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At least 37 records · Page 2

Chondrite chronology by initial Sr-87/Sr-86 in phosphates?

New data are presented on Rb-Sr isotope analyses of phosphates from nine ordinary chondrites, including accurate identification of initial Sr-87/Sr-86. The initial Sr-87/Sr-86 ratios found in this study were generally significantly higher than the more primitive initial Sr-87/Sr-86 ratios inferred for carbonaceous chondrite refractory inclusions, basaltic achondrites, or bulk ordinary chondrites. Such elevation of initial Sr-87/Sr-86 is generally considered to reflect isotopic redistribution during metamorphism. However, in this study, no evident correlation was found between the phosphate initial Sr-87/Sr-86 compositions and the metamorphic grade. Two possible alternative hypotheses for high initial Sr-87/Sr-86 ratios are considered.

Podosek, Frank A.↗

Elevated initial Sr-87/Sr-86 in ordinary chondrite metal

The metal phase of ordinary chondrites has been found to contain a complex assemblage of non-metal phases, evidently formed when elements such as Si, Cr and P, originally dissolved in the metal, were subsequently oxidized and exsolved. We have investigated the Rb-Sr isotopic system in samples of H-chondrite metal, finding small but nontrivial amounts of Sr, apparently concentrated toward the surface of metal grains, and characterized by pronounced excesses of Sr-87/Sr-86 in chondritic metal can plausibly account for the characteristically elevated initial Sr-87/Sr-86 found in ordinary chondrite phosphates, but it remains unclear when and where the metal experienced the high Rb/Sr environment needed to account for such high Sr-87/Sr-86. We have previously reported Rb-Sr data for separated metal from Dhajala (H3), Forest Vale (H4) and Estacado (H6). Here we report data for two size fractions (80-160 and 280-450 microns) of separated metal from the H4 chondrite Ste. Marguerite. These samples were etched twice (.5N HCl for one hour) before dissolution (6N HCl). Aliquots of the solutions were spiked for Fe, Ca and Rb + Sr. The results for Ste. Marguerite metal are presented; errors are two-sigma and elemental concentrations are stated in terms of total sample weight.

Podosek, F. A.↗

Preliminary airborne measurements for the SR-71 sonic boom propagation experiment

SR-71 sonic boom signatures were measured to validate sonic boom propagation prediction codes. An SR-71 aircraft generated sonic booms from Mach 1.25 to Mach 1.6, at altitudes of 31,000 to 48,000 ft, and at various gross weights. An F-16XL aircraft measured the SR-71 near-field shock waves from close to the aircraft to more than 8,000 ft below, gathering 105 signatures. A YO-3A aircraft measured the SR-71 sonic booms from 21,000 to 38,000 feet below, recording 17 passes. The sonic booms at ground level and atmospheric data were recorded for each flight. Data analysis is underway. Preliminary results show that shock wave patterns and coalescence vary with SR-71 gross weight, Mach number, and altitude. For example, noncoalesced shock wave signatures were measured by the YO-3A at 21,000 ft below the SR-71 aircraft while at a low gross weight, Mach 1.25, and 31,000-ft altitude. This paper describes the design and execution of the flight research experiment. Instrumentation and flight maneuvers of the SR-71, F-16XL, and YO-3A aircraft and sample sonic boom signatures are included.

Haering, Edward A., Jr.↗

Sm-Nd and Rb-Sr Ages for Northwest Africa 2977, A Young Lunar Gabbro from the PKT

