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At least 37 records · Page 2

The NREL Sensor Laboratory: Hydrogen Leak Detection for Large Scale Deployments: Preprint

The NREL Hydrogen Sensor Laboratory was commissioned in 2010 as a resource for sensor developers, end-users, and regulatory agencies within the national and international hydrogen community. The Laboratory continues to provide as its core capability the unbiased verification of hydrogen sensor performance to assure sensor availability and their proper use. However, the mission and strategy of the NREL Sensor Laboratory has evolved to meet the needs of the growing hydrogen market. The Sensor Laboratory program has expanded to support research in conventional and alternative detection methods as hydrogen use expands to large-scale markets as envisioned by the DOE National Clean Hydrogen Strategy and Roadmap. Current research encompasses advanced methods of hydrogen leak detection including stand-off and wide area monitoring approaches for large scale and distributed applications. In addition to safety applications, low-level detection strategies to support the potential environmental impacts of hydrogen and hydrogen product losses along the value chain are being explored. Many of these applications utilize detection strategies that supplement and may supplant the use of traditional point sensors. The latest results of the hydrogen detection strategy research at NREL will be presented.

detection↗

Integrated Harsh Environment Gas / Temperature Wireless Microwave Acoustic Sensor System for Fossil Energy Applications

There is a significant need for sensors capable of detecting gases, such as H 2 , O 2 , NO x , SO x within harsh environments encountered in power plants, industrial manufacturing, oil and gas exploration, and aerospace applications. This project successfully demonstrated the use of wireless microwave acoustic sensor technology for the detection of gases (H 2 or O 2 ) from ambient temperatures up to 650°C. The work focused on langasite (LGS) based surface acoustic wave resonator (SAWR) sensors as the harsh-environment sensor platform and explored multiple combinations of high-temperature thin films and device structures which were used to increase the sensor platform stability and detection capability at temperatures in the operational range of 150°C to 700°C. Specific material configurations that were investigated include: yttria-stabilized-zirconia (YSZ) decorated with Pt nanoparticles, atomic layer deposited (ALD) Al 2 O 3 , palladium, and Pt/Al 2 O 3 co-deposited electrode alloys. Through the deposition of YSZ at temperatures as high as 850°C and the use of graded alloy concentrations of Pt in the fabrication of the Pt/Al 2 O 3 electrode structures, film stress problems were mitigated, and sensor operation and stability achieved. To test and evaluate SAWR sensor performance for the detection of H 2 and O 2 under the influence of temperature variations, a comprehensive gas sensor control system and test apparatus was created to operate within a laboratory box furnace-controlled environment. In addition to the advancement in thin film materials through the deposition and fabrication techniques mentioned above, the work characterized the performance of sensors containing these films in the presence of oxidizing and reducing gases between 25°C and 700°C. In particular, the work revealed that the exposure of the SAWR sensor surfaces to oxidizing environments significantly improve the sensor response to H 2 , whereas the exposure of the sensor to reducing environments at high temperatures (≈ 500°C) renders the sensor irresponsive to H 2 , requiring sensor surface treatment at high temperatures (above 500°C) to recover the responsiveness to H 2 . The SAWR sensors have been also tested for wireless operation and array operation using multiple orientations to resolve the detection of gases under temperature variations. The work developed at the University of Maine was aided by a collaboration with the NETL Research and Innovation Center, Pittsburgh, PA, where thin film materials and device structures fabricated at UMaine were tested and characterized using NETL gas reactors and surface analysis techniques. SAWR sensors fabricated at UMaine were exposed multiple times to temperatures up to 700°C and H 2 concentrations up to 100% in the NETL facilities to measure the sensor performance. Environetix Technologies Corporation, a UMaine harsh-environment sensor spin-off company, also provided support and assistance in sensor system testing and implementation. The sensor small size and configuration allows flexible sensor placement and embedding of multiple sensor arrays into a variety of components within power systems and other aerospace or industrial settings that need to be interrogated wirelessly. The SAW platform is an attractive option for high-temperature harsh-environment gas sensing applications due to its inherent features, namely small size, capability of battery-free and wireless operation, and cost effective scale production using well-established production techniques from the semiconductor industry. The research findings achieved in this work, particularly advances regarding the fabrication and performance of the SAWR gas sensor platform, can be adapted and transferred to industrial power plants and other harsh environments.

