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At least 37 records · Page 2

Solar energy conversion through the interaction of plasmons with tunnel junctions. Part A: Solar cell analysis. Part B: Photoconductor analysis

A solar cell utilizing guided optical waves and tunnel junctions was analyzed to determine its feasibility. From this analysis, it appears that the limits imposed upon conventional multiple cell systems also limit this solar cell. Due to this limitation, it appears that the relative simplicity of the conventional multiple cell systems over the solar cell make the conventional multiple cell systems the more promising candidate for improvement. It was discovered that some superlattice structures studied could be incorporated into an infrared photodetector. This photoconductor appears to be promising as a high speed, sensitive (high D sup star sub BLIP) detector in the wavelength range from 15 to over 100 micrometers.

Welsh, P. E.↗

Demonstration of Complete Recycling Processes of Reversible Epoxies Using Solar Energy Conversion

Reversible epoxies using the Diels–Alder chemistry enables recycling processes through depolymerizing the polymer at higher temperature and then repolymerizing upon cooling. Compared to conventional bulk heating, photothermal heating can save time and resource and, consequently, reduce costs to reach an elevated temperature for recycling processes of the reversible epoxies. In previous studies, self‐healing of cracks and reattachments of two broken pieces have been presented using a laser; however, recycling of a sample as a whole is not feasible by using such a point light source. Herein, complete recycling processes are demonstrated utilizing an area light source, i.e., sunlight. Reversible epoxies are incorporated with carbon black and refractory plasmonic titanium nitride nanoparticles (NPs). Under concentrated (10 times) sunlight, they can generate sufficient heat (≈140 °C) to completely liquefy, reprocess, and reshape the samples multiple times. Recycling processes are validated by evaluation of mechanical properties for each cycle. Using an integrated experimental and theoretical approach, photothermal performance is investigated in terms of the dispersion and loading of photothermal NPs in the matrix, as well as the sample thickness. In this study, an insight is provided into the design of polymer/photothermal nanomaterial composites which can be sustainably recycled using abundant solar energy.

14 SOLAR ENERGY↗

Study of radiatively sustained cesium plasmas for solar energy conversion

The results of a study aimed at developing a high temperature solar electric converter are reported. The converter concept is based on the use of an alkali plasma to serve as both an efficient high temperature collector of solar radiation as well as the working fluid for a high temperature working cycle. The working cycle is a simple magnetohydrodynamic (MHD) Rankine cycle employing a solid electrode Faraday MHD channel. Research milestones include the construction of a theoretical model for coupling sunlight in a cesium plasma and the experimental demonstration of cesium plasma heating with a solar simulator in excellent agreement with the theory. Analysis of a solar MHD working cycle in which excimer laser power rather than electric power is extracted is also presented. The analysis predicts a positive gain coefficient on the cesium-xenon excimer laser transition.

Palmer, A. J.↗

A new strategy for efficient solar energy conversion: Parallel-processing with surface plasmons

This paper introduces an advanced concept for direct conversion of sunlight to electricity, which aims at high efficiency by tailoring the conversion process to separate energy bands within the broad solar spectrum. The objective is to obtain a high level of spectrum-splitting without sequential losses or unique materials for each frequency band. In this concept, sunlight excites a spectrum of surface plasma waves which are processed in parallel on the same metal film. The surface plasmons transport energy to an array of metal-barrier-semiconductor diodes, where energy is extracted by inelastic tunneling. Diodes are tuned to different frequency bands by selecting the operating voltage and geometry, but all diodes share the same materials.

Anderson, L. M.↗

Thermal optical surface properties and high-temperature solar energy conversion

The effects of thermal surface properties on the performance of representative point focusing solar power plants are assessed in this paper. The tradeoff relationships are presented in terms of normalized system performance as a function of thermal optical design parameters. Crucial surface properties include solar reflectance, specular spreading due to microscopic roughness, surface error due to manufacturing slope tolerance or waviness and concentrator pointing accuracy. Two representative power conversion systems, a Rankine steam cycle and an open air Brayton cycle, are considered.

Wen, L.↗

Preliminary design of an advanced Stirling system for terrestrial solar energy conversion

A preliminary design was generated for an advanced Stirling conversion system (ASCS) that will be capable of delivering about 25 kW of electric power to an electric utility grid. Stirling engines are being evaluated for terrestrial solar applications. A two-year task to complete detailed design, fabrication, assembly and testing of an ASCS prototype began in April, 1990. The ASCS is designed to deliver maximum power per year over a range of solar inputs with a design life of 30 years (60,000 h). The ACSC has a long-term cost goal of about $450 per kilowatt, exclusive of the 11-m parabolic dish concentrator. The proposed system includes a Stirling engine with high-pressure hydraulic output, coupled with a bent axis variable displacement hydraulic motor and a rotary induction generator. The major thrusts of the preliminary design are described, including material selection for the hot-end components, heat transport system (reflux pool boiler) design, system thermal response, improved manufacturability, FMECA/FTA analysis, updated manufacturing cost estimate, and predicted system performance.

