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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Preliminary Study on Fatigue Strengths of Fretted Ti-48Al-2Cr-2Nb

The fatigue behavior (stress-life curve) of gamma titanium aluminide (Ti-48Al-2Cr-2Nb, atomic percent) was examined by conducting two tests: first, a fretting wear test with a fatigue specimen in contact with a typical nickel-based superalloy contact pad in air at temperatures of 296 and 823 K and second, a high-cycle fatigue test of the prefretted Ti-48Al-2Cr-2Nb fatigue specimen at 923 K. Reference high-cycle fatigue tests were also conducted with unfretted Ti-48Al-2Cr-2Nb specimens at 923 K. All Ti-48Al-2Cr-2Nb fatigue specimens were machined from cast slabs. The results indicate that the stress-life results for the fretted Ti-48Al-2Cr-2Nb specimens exhibited a behavior similar to those of the unfretted Ti-48Al-2Cr-2Nb specimens. The values of maximum stress and life for the fretted specimens were almost the same as those for the unfretted specimens. The resultant stress-life curve for the unfretted fatigue specimens was very flat. The flat appearance in the stress-life curve of the unfretted specimens is attributed to the presence of a high density of casting pores. The fatigue strengths of both the fretted and unfretted specimens can be significantly affected by the presence of this porosity, which can decrease the fatigue life of Ti-48Al-2Cr-2Nb. The presence of the porosity made discerning the effect of fretting damage on fatigue strength and life of the specimens difficult.

Miyoshi, Kazuhisa↗
NASA NTRS2016

The Distribution of Radioactive Ti-44 in Cassiopeia A

The distribution of elements produced in the innermost layers of a supernova explosion is a key diagnostic for studying the collapse of massive stars. Here we present the results of a 2.4 Ms NuSTAR observing campaign aimed at studying the supernova remnant Cassiopeia A (Cas A). We perform spatially resolved spectroscopic analysis of the Ti-44 ejecta, which we use to determine the Doppler shift and thus the three-dimensional (3D) velocities of the Ti-44 ejecta. We find an initial Ti-44 mass of (1.54 +/- 0.21) x 10(exp. -4) Solar Mass, which has a present-day average momentum direction of 340 degrees +/- 15 degrees projected onto the plane of the sky (measured clockwise from celestial North) and is tilted by 58 degrees +/- 20 degrees into the plane of the sky away from the observer, roughly opposite to the inferred direction of motion of the central compact object. We find some Ti-44 ejecta that are clearly interior to the reverse shock and some that are clearly exterior to it. Where we observe Ti-44 ejecta exterior to the reverse shock we also see shock-heated iron; however, there are regions where we see iron but do not observe Ti-44. This suggests that the local conditions of the supernova shock during explosive nucleosynthesis varied enough to suppress the production of Ti-44 by at least a factor of two in some regions, even in regions that are assumed to be the result of processes like Alpha-rich freezeout that should produce both iron and titanium.

rays: general – ISM: supernova remnants – nucl↗
NASA NTRS1982

Low cost fabrication of sheet structure using a new beta titanium alloy, Ti-15V-3Cr-3Al-3Sn

Development efforts have been undertaken to improve the processing and structural efficiencies of advanced cold-formable beta Ti alloys, using the standard, hot-formed and rivetted construction of Ti-6Al-4V sheet structures as a basis for comparison. Ti-15V-3Cr-3Al-3Sn (Ti-15-3) beta alloy is formable, brazable and weldable in the solution-treated condition, and after aging displays mechanical properties suitable for postulated service in the -65 to 600 F temperature range. A novel methodology using cold-formed Ti-15-3 stringers and Ti-6Al-4V face sheets that are joined by means of an out-of-furnace isothermal brazing process, followed by low temperature aging, can reduce production costs by as much as 28 per cent. Structural efficiency has been demonstrated in room and elevated temperature crippling tests of small skin-stringer assemblies.

