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The collection and dissemination of thermal energy storage (TES) system technology for the pulp and paper industry with the intent of reducing fossil fuel usage is discussed. The study plan is described and a description presented of example TES systems.
Experimental results of compatibility screening studies of 100 salt/containment/thermal conductivity enhancement (TCE) combinations for the high temperature solar thermal application range of 704 deg to 871 C (1300 to 1600 F) are presented. Nine candidate containment/HX alloy materials and two TCE materials were tested with six candidate solar thermal alkali and alkaline earth carbonate storage salts (both reagent and technical grade of each). Compatibility tests were conducted with salt encapsulated in approx. 6.0 inch x 1 inch welded containers of test material from 300 to 3000 hours. Compatibility evaluations were end application oriented, considering the potential 30 year lifetime requirement of solar thermal power plant components. Analyses were based on depth and nature of salt side corrosion of materials, containment alloy thermal aging effects, weld integrity in salt environment, air side containment oxidation, and chemical and physical analyses of the salt. A need for more reliable, and in some cases first time determined thermophysical and transport property data was also identified for molten carbonates in the 704 to 871 C temperature range. In particular, accurate melting point (mp) measurements were performed for Li2CO3 and Na2CO3 while melting point, heat of fusion, and specific heat determinations were conducted on 81.3 weight percent Na2CO3-18.7 weight percent K2CO3 and 52.2 weight percent BaCO3-47.8 weight percent Na2CO3 to support future TES system design and ultimate scale up of solar thermal energy storage (TES) subsystems.
Over forty thermal energy storage (TES) concepts gathered from the literature and personal contacts were studied for their suitability for the electric utility application of storing energy off-peak discharge during peak hours. Twelve selections were derived from the concepts for screening; they used as storage media high temperature water (HTW), hot oil, molten salts, and packed beds of solids such as rock. HTW required pressure containment by prestressed cast-iron or concrete vessels, or lined underground cavities. Both steam generation from storage and feedwater heating from storage were studied. Four choices were made for further study during the project. Economic comparison by electric utility standard cost practices, and near-term availability (low technical risk) were principal criteria but suitability for utility use, conservation potential, and environmental hazards were considered.
Report discusses cost effectiveness of high-temperature thermal storage system for representative parabolic dish solar powerplant. Economic viability of thermal storage system assesses; cost and performance projections made; cost of electricity generated by solar power plant also calculated.
The viability of using fluidized bed heat exchangers (FBHX) for thermal energy storage (TES) in applications with potential for waste heat recovery was investigated. Of the candidate applications screened, cement plant rotary kilns and steel plant electric arc furnaces were identified, via the chosen selection criteria, as having the best potential for successful use of FBHX/TES system. A computer model of the FBHX/TES systems was developed and the technical feasibility of the two selected applications was verified. Economic and tradeoff evaluations in progress for final optimization of the systems and selection of the most promising system for further concept validation are described.
In support of the DOE thermal and chemical energy storage program, the solar energy storage program (SERI) provides research on advanced technologies, systems analyses, and assessments of thermal energy storage for solar applications in support of the Thermal and Chemical Energy Storage Program of the DOE Division of Energy Storage Systems. Currently, research is in progress on direct contact latent heat storage and thermochemical energy storage and transport. Systems analyses are being performed of thermal energy storage for solar thermal applications, and surveys and assessments are being prepared of thermal energy storage in solar applications. A ranking methodology for comparing thermal storage systems (performance and cost) is presented. Research in latent heat storage and thermochemical storage and transport is reported.
The Thermal Storage Advanced Thruster System (TSATS) rocket test stand is completely assembled and operational. The first trial experimental runs of a low-energy TSATS prototype rocket was made using the test stand. The features of the rocket test stand and the calibration of the associated diagnostics are described and discussed. Design and construction of the TSATS prototype are discussed, and experimental objectives, procedures, and results are detailed.