Northwest Africa (NWA) 2977 is an olivine gabbro cumulate equivalent to one of the lithologies in lunar mare breccia NWA 773 [1,2,3]. The Ar-39-Ar-40 age is 2.77+/-0.04 Ga based on the last approx.57% of the gas release [4], similar to results for NWA 773 [5]. A Sm-Nd age (T) of 2.865+/-0.031 Ga and Epsilon(sub Nd) = -7.84+/-0.22 for the NWA 773 gabbro reported by [6] has been revised to T = 2.993+/-=0.032 Ga, Epsilon(sub Nd) -4.5+/-0.3 [7]. Sm-147-Nd-143 isochron for NWA 2977: Whole rock, pyroxene, olivine, plagioclase, whole rock leachate (approx.phosphate) and the combined leachates from the mineral separates yield a well defined Sm-Nd isochron for an age T = 3.10+/-0.05 Ga and Epsilon(sub Nd-CHUR) = -3.74+/-0.26 [8], or Epsilon(sub Nd-HEDR) = -4.61+/-0.26 [9]. Rb-87-Sr-87 isochron: NWA 2977 contains only a modest amount of Rb and/or Sr contamination. The Sr-isotopic composition of the contaminant closely resembles that of seawater. The whole rock residue after leaching combined with leach residues for plagioclase and pyroxene define an isochron age of 3.29+/-0.11 Ga for initial Sr-87/Sr-86 = 0.70287+/-18. The olivine residue, with lower Sr abundance of approx 1.5 ppm, is only slightly displaced from the isochron. The relatively small uncertainties of the Rb-Sr isochron parameters and near-concordancy with the Sm-Nd age indicate that both the Rb-Sr and the Sm-Nd ages are reliable.

Nyquist, L. E.↗

Structural evolution, electrochemical kinetic properties, and stability of A-site doped perovskite Sr(1-x)Yb(x)CoO(3-δ)

Mixed ionic and electronic conducting (MIEC) perovskite SrCoO(3-δ) is a widely studied (electro)catalyst for the oxygen reduction reaction (ORR) and possesses different crystal structures at different temperatures. These temperature dependent phase transitions significantly impact the ordering of oxygen vacancies and electrochemical kinetic properties as well as the reliability of the related devices. Some of the crystal structures formed, e.g. hexagonal phases, turn out to be almost impermeable to oxygen gas. Therefore, it is important to stabilize the crystal structure of SrCoO(3-δ) that favors the ORR over a wide temperature range. Herein, the partial substitution of the A-site Sr with Yb is systematically studied, including synthesis, characterization and analysis of structural evolution, electrochemical kinetic properties, thermal stability, and stability in a CO2-containing atmosphere. The results indicate that Sr(0.90)Yb(0.10)CoO(3-δ) is able to stabilize the tetragonal crystal structure with less ordered oxygen vacancies, leading to polarization resistances of 0.051, 0.115 and 0.272 U sq.cm at 750, 700 and 650 °C, respectively, on symmetrical cells. Sr(0.90)Yb(0.10)CoO(3-δ) demonstrates a very stable surface oxygen vacancy distribution and electronic structure near oxygen vacancies but dissociation of adsorbed oxygen molecules into atomic oxygen is affected by surface Sr segregation, and polarization resistance degradation is mainly induced by surface Sr segregation. Furthermore, Sr(0.90)Yb(0.10)CoO(3-δ) exhibits excellent thermal stability as well as excellent recovery stability and improved polarization performance after a few pure air/CO2-containing air treatment cycles at 700 °C. However, a hysteresis behavior of polarization performance is observed at 650 °C during gas cycling treatment, which may cause long-term degradation of the Sr(0.90)Yb(0.10)CoO(3-δ) electrode. The different polarization behaviors during gas cycling treatment are induced by different sensitivities of the formed surface strontium carbonate and chemisorbed surface oxo-carbonaceous species to different operating temperatures.

electrochemical kinetic↗

Direct Simulation Monte Carlo Studies of the Gas Sampling for the VATMOS-SR Mission Concept

