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At least 37 records · Page 2

Wet waste-to-energy resources in the United States

Waste-to-energy (WTE) technologies present an opportunity to recycle organic waste material into renewable energy while offsetting disposal and environmental costs. A key challenge to ensuring economic and environmental viability of WTE is understanding the variability of individual WTE resource characteristics, including their location, amount, and quality. The main objective of this study is to estimate the wet WTE resource potential in the United States and illustrate its geographic distribution. The wet resources considered in this study are wastewater sludge, animal manure, food waste, and FOG (fats, oils, and greases). This study is the first to achieve results below national level, at the finest geographic resolution. Our analysis indicates that about 566 teragrams (Tg) of wet WTE resources are generated annually in the United States. This amount corresponds to about 1 exajoule (EJ), which is sufficient to displace about 18% of the 2015 U.S. on-highway diesel consumption on an energy basis. About half of this potential is generated by animal manure.

waste-to-energy, WTE, water resource, wastewater s↗

Anaerobic co-digestion of the organic fraction of municipal solid waste with FOG waste from a sewage treatment plant: Recovering a wasted methane potential and enhancing the biogas yield

Anaerobic digestion is applied widely to treat the source collected organic fraction of municipal solid wastes (SC-OFMSW). Lipid-rich wastes are a valuable substrate for anaerobic digestion due to their high theoretical methane potential. Nevertheless, although fat, oil and grease waste from sewage treatment plants (STP-FOGW) are commonly disposed of in landfill, European legislation is aimed at encouraging more effective forms of treatment. Co-digestion of the above wastes may enhance valorisation of STP-FOGW and lead to a higher biogas yield throughout the anaerobic digestion process. In the present study, STP-FOGW was evaluated as a co-substrate in wet anaerobic digestion of SC-OFMSW under mesophilic conditions (37 {sup o}C). Batch experiments carried out at different co-digestion ratios showed an improvement in methane production related to STP-FOGW addition. A 1:7 (VS/VS) STP-FOGW:SC-OFMSW feed ratio was selected for use in performing further lab-scale studies in a 5 L continuous reactor. Biogas yield increased from 0.38 {+-} 0.02 L g VS{sub feed}{sup -1} to 0.55 {+-} 0.05 L g VS{sub feed}{sup -1} as a result of adding STP-FOGW to reactor feed. Both VS reduction values and biogas methane content were maintained and inhibition produced by long chain fatty acid (LCFA) accumulation was not observed. Recovery of a currently wasted methane potential from STP-FOGW was achieved in a co-digestion process with SC-OFMSW.

09 BIOMASS FUELS↗

UNREVIEWED DISPOSAL QUESTION EVALUATION: Disposal of the TRU Waste Processing Center Mixed Low Level Waste at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This Unreviewed Disposal Question Evaluation (UDQE) assesses whether the U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA) Transuranic (TRU) Waste Processing Center Mixed Low Level Waste (MLLW), FWORCHMLLW103, Revision 13 [TWPC 2021]), is suitable for shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the TRU Waste Processing Center MLLW meets all performance objectives of DOE Manual DOE M 435.1-1, Radioactive Waste Management Manual, Chapter IV, Section P (DOE 1999). The TRU Waste Processing Center MLLW waste stream is recommended for acceptance without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

An international initiative on long-term behavior of high-level nuclear waste glass

Nations using borosilicate glass as an immobilization material for radioactive waste have reinforced the importance of scientific collaboration to obtain a consensus on the mechanisms controlling the long-term dissolution rate of glass. This goal is deemed to be crucial for the development of reliable performance assessment models for geological disposal. The collaborating laboratories all conduct fundamental and/or applied research using modern materials science techniques. This paper briefly reviews the radioactive waste vitrification programs of the six participant nations and summarizes the current state of glass corrosion science, emphasizing the common scientific needs and justifications for on-going initiatives.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Unreviewed Disposal Question Evaluation: Disposal of the Transuranic Waste Processing Center Mixed Low-Level Waste at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This Unreviewed Disposal Question Evaluation (UDQE) assesses whether the Transuranic Waste Processing Center (TWPC) Mixed Low-Level Waste (MLLW) (FWORCHMLLW103, Revision 11 [TWPC 2018]) is suitable for shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the TWPC MLLW waste stream meets all performance objectives of U.S. Department of Energy (DOE) Manual DOE M 435.1-1, Radioactive Waste Management Manual, Chapter IV, Section P (DOE 1999). The TWPC MLLW waste stream is recommended for acceptance without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

