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At least 37 records · Page 2

Thermal transport in shock wave–compressed solids using pulsed laser heating

A pulsed laser heating method was developed for determining thermal transport properties of solids under shock-wave compression. While the solid is compressed, a laser deposits a known amount of heat onto the sample surface, which is held in the shocked state by a transparent window. The heat from the laser briefly elevates the surface temperature and then diffuses into the interior via one-dimensional heat conduction. The thermal effusivity is determined from the time history of the resulting surface temperature pulse, which is recorded with optical pyrometry. Thermal effusivity is the square root of the product of thermal conductivity and volumetric heat capacity and is the key thermal transport parameter for relating the surface temperature to the interior temperature of the sample in a dynamic compression experiment. Therefore, this method provides information that is needed to determine the thermodynamic state of the interior of a compressed metal sample from a temperature measurement at the surface. The laser heat method was successfully demonstrated on tin that was shock compressed with explosives to a stress and temperature of ∼25 GPa and ∼1300 K. In this state, tin was observed to have a thermal effusivity of close to twice its ambient value. The implications on determining the interior shock wave temperature of tin are discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Influence of multi-species solute transport on modeling of hydrated Portland cement leaching in strong nitrate solutions

The differences between the predictions of Fickian diffusion and Nernst-Planck electro-diffusion based reactive transport models are investigated in the context of an important practical problem – leaching of Portland cement in strong nitrate porewater solutions under saturated conditions. Numerical results are presented for three distinct porewater solutions: deionized water, ammonium nitrate solution, and diluted porewater from a cementitious low-activity nuclear waste form. Solute concentrations predicted by the two transport models show significant differences: as much as a factor of two for ammonium nitrate leaching and as much as a factor of four for waste form leaching; whereas, negligible differences are observed for deionized water leaching. The major conclusion is that Fickian diffusion may be accurate enough for deionized water leaching, but electro-diffusion should be considered in the reactive solute transport modeling of ammonium nitrate decalcification and in the degradation modeling of cementitious materials exposed to nuclear waste form solutions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Electronic Transport in Lithiated Iron and Bismuth Fluoride

Metal networks are formed during the lithiation of metal fluorides. Previous reports indicate that these networks are bi-continuous with the possibility to support electronic transport, though no quantitative analysis has been performed. In this study, thin films of FeF 2 and BiF 3 were chemically lithiated using n-butyllithium to form these metal networks. Direct current (DC) polarization and electrochemical impedance spectroscopy (EIS) were utilized to find electronic conductivity and results were compared to their pure metals. Here, the results indicate films to have higher than expected conductivity value which indicates that these metal networks support electronic transport during lithiation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Crystallographic study of FABP5 as an intracellular endocannabinoid transporter

FABP5 was recently found to intracellularly transport endocannabinoid signaling lipids. The structures of FABP5 complexed with two endocannabinoids and an inhibitor were solved. Human FABP5 was found to dimerize via a domain-swapping mechanism. This work will help in the development of inhibitors to raise endocannabinoid levels. In addition to binding intracellular fatty acids, fatty-acid-binding proteins (FABPs) have recently been reported to also transport the endocannabinoids anandamide (AEA) and 2-arachidonoylglycerol (2-AG), arachidonic acid derivatives that function as neurotransmitters and mediate a diverse set of physiological and psychological processes. To understand how the endocannabinoids bind to FABPs, the crystal structures of FABP5 in complex with AEA, 2-AG and the inhibitor BMS-309403 were determined. These ligands are shown to interact primarily with the substrate-binding pocket via hydrophobic interactions as well as a common hydrogen bond to the Tyr131 residue. This work advances our understanding of FABP5–endocannabinoid interactions and may be useful for future efforts in the development of small-molecule inhibitors to raise endocannabinoid levels.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Technology for design of transport aircraft. Lecture notes for MIT courses: Seminar 1.61 freshman seminar in air transportation and graduate course 1.201, transportation systems analysis

The design parameters which determine cruise performance for a conventional subsonic jet transport are discussed. It is assumed that the aircraft burns climb fuel to reach cruising altitude and that aeronautical technology determines the ability to carry a given payload at cruising altitude. It is shown that different sizes of transport aircraft are needed to provide the cost optimal vehicle for different given payload-range objectives.