VATMOS-SR (Venus ATMOSpheric - Sample Return) is a small spacecraft mission concept which would return a gas sample from the upper atmosphere of Venus to Earth for scientific analysis. This could be the first sample return mission for an extra-terrestrial atmosphere, and potentially the first sample return from an Earth-sized planet. The VATMOS-SR mission concept consists of a SmallSat atmospheric sampling probe (45 deg. sphere/cone geometry, <1 m diameter) that is designed to skim through the Venus upper atmosphere and acquire gas samples below the homopause altitude (around ~110 km altitude), where the different atmospheric gases are mixed. The velocity of the spacecraft where sampling would occur is expected to be between ~10.5 km/s and ~13.1 km/s, depending on the trajectory chosen. This presentation will discuss hypervelocity sampling in the upper atmosphere of Venus, with respect to the VATMOS-SR mission concept. VATMOS-SR would enable critical atmospheric measurements to form a full picture of how, why, and when Venus evolved to be so different from Earth and Mars. The abundances and isotopic compositions of volatile elements (such as N, C, S, O and the noble gases) in planetary atmospheres record volatile delivery during accretion, outgassing from planetary interiors, and atmospheric loss to space. Precise and accurate determinations of atmospheric volatile signatures are the key to understanding the origins and geodynamical evolution of Venus compared to the other terrestrial planets. Hypersonic sampling poses unique technical and scientific challenges. To ensure it is possible to relate the composition of the sampled gases to the free stream atmospheric composition, large-scale numerical simulations are employed to model the flow through the VATMOS-SR sampling system. In particular, an emphasis is placed on quantifying noble gas isotopic fractionation that occurs during the sample acquisition and transfer process in order to determine how measured isotopic ratios of noble gases in the sample compare to actual isotopic ratios in the Venusian atmosphere. The Direct Simulation Monte Carlo (DSMC) code SPARTA, an open source software package developed by Sandia National Laboratories, is used in this work. SPARTA, based on Bird’s DSMC method, is a molecular-level gas-kinetic technique. As SPARTA is able to model hypervelocity reacting flows in strong chemical and thermal non-equilibrium, this software package is well suited to determine relevant flow properties for the VATMOS-SR mission concept, and to numerically quantify the expected level of elemental and/or isotopic fractionation in the sample acquired by VATMOS-SR. This presentation will show results from 3D simulations correlating the noble gas isotopic fractionation in the gas acquired at hypervelocity speeds to its ambient atmosphere value. In particular, emphasis will be placed at Xenon isotopes of masses 128 and 130, as precise measurements of that ratio would yield a comparison to Earth’s atmosphere. Additionally, sensitivity studies that quantify the uncertainties due to the freestream parameters as well as the modeling parameters will be performed.

direct simulation Monte Carlo↗

The VATMOS-SR Mission Concept: DSMC Studies of the Gas Sampling

VATMOS-SR (Venus ATMOSpheric - Sample Return) is a small spacecraft mission concept that would return a gas sample from the upper atmosphere of Venus to Earth for scientific analysis. This could be the first sample return mission for an extra-terrestrial atmosphere and potentially the first sample return from an Earth-sized planet. The VATMOS-SR mission concept consists of a SmallSat atmospheric sampling probe (45 deg. sphere/cone geometry, <1 m diameter) that is designed to skim through the Venus upper atmosphere and acquire gas samples below the homopause altitude (around ~110 km altitude), where the different atmospheric gases are mixed. The velocity of the spacecraft where sampling would occur is expected to be between ~10.5 km/s and ~13.1 km/s, depending on the trajectory chosen. This presentation will discuss hypervelocity sampling in the upper atmosphere of Venus with respect to the VATMOS-SR mission concept. VATMOS-SR would enable critical atmospheric measurements to form a complete picture of how, why, and when Venus evolved to be so different from Earth and Mars. The abundances and isotopic compositions of volatile elements (such as N, C, S, O, and the noble gases) in planetary atmospheres record volatile delivery during accretion, outgassing from planetary interiors, and atmospheric loss to space. Precise and accurate determinations of volatile atmospheric signatures are the key to understanding the origins and geodynamical evolution of Venus compared to the other terrestrial planets. Hypersonic sampling poses unique technical and scientific challenges. To ensure it is possible to relate the composition of the sampled gases to the free stream atmospheric composition, large-scale numerical simulations are employed to model the flow through the VATMOS-SR sampling system. In particular, an emphasis is placed on quantifying noble gas isotopic fractionation that occurs during the sample acquisition and transfer process to determine how measured isotopic ratios of noble gases in the sample compared to actual isotopic ratios in the Venusian atmosphere. The Direct Simulation Monte Carlo (DSMC) code SPARTA, an open-source software package developed by Sandia National Laboratories, is used in this work. SPARTA, based on Bird’s DSMC method, is a molecular-level gas-kinetic technique. As SPARTA is able to model hypervelocity reacting flows in strong chemical and thermal non-equilibrium, this software package is well suited to determine relevant flow properties for the VATMOS-SR mission concept and to numerically quantify the expected level of elemental and/or isotopic fractionation in the sample acquired by VATMOS-SR. This presentation will show results from 3D simulations correlating the noble gas isotopic fractionation in the gas acquired at hypervelocity speeds to its ambient atmosphere value. In particular, emphasis will be placed on Xenon isotopes of masses 128 and 130, as precise measurements of that ratio would yield comparison to Earth’s atmosphere. Additionally, sensitivity studies that quantify the uncertainties due to the freestream parameters, as well as the modeling parameters, will be performed.

