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At least 37 records · Page 2

From broadband biphotons to frequency combs via spectral compression with time-varying cavities

Biphoton frequency combs are promising resources for quantum networking due in large part to their compatibility with the telecommunication infrastructure. Here, in this work, we propose a method to periodically compress broadband frequency-entangled photons into biphoton frequency combs by utilizing time-varying linear cavities. Our approach hinges on rapid modulation of the input cavity coupling, yielding high spectral purity in each output comb line similar to that achieved with narrowband filters, but without the associated loss in flux. We examine the dependence of spectral purity and compression on coupling strength, cavity loss, and switching speed, finding realistic regimes supporting purities in excess of 0.999 and peak enhancement factors of 100× and beyond.

Myilswamy, Karthik V. [Purdue Univ., West Lafayett

Quantum teleportation coexisting with classical communications in optical fiber

The ability for quantum and conventional networks to operate in the same optical fibers would aid the deployment of quantum network technology on a large scale. Quantum teleportation is a fundamental operation in quantum networking, but has yet to be demonstrated in fibers populated with high-power conventional optical signals. Here we report, to the best of our knowledge, the first demonstration of quantum teleportation over fibers carrying conventional telecommunications traffic. Quantum state transfer is achieved over a 30.2-km fiber carrying 400-Gbps C-band classical traffic with a Bell state measurement performed at the fiber’s midpoint. To protect quantum fidelity from spontaneous Raman scattering noise, we use optimal O-band quantum channels, narrow spectro-temporal filtering, and multi-photon coincidence detection. Fidelity is shown to be well maintained with an elevated C-band launch power of 18.7 dBm for the single-channel 400-Gbps signal, which we project could support multiple classical channels totaling many terabits/s aggregate data rates. These results show the feasibility of advanced quantum and classical network applications operating within a unified fiber infrastructure.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC

Distributed Acoustic Sensing for Whale Vocalization Monitoring: A Vertical Deployment Field Test

Abstract There is growing interest in floating offshore wind turbine (FOWT) technology, where turbines are installed on floating structures anchored to the seabed, allowing wind energy development in areas unsuitable for traditional fixed-platform turbines. Responsible development requires monitoring the impact of FOWTs on marine wildlife, such as whales, throughout the operational lifecycle of the turbines. Distributed acoustic sensing (DAS)—a technology that transforms fiber-optic cables into vibration sensor arrays—has been demonstrated for acoustic monitoring of whales using seafloor telecommunications cables. However, no studies have yet evaluated DAS performance in dynamic, engineered environments, such as floating platforms or moving vessels with complex, dynamic strain loads, despite their relevance to FOWT settings. This study addresses that gap by deploying DAS aboard a boat in Monterey Bay, California, where a fiber-optic cable was lowered using a weighted and suspended mooring line, enabling vertical deployment. Humpback whale vocalizations were captured and identified in the DAS data, noise sources were identified, and DAS data were compared to audio captured by a standalone hydrophone attached to the mooring line and a nearby hydrophone on a cabled observatory. This study is unique in: (1) deploying DAS in a vertical deployment mode, where noise from turbulence, cable vibrations, and other sources posed additional challenges compared to seafloor DAS applications; (2) demonstrating DAS in a dynamic, nonstationary setup, which is uncommon for DAS interrogators typically used in more stable environments; and (3) leveraging looped sections of the cable to reduce the noise floor and mitigate the effects of excessive cable vibrations and strain. This research demonstrates DAS’s ability to capture whale vocalizations in challenging environments, highlighting its potential to enhance underwater acoustic monitoring, particularly in the context of renewable energy development in offshore environments.