Simpson, R. W.↗

First Road / River Barge Security Transport of SNF under the New German Transport Security Guidelines - 19102

A transfer of 342 spent fuel assemblies from NPP Obrigheim to NPP Neckarwestheim, both located alongside the river Neckar in the south of Germany, is required to promote the decommissioning process of NPP Obrigheim, which started in 2008 after the NPP had been shut down three years before. The spent fuel storage facility in Neckarwestheim offers sufficient storage space to accept the 342 SNF assemblies, stored in fifteen dry casks type CASTOR{sup R} 440/84 mvK. After several transport feasibility studies had been conducted, Daher Nuclear Technologies GmbH was awarded the commission to plan, prepare and conduct the SNF transport. Since the combined road / river barge transport promised to be the most suitable mode of transportation Daher Nuclear Technologies started to prepare its security concept, a prerequisite to apply for and attain the transport license mandatory for transporting spent nuclear fuel in Germany. In March 2014 the company applied for the transport license, which, after more than three years and numerous amendments to the security concept, was finally granted to Daher Nuclear Technologies on May 16, 2017 by the German Federal Office for the Safety of Nuclear Waste Management (successor organization of the BfS). Simultaneously to the license application phase the transport equipment - amongst others the heavy-duty trucks and trailers, the pusher tugs, the river barge and transport frames - had to be provided and modified to meet the intensified requirements of the New German Transport Security Guidelines Road / Rail as well as several other legal regulations referring to the transport of dangerous goods by road and inland waterways (e.g. ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road and ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways). The planning process involved various meetings with representatives of different authorities and administrative bodies incl. accredited experts as well as subcontractors. Tremendous training efforts had to be undertaken to train more than 100 transport participants regarding security measures, health, safety and environmental measures, as well as the proper handling of radioactive material. This also included the training of the security staff, that had to be qualified in compliance with the new Transport Security Guidelines Road and Rail. Finally, in June 2017, when all preparations where complete, all requirements met, and all permits obtained, the first ever security SNF transport on a German river was performed. Three laden CASTOR{sup R} 440/84 mvK transport and storage casks were transported in one batch via heavy-duty truck-trailer from the NPP Obrigheim to the NPP's own harbor, to be rolled on to the river barge, that would carry the three casks upstream the river Neckar to the approx. fifty kilometer distant NPP Neckarwestheim. The journey on the river took about eleven hours, in which several bridges and locks had to be passed. The entire transport was escorted by qualified security staff and auxiliary police forces on waterways and alongside on roads. It attracted nationwide public attention, due to its pioneer status and the fact, that there hadn't been any SNF or HLW shipments in Germany since 2011. After the convoy safely arrived at NPP Neckarwestheim's pier the three laden CASTOR{sup R} 440/84 mvK casks were rolled off the river barge via heavy-duty truck-trailers to be stored in the on-site interim storage facility. This first transport was a success and was followed by four additionally successful security transports in September, October, November and December 2017. The public attention receded significantly during the transport campaign, which ended on December 19, 2017 with the transfer of the last three of fifteen casks to the on-site interim storage facility in Neckarwestheim. With the last cask safely transferred to the interim storage facility Daher Nuclear Technologies successfully completed the transport campaign on schedule, meeting one of EnBW's fundamental objectives to finish the transfer of the 342 SNF assemblies by the end of 2017. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Improving representation of convective transport for scale‐aware parameterization: 2. Analysis of cloud‐resolving model simulations

Abstract Following Part I, in which 3‐D cloud‐resolving model (CRM) simulations of a squall line and mesoscale convective complex in the midlatitude continental and the tropical regions are conducted and evaluated, we examine the scale dependence of eddy transport of water vapor, evaluate different eddy transport formulations, and improve the representation of convective transport across all scales by proposing a new formulation that more accurately represents the CRM‐calculated eddy flux. CRM results show that there are strong grid‐spacing dependencies of updraft and downdraft fractions regardless of altitudes, cloud life stage, and geographical location. As for the eddy transport of water vapor, updraft eddy flux is a major contributor to total eddy flux in the lower and middle troposphere. However, downdraft eddy transport can be as large as updraft eddy transport in the lower atmosphere especially at the mature stage of midlatitude continental convection. We show that the single‐updraft approach significantly underestimates updraft eddy transport of water vapor because it fails to account for the large internal variability of updrafts, while a single downdraft represents the downdraft eddy transport of water vapor well. We find that using as few as three updrafts can account for the internal variability of updrafts well. Based on the evaluation with the CRM simulated data, we recommend a simplified eddy transport formulation that considers three updrafts and one downdraft. Such formulation is similar to the conventional one but much more accurately represents CRM‐simulated eddy flux across all grid scales.

Liu, Yi‐Chin↗

Aggregation control in natural brush-printed conjugated polymer films and implications for enhancing charge transport

Shear-printing of electroactive polymers using natural brushes is a promising film deposition technique for printed electronics capable of microstructure control and electrical properties enhancement over large areas. Nevertheless, the interplay between film printing parameters, microstructure development, and charge transport is not well-understood. We report that natural brush-printing greatly enhances charge transport by as much as 5.7× through control of polymer nanofibril aggregate growth and backbone alignment, attributable to the oriented squamae of the natural hair. However, while brush shear-induced aggregation enhances charge transport, we show that backbone alignment alone does not guarantee charge transport anisotropy. These results provide additional understanding of shear-induced enhanced charge transport and set processing guidelines for high-performance printed organic circuitry.

natural brush-printing↗