direct simulation Monte Carlo↗

Rb-Sr studies of CI and CM chondrites

Rb-Sr whole rock analyses have been performed on 2 CI and 3 CM chondrites. Four of these stones (Ivuna, Orgueil, Cold Bokkeveld and Erakot) were previously studied in this laboratory and were shown to be discordant from a 4.6 Gyr isochron. The fifth, Murchison, was not previously studied. The new data support the discordance of the first four stones, and indicate that Murchison is also discordant. Studies of Sr isotope ratios in unspiked Orgueil show that the discordance is not due to inhomogeneities in the Sr-84/Sr-86 ratio caused by incomplete mixing of nucleosynthesis products. In order to gauge the effects of weathering, two leaching experiments were performed on fresh, interior samples of Murchison; one for a period of 1.5 hr and the other for 117 hr. The results indicate that the relative solubility of nonradiogenic Sr is approximately twice that of Rb and radiogenic Sr is more soluble than the nonradiogenic Sr.

Mittlefehldt, D. W.↗

Oxidation of the Si(100) surface promoted by Sr overlayer - An X-ray photoemission study

The interaction of strontium films with the underlaying Si (100) surface and the Sr-promoted low-temperature oxidation of Si were investigated, using XPS, at three different Sr coverages (theta): theta = 0.55 monolayer (ML), theta = 1 ML, and theta = 1.85 ML. Oxygen adsorption was studied both at room temperature and at 500 C, and at oxygen exposures up to 2 x 10 to the 6th L (1 L = 10 to the -6th torr) and 2 x 10 to the 5th L, respectively. The XPS spectra of the Si2p, O1s, and Sr3d core levels were measured for the atomically clean Si, the Sr-covered Si, and for the Sr-covered Si after each oxygen exposure. Results indicate that Sr interacts with the Si(100) surface forming a strong ionic bond, and that Sr promotes the oxidation of the Si (100) surface.

Mesarwi, A.↗

Derivation of Apollo 14 High-Al Basalts at Discrete Times: Rb-Sr Isotopic Constraints

Pristine Apollo 14 (A-14) high-Al basalts represent the oldest volcanic deposits returned from the Moon [1,2] and are relatively enriched in Al2O3 (>11 wt%) compared to other mare basalts (7-11 wt%). Literature Rb-Sr isotopic data suggest there are at least three different eruption episodes for the A-14 high-Al basalts spanning the age range approx.4.3 Ga to approx.3.95 Ga [1,3]. Therefore, the high-Al basalts may record lunar mantle evolution between the formation of lunar crust (approx.4.4 Ga) and the main basin-filling mare volcanism (<3.85 Ga) [4]. The high-Al basalts were originally classified into five compositional groups [5,6], and then regrouped into three with a possible fourth comprising 14072 based on the whole-rock incompatible trace element (ITE) ratios and Rb-Sr radiometric ages [7]. However, Rb-Sr ages of these basalts from different laboratories may not be consistent with each other because of the use of different 87Rb decay constants [8] and different isochron derivation methods over the last four decades. This study involved a literature search for Rb-Sr isotopic data previously reported for the high-Al basalts. With the re-calculated Rb-Sr radiometric ages, eruption episodes of A-14 high-Al basalts were determined, and their petrogenesis was investigated in light of the "new" Rb-Sr isotopic data and published trace element abundances of these basalts.

Hui. Hejiu↗

Chemical and Sr-isotopic characteristics of the Luna 24 samples

The chemical and Sr isotopic characteristics of Luna 24 bulk soil samples are determined and interpreted within the framework of lunar mare basalt evolution. Major and trace element compositions lead to the suggestion of candidate rock types consisting of a basalt/gabbro with very low TiO2 and MgO content (52%), a very low TiO2 basalt with 10% MgO (23%), olivine vitrophyre (20%), low K Fra Mauro basalt (4%) and anorthositic gabbro (1%). The proposed compositions are supported by the agreement of mixing models based on the proposed compositions with observed soil compositions. Sr ratios for plagioclase samples imply a lower Sr-87/Sr-86 value for low Mg soils than for other mare basalts and higher Rb/Sr and a more evolved Sr ratio in high Mg basalts. Rb, Sr and rare earth element compositions for low Mg basalts fit a model of partial remelting of cumulates containing small amounts of plagioclase.