Saw, Jaewon

Applying Machine Learning and Bayesian Inference to Identify and Locate Moving Anthropogenic Sources Using Distributed Acoustic Sensing Data

Distributed acoustic sensing (DAS) systems, which use existing telecommunication fibers, offer high‐resolution capabilities ideal for recording anthropogenic sources. However, the complexity of urban environments and the large amount of data recorded by DAS require automated methods to efficiently detect and categorize anthropogenic sources. Here, we evaluate how well three machine learning models (k‐nearest neighbor [k‐NN], convolutional neural networks, and recurrent‐convolutional neural networks) can identify various anthropogenic sources recorded by DAS. Our findings reveal that both k‐NN and neural network methods perform well in high signal‐to‐noise ratio (SNR) settings. However, their accuracy decreases at SNRs <4. We also use Kalman filtering, a form of Bayesian inference, on backprojected locations of these sources to recover locations that generally fall within standard smartphone Global Positioning System errors. By combining machine learning and Kalman filter results, we calculate a multidimensional model of moving anthropogenic sources. These results demonstrate the potential of DAS data in urban seismology for accurately identifying and locating such sources. Depending on the research objectives, these sources can be further studied or filtered out to improve the quality of seismic data for earthquake studies. Such methods provide a valuable tool for urban seismology and seismic hazard analysis.

Luckie, Thomas William [Sandia National Laboratori

Rare Earth Elements (REE) and Critical Minerals (CM) in Middle Pennsylvanian-Age Coals and Associated Sediments in the Central Appalachian Basin, Eastern U.S.A.

The Central Appalachian Basin (CAB) of Kentucky, Tennessee, West Virginia and Virginia has a long history of coal mining and oil and gas extraction that has empowered the regional and national economies, the development of infrastructure, and a highly trained energy resources work force. As our societal demands for advanced technologies have rapidly increased in recent years, coal-related materials are viewed as an important new unconventional domestic source of critical minerals (CM) that are required for telecommunications, aerospace and transportation industries, electronics, the transition to low-carbon emissions energy production, and many consumer products. Coal-related materials encompass coal, associated sediments, coal mining waste materials, produced waters, and ash residues from coal-fired power plants. An important objective of the Evolve Central Appalachia Project (Evolve CAPP), sponsored by the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to assess the quantity and distribution of CM resources in the CAB region. The rare earth elements (REE) are considered highest priority, although other important CM such as niobium, gallium, and zirconium are known to occur in the Middle Pennsylvanian-age coals and sediments. Working with coal industry partners who provided access to drill cores, coal-related sediments and waste materials, over 600 samples have been collected for laboratory analysis, and over 730 materials have been scanned using portable x-ray fluorescence (pXRF) equipment. The application of pXRF provides the means for real-time semiquantitative analysis of CM content at very close spacings (typically 2-3 inch intervals) along drill core and in-situ channel samples that span the roof, coal seam, and floor rock. The comparison of pXRF geochemical data with laboratory results, geologic data, and downhole spectral gamma logs can provide high resolution input to lithologic and depositional models for future CM resource evaluations. The preliminary findings show that pXRF is capable of accurately measuring low concentrations of many of the CM with a high level of confidence (Ba, Cr, Ga, K, Nb, Rb, Sr, Th, Y), whereas for others (La, Ce, Co, Mn, Nd, Ni, Sc, Ti, V) the detection limits are very high or spectral interferences increase the uncertainty. Notably, the mean abundances of Y (34 ppm), La (86 ppm), Ga (40 ppm), and V (146 ppm) in coal underclays in the CAB region are up to 7X enriched compared with the overlying coal. These values also exceed the reported concentrations in published reference materials for upper continental crustal rocks (Rudnick and Gao, 2003), North American Shale Composite (Gromet et al., 1984), and North American coal (Finkelman, 1993). The pXRF data are in part verified by laboratory results that indicate the mean Y abundance (36 ppm) is highly correlated (R2 = 0.807) with total REE (ΣREE). The correlation is even higher (R2 = 0.957) with heavy REE (ΣHREE). Applying these correlations to the pXRF data for the coal underclays, the mean estimated values for ΣREE+Y and ΣHREE+Y are 270 ppm and 58 ppm, respectively. Although these average values are not considered high, the range of Y measured by pXRF in the coal underclays extended as high as 114 ppm, which would suggest ΣREE+Y equal to 847 ppm. The mean abundances of Zr (192 ppm) and Th (21 ppm) in coal underclays are also enriched compared with the overlying coal and these results likely reflect the presence of resistant detrital heavy minerals such as monazite, xenotime, and zircon in the underclay matrix. Several of the profiled coal seams and associated wall rocks contained thin volcanic ash layers up to 4-5 inches in thickness. The extent to which these ash fall layers provided a source for CM under the paleoenvironmental conditions that resulted in coal deposits in the CAB remains to be fully studied. Continuing investigations in the Evolve CAPP study area will include laboratory determinations of mineralogic and clay compositions, and evaluations of CM geochemical mobility in the coal and coal underclays.

