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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Role of HF and Zr in the hydrogen embrittlement of Ta and Cb alloys

An attempt is made to characterize the hydrogen embrittlement of aged T-111 and similar Ta and Cb alloys and to describe the mechanisms believed responsible for the increased sensitivity of T-111 to low temperature hydrogen embrittlement after aging for 1000 hr or longer near 1040 C. A total of eight Ta-base alloys and two Cb-base alloys were investigated. The effects of pre-age annealing temperature, aging time, temperature and environment, and alloy composition on the susceptibility to hydrogen embrittlement were investigated. The primary method of determining the effects of these variables on the ductility of T-111 was by bend testing at 25 and -196 C. Fractured specimens were examined by the scanning electron microscope, electron microprobe, metallography, and X-ray diffraction.

Stephens, J. R.↗
NASA NTRS1983

The effects of Cr, Al, Ti, Mo, W, Ta, and Cb on the cyclic oxidation behavior of cast Ni-base superalloys at 1100 and 1150 C

Fifty Ni-base superalloys with concentrations of Cr, Al, Ti, Mo, W, Ta, and Cb systematically varied between two nonzero levels, were tested for cyclic oxidation resistance at 1100 and 1150 C. Oxidation resistance was interpreted in terms of the rate of specific weight change and the types of oxides formed. It is found that the resistance of the alloys to cyclic oxidation is largely determined by Al content, with a sharp increase in the oxidation resistance observed in the Al concentration range 5-8 at. pct. The effects of the other elements studied were small compared with that of aluminum. Best oxidation resistance characteristics were predicted for high Al (13 at. pct), low Cr (10 at. pct), low Ti (2 at. pct), low Cb (1 at. pct), and high Mo, W, and Ta (3 at. pct each). The effects of the refractory metals, however, are somewhat ambiguous and should be investigated further. Higher boron contents, which were unintentionally varied, were clearly detrimental even for the most resistant compositions.

Barrett, C. A.↗
NASA NTRS1986

The effect of Cr, Co, Al, Mo and Ta on a series of cast Ni-base superalloys on the stability of an aluminide coating during cyclic oxidation in Mach 0.3 burner rig

The influence of varying the content of Co, Cr, Mo, Ta, and Al in a series of cast Ni-based gamma/gamma'superalloys on the behavior of aluminide coatings was studied in burner rig cyclic oxidation tests at 1100 C. The alloys had nominally fixed levels of Ti, W, Cb, Zr, C, and B. The alloy compositions were based on a full 2(sup 5)-fractional statistical design supplemented by 10 star point alloys and a center point alloy. This full central composite design of 43 alloys plus two additional alloys with extreme Al levels allowed a complete second degree estimating equation to be derived from the 5-compositional variables. The weight change/time data for the coated samples fitted well to the paralinear oxidation model and enabled a modified oxidation attack parameter, K'(sub a) to be derived to rank the alloys and log K' (sub a ) to be used as the dependent variable in the estimating equation to determine the oxidation resistance of the coating as a function of the underlying alloy content. The most protective aluminide coatings are associated with the highest possible base ally contents of CR and Al and at a 4 percent Ta level. The Mo and Co effects interact but at fixed levels of 0, 5, or 10% Co. A 4% Mo level is optimum.

Zaplatynsky, I.↗
NASA NTRS1995

Advanced transportation system studies technical area 2(TA-2): Heavy lift launch vehicle development: Executive summary - volume 1

The purpose of the TA-2 contract was to provide advanced launch vehicle concept definition and analysis to assist NASA in the identification of future launch vehicle requirements. Contracted analysis activities included vehicle sizing and performance analysis, subsystem concept definition, propulsion subsystem definition (foreign and domestic), ground operations and facilities analysis, and life cycle cost estimation. This document is part of the final report for the TA-2 contract. The final report consists of three volumes: Volume 1 is the Executive Summary, Volume 2 is Technical Results, and Volume 3 is Program Cost Estimates. The document-at-hand, Volume 1, provides a summary description of the technical activities that were performed over the entire contract duration, covering three distinct launch vehicle definition activities: heavy-lift (300,000 pounds injected mass to low Earth orbit) launch vehicles for the First Lunar Outpost (FLO), medium-lift (50,000-80,000 pounds injected mass to low Earth orbit) launch vehicles, and single-stage-to-orbit (SSTO) launch vehicles (25,000 pounds injected mass to a Space Station orbit).

McCurry, J.↗
NASA NTRS1981

Development of W-Ta generator

This research program was used to further develop the existing W-Ta generator and to evaluate alternative adsorbents, preferably inorganic materials, as supports for the generator. During the first half year, combinations of non-complexing eluents and a variety of adsorbents, both inorganic and organic, were evaluated. Some of these adsorbents were synthetic, such as chelate resins that could be specific for tungsten. In the second half of the year, the stress was mainly on the use of complexing eluents because of the high affinity of hydrous oxides for tantalum, on the synthesis of chelate resins and on the use novel techniques (electrolytic) to solve the tantalum-adsorption problem.

Source record↗
NASA NTRS1986

High-temperature oxidation of a rapidly solidified amorphous Ta-Ir alloy

The oxidation products formed at 500 and 700 C on an amorphous Ta-44.5 at. pct Ir alloy in an Ar-0.1 percent O2 gas mixture were characterized using SEM, XRD, EPMA, TEM, STEM, AES, and XPS. Initially, a thin (3-4 nm) layer of Ta2O5 formed at the surface of the alloy. Continued growth of the Ta2O5, which occurred very rapidly, involved diffusion of oxygen anions from the Ta2O5/gas interface to the alloy/Ta2O5 interface, where tantalum was selectively oxidized. Because the oxide grew more quickly than iridium could diffuse back into the alloy, the iridium coalesced into platelets of crystalline iridium-rich alloy that were oriented approximately parallel to the oxide/alloy interface, and which became embedded in a matrix of Ta2O5. The unoxidized core remained in the glassy state. The oxidation process and/or the dissolution of oxygen into the unoxidized alloy caused the alloy to become embrittled.

Cotell, Catherine M.↗
NASA NTRS1987

Analysis of NiAlTa precipitates in beta-NiAl + 2 at. pct Ta alloy

Results are reported from experiments performed to identify the precipitates, and their orientation in the matrix, in a beta-NiAl alloy containing 2 at. pct. Ta after undergoing creep test at 1300 K. Test specimens formed by extruding hot powders were compressed at 1300 K for about 50 hr at a strain rate averaging 6/1 million per sec. The specimens were then thinned and examined under an electron microscope and by X-ray diffractometry. An intermetallic NiAlTa compound with a hexagonal Cl4 structure appeared as second phase precipitates in the samples, exhibiting plate-like shapes and a habit plane close to (012). The prism planes of the hexagonal NiAlTa precipitates paralleled the closest packed planes in the cubic beta-NiAl matrix.

Pathare, V.↗
NASA NTRS1987

Hemispherical emissivity of V, Nb, Ta, Mo, and W from 300 to 1000 K

The hemispherical emissivities of five transition elements, V, Nb, Ta, Mo, and W, have been measured from 300 to 1000 K, complementing earlier higher-temperature results. These low-temperature data, which are similar, are fitted to a Drude model in which the room-temperature parameters have been obtained from optical measurements and the temperature dependence of the dc resistivity is used as input to calculate the temperature dependence of the emissivity. A frequency-dependent free-carrier relaxation rate is found to have a similar magnitude for all these elements. For temperatures larger than 1200 K the calculated emissivity is always greater than the measured value, indicating that the high-temperature interband features of transition elements are much weaker than those determined from room-temperature measurements.