UNREVIEWED DISPOSAL QUESTION EVALUATION: Disposal of the Idaho National Laboratory Radioactive Waste Management Complex Low-Level Waste at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This Unreviewed Disposal Question Evaluation (UDQE) assesses whether the Idaho National Laboratory (INL) Radioactive Waste Management Complex (RWMC) Low-Level Waste (INEL11006367N, Revision 4 [INL 2017]) is suitable for shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the INL RWMC Low-Level Waste meets all U.S. Department of Energy (DOE) Manual DOE M 435.1-1, Radioactive Waste Management Manual, Chapter IV, Section P performance objectives (DOE 1999). The INL RWMC Low-Level Waste is recommended for acceptance without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Special Analysis for the Disposal of the Transuranic Waste Processing Center Mixed Low-Level Waste Stream at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This special analysis (SA) evaluates whether the Transuranic Waste Processing Center (TWPC) Mixed Low-Level waste stream is suitable for disposal by shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the TWPC Mixed Low-Level waste was meets all U.S. Department of Energy (DOE) Manual DOE M 435.1-1, “Radioactive Waste Management Manual,” Chapter IV, Section P performance objectives. The TWPC Mixed Low-Level waste stream is recommended for acceptance without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Waste Form Development for Solidification of Liquid Secondary Wastes to Support Hanford Direct Feed Low Activity Waste Vitrification - 17484

The US Department of Energy/Office of River Protection DOE/ORP has funded a program led by Washington River Protection Solutions (WRPS) to develop and test cementitious waste forms for immobilization of liquid secondary waste (LSW) at the Hanford site in Southeastern Washington State. The LSW comprises a concentrated brine from processing liquid effluents at Hanford's Effluent Treatment Facility. The liquid effluents include condensates from the 242-A tank waste evaporator and future offgas condensates from the Low Activity Waste (LAW) Vitrification Facility. To facilitate waste form formulation development and testing, WRPS developed LSW simulants and engaged subject matter experts at the Savannah River National Laboratory (SRNL) and Pacific Northwest National Laboratory (PNNL). This paper describes results of recent work done to develop and test a grout formulation tailored to address the elevated sulfate levels in Hanford LSW. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Assessment of lead tellurite glass for immobilizing electrochemical salt wastes from used nuclear fuel reprocessing

This paper provides an overview of research evaluating the use of lead tellurite glass as a waste form for salt wastes from electrochemical reprocessing of used nuclear fuel. The efficacy of using lead tellurite glass to immobilize three different salt compositions was evaluated: a LiCl-Li2O oxide reduction salt containing fission products from oxide fuel, a LiCl-KCl eutectic salt containing fission products from metallic fuel, and SrCl2. Physical and chemical properties of glasses made with these salts were characterized with X-ray diffraction, bulk density measurements, differential thermal analysis, chemical durability tests, scanning and transmission electron microscopies, and energy-dispersive X-ray spectroscopy. These glasses were found to accommodate high salt concentrations and have high densities, but further development is needed to improve chemical durability. (C) 2017 Published by Elsevier B.V.