Lassetter, Billy

Non-invasive Pipe Pressure Monitoring for Safeguards

Our project explores a new solution to complement current safeguards toolbox by independently, and noninvasively, determining the pressure inside uranium hexafluoride (UF 6 )-carrying Gas Centrifuge Enrichment Plant (GCEP) pipes. Proof-of-principle, non-invasive pipe pressure monitoring tests were conducted through measurements of hoop and axial strain using an optical-interference dilatometry technique based on fiber Bragg gratings (FBGs) inscribed in the core of telecommunication-type 125 µm diameter optical fibers. The fibers were affixed to commercial stainless steel and aluminum tubes and pipes of the type expected to be found at GCEP’s, each measuring four inches in diameter. When the internal air pressure in the pipes changes their external diameter and length follow, and the pitch in the FBG shrinks and/or expands accordingly. In turn, these changes result in a shift of the light wavelength reflected by the FBGs. Several FBGs physically attached to the pipe, as well as control FBGs not attached, were interrogated during the process using state-of-the-art commercial interrogators that operate on swept-wavelength laser technology. Strains measured were contrasted against calculations based on the known elastic and mechanical properties of the pipes. Good agreement is found, and strategies are proposed for further improvement of the experimental resolution as well as future implementation of this novel approach for GCEP safeguards.

22 GENERAL STUDIES OF NUCLEAR REACTORS

Steel Creek, Pen Branch, and D-Area Watershed Stream Gauging Stations

A network of stream gauging systems were installed in the Steel Creek, Pen Branch, D-Area Discharge Canal, and the D006 Stream in support of the groundwater modeling efforts for the P-Area Groundwater Operable Unit (OU); Chemical, Metals, and Pesticides (CMP) Pits OU; and the D-Area Watershed, respectively. Each location is monitored by a MACE Floseries3 FloPro data logger and a MACE doppler ultrasonic area/velocity sensor. Each stream gauging system is powered by an internal 12-volt battery supplied by a solar panel with a trickle charger. Information collected by each data logger is logged internally and telecommunicated via a cellular network to an online server for real time analysis and monitoring. The MACE doppler ultrasonic area/velocity sensor can measure stream depth and velocities to give output values of flow rates, total flow, net flow, and volumes. The water depth is measured by a ceramic pressure transducer located on the top of the sensor. The velocity is measured by a continuous wave doppler sensor to give an average velocity across the whole stream profile. This report discusses the equipment and methods used to install continuous stream gauging stations and provides a summary of data collected through FY2025.

54 ENVIRONMENTAL SCIENCES

The Next Stage for Smart Cities: Metrics to Spur an Evolution from Technology for Efficiency to Technology for People's Needs

