface emittance and temperature, atmospheric water vapor distribution, cloud altitude and fractional cover, and the concentrations of other infrared active constituents. The outgoing infrared flux and limb darkening functions obtained from this model agree well with the satellite measured data. Important sensitivity parameters obtained agree with the results of the various empirical and theoretical models. It is concluded that the effect of cloud depth should be taken into account to obtain better agreement with the measured limb darkening functions.

Gupta, S. K.

STRATCOM-8 scientific objectives and mission orginization

Stratospheric photochemistry was studied, with emphasis on the Ozone-NOx-ultraviolet flux interactions, but also including members of the chlorine, water vapor, and carbon-containing families. Secondary objectives include: (1) study of the balloon environment, (2) comparison of independent measurements of ozone and of NO, (3) development of new sensor systems; and (4) some measurements for exploratory purposes. Most, but not all, systems and instruments performed as planned, and it is believed that data are available to achieve most of the planned scientific and engineering objectives. The emphasis on photochemistry in the 35 to 40 km region is greater than anticipated, and observations are more complete for sunset than for sunrise. The planned instruments and a summary of the flight operations is discussed partly for the mutual information of those participating and partly for the wider scientific community.

Reed, E. I.

Stereochemically‐Controlled Fluorinated Copolymers for Selectively Permeable Barrier Applications

Selective oxygen permeability coupled with low water vapor transmission is essential for biomedical and packaging applications requiring controlled oxygen flux under humid conditions. However, most high‐performance barrier polymers depend on perfluoroalkyl substances (PFAS), whose persistence and regulatory restrictions limit their long‐term applicability. We designed a series of stereocontrolled thiol‐yne‐based polyesters, including both fluorinated and non‐fluorinated variants, for selective oxygen permeability with considerable water barrier performance. Tailoring polymer crystallinity and morphology tuned both oxygen transport and mechanical properties. Fluorinated polymers demonstrated enhanced hydrophobicity and water resistance while maintaining oxygen diffusivity within a range relevant to oxygen‐sensing applications. Structure–property relationships were elucidated through small‐ and wide‐angle X‐ray scattering, revealing semi‐crystalline domains influenced by fluorine content and dithiol chain length. Barrier performance was rigorously evaluated via water vapor transmission rate and dynamic vapor sorption, showing reduced water uptake with increasing dithiol monomer length and crystallinity. In conclusion, this work introduces a PFAS‐free alternative to conventional barrier materials and establishes a tunable materials platform with potential relevance for biomedical devices and packaging systems requiring controlled oxygen permeability.

36 MATERIALS SCIENCE

Longwave radiative transfer in the atmosphere

The reported investigation has the objective to develop an accurate radiative transfer model for the thermal infrared region using a quasi-random band model. It is intended to use this model to examine the sensitivity of the outgoing radiance and flux density to the perturbations of such meteorological parameters on the surface emittance and temperature, atmospheric water vapor distribution, cloud altitude and fractional cover, and the concentrations of other infrared active constituents. It is found that the combined effect of N2O and CH4 on the flux is significant and exceeds 1 percent. These two constituents should, therefore, not be neglected in accurate modeling work. The effect of ozone on the flux is too large to be neglected and was partly responsible for the discrepancy between earlier model results and measurements. The effect of cloud depth should be taken into account to obtain better agreement with the measured limb darkening functions.

Gupta, S. K.

Using ground-based lidar data to investigate the water–vapor budget in the daytime atmospheric boundary layer

The moisture advection term in the water–vapor budget equation is investigated with a combination of a vertically-staring water–vapor lidar and Doppler lidar systems. These instruments make it possible to get the mean profile of moisture tendency and the latent heat flux (LHF) divergence. We use data of the Land–Atmosphere Feedback Experiment (LAFE) at the Atmospheric Radiation Measurement (ARM) Program’s Southern Great Plains (SGP) site, Oklahoma, USA, collected on 30 August 2017 between 15 and 24 UTC, which corresponds to 09 to 18 LT. The lidars provide turbulence resolving profiles of moisture and vertical wind fluctuations. The LHF profile is derived from the covariance of these moisture and vertical wind fluctuations. The mean boundary layer height z i is determined from the peak of the moisture variance. The results demonstrate that the combination of two remote sensing instruments can be applied for determining the dominant water–vapor budget terms, namely moisture tendency, latent heat flux divergence and moisture advection.

Advection

Geothermal flux through palagonitized tephra, Surtsey, Iceland - The Surtsey temperature-data-relay experiment via Landsat-1

The net geothermal flux through palagonitized basaltic tephra rims of the Surtur I and Surtur II craters at Surtsey, Iceland, in 1972, is estimated at 780 plus or minus 325 microcal/sq cm/s, indicating a decline since 1969 when a flux of 1500 microcal/sq cm/s was estimated. Heat flux in this range characterizes the postvolcanic environment on Surtsey in which the subaerial polagonitization of basaltic tephra is associated with mass transfer of hydrothermal vapor, either of meteoric or sea-water origin, only a few years after cessation of eruptive activity. The flux estimation is the result of the Surtsey data-relay experiment via Landsat-1 which was carried out in several phases. Temperature data were transmitted for a 38-day period in November and December 1972. A near-surface vertical gradient of 69.4 C/m was obtained, suggesting a mixed mechanism of heat transfer, partitioned between conduction and convection.

Friedman, J. D.

Eddy Correlation Flux Measurement System (ECOR) Instrument Handbook

The eddy correlation (ECOR) flux measurement system provides in situ, half-hour measurements of the surface turbulent fluxes of momentum, sensible heat, latent heat, and carbon dioxide (CO 2 ) (and methane at the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility’s North Slope of Alaska central facility [NSA Barrow], and at the ARM Mobile Facility (AMF) deployment at Oliktok Point). The fluxes are obtained with the eddy covariance technique, which involves correlation of the vertical wind component with the horizontal wind component, the air temperature, the water vapor density, and the CO 2 concentration. The instruments used are: a fast-response, three-dimensional (3D) wind sensor (sonic anemometer) to obtain the orthogonal wind components and the speed of sound (SOS) (used to derive the air temperature), an open-path infrared gas analyzer (IRGA) to obtain the water vapor density and the CO 2 concentration, and an open-path infrared gas analyzer (IRGA) to obtain methane density and methane flux at NSA Barrow and at the AMF deployment at Oliktok Point. The ECOR systems are deployed at the locations where other methods for surface flux measurements (e.g., energy balance Bowen ratio [EBBR] systems) are difficult to employ, primarily at the north edge of a field of crops. A surface energy balance system (SEBS) has been installed collocated with each deployed ECOR system in SGP, NSA, Tropical Western Pacific (TWP), and each of three ARM Mobile Facilities. The surface energy balance system consists of upwelling and downwelling solar and infrared radiometers within one net radiometer, a wetness sensor, and soil measurements. Finally, the SEBS measurements allow the comparison of ECOR sensible and latent heat fluxes with the energy balance determined from the SEBS and provide information on wetting of the sensors for data quality purposes.

47 OTHER INSTRUMENTATION