The results of comparative screening studies of candidate molten carbonate salts as phase change materials (PCM) for advanced solar thermal energy storage applications at 540 to 870 C (1004 to 1600 F) and steam Rankine electric generation at 400 to 540 C (752 to 1004 F) are presented. Alkali carbonates are attractive as latent heat storage materials because of their relatively high storage capacity and thermal conductivity, low corrosivity, moderate cost, and safe and simple handling requirements. Salts were tested in 0.1 kWhr lab scale modules and evaluated on the basis of discharge heat flux, solidification temperature range, thermal cycling stability, and compatibility with containment materials. The feasibility of using a distributed network of high conductivity material to increase the heat flux through the layer of solidified salt was evaluated. The thermal performance of an 8 kWhr thermal energy storage (TES) module containing LiKCO3 remained very stable throughout 5650 hours and 130 charge/discharge cycles at 480 to 535 C (896 to 995 F). A TES utilization concept of an electrical generation peaking subsystem composed of a multistage condensing steam turbine and a TES subsystem with a separate power conversion loop was defined. Conceptual designs for a 100 MW sub e TES peaking system providing steam at 316 C, 427 C, and 454 C (600 F, 800 F, and 850 F) at 3.79 million Pa (550 psia) were developed and evaluated. Areas requiring further investigation have also been identified.
A rotary cement kiln and an electric arc furnace were chosen for evaluation to determine the applicability of a fluid bed heat exchanger (FBHX) for thermal energy storage (TES). Multistage shallow bed FBHX's operating with high temperature differences were identified as the most suitable for TES applications. Analysis of the two selected conceptual systems included establishing a plant process flow configuration, an operational scenario, a preliminary FBHX/TES design, and parametric analysis. A computer model was developed to determine the effects of the number of stages, gas temperatures, gas flows, bed materials, charge and discharge time, and parasitic power required for operation. The maximum national energy conservation potential of the cement plant application with TES is 15.4 million barrels of oil or 3.9 million tons of coal per year. For the electric arc furnance application the maximum national conservation potential with TES is 4.5 million barrels of oil or 1.1 million tons of coal per year. Present time of day utility rates are near the breakeven point required for the TES system. Escalation of on-peak energy due to critical fuel shortages could make the FBHX/TES applications economically attractive in the future.
Spacecraft solar dynamic power systems typically use high-temperature phase-change materials to efficiently store thermal energy for heat engine operation in orbital eclipse periods. Lithium fluoride salts are particularly well suited for this application because of their high heat of fusion, long-term stability, and appropriate melting point. Considerable attention has been focused on the development of thermal energy storage (TES) canisters that employ either pure lithium fluoride (LiF), with a melting point of 1121 K, or eutectic composition lithium-fluoride/calcium-difluoride (LiF-20CaF2), with a 1040 K melting point, as the phase-change material. Primary goals of TES canister development include maximizing the phase-change material melt fraction, minimizing the canister mass per unit of energy storage, and maximizing the phase-change material thermal charge/discharge rates within the limits posed by the container structure.
The cost effectiveness of a high temperature thermal storage system is investigated for a representative parabolic dish solar power plant. The plant supplies electrical power in accordance with a specific, seasonally varying demand profile. The solar power received by the plant is supplemented by power from fuel combustion. The cost of electricity generated by the solar power plant is calculated, using the cost of mass-producible subsystems (specifically, parabolic dishes, receivers, and power conversion units) now being designed for this type of solar plant. The trade-off between fuel and thermal storage is derived in terms of storage effectiveness, the cost of storage devices, and the cost of fuel. Thermal storage requirements, such as storage capacity, storage effectiveness, and storage cost are established based on the cost of fuel and the overall objective of minimizing the cost of the electricity produced by the system. As the cost of fuel increases at a rate faster than general inflation, thermal storage systems in the $40 to $70/kWthr range could become cost effective in the near future.