The Smart Cities movement is about a decade old, energized by the USDOT Smart Cities grant that sparked cities to dream big. Now, 10 years later, and multitudes of conferences and papers later, the biggest question regarding Smart Cities is whether any progress has been made? Smart Cities forums are typically led by the technology sector, either telecommunications, internet access, or most recently artificial intelligence (AI) concerns. Each of these areas have grown and found new applications in the context of Smart Cities, however, these technology applications are just tools toward ends. Do digital communications and assistance enable or foster improved access to real, tactile, non-virtual goods and services such as transportation, food, housing, trash removal, health care, education, social interaction? These and other topics are not 'big tech', but are each critical to quality of life outcomes and are day-to-day necessities, comprising many of the touch points through which citizens interact with municipal agencies. Regarding Smart Cities, relationships have not been fully refined as to how best to merge the emerging generation of technology and related trends with more mundane but essential requirements of tactile services. How should municipal managers and operators bring the range of new technology tools (e.g. on-demand transit, automated vehicles, digital connectivity) to bear to improve functions serving real- physical- non-virtual needs? How do we make cities more efficient in providing access to services and opportunities for improved quality of life? This paper examines the current Smart City movement, emerging trends, and the need to put metrics with respect to the delivery, access, and provision of real-life needs. Using a few case studies of past, present, and projected future scenarios, this paper attempts to bring Smart Cities into the real cities domain, perhaps pushing the moniker away from 'Smart' to 'Efficient' - something that can be measured, counted, and assessed. Through the consideration of the next stage of the evolution of cities from 'Smart' to 'Efficient', the combined efforts and experience of multiple researchers at the NREL and their network of collaborators highlights the need for updates metrics that can be used to start guiding efforts toward productive initiatives to improve quality of life.

29 ENERGY PLANNING, POLICY, AND ECONOMY

FAIR Data and Interpretable AI Framework for Architectured Metamaterials

Our interdisciplinary effort successfully generated FAIR (Findable, Accessible, Interoperable, and Reusable) benchmark datasets for mechanical metamaterials while introducing a novel Artificial Intelligence (AI) framework known as Learning Refined Compositional Rules (LRCR). This framework was specifically designed to bridge the gap across varying computational length scales and extract the underlying physical mechanisms that connect a material's structural geometry to its bulk acoustic properties. Historically, the discovery of such structured materials relied heavily on human intuition or opaque, black-box optimization algorithms that were difficult to generalize. By combining interpretable machine learning techniques with rigorous experimental validation, this project established clear, generalizable design guidelines for tuning wave dispersion and controlling vibrations. Ultimately, the public availability of these structured datasets and algorithms will significantly reduce computational costs and accelerate the design of advanced multi-functional acoustic devices, offering broad societal impacts across fields like aerospace engineering, telecommunications, and biomedical implant design.

36 MATERIALS SCIENCE

Performance of synthetic DAS as a function of array geometry

Distributed Acoustic Sensing (DAS) can record acoustic wavefields at high sampling rates and with dense spatial resolution difficult to achieve with seismometers. Using optical scattering induced by cable deformation, DAS can record strain fields with spatial resolution of a few meters. However, many experiments utilizing DAS have relied on unused, dark telecommunication fibers. As a result, the geophysical community has not fully explored DAS survey parameters to characterize the ideal array design. This limits our understanding of guiding principles in array design to deploy DAS effectively and efficiently in the field. A better quantitative understanding of DAS array behavior can improve the quality of the data recorded by guiding the DAS array design. Here we use steered response functions, which account for DAS fiber’s directional sensitivity, as well as beamforming and back-projection results from forward modelling calculations to assess the performance of varying DAS array geometries to record regional and local sources. A regular heptagon DAS array demonstrated improved capabilities for recording regional sources over other polygonal arrays, with potential improvements in recording and locating local sources. These results help reveal DAS array performance as a function of geometry and can guide future DAS deployments.

58 GEOSCIENCES

High-Speed and Hysteresis-Free Near-Infrared Optical Hydrogen Sensor Based on Ti/Pd Bilayer Thin Films