White, M. A.↗

A space-based combined thermophotovoltaic electric generator and gas laser solar energy conversion system

This paper describes a spaceborne energy conversion system consisting of a thermophotovoltaic electric generator and a gas laser. As a power source for the converson, the system utilizes an intermediate blackbody cavity heated to a temperature of 2000-2400 K by concentrated solar radiation. A double-layer solar cell of GaAs and Si forms a cylindrical surface concentric to this blackbody cavity, receiving the blackbody radiation and converting it into electricity with cell conversion efficiency of 50 percent or more. If the blackbody cavity encloses a laser medium, the blackbody radiation can also be used to simultaneously pump a lasing gas. The feasibility of blackbody optical pumping at 4.3 microns in a CO2-He gas mixture was experimentally demonstrated.

Yesil, Oktay↗

Thermodynamic limits for solar energy conversion by a quantum-thermal hybrid system

The limits are presented fo air mass 1.5 conditions. A maximum conversion efficiency of 74 percent is thermodynamically achievable for the quantum device operating at 3500 K and the heat engine in contact with a reservoir at 0 K. The efficiency drops to 56 percent for a cold reservoir at approximately room temperature conditions. Hybrid system efficiencies exceed 50 percent over receiver temperatures ranging from 1400 K to 4000 K, suggesting little benefit is gained in operating the system above 1400 K. The results are applied to a system consisting of a photovoltaic solar cell in series with a heat engine.

Byvik, C. E.↗

Solar energy conversion by photosystem II: principles and structures

Photosynthetic water oxidation by Photosystem II (PSII) is a fascinating process because it sustains life on Earth and serves as a blue print for scalable synthetic catalysts required for renewable energy applications. The biophysical, computational, and structural description of this process, which started more than 50 years ago, has made tremendous progress over the past two decades, with its high-resolution crystal structures being available not only of the dark-stable state of PSII, but of all the semi-stable reaction intermediates and even some transient states. Here, we summarize the current knowledge on PSII with emphasis on the basic principles that govern the conversion of light energy to chemical energy in PSII, as well as on the illustration of the molecular structures that enable these reactions. The important remaining questions regarding the mechanism of biological water oxidation are highlighted, and one possible pathway for this fundamental reaction is described at a molecular level.

59 BASIC BIOLOGICAL SCIENCES↗

Integrated photovoltaic-thermal solar energy conversion systems

A combined photovoltaic/thermal collector has been built and is now being tested. Initial tests have concentrated on evaluating the thermal efficiency of the collector before and after the silicon cells are mounted. With likely improvements in bonding between cells and receiver and in the absorptivity of the cells, thermal efficiencies greater than 50% can be expected for the combined receiver operating at 100 C.

Samara, G. A.↗

Direct solar energy conversion for large scale terrestrial use

Various techniques to increase the open circuit voltage are being explored. It had been previously observed that cells made on CdS deposited from a single source gave a consistently higher V sub oc. Further tests have now shown that this effect may in fact relate to differences in source and substrate temperatures. The resulting differences in CdS structure and crystallinity are being documented. Deposits of mixed CdS and ZnS are being produced and will be initially made into cells using the conventional barriering technique. Analysis of I-V characteristics at temperatures between 25 and 110 C is being perfected to provide nondestructive analysis of the Cu2S. Changes due to vacuum heat treatments and exposure to oxygen are also being monitored by the same technique. Detailed spectral response measurements are being made.

Boeer, K. W.↗

Solar energy, its conversion and utilization

The work being carried out at the University of Florida Solar Energy and Energy Conversion Laboratory in converting solar energy, our only income, into other needed and useful forms of energy is described. A treatment such as this demonstrates, in proper perspective, how solar energy can benefit mankind with its many problems of shortages and pollution. Descriptions were given of the conversion processes, equipment, and performance. The testing of materials, solar water heating, space heating, cooking and baking, solar distillation, refrigeration and air-conditioning, work with the solar furnace, conversion to mechanical power, hot air engines, solar-heated sewage digestion, conversion to electricity, and other devices will be discussed.

Farber, E. A.↗