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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Surface activation of air oxidation of hydrazine on kaolinite. 2. Consideration of oxidizing/reducing entities in relationship to other compositional, structural, and energetic factors

The rates (previously reported) for the air oxidation of hydrazine on kaolinite and substituent oxides of kaolinite showed a complex dependence on the relative amounts of several structural oxidizing/reducing entities within the reaction-promoting solids. The rates indicated an important role of the clay but no dominant role of any one of the oxidizing/reducing entities. In this paper we review (a) the reaction-promoting activity of these centers as studied in other systems, (b) various spectroscopic results showing interaction between these entities in clays, and (c) reported spectroscopic studies of the complexation between hydrazine and aluminosilicate surfaces as a whole, in an effort to propose a mechanism for the reaction. Whereas some uncertainties remain, the present synthesis concludes that a mechanism operating through single electron/hole transfers and hydrogen atom transfers by discrete centers is adequate to explain the observed rate behaviors including the observed second order dependence of the oxidation rate on catalyst amount. The effects of these operations on the catalyst can result in no alteration of, or complete or partial electronic relaxation of its contingent of trapped separated charge pairs. The degree to which surface complexation as a whole, intercalation, or luminescent processes may also be associated with the reaction cannot be adequately assessed with the information in hand.

NASA Program Exobiology↗
NASA NTRS1991

Kaolinite-catalyzed air oxidation of hydrazine: Consideration of several compositional, structural and energetic factors in surface activation

Clay minerals have been shown to have numerous, curious, energetic properties by virtue of ultra-violet light release which can be triggered by gentle environmental changes such as wetting and dewetting by a variety of liquids, unique among them water and hydrazine. Since both water and hydrazine play multiple key roles in the air-oxidation of hydrazine on kaolinite surfaces, this reaction would seem to have prime potential for studying interrelationships of energy storage, release and chemical reactivity of clay surfaces, capacities basic to either the Bernal or Cairns-Smith roles of minerals in the origin of life. Establishment of the capacity for stored electronic energy to significantly alter surface chemistry is important, regardless of the reaction chosen to demonstrate it. Hydrazine air oxidation is overawingly complex, given the possibilities for step-wise control and monitoring of parameters. In the light of recently extended characterization of the kaolinite and model sheet catalysts we used to study hydrazine oxidation and gamma-irradiated silica, previous studies of hydrazine air-oxidation on aluminosilicate surfaces have been reevaluated. Our former conclusion remains intact that, whereas trace structural and surface contaminants do play some role in the catalysis of oxidation, they are not the only, nor even the dominant, catalytic centers. Initial intermediates in the oxidation can now be proposed which are consistent with production via O(-)-centers as well as ferric iron centers. The greater than square dependence of the initial reaction rate on the weight of the clay is discussed in the light of these various mechanistic possibilities.

Coyne, L. M.↗
NASA NTRS1992

Surface activation of Concorde by Be-7

Activation analysis of two airframe components from the Concorde aircraft has identified the presence of Be-7, a nuclide found by other investigators that was deposited on the forward edge of the Long Duration Exposure Facility (LDEF) structure. The results of the Concorde analysis indicate that this phenomenon is very much a surface effect, and that the areal densities of the Be-7 are comparable to those found for LDEF. The collection of Be-7 by the aircraft must be greater than in the case of LDEF (since duration for which Concorde is accumulating the nuclide is shorter) and is of the order of 1.2 to 41 nuclei/sq cm(-)s(exp -1) depending upon assumptions made regarding the altitude at which collection becomes appreciable, and the efficiency of the process which removes the radionuclide.

Truscott, P. R.↗
NASA NTRSDate not supplied

Orbital Drag Near Small Bodies Due to Lofted Fines from Surface Activity

Recent exploratory missions have revealed that small bodies are more granular and dusty than previously expected. As a result of landings, mining, impacts, or other natural phenomena, bodies with negligible atmospheres such as moons and asteroids may experience an exospheric environment abundant in lofted fines. Significant quantities of these may interfere with the nominal trajectories of spacecraft in low orbits. This paper applies data collected from remote sensor and direct sample collection to approximate the density of atmospheric fines in three environments: high-velocity lunar fines generated during landings, the coma of active comets, and cryovolcanic plumes from the Saturnian moon Enceladus. It also investigates the threshold of activity that would induce concerns about a spacecraft's nominal mission. Coupled motion of spacecraft navigation and control is expressed in SE(3).