Palladium (Pd) and titanium (Ti) exhibit opposite dielectric responses upon hydrogenation, with stronger effects observed in the near-infrared (NIR) region. Leveraging this contrast, we investigated Ti/Pd bilayer thin films as a platform for NIR hydrogen sensing—particularly at telecommunication-relevant wavelengths, where such devices have remained largely unexplored. Ti/Pd bilayers coated with Teflon AF (TAF) and fabricated via sequential electron-beam and thermal evaporation were characterized using optical transmission measurements under repeated hydrogenation cycles. The Ti (5 nm)/Pd (x = 2.5 nm)/TAF (30 nm) architecture showed a 2.7-fold enhancement in the hydrogen-induced optical contrast at 1550 nm compared to Pd/TAF reference films, attributed to the hydrogen ion exchange between the Ti and Pd layers. The optimized structure, with a Pd thickness of x = 1.9 nm, exhibited hysteresis-free sensing behavior, a rapid response time (t90 < 0.35 s at 4% H2), and a detection limit below 10 ppm. It also demonstrated excellent selectivity with negligible cross-sensitivity to CO2, CH4, and CO, as well as high durability, showing less than 6% signal degradation over 135 hydrogenation cycles. These findings establish a scalable, room-temperature NIR hydrogen sensing platform with strong potential for deployment in automotive, environmental, and industrial applications.

Chemistry

Entanglement swapping systems toward a quantum internet

We demonstrate conditional entanglement swapping, i.e. teleportation of entanglement, between time-bin qubits at the telecommunication wavelength of 1536.4 nm with high fidelity of 87%. Our system is deployable, utilizing modular, off-the-shelf, fiber-coupled, and electrically controlled components such as electro-optic modulators. It leverages the precise timing resolution of superconducting nanowire detectors, which are controlled and read out via a custom developed graphical user interface. The swapping process is described, interpreted, and guided using characteristic function-based analytical modeling that accounts for realistic imperfections. Our system supports quantum networking protocols, including source-independent quantum key distribution, with an estimated secret key rate of approximately 0.5 bits per sifted bit.

Davis, Samantha I. [Caltech] (ORCID:00000001999481

Optimal spin-qubit hallmarks of sulfur-vacancy defects in 4H-SiC: Design from first principles

We propose neutral defects in 4H-SiC comprising a silicon vacancy and a sulfur atom dopant substituting a carbon atom as an optically controllable spin qubit with application in quantum computing and quantum telecommunications. According to our state-of-the-art first-principles calculation, the proposed defect possess very promising qubit functionalities. This system once again confirms our hypothesis for the rational design of spin qubits and single-photon emitters. Importantly, the atoms of this system have high-abundance isotopes with zero nuclear spin ensuring high spin-coherence time of the qubit.

36 MATERIALS SCIENCE

Distributed optical fibre sensing in physical oceanography: emergence and future prospects

Distributed optical fibre sensing (DOFS) is a technology that enables continuous, real-time measurements of a range of environmental parameters along the length of a fibre optic cable. In this article, we review the recently emerged applications of DOFS techniques in physical oceanography and offer a perspective on the technology's potential for future growth within the field. The introduction of DOFS to physical oceanography is contextualised with a brief history of the technology, which spun off primarily from the use of seafloor-laid optical fibres for telecommunications purposes. The key components and underpinning physics of a DOFS system are outlined and, on their basis, the suite of variables that are observable with DOFS are discussed. The implementation factors of DOFS, which include trade-offs between measurement accuracy and spatio-temporal resolutions and ranges, are also examined. The physical oceanographic applications of DOFS to date are then illustrated with case examples of four distinct DOFS techniques: distributed temperature sensing (DTS), which can provide ocean temperature observations; distributed static strain sensing (DSS) and distributed acoustic sensing (DAS), which are sensitive to temperature, cable strain and strain-associated variables, such as pressure and ocean velocity; and ultra-long-range observations of ocean currents with optical interferometry. The forthcoming prospects of DOFS in physical oceanography are considered, and are proposed to include new fibre optic-based approaches to sense ocean salinity and measure through the water column. We conclude with reflections on the future role of DOFS within the Global Ocean Observing System, and highlight the opportunities provided by the existing world-wide network of seafloor-laid optical fibres.