Kaneko, R. S.↗
NASA NTRS1988

Synchronously pumped mode-locked Ti:Al2O3 lasers

Synchronously pumped mode-locked laser operation in a Ti:Al2O3 ring laser is demonstrated. The laser pump source was a frequency-doubled Nd:YAG laser-amplifier system producing a 60-micron-long macropulse that comprised a wavetrain of mode-locked 70-ps micropulses with a 10-ns spacing (100 MHz). The Ti:Al2O3 laser consisted of a 1-cm-long crystal with faces cut at the Brewster angle and placed in a ring laser cavity configuration with a 2 percent output coupling mirror. The cavity was adjusted for a 5-ns round trip transit time, which was close to half the temporal spacing of the pump pulse. When the crystal was pumped synchronously at 532 nm with a 30-mJ macropulse, which was approximately an order of magnitude above the laser threshold, mode-locked lasing at approximately 200 MHz was obtained. This macropulse pump energy corresponds to an average micropulse pump energy of about 5 microJ at the Ti:Al2O3 crystal face. The mode-locked operation of the Ti:Al2O3 was observed only after several microseconds into the macropulse, indicating a long build-up process over many cavity trips. During this time, relaxation oscillations were observed. When mode locking started, the relaxation oscillation frequency increased by an order of magnitude. Synchronous pumping has been limited to operation with dye lasers and used either a CW or pulsed mode-locked pump source. Recent work has demonstrated CW mode-locked operation of a Ti:Al2O3 laser. The result raises the possibility that pulsed synchronous pumping may be used to obtain significantly narrowed laser pulses in Ti:Al2O3.

Source record↗
NASA NTRS1988

Residual infrared absorption in Ti:Al2O3 crystals

The performance of Ti:Al2O3 lasers is impaired generally by an infrared absorption that occurs in the laser output wavelength region. On the basis of data for as-grown and annealed samples cut from Ti:Al2O3 crystals grown by the vertical-gradient-freeze (VGF) technique, we previously proposed that the residual absorption is due to Ti(3+) to Ti(4+) pairs. In this report, we present additional data that confirm this ion-pair model for the residual absorption, which can be attributed to excitation of the 3d electron of the Ti(3+) ion perturbed by the Coulomb field of the neighboring Ti(4+) ion and/or an associated Al vacancy.

Source record↗
NASA NTRS2007

[Ti II] and [Ni II] Emission from the Strontium Filament of eta Carinae

We study the nature of the [Ti II] and [Ni II] emission from the so-called strontium filament found in the ejecta of eta Carinae. To this purpose we employ multilevel models of the Ti II and Ni II systems which are used to investigate the physical condition of the filament and the excitation mechanisms of the observed lines. For the Ti II ion, for which no atomic data was previously available, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. It is found that the observed spectrum is consistent with the lines being excited in a mostly neutral region with an electron density of the order of 10(exp 7) per cubic centimeter and a temperature around 6000 K. In analyzing three observations with different slit orientations recorded between March 2000 and November 2001 we find line ratios that change among various observations, in a way consistent with changes of up to an order of magnitude in the strength of the continuum radiation field. These changes result from different samplings of the extended filament, due to the different slit orientations used for each observation, and yield clues on the spatial extent and optical depth of the filament. The observed emission indicates a large Ti/Ni abundance ratio relative to solar abundances. It is suggested that the observed high Ti/Ni ratio in gas is caused by dust-gas fractionation processes and does not reflect the absolute Ti/Ni ratio in the ejecta of eta Carinae. We study the condensation chemistry of Ti, Ni and Fe within the filament and suggest that the observed gas phase overabundance of Ti is likely the result of selective photo-evaporation of Ti-bearing grains. Some mechanisms for such a scenario are proposed.

Bautista, M. A.↗
NASA NTRS2012

TEM Observation of the Ti Interlayer Between SiC Substrates During Diffusion Bonding

Diffusion bonding was carried out to join SiC to SiC substrates using titanium interlayers. In this study, 10 m and 20 m thick physical vapor deposited (PVD) Ti surface coatings, and 10 and 20 m thick Ti foils were used. Diffusion bonding was performed at 1250 C for PVD Ti coatings and 1200 C for Ti foil. This study investigates the microstructures of the phases formed during diffusion bonding through TEM and selected-area diffraction analysis of a sample prepared with an FIB, which allows samples to be taken from the reacted area. In all samples, Ti3SiC2, Ti5Si3Cx and TiSi2 phases were identified. In addition, TiC and unknown phases also appeared in the samples in which Ti foils were used as interlayers. Furthermore, Ti3SiC2 phases show high concentration and Ti5Si3Cx formed less when samples were processed at a higher temperature and thinner interlayer samples were used. It appears that the formation of microcracks is caused by the presence of intermediate phase Ti5Si3Cx, which has anisotropic thermal expansion, and by the presence of an unidentified Ti-Si-C ternary phase with relatively low Si content.