The NASA Lewis Research Center is currently working with RSC-Energia, the Russian Space Agency, and Allied Signal in developing a flight demonstration solar dynamic power system. This type of power system is dependent upon solar flux that is reflected and concentrated into a thermal storage system to provide the thermal energy input to a closed-cycle Brayton heat engine. The solar dynamic unit will be flown on the Russian Mir space station in anticipation of use on the International Space Station Alpha. By the time the power system is launched, the Mir will be a spatially complex configuration which will have, in addition to the three-gimbaled solar dynamic unit, eleven solar array wings that are either fixed or track the Sun along one axis and a variety or repositionable habitation and experiment modules. The proximity of arrays to modules creates a situation which makes it highly probable that there will be varying solar flux due to shadowing on the solar dynamic unit and some of the arrays throughout the orbit. Shadowing causes fluctuations in the power output from the arrays and the solar dynamic power system, thus reducing the energy capabilities of the spacecraft. An assessment of the capabilities of the power system under these conditions is an important part in influencing the design and operations of the spacecraft and predicting its energy performance. This paper describes the results obtained from using the Orbiting Spacecraft Shadowing Analysis Station program that was integrated into the Station Power Analysis for Capability Evaluation (SPACE) electrical power system computer program. OSSA allows one to consider the numerous complex factors for analyzing the shadowing effects on the electrical power system including the variety of spacecraft hardware geometric configurations, yearly and daily orbital variations in the vehicle attitude and orbital maneuvers (for communications coverage, payload pointing requirements and rendezvous/docking with other vehicles). The geometric models of the MIR with a solar dynamic power unit that were used in performing shadowing analyses are described. Also presented in this paper are results for individual orbits for several flight attitude cases which include assessments of the shadowing impacts upon the solar dynamic unit and the solar arrays. These cases depict typical MIR flight attitudes likely to have shadowing impact. Because of the time varying nature of the Mir orientation with respect to the Sun and the lack of knowledge of the precise timing of the attitude changes, strategies must be devised to assess and depict the shadowing impacts on power generation throughout the year. To address this, the best, nominal and worst impacts of shadowing considering a wide possible range of parameter changes for typical mission operation period are shown.
Alkali and alkaline earth carbonate latent-heat storage salts, metallic containment materials, and thermal conductivity enhancement materials were investigated to satisfy the high temperature (704 to 871 C) thermal energy storage requirements of advanced solar-thermal power generation concepts are described. Properties of the following six salts selected for compatibility studies are given: three pure carbonates, K2CO3, Li2CO3 and Na2CO3; two eutectic mixtures, BaCO3/Na2CO3 and K2CO3/NaCO3, and one off-eutectic mixture of Na2CO3/K2CO3.
Existing and advanced electrochemical storage and inversion/conversion systems that may be used with terrestrial solar-thermal power systems are evaluated. The status, cost and performance of existing storage systems are assessed, and the cost, performance, and availability of advanced systems are projected. A prime consideration is the cost of delivered energy from plants utilizing electrochemical storage. Results indicate that the five most attractive electrochemical storage systems are the: iron-chromium redox (NASA LeRC), zinc-bromine (Exxon), sodium-sulfur (Ford), sodium-sulfur (Dow), and zinc-chlorine (EDA).
Volume 2 of this 2 volume report is represented. This volume contains three appendices: (1) bibliography and cross references; (2) taxonomy - proponents and sources; and (3) concept definitions.
Potential concepts for near term electric utility applications were identified. The most promising ones for conceptual design were evaluated for their economic feasibility and cost benefits. The screening process resulted in selecting two coal-fired and two nuclear plants for detailed conceptual design. The coal plants utilized peaking turbines and the nuclear plants varied the feedwater extraction to change power output. It was shown that the performance and costs of even the best of these systems could not compete in near term utility applications with cycling coal plants and typical gas turbines available for peaking power. Lower electricity costs, greater flexibility of operation, and other benefits can be provided by cycling coal plants for greater than 1500 hours of peaking or by gas turbines for less than 1500 hours if oil is available and its cost does not increase significantly.
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