Naveira Garabato, Alberto C. [Univ. of Southampton

Distributed and Secure Spectrum Sharing for 5G and 6G Networks

Secure spectrum sharing or spectrum co-existence of multiple 5G networks and future 6G networks is a powerful enabler technology. The National Spectrum Strategy (NSS) published by the White House in November, 2023, and the subsequent NSS implementation plan led by the National Telecommunication and Information Administration (NTIA) is the driver of a national effort to enable co-existence of government incumbents and commercial networks in selected spectrum bands. Cellular networks such as 5G & 6G and non-cellular Wi-Fi 6E & 7 are the prominent wireless technologies considered for co-existence with incumbent wireless links. Security of the spectrum sharing solutions is a must to make this transformation of spectrum use possible, specially for mission critical communications. However, current spectrum sharing solutions rely on centralized data bases with inherent vulnerabilities. This paper focuses on secure spectrum sharing among multiple 5G networks using unlicensed and shared frequency bands. It presents an innovative AI/ML based distributed spectrum sharing approach that can be autonomously used by multiple networks. Each sharing network uses its own observation of the Radio Frequency (RF) environment, which consists of RF measurements reported from the 5G User Equipment (UE), to adjust the transmission power levels for secure co-existence. Data is presented to illustrate the superior performance of this solution compared to other spectrum sharing solutions where each network can utilize usage data of the other networks. Finally it discusses how this efficient spectrum sharing solution can evolve in the future for the 6G networks.

5G

Entropy-defect synergy for dual luminescence mechanism in spinel: Time-resolved anti-counterfeiting and fingerprint visualization

Multimodal luminescent materials, while promising for anti-counterfeiting, often lack dynamic time-dependent responses and controllable spatial distribution, limiting their encryption capabilities in the spatiotemporal dimension. Here, this work presents a coordinated control strategy based on entropy and defect engineering, and uses a backpropagation (BP) neural network for material screening to successfully prepare spinel Mg 0.8 (Fe 0.04 Co 0.04 Ni 0.04 Cu 0.04 Zn 0.04 )Cr 2 O 4 (MgA 5 CO) phosphors with time-dependent dynamic luminescence behavior. This phosphor simultaneously activated the d-d transition luminescence (∼618 nm) derived from Co 2+ /Cr 3+ and the defect luminescence (∼398 nm) related to zinc vacancies (V Zn ) in a single-phase solid solution. The phosphor exhibits a time-dependent color evolution from pink to purple under fixed-wavelength excitation, due to the different excited-state dynamics and decay lifetimes associated with the d-d transition and defect luminescence. Structural characterization and spectral analysis confirmed the existence of V Zn and its significant role in defect luminescence process. The fluorescent and dynamic luminescent properties of entropy-based spinel oxide enable its use in advanced anti-counterfeiting applications like fingerprint recognition and color-changing dedicated anti-counterfeiting mark, showing promise in high-end and time-dynamic anti-counterfeiting fields. This research not only developed a new type of fluorescent dynamic anti-counterfeiting material, but also provided a new idea for constructing advanced optical functional materials with multiple luminescence mechanisms.

Defect project

Topochemical Synthesis and Electronic Structure of High-Crystallinity Infinite-Layer Nickelates on an Orthorhombic Substrate

Superconductivity in infinite-layer nickelates has stirred much research interest, to which questions regarding the nature of superconductivity remain elusive. A critical leap forward to address these intricate questions is through the growth of high-crystallinity infinite-layer nickelates, including the “parent” phase. Here, we report the synthesis of a high-quality thin-film nickelate, NdNiO 2 . This is achieved through the growth of a perovskite precursor phase (NdNiO 3 ) of superior crystallinity on the NdGaO 3 substrate by off-axis RF magnetron sputtering and a low-temperature topochemical reduction using NaH. We observe a nonlinear Hall effect at low temperatures in this “non-doped” phase. We further study the electronic properties using advanced X-ray scattering and first-principles calculations. We observe spectroscopic indications of the enhanced two-dimensionality and a reduced hybridization of Nd 5d and Ni 3d orbitals. These findings unlock new pathways for preparing high-quality infinite-layer nickelates and provide new insights into the intrinsic features of these compounds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH