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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Application of Cyclic Voltammetry with W Electrodes for Measurement of High CaO Concentration in Molten CaCl 2

Molten CaCl 2 is a useful electrolyte for certain pyroprocessing techniques, and the solubility of oxide ions in this salt is a critical characteristic of many of these techniques. CaO is a byproduct of direct oxide reduction (DOR), so the concentration of oxide ions can be used to determine the extent of these reactions. Using cyclic voltammetry (CV) with tungsten electrodes, the CaO concentration in the salt up to approximately 5 wt% was correlated to both oxidation peak height and power density values. This correlation was demonstrated in both equilibrium and transient conditions. CV is a promising method for the in situ real-time monitoring of CaO concentrations in DOR processes.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
NASA NTRS1968

Voltammetry of iodine

Electrochemistry of iodine oxidation states from voltammetry of iodine chloride, iodine and iodate at rotated platinum disk and ring disk electrodes

Beran, P.↗
NASA NTRS1991

Linear-sweep voltammetry of a soluble redox couple in a cylindrical electrode

An approach is described for using the linear sweep voltammetry (LSV) technique to study the kinetics of flooded porous electrodes by assuming a porous electrode as a collection of identical noninterconnected cylindrical pores that are filled with electrolyte. This assumption makes possible to study the behavior of this ideal electrode as that of a single pore. Alternatively, for an electrode of a given pore-size distribution, it is possible to predict the performance of different pore sizes and then combine the performance values.

Weidner, John W.↗
NASA NTRS1991

Effect of ohmic, mass-transfer, and kinetic resistances on linear-sweep voltammetry in a cylindrical-pore electrode

A means is presented to account for the effect of ohmic, mass-transfer, and kinetic resistances on linear-sweep voltammograms by modeling a pore in a porous matrix as a cylindrical-pore electrode, and solving the mass and charge conservation equations in the context of this geometry for the simply redox reaction O + ne(-) yield R where both O and R are soluble species. Both analytical and numerical techniques are used to solve the governing equations. The calculated peak currents and potentials are correlated by empirical formulas to the measurable parameters: sweep rate, concentration of the redox species, diffusion coefficient, conductivity of the electrolyte, and pore dimensions. Using the correlations, a methodology is established for determining if the redox reaction kinetics are irreversible or reversible (Nernstian). If the reaction is irreversible, it is shown how the standard rate constant and the transfer coefficient may be extracted from linear-sweep voltammetry data, or, if the reaction is reversible, how the number of electrons transferred may be deduced.

Weidner, John W.↗
NASA NTRS1993

Hairy carbon electrodes studied by cyclic voltammetry and battery discharge testing

Hairy carbon is a new material developed by growing submicron carbon filaments on conventional carbon substrates. Typical substrate materials include carbon black, graphite powder, carbon fibers, and glassy carbon. A catalyst is used to initiate hair growth with carbonaceous gases serving as the carbon source. To study the electrochemical behavior of hairy carbons, cyclic voltammetry (CV) and discharge testing were conducted. In both cases, hairy carbon results surpassed those of the substrate material alone.

Chung, Deborah D. L.↗
DOE OSTI2024

Quantitative Correction of Ohmic Effects on Square Wave Voltammetry for High-Concentration Soluble-Soluble Redox Reactions in Molten Salts

Molten salts are of particular interest for a variety of industrial applications. As such, accurate characterization of species’ concentrations within the molten salt media is critical to ensure a well-controlled unit operation. Although electroanalytical tools are properly suited for precise in situ monitoring in these systems, uncompensated ohmic resistance R Ω can lead to erroneous, technique-dependent results. Using numerical simulations applied to a model system, this work will first illustrate then quantify the extent to which R Ω attenuates square wave voltammograms. This approach allows for post-experiment correction that leads to converging results across voltammetric techniques and facilitates accurate predictions of species’ concentrations.

Shaheen, Nora A. [Argonne National Laboratory (ANL↗