Nyquist, L. E.↗

Preliminary measurement of the noise from the 2/9 scale model of the Large-scale Advanced Propfan (LAP) propeller, SR-7A

Noise data on the Large-scale Advanced Propfan (LAP) propeller model SR-7A were taken into the NASA Lewis 8- by 6-Foot Wind Tunnel. The maximum blade passing tone decreases from the peak level when going to higher helical tip Mach numbers. This noise reduction points to the use of higher propeller speeds as a possible method to reduce airplane cabin noise while maintaining high flight speed and efficiency. Comparison of the SR-7A blade passing noise with the noise of the similarly designed SR-3 propeller shows good agreement as expected. The SR-7A propeller is slightly noisier than the SR-3 model in the plane of rotation at the cruise condition. Projections of the tunnel model data are made to the full-scale LAP propeller mounted on the test bed aircraft and compared with design predictions. The prediction method is conservative in the sense that it overpredicts the projected model data.

Dittmar, J. H.↗

Rb-Sr and Sm-Nd isotope geochemistry and chronology of cherts from the Onverwacht Group (3.5 AE), South Africa

An Rb-Sr and Sm-Nd isotopic analysis of Archean chert samples from the Onverwacht Group, South Africa is presented, showing the same characteristic Rb and Sr concentrations as Phanerozoic cherts, with a very large range of Rb-87/Sr-86 ratios. A good correlation line in the Rb-87 to Sr-87 evolution diagram, corresponding to an age of about 2119 My and an initial Sr-87/Sr-86 ratio of about 0.72246, is derived which may be interpreted as reflecting the age of rehomogenization of the Sr in the protolith and the recrystallization of these cherts due to circulating hydrothermal fluids during regional metamorphism about 1.4 AE after deposition of the Onverwacht Group. The Sm-Nd systematics reflect an ancient source age of about 3.5 AE.

Weis, D.↗

Decoupled Rb-Sr and Sm-Nd isotopic evolution of the continental crust

Evidence was presented that the Rb-Sr and Sm-Nd isotopic systems are decoupled in crust-mantle evolution. Rare earth element (including Sm and Nd) residue principally in silicates, and are resistant to mobilization by weathering and metamorphism. In contrast, Rb and Sr are easily fractionated by crustal processes and residue in carbonates as well as in silicates. As a result, continental Sr, but not Nd, can be recycled into the mantle by exchange of seawater with basalt at spreading ridges and by subduction of carbonates associated with ridge processes. These effects result in mean Rb-Sr ages of the continental crust and of the upper mantle that are too young. Crustal growth curves based largely on Rb-Sr data, such that of Hurley and Rand, are therefore incorrect.

Goldstein, S. L.↗

Predicted Performance of a Thrust-Enhanced SR-71 Aircraft with an External Payload

NASA Dryden Flight Research Center has completed a preliminary performance analysis of the SR-71 aircraft for use as a launch platform for high-speed research vehicles and for carrying captive experimental packages to high altitude and Mach number conditions. Externally mounted research platforms can significantly increase drag, limiting test time and, in extreme cases, prohibiting penetration through the high-drag, transonic flight regime. To provide supplemental SR-71 acceleration, methods have been developed that could increase the thrust of the J58 turbojet engines. These methods include temperature and speed increases and augmentor nitrous oxide injection. The thrust-enhanced engines would allow the SR-71 aircraft to carry higher drag research platforms than it could without enhancement. This paper presents predicted SR-71 performance with and without enhanced engines. A modified climb-dive technique is shown to reduce fuel consumption when flying through the transonic flight regime with a large external payload. Estimates are included of the maximum platform drag profiles with which the aircraft could still complete a high-speed research mission. In this case, enhancement was found to increase the SR-71 payload drag capability by 25 percent. The thrust enhancement techniques and performance prediction methodology are described.