Fines↗
NASA NTRS1991

Surface activation of Concorde by Be-7

Activation analysis of two airframe parts from Concorde aircraft has identified the presence of Be-7, a nuclide which was found by other investigators to have been collected on the forward edge of the Long Duration Exposure Facility (LDEF) structure. The results of the Concorde analysis indicate that this phenomenon is very much a surface effect, and that the areal densities of the Be-7 are comparable to those found for LDEF. The collection of Be-7 by the aircraft must be greater than in the case of LDEF (since the duration for which Concorde is accumulating the nuclide is shorter) and is of the order of 1.9 to 40 nuclei sq cm/s, depending upon assumptions made regarding the efficiency of the process which removes the radionuclide.

Truscott, P. R.↗
NASA NTRS1987

Surface activities on the first piloted Mars mission

The objectives of the first piloted Mars mission, in addition to safe Mars landing and return to earth for the crew, would encompass a demonstration of human working capabilities in the Martian environment, the exploration of the landing site, and the establishment of that planet's potential for the support of permanent human habitation. An evaluation is presently made of constraints on Martian service activities, mission risk considerations, and the three mission profiles that can be envisioned for total durations of 14, 21, and 35 months.

Duke, Michael B.↗
NASA NTRS1996

Dual-Active-Surface Miniature Plug-Type Heat-Flux Gauges

Improved miniature plug-type heat-flux gauges developed for determining fluxes of heat through surfaces on both sides of heat-transfer walls. Walls are those of heat exchangers, engine housings, furnaces, chemical reactors, or any of variety of other structures in which fluxes of heat important quantities one seeks to measure.

Liebert, Curt H.↗
NASA NTRS2000

A Brief Summary of the Geomorphic Evidence for an Active Surface Hydrologic Cycle in Mars' Past

Because Mars is just over half the Earth's diameter (about 6800 km), it does not exhibit global tectonism on a scale comparable to Earth and Venus. But because it is still a large body compared to Mercury and the moon, it has had an atmosphere and climate over the history of the solar system. This is why Mars has been able to retain surfaces produced both through volcanic and climatic processes that are intermediate in age between volcanic surfaces on the moon and Mercury and both types of surfaces on Venus and Earth. For the purposes of this discussion, this has important implications about the origins and evolution of topographic depressions that potentially may have contained lakes. Tectonism is probably the most important process on Earth for producing closed depressions on the continents, and is clearly responsible for maintenance of the ocean basins through geologic time. This is probably also true for depressions in the highland terrains and lowland plains of Venus. On Mars, however, tectonism appears limited to relatively small amounts of regional extension, compression, and vertical motion largely due to crustal loading of the two major volcanic provinces - Tharsis and Elysium Impact craters and large impact basins (including all or parts of the northern plains) are clearly more important sites for potential lake basins on Mars, though they were likely more important on Earth, and Venus as well, during the period of heavy meteorite bombardment throughout the solar system prior to 3.5 Ga. Comparisons of the relative importance of other formative processes on Mars with those on Earth are less obvious, and some may be quite speculative, since our understanding of the early Martian environment is still rather limited. Additional information is contained in the original extended abstract.

Parker, T. J.↗
NASA NTRS2002

Mapping the Potential for Eolian Surface Activity in Grasslands of the High Plains using Landsat Images

There are over 100,000 square kilometers of eolian sand dunes and sand sheets in the High Plains of the central United States. These land-forms may be unstable and may reactivate again as a result of land-use, climate change, or natural climatic variability. The main goal of this thesis was to develop a model that could be used to map an estimate of future dune activity. Multi-temporal calibrated Landsats 5 Thematic Mapper (TM) and 7 Enhanced Thematic Map per Plus (ETM+) NDVI imagery were used in conjunction with the CENTURY vegetation model to correlate vegetation cover to climatic variability. This allows the creation of a predicted vegetation map which, combined with current wind and soil data, was used to create a potential sand transport map for range land in the High Plains under drought conditions.