Riley, Brian J.↗

Unreviewed Disposal Question Evaluation: Disposal of the Transuranic Waste Processing Center Low-Level Waste at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This Unreviewed Disposal Question Evaluation assesses whether the Transuranic Waste Processing Center (TWPC) Low-Level waste stream is suitable for shallow land burial at the Area 5 Radioactive Waste Management Site on the Nevada National Security Site. Disposal of the TWPC Low-Level Waste meets all DOE M 435.1-1 performance objectives. The TWPC Low-Level Waste stream is recommended for acceptance without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

UNREVIEWED DISPOSAL QUESTION EVALUATION: Disposal of the Transuranic Waste Processing Center Low-Level Waste at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This Unreviewed Disposal Question Evaluation (UDQE) assesses whether the Transuranic Waste Processing Center (TWPC) Low-Level Waste (LLW), FWORCHLLW0102, Revision 12 (TWPC 2021), is suitable for shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the TWPC LLW meets all performance objectives of DOE Manual DOE M 435.1-1, Radioactive Waste Management Manual, Chapter IV, Section P (DOE 1999). The TWPC LLW waste stream is recommended for acceptance without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Bioelectrochemical Integration of Waste Heat Recovery, Waste-to- Energy Conversion, and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes

Many U.S. manufacturing facilities generate unrecovered, low-grade waste heat, and also generate or are located near organic-content waste effluents. Bioelectrochemical systems, such as microbial fuel cells and microbial electrolysis cells, provide a means to convert organic-content effluents into electric power and useful chemical products. A novel biochemical electrical system for industrial manufacturing processes uniquely integrates both waste heat recovery and waste effluent conversion, thereby significantly reducing manufacturing energy requirements. This project will enable the further development of this technology so that it can be applied across a wide variety of US manufacturing segments, including the chemical, food, pharmaceutical, refinery, and pulp and paper industries. It is conservatively estimated that adoption of this technology could provide nearly 40 TBtu/yr of energy, or more than 1% of the U.S. total industrial electricity use, while reducing CO 2 emissions by more than 6 million tons per year. Commercialization of this technology will make a significant contribution to DOE’s Industrial Technology Program goals for doubling energy efficiency and providing a more robust and competitive domestic manufacturing base.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Waste Treatment Technology Process Development Plan For Hanford Waste Treatment Plant Low Activity Waste Recycle

The purpose of this Process Development Plan is to summarize the objectives and plans for the technology development activities for an alternative path for disposition of the recycle stream that will be generated in the Hanford Waste Treatment Plant Low Activity Waste (LAW) vitrification facility (LAW Recycle). This plan covers the first phase of the development activities. The baseline plan for disposition of this stream is to recycle it to the WTP Pretreatment Facility, where it will be concentrated by evaporation and returned to the LAW vitrification facility.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Charge-Coupled Substituted Garnets (Y 3-x Ca 0.5x M 0.5x )Fe 5 O 12 (M = Ce, Th): Structure and Stability as Crystalline Nuclear Waste Forms

The garnet structure has been proposed as a potential crystalline nuclear waste form for accommodation of actinide elements, especially uranium (U). In this study, yttrium iron garnet (YIG) as a model garnet host was studied for the incorporation of U analogs, cerium (Ce) and thorium (Th), incorporated by a charge-coupled substitution with calcium (Ca) for yttrium (Y) in YIG, namely, 2Y 3+ = Ca 2+ + M 4+ , where M 4+ = Ce 4+ or Th 4+ . Single-phase garnets Y 3–x Ca 0.5x M 0.5x Fe 5 O 12 (x = 0.1–0.7) were synthesized by the citrate–nitrate combustion method. Ce was confirmed to be tetravalent by X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. X-ray diffraction and 57 Fe–Mössbauer spectroscopy indicated that M 4+ and Ca 2+ cations are restricted to the c site, and the local environments of both the tetrahedral and the octahedral Fe 3+ are systematically affected by the extent of substitution. The charge-coupled substitution has advantages in incorporating Ce/Th and in stabilizing the substituted phases compared to a single substitution strategy. Enthalpies of formation of garnets were obtained by high temperature oxide melt solution calorimetry, and the enthalpies of substitution of Ce and Th were determined. The thermodynamic analysis demonstrates that the substituted garnets are entropically rather than energetically stabilized. This suggests that such garnets may form and persist in repositories at high temperature but might decompose near room temperature.

Guo, Xiaofeng↗