Cheng, S. X.↗
NASA NTRS1991

Oxidation characteristics of Ti-33Al-6Nb-1.4Ta

Static oxidation kinetics of the gamma titanium-aluminide alloy Ti-33Al-6Nb-1.4Ta (wt pct) have been investigated in air from 700 to 1000 C and in oxygen from 800 to 1000 C using thermogravimetric analysis. The oxidation kinetics were controlled by the presence of alumina for all oxygen exposures and in air below 800 C, while the kinetics in air above 800 C were more complex. Oxidation products were identified using X-ray diffraction techniques. Oxide scale morphology was examined by SEM and TEM of the surfaces and across sections of oxidized specimens. The oxidation products formed depended on the exposure: Al2O3 and TiO2 were identified on all specimens exposed in and air and oxygen; the nitride phases TiN and Ti2AlN were also found on specimens exposed in air.

Wallace, T. A.↗
NASA NTRS1995

Advanced Transportation System Studies Technical Area 2 (TA-2) Heavy Lift Launch Vehicle Development Contract: Technical Results - Volume 2

The sections in this report include: Single Stage to Orbit (SSTO) Design Ground-rules; Operations Issues and Lessons Learned; Vertical-Takeoff/Landing Versus Vertical-Takeoff/Horizontal-Landing; SSTO Design Results; SSTO Simulation Results; SSTO Assessment Results; SSTO Sizing Tool User's Guide; SSto Turnaround Assessment Report; Ground Operations Assessment First Year Executive Summary; Health Management System Definition Study; Major TA-2 Presentations; First Lunar Outpost Heavy Lift Launch Vehicle Design and Assessment; and the section, Russian Propulsion Technology Assessment Reports.

Source record↗
NASA NTRS2001

Radar Observations of Near Earth Asteroids 6489 Golevka and 4197 (1982 TA)

Radar observations of two near-Earth asteroids were performed using a bi-static radar technique with Kashima 34-m antenna and Usuda 64-m antenna as receiving stations and Goldstone 70-m antenna as a transmitting station. The asteroid 6489 Golevka was observed on June 15, 1995 when its distance from the Earth became 0.048 AU and the radar echo from the asteroid was detected from the data observed with Kashima 34-m antenna. The success of the trans-continental bistatic radar observations became the first detection of a radar echo from a solar system object beyond Moon in Japan. The asteroid 4197 (1982 TA) was observed on October 24, 1996 when its distance to the Earth became 0.086 AU. The radar echo signal from the asteroid was detected from both of the data observed at Kashima and at Usuda. The received signal was coherently sampled and recorded at both stations. By using these data, interferometric data analysis was examined.

Koyama, Yasuhiro↗
NASA NTRS2003

Oxidation of ZrB2-and HfB2-Based Ultra-High Temperature Ceramics: Effects of Ta Additions

Several compositions of ZrB2- and HfB2-based Ultra-High Temperature Ceramics (UHTC) were oxidized in stagnant air at 1627 C in ten minute cycles for times up to 100 minutes. These compositions include: ZrB2 - 20v% SiC, HfB2 - 20v% SiC, ZrB2 - 20v% SiC - 20v% TaSi2, ZrB2 - 33v% SiC, HfB2 - 20v% SiC - 20v% TaSi2, and ZrB2 - 20v% SiC - 20v% TaC. The weight change due to oxidation was recorded. The ZrB2 - 20v% SiC - 20v% TaSi2 composition was also oxidized in stagnant air at 1927 C and in an arc jet atmosphere. Samples were analyzed after oxidation by x-ray diffraction, field emission scanning electron microscopy, and energy dispersive spectroscopy to determine the reaction products and to observe the microstructure. The ZrB2 - 20v% SiC - 20v% TaSi2 showed the lowest oxidation rate at 1627 C, but performed poorly under the more extreme tests due to liquid phase formation. Effects of Ta-additions on the oxidation of the diboride-based UHTC are discussed.

Opila, Elizabeth↗