Gutmann, Ethan Dain↗
NASA NTRS2003

Lunar Surface Reference Missions: A Description of Human and Robotic Surface Activities

Most medical equipment to the International Space Station (ISS) is manisfested as part of the U.S. or the Russian medical hardware systems. However, certain medical hardware is also available as part of the Human Research Facility. The HRF and the JSC Medical Operations Branch established a Memorandum of Agreement for joint use of certain medical hardware, including the HRF ultrasound system, the only diagnostic imaging device currently manifested to fly on ISS. The outcome of a medical contingency may be changed drastically, or an unnecessary evacuation may be prevented, if clinical decisions are supported by timely and objective diagnostic information. In many higher-probability medical scenarios, diagnostic ultrasound is a first-choice modality or provides significant diagnostic information. Accordingly, the Clinical Care Capability Development Project is evaluating the HRF ultrasound system for its utility in relevant clinical siruations on board ISS. For effective management of these ultrasound-supported ISS medical scenarios, the resulting data should be available for viewing and interpretation on the ground, and bidirectional voice communication should be readily available to allow ground experts (sonographers, physicians) to provide guidance to the Crew Medical Officer. It may also be vitally important to have the capability of real-time guidance via video uplink to the CMO-opertor during an exam to facilitate the diagnosis in a timely fashion.

Duke, Michael B.↗
NASA NTRS2022

Reference Surface Activities for Crewed Mars Mission Systems and Utilization

This document details constraints and considerations in planning daily activity timelines for crewed exploration on Mars. This work was done for the purpose of estimating how much time during each Martian day (hereafter referred to as a sol) might be available for exploration activities, (also referred to as utilization activities in this document), after accounting for crew and equipment care. These results become part of the factors taken into consideration as specific goals and objectives are assembled into a mission plan.

Stephen J Hoffman↗
NASA NTRSDate not supplied

Orbital Drag Near Small Bodies Due to Lofted Fines from Surface Activity

Small bodies have been shown to be more granular and dusty than previously expected. Furthermore, as a result of landings, mining, or natural impacts, bodies with negligible atmospheres, such as moons and asteroids, may experience an exospheric environment abundant in lofted fines. Significant quantities of these may interfere with the nominal trajectories of spacecraft in low orbits. This work investigates the threshold of activity that would induce concerns to a spacecraft's nominal mission around various bodies including the Moon, Bennu, Comet Wild-2, and Phobos. Coupled motion of spacecraft navigation and control is expressed in SE(3).

Fines↗
DOE OSTI2026

Tuning the Coordination Environment of Rh Single Atoms on Highly Dispersed Reducible Oxides for Enhanced Reverse Water-Gas Shift Performance

Controlling the dynamic mobility of catalyst surface active sites and their interactions with the surrounding environment is critical in generating active surfaces that directly influence the catalytic activity and selectivity. Here, we report a strategy for tailoring the dispersion and electronic environment of single atom Rh catalysts by decorating the alumina support with highly dispersed (HD) cerium and molybdenum oxides. The resulting catalysts exhibit markedly different behavior in the Reverse Water Gas Shift (RWGS) reaction. In particular, Rh/MoOx(HD)/Al2O3 maintains atomically dispersed Rh even at elevated temperatures (up to 400 °C), achieving CO selectivity of up to 100% and resists sintering via the formation of a newly developed structure featuring Rh single atoms embedded in MoOx clusters. In situ spectroscopy and microscopy analyses confirm the stabilization of Rh and the dynamic evolution of Rh–Mo coordination under reaction conditions. Our findings highlight the power of support modification in steering active site structure and activity, offering a pathway toward enhanced and tunable single atom catalysts for CO2 valorization.

CO selectivity↗
NASA NTRS2010

Active Flow Control Stator With Coanda Surface

Active Flow Control increases the permissible aerodynamic loading. Curved surface near the trailing edge ("Coanda surface"): a) increases turning -> higher pressure ratio. b) controls boundary layer separation -> increased surge margin. Objective: Reduce the number of vanes or compressor stages. Constraints: 1. In a real compressor, the vane must still function entirely without blowing. 2. Maintain the flow exit angle of the reference stator despite the resulting increase in stator loading.

Guendogdu↗