Conners, Timothy R.↗

CFD Predictions of Sonic-Boom Characteristics for Unmodified and Modified SR-71 Configurations

Shaped sonic-boom signatures refer to signatures that look something other than the typical N-waves. Shaped sonic-boom signatures such as "flat-top," "ramp-type," or "hybrid-type" waveforms have been shown to reduce the subjective loudness without requiring reductions in overpressure peaks. The shaping of sonic-boom signatures requires increasing the shock rise time and changes in frequency spectra. So far, a flat-top waveform was shown to be achievable in wind tunnels; however, the influence of long propagation distance and real atmosphere on shaped signatures should be addressed using flight tests. Two different approaches have been proposed for sonic-boom minimization flight tests. The first approach, proposed by Eagle Aerospace, is for a flight test using a modified BQM-34 "FIREBEE" remotely piloted vehicle. The 30-foot long FIREBEE has a steady state flight condition at the Mach number and altitude of interest, and it can be recovered by helicopter from the water. As an alternative approach, a modified SR-71 vehicle has been proposed by the McDonnell Douglas Corporation. Benefits of the SR-71 include its variable geometry supersonic inlets, small cockpit bulge, higher Mach number capabilities, slender design, and longer length (105 foot). The present investigation addresses the sonic-boom analysis for the second vehicle.The objective of the current investigation is to assess the feasibility of a modified SR-71 configuration, with McDonnell Douglas-designed fuselage modifications, intended to produce shaped sonic-boom signatures on the ground. The present study describes the use of a higher-order computational fluid dynamics (CFD) method to predict the sonic-boom characteristics for both unmodified and modified SR-71 configurations. An Euler unstructured grid methodology is used to predict the near-field, three-dimensional pressure patterns generated by both SR-71 models. The computed near-field pressure signatures are extrapolated to specified distances below the aircraft down to impingement on the ground using the code MDBOOM. Comparisons of the near-field pressure signatures with available flight-test data are presented in the current paper.

Fouladi, Kamran↗

The SR-71 Test Bed Aircraft: A Facility for High-Speed Flight Research

The SR-71 test bed aircraft is shown to be a unique platform to flight-test large experiments to supersonic Mach numbers. The test bed hardware mounted on the SR-71 upper fuselage is described. This test bed hardware is composed of a fairing structure called the "canoe" and a large "reflection plane" flat plate for mounting experiments. Total experiment weights, including the canoe and reflection plane, as heavy as 14,500 lb can be mounted on the aircraft and flight-tested to speeds as fast as Mach 3.2 and altitudes as high as 80,000 ft. A brief description of the SR-71 aircraft is given, including details of the structural modifications to the fuselage, modifications to the J58 engines to provide increased thrust, and the addition of a research instrumentation system. Information is presented based on flight data that describes the SR-71 test bed aerodynamics, stability and control, structural and thermal loads, the canoe internal environment, and reflection plane flow quality. Guidelines for designing SR-71 test bed experiments are also provided.

Corda, Stephen↗

Use of 2d-video Disdrometer to Derive Mean Density-size and Ze-SR Relations: Four Snow Cases from the Light Precipitation Validation Experiment

The application of the 2D-video disdrometer to measure fall speed and snow size distribution and to derive liquid equivalent snow rate, mean density-size and reflectivity-snow rate power law is described. Inversion of the methodology proposed by Böhm provides the pathway to use measured fall speed, area ratio and '3D' size measurement to estimate the mass of each particle. Four snow cases from the Light Precipitation Validation Experiment are analyzed with supporting data from other instruments such as Precipitation Occurrence Sensor System (POSS), Snow Video Imager (SVI), a network of seven snow gauges and three scanning C9 band radars. The radar-based snow accumulations using the 2DVD-derived Ze-SR relation are in good agreement with a network of seven snow gauges and outperform the accumulations derived from a climatological Ze-SR relation used by the Finnish Meteorological Institute (FMI). The normalized bias between radar-derived and gauge accumulation is reduced from 96% when using the fixed FMI relation to 28% when using the Ze-SR relations based on 2DVD data. The normalized standard error is also reduced significantly from 66% to 31%. For two of the days with widely different coefficients of the Ze-SR power law, the reflectivity structure showed significant differences in spatial variability. Liquid water path estimates from radiometric data also showed significant differences between the two cases. Examination of SVI particle images at the measurement site corroborated these differences in terms of unrimed versus rimed snow particles. The findings reported herein support the application of Böhm's methodology for deriving the mean density-size and Ze-SR power laws using data from 2D-video disdrometer.

radar↗