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At least 37 records · Page 2

Machine learning interatomic potential for predicting the thermal properties of uranium nitride

We present a combined computational and experimental investigation of the thermal properties of uranium nitride (UN), focusing on the development of a machine learning interatomic potential (MLIP) using the moment tensor potential framework. The MLIP was trained on density functional theory (DFT) data and validated against various quantities including energies, forces, elastic constants, phonon dispersion, and defect formation energies, achieving excellent agreement with DFT calculations, prior experimental results, and our thermal conductivity measurement. The potential was then employed in molecular dynamics simulations to predict key thermal properties such as melting point, thermal expansion, specific heat, and lattice thermal conductivity. To further assess model accuracy, we fabricated a UN sample and performed new thermal conductivity measurements representative of single-crystal properties, which showed strong agreement with the MLIP predictions. This work confirms the reliability and predictive capability of the developed potential for determining the thermal properties of UN.

36 - MATERIALS SCIENCE

Thermal properties of the Galilean satellites.

Radiometry in the 20-micron band of eclipses of each of the four Galilean satellites of Jupiter provides information about the thermal properties of the uppermost surface layers of these bodies. Their thermal inertias are all smaller than those of the moon or of Mercury; there is no evidence for atmospheres, and where the data are of high quality vertically homogeneous thermal properties are excluded. The thermal properties, together with other observational evidence, suggest that the surfaces of these satellites are largely composed of ices. A thin coating of frost provides the upper, low-conductivity layer, while the subsurface material maintains a high thermal conductivity by fusion of a mixture of ice and rock.

Morrison, D.

Effect of Temperature History on Thermal Properties of Additively Manufactured C-18150 Alloy Samples

The effects of thermal history on the thermal properties of C-18150 (Cu-1.5Cr-0.5Zr, wt.%) parts made by the laser powder-bed-fusion (L-PBF) additive manufacturing (AM) process with three different fabrication orientations (horizontal, angled, and vertical to the build direction) were investigated. A significant difference in thermal properties between as-fabricated and fully heat-treated L-PBF C-18150 samples was observed, and the mechanisms of such behaviors are discussed.

C-18150

Thermal Properties of Moving UV Features in Prominences

Multi-thermal features with speeds of 5-70 kilometers per second perpendicular to the line of sight are common in the prominences which showed traceable motions. These speeds are noticeably higher than the typical speeds of 5-20 kilometers per second observed in H-alpha data from "quiet" prominences and are more typical of "activated" prominences in which H-alpha blob speeds of up to 40 kilometers per second have been reported. In order to make a more quantitative determination of the thermal properties of the moving features seen in the UV, we use the SOHO instruments SUMER and CDS to take a time series of exposures from a single pointing position, providing a measurement of spectral line properties as a function of time and position along the slit. The resulting observations in lines spectral lines in a range of "transition region" temperatures allow us to analyze the thermal properties of the moving prominence sources as a function of time.

Kucera, Therese A.

Review of electrical and thermal properties of carbon and graphite

Some of the electrical and thermal properties of ordered and partially ordered carbons are reviewed. Earlier and current research areas are discussed relative to electrical properties of pyrolytic and polycrystalline graphite; thermal, electrical, and magnetic properties of graphitizable and glassy carbon with heat treatment temperatures in the range 600-2500 C; Josephson junction-like and switching behavior in carbon films; and some high-conductivity and superconducting compounds made from carbon. Due to the newness and complexity of many of the areas examined, the results are not always completely understood, nor have these areas been completely investigated experimentally. Suggestions for future research are made.

Woollam, J. A.

The anomalous thermal properties of glasses at low temperatures

While experimentally there is great regularity below 1 deg K in the behavior of a particular thermal property for all amorphous dielectrics it is not understood why these properties should differ from those of crystalline dielectrics, since it would seem that at low temperatures long-wavelength elastic waves, similar in both cases, would determine the thermal properties. A model involving systems having very few levels is used in the present study, although the relation between the model's systems and the nature of the glassy state is not known. It is shown, among other effects, that: specific heat measurements above 0.1 K indicate a distribution of local modes independent of energy; ultrasonic velocity measurements give information about phonon-local mode coupling parameters; and thermal expansion and far infrared experiments indicate a phonon-assisted tunneling model.

Pohl, R. O.

A geologic evaluation of thermal properties for the Elysium and Aeolis quadrangles of Mars

The results of an analysis of high-resolution thermal inertia data (obtained with the IR Thermal Mapper) for the Elysium and Aeolis quadrangles of Mars are presented. The results indicate that aeolian features, both with dark and light albedos relative to their surroundings, have thermal inertias higher than that of the surrounding terrains. On the other hand, terrains with distinctive surface relief do not have distinguishable thermal properties, even when these terrains can be spatially resolved from surrounding units. Thermal inertias for individual geologic units within the two quadrangles appear to be more strongly controlled by the location of the terrain in either the northern plains or the southern highlands than by properties intrinsic to the unit. The similarity of regional thermal properties observed at both high and low spatial resolutions indicates a regional homogeneity of much of the Martian surface at scales larger than 5 km.

Zimbelman, James R.

Thermal Properties of Microstrain Gauges Used for Protection of Lithium-Ion Cells of Different Designs

The purpose of this innovation is to use microstrain gauges to monitor minute changes in temperature along with material properties of the metal cans and pouches used in the construction of lithium-ion cells. The sensitivity of the microstrain gauges to extremely small changes in temperatures internal to the cells makes them a valuable asset in controlling the hazards in lithium-ion cells. The test program on lithium-ion cells included various cell configurations, including the pouch type configurations. The thermal properties of microstrain gauges have been found to contribute significantly as safety monitors in lithium-ion cells that are designed even with hard metal cases. Although the metal cans do not undergo changes in material property, even under worst-case unsafe conditions, the small changes in thermal properties observed during charge and discharge of the cell provide an observable change in resistance of the strain gauge. Under abusive or unsafe conditions, the change in the resistance is large. This large change is observed as a significant change in slope, and this can be used to prevent cells from going into a thermal runaway condition. For flexible metal cans or pouch-type lithium-ion cells, combinations of changes in material properties along with thermal changes can be used as an indication for the initiation of an unsafe condition. Lithium-ion cells have a very high energy density, no memory effect, and almost 100-percent efficiency of charge and discharge. However, due to the presence of a flammable electrolyte, along with the very high energy density and the capability of releasing oxygen from the cathode, these cells can go into a hazardous condition of venting, fire, and thermal runaway. Commercial lithium-ion cells have current and voltage monitoring devices that are used to control the charge and discharge of the batteries. Some lithium-ion cells have internal protective devices, but when used in multi-cell configurations, these protective devices either do not protect or are themselves a hazard to the cell due to their limitations. These devices do not help in cases where the cells develop high impedance that suddenly causes them to go into a thermal runaway condition. Temperature monitoring typically helps with tracking the performance of a battery. But normal thermistors or thermal sensors do not provide the accuracy needed for this and cannot track a change in internal cell temperatures until it is too late to stop a thermal runaway.

Jeevarajan, Judith