Tsuda, Hiroshi↗
NASA NTRS2001

Fretting Wear of Ti-48Al-2Cr-2Nb

An investigation was conducted to examine the wear behavior of gamma titanium aluminide (Ti-48Al-2Cr-2Nb in atomic percent) in contact with a typical nickel-base superalloy under repeated microscopic vibratory motion in air at temperatures from 296-823 K. The surface damage observed on the interacting surfaces of both Ti-48Al-2Cr-2Nb and superalloy consisted of fracture pits, oxides, metallic debris, scratches, craters, plastic deformation, and cracks. The Ti-48Al-2Cr-2Nb transferred to the superalloy at all fretting conditions and caused scuffing or galling. The increasing rate of oxidation at elevated temperatures led to a drop in Ti-48Al-2Cr-2Nb wear at 473 K. Mild oxidative wear was observed at 473 K. However, fretting wear increased as the temperature was increased from 473-823 K. At 723 and 823 K, oxide disruption generated cracks, loose wear debris, and pits on the Ti-48Al-2Cr-2Nb wear surface. Ti-48Al-2Cr-2Nb wear generally decreased with increasing fretting frequency. Both increasing slip amplitude and increasing load tended to produce more metallic wear debris, causing severe abrasive wear in the contacting metals. Keywords

Miyoshi, Kazuhisa↗
NASA NTRS1975

Studies on the Al2O3-Ti-Mo-Au metallization system

The behavior of Ti-Mo-Au metallization on Al2O3 and C has been investigated by backscattering spectrometry. Results show that Mo-Au bimetal films typically mix during deposition. Diffusion of Ti in Mo film occurs at 600 C, but is inhibited by the presence of oxygen in the Ti film. Even 1000 A of Mo is not a barrier against interdiffusion of Ti and Au during 20-min anneals at 600 C. The amount of mixing observed also depends on the nature of the substrate which supports the Ti-Mo-Au metallization.

Harris, J. M.↗
NASA NTRS1981

Ubiquitous isotopic anomalies in Ti from normal Allende inclusions

A novel technique for the high-precision isotopic analysis of titanium was applied to three terrestrial rocks and coarse- and fine-grained Allende inclusions. Repeated analyses of the three terrestrial rocks gave excellent agreement with a Ti metal standard. All seven Allende inclusions were previously determined to contain isotopically normal Nd and/or Sm, indicating that none belongs to a small group of peculiar intrusions. The discovery of widespread Ti isotopic anomalies in normal Allende inclusions establishes Ti as the first non-noble gas element studied since oxygen to show such isotopic heterogeneity. A survey of nucleosynthetic origins of Ti isotopes suggests that the dominant Ti-50 excesses in these inclusions are due to the relative enrichment of isotopes synthesized during hydrostatic burning in, or near, the core of a massive star.

Niemeyer, S.↗
NASA NTRS1986

Large Ca-48 anomalies are associated with Ti-50 anomalies in Murchison and Murray hibonites

Ion microprobe measurements of the Ca isotopic compositions of eight individual hibonite grains from the Ca chondrites Murray and Murchison are reported. Large Ca-48 anomalies two orders of magnitude larger than those observed in normal inclusions and at least a factor of four larger than in the FUN inclusions are found. These anomalies are qualitatively correlated with the Ti-50 anomalies in the sense that the delta Ca-48 and delta Ti-50 values have the same sign. These results confirm previous conclusions concerning the presence of a nucleosynthetic component produced by neutron-rich nuclear statistical equilibrium processes. They suggest the preservation of the isotopic anomalies with interstellar dust grains as carriers of the n-rich Ca and Ti components. The large variation in the delta Ca-48/delta Ti-50 ratios indicates multiple nucleosynthetic components and/or chemical fractionation between Ca and Ti prior to hibonite formation.

Zinner, Ernst K.↗
NASA NTRS1987

Al-26, Pu-244, Ti-50, REE, and trace element abundances in hibonite grains from CM and CV meteorites

Hibonites from the CM meteorites Murchison, Murray, and Cold Bokkeveld, and hibonites and Ti-rich pyroxene from the CV chondrite Allende are studied. Electron microprobe measurements of major element concentrations and track and ion probe measurements of Mg and Ti isotopic ratios, rare earth elements (REEs), and trace element abundances are analyzed. Correlations between isotopic anomalies in Ti, Al-26, Pu-244, and Mg-26(asterisk) are examined. Ti isotopic anomalies are compared with REE and trace element abundance patterns. Reasons for the lack of Al-26 in the hibonites are investigated and discussed. It is observed that there is no correlation between the Ti isotopic compositions, and the presence of Mg-26(asterisk), Pu-244, and REE and trace element patterns in individual hibonite samples. The data reveal that hibonites are not interstellar dust grains but formed on a short time scale and in localized regions of the early solar system.

Fahey, A. J.↗
NASA NTRS1997

Atomistic Simulations and Experimental Analysis of the Effect of Ti Additions on the Structure of NiAl

The Bozzolo-Ferrante-Smith (BFS) semiempirical method for alloy energetics is applied to the study of ternary additions to NiAl alloys. A detailed description of the method and its application to alloy design is given. Two different approaches are used in the analysis of the effect of Ti additions to NiAl. First, a thorough analytical study is performed, where the energy of formation, lattice parameter and bulk modulus are calculated for hundreds of possible atomic distributions of Ni, Al and Ti. Substitutional site preference schemes and formation of precipitates are thus predicted and analyzed. The second approach used consists of the determination of temperature effects on the final results, as obtained by performing a number of large scale numerical simulations using the Monte Carlo - Metropolis procedure and BFS for the calculation of the energy at every step in the simulation. The results indicate a sharp preference of Ti for Al sites in Ni-rich NiAl alloys and the formation of ternary Heusler precipitates beyond the predicted solubility limit of 5 at. % Ti. Experimental analysis of three NiAl+Ti alloys confirms the theoretical predictions.

Bozzolo, Guillermo↗
NASA NTRS1992

Thermodynamics, Solubility, and Diffusivity of Oxygen in Titanium and Ti-Al Alloys

Titanium aluminides and titanium aluminide-based composites are attractive candidate materials for high-temperature structural applications. As these materials may be exposed to oxidizing environments durine their use at elevated temperatures, it is essential that they possess a good oxidation resistance. Previous studies have shown that the oxidation resistance of Al-rich alloys in the Ti-Al system is superior to that of the Ti-rich alloys. The scales formed on the surface of the Al-rich and Ti-rich alloys have been reported to be predominantly Al2O3 and TiO2, respectively. Since the relative stabilities of the oxides of Al and Ti at various temperatures and oxygen pressures can be assessed from their thermodynamic data, it is possible, With the help of thermodynamic calculations, to determine the compositions of the alloys which would form scales of Al2O3, TiO(x) or a ternary oxide such as TiAl2O5 during oxidation at a given temperature. The thermodynamic calculations require reliable activity data for the Ti-Al system. These data have not been determined for the entire composition and temperature range of interest. Using the data available in the literature, recently performed thermodynamic calculations and concluded that the stable oxide changed from TiO to Al2O3 in the existence region of the tial phase. In the case of titanium aluminide-based composites, another major concern is the mutual chemical compatibility of the matrix material with the reinforcement phase. Fibers of SiC, TiB2 and Al2O3 are currently being investigated for reinforcement of titanium aluminide matrices.

Mehrotra, Gopal M.↗
NASA NTRS1999

BFS Simulation and Experimental Analysis of the Effect of Ti Additions on the Structure of NiAl

The Bozzolo-Ferrante-Smith (BFS) method for alloy energetics is applied to the study of ternary additions to NiAl. A description of the method and its application to alloy design is given. Two different approaches are used in the analysis of the effect of Ti additions to NiAl. First, a thorough analytical study is performed, where the energy of formation, lattice parameter and bulk modulus are calculated for a large number of possible atomic distributions of Ni, Al and Ti. Substitutional site preference schemes and formation of precipitates are thus predicted and analyzed. The second approach used consists of the determination of temperature effects on the final results, as obtained by performing a number of large scale numerical simulations using the Monte Carlo-Metropolis procedure and BFS for the calculation of the energy at every step in the simulation. The results indicate a sharp preference of Ti for Al sites in Ni-rich NiAl alloys and the formation of ternary Heusler precipitates beyond the predicted solubility limit of 5 at. % Ti. Experimental analysis of three Ni-Al-Ti alloys confirms the theoretical predictions.

Bozzolo, Guillermo↗
NASA NTRS2003

Fe-Ti-Cr-Oxides in Martian Meteorite EETA79001 Studied by Point-counting Procedure Using Raman Spectroscopy

Fe-Ti-Cr-Oxide minerals contain much information about rock petrogenesis and alteration. Among the most important in the petrology of common intrusive and extrusive rocks are those of the FeO-TiO2-Cr2O3 compositional system chromite, ulv spinel-magnetite, and ilmenite-hematite. These minerals retain memories of oxygen fugacity. Their exsolution into companion mineral pairs give constraints on formation temperature and cooling rate. Laser Raman spectroscopy is anticipated to be a powerful technique for characterization of materials on the surface of Mars. A Mars Microbeam Raman Spectrometer (MMRS) is under development. It combines a micro sized laser beam and an automatic point-counting mechanism, and so can detect minor minerals or weak Raman-scattering phases such as Fe- Ti-Cr-oxides in mixtures (rocks & soils), and provide information on grain size and mineral mode. Most Fe-Ti-Cr-oxides produce weaker Raman signals than those from oxyanionic minerals, e.g. carbonates, sulfates, phosphates, and silicates, partly because most of them are intrinsically weaker Raman scatters, and partly because their dark colors limit the penetration depth of the excitation laser beam (visible wavelength) and of the Raman radiation produced. The purpose of this study is to show how well the Fe-Ti-Cr-oxides can be characterized by on-surface planetary exploration using Raman spectroscopy. We studied the basic Raman features of common examples of these minerals using well-characterized individual mineral grains. The knowledge gained was then used to study the Fe-Ti-Cr-oxides in Martian meteorite EETA79001, especially effects of compositional and structural variations on their Raman features.

Wang, Alian↗
NASA NTRS2005

Is the 21-micron Feature Observed in Some Post-AGB Stars Caused by the Interaction Between Ti Atoms and Fullerenes?

Recent measurements of fullerenes and Ti atoms recorded in our laboratory have demonstrated the presence of an infrared feature near 21 pm. The feature observed has nearly the same shape and position as is observed for one of the most enigmatic features in post-asymptotic giant blanch (AGB) stars. In our experimental system large cage carbon particles, such as large fullerenes, were produced from CO gas by the Boudouard reaction. Large-cage carbon particles intermixed with Ti atoms were produced by the evaporation of a Ti metal wrapped carbon electrode in CO gas. The infrared spectra of large fullerenes interacting with Ti atoms show a characteristic feature at 20.3 micron that closely corresponds to the 20.1 micron feature observed in post-AGB stars. Both the lab- oratory and stellar spectra also show a small but significant peak at 19.0 micron, which is attributed to fullerenes. Here, we propose that the interaction between fullerenes and Ti atoms may be a plausible explanation for the 21-micron feature seen in some post-AGB stars.

Kimura, Yuki↗
NASA NTRS2008

Nb(x)Ti(1-x)N Superconducting-Nanowire Single-Photon Detectors

Superconducting-nanowire single-photon detectors (SNSPDs) in which Nb(x)Ti(1-x)N (where x<1) films serve as the superconducting materials have shown promise as superior alternatives to previously developed SNSPDs in which NbN films serve as the superconducting materials. SNSPDs have potential utility in optical communications and quantum cryptography. Nb(x)Ti(1-x)N is a solid solution of NbN and TiN, and has many properties similar to those of NbN. It has been found to be generally easier to stabilize Nb(x)Ti(1-x)N in the high-superconducting-transition temperature phase than it is to so stabilize NbN. In addition, the resistivity and penetration depth of polycrystalline films of Nb(x)Ti(1-x)N have been found to be much smaller than those of films of NbN. These differences have been hypothesized to be attributable to better coupling at grain boundaries within Nb(x)Ti(1-x)N films.

Stern, Jeffrey A.↗