01 COAL, LIGNITE, AND PEAT↗

WellSTIC: A Cost-Effective Sensor for Performing Point Dilution Tests to Measure Groundwater Velocity in Shallow Aquifers

Many individual measurement points are required to characterize groundwater velocity within an aquifer. Groundwater velocity is most commonly measured using a network of >5 cm diameter monitoring wells, which, if not already present at a site, are expensive and labor-intensive to install. Drive-point piezometers—simple, cost-effective wells that can be installed by hand—are a common tool for sampling groundwater in shallow, alluvial aquifers, but most groundwater velocity measurement techniques require equipment that is too large for these narrow (usually <2 cm inside diameter) piezometers. In this technical note, we introduce a low-cost sensor and well packer system (<$90 USD) for performing point dilution tests in narrow piezometers. Field data show that the magnitude of groundwater velocity measured with this technique agrees with velocities computed from natural gradient tracer tests. Additionally, with proper calibration, these sensors can be used to continuously monitor in-well specific conductance, either during inter-well tracer tests with saline tracers or for water quality monitoring. Finally, this system is a viable tool for rapid assessment of the magnitude of groundwater velocity in shallow aquifers.

54 ENVIRONMENTAL SCIENCES↗

Functional metal–organic frameworks as effective sensors of gases and volatile compounds

Developing efficient sensor materials with superior performance for selective, fast and sensitive detection of gases and volatile organic compounds (VOCs) is essential for human health and environmental protection, through monitoring indoor and outdoor air pollutions, managing industrial processes, controlling food quality and assisting early diagnosis of diseases. Metal–organic frameworks (MOFs) are a unique type of crystalline and porous solid material constructed from metal nodes (metal ions or clusters) and functional organic ligands. They have been investigated extensively for possible use as high performance sensors for the detection of many different gases and VOCs in recent years, due to their large surface area, tunable pore size, functionalizable sites and intriguing properties, such as electrical conductivity, magnetism, ferroelectricity, luminescence and chromism. The high porosity of MOFs allows them to interact strongly with various analytes, including gases and VOCs, thus resulting in easily measurable responses to different physicochemical parameters. Although much of the recent work on MOF-based luminescent sensors have been summarized in several excellent reviews (up to 2018), a comprehensive overview of these materials for sensing gases and VOCs based on chemiresistive, magnetic, ferroelectric, and colorimertic mechanisms is missing. In this review, we highlight the most recent progress in developing MOF sensing and switching materials with an emphasis on sensing mechanisms based on electricity, magnetism, ferroelectricity and chromism. We provide a comprehensive analysis on the MOF–analyte interactions in these processes, which play a key role in the sensing performance of the MOF-based sensors and switches. We discuss in detail possible applications of MOF-based sensing and switching materials in detecting oxygen, water vapor, toxic industrial gases (such as hydrogen sulfide, ammonia, sulfur dioxide, nitrous oxide, carbon oxides and carbon disulfide) and VOCs (such as aromatic and aliphatic hydrocarbons, ketones, alcohols, aldehydes, chlorinated hydrocarbons and N,N'-dimethylformamide). Altogether, this review serves as a timely source of information and provides insight for the future development of advanced MOF materials as next-generation gas and VOC sensors.

36 MATERIALS SCIENCE↗

NREL Hydrogen Sensor Testing Laboratory

Relevance: Detection is recognized as a critical element for hydrogen facility safety design and supports risk mitigation. Detection methodologies will support validation of H2 behavior research. Hydrogen point sensors play a critical role for safety and process monitoring, but other methodologies can be developed. Approach: NREL Sensor Laboratory tests and verifies sensor performance for manufacturers, developers, end-users, regulatory agencies and SDOs/CDOs NREL deployment activity supports regulatory requirement verification, hydrogen behavior models, and method development for use by stakeholders. Accomplishments and Progress: NREL's R&D accomplishments have supported developers, industry, and SDOs by providing sensor performance and deployment expertise not otherwise available. Development of alternative detection strategies for hydrogen applications have been initiated. HyWAM and advanced detection methodologies deployments at H2@Scale Facilities are being implemented. Collaborations: Collaboration with government laboratories, universities, private organizations and regulatory agencies has leveraged the NREL Sensor Laboratory's success in advancing hydrogen safety sensors and process control. Proposed Future Work: NREL will support hydrogen deployment by the proper implementation of hydrogen sensors and advanced detection strategies. NREL will continue to support science-based codes and standards. This effort will be guided by the needs of the hydrogen community.

codes and standards↗

Assessing the limitations of commercial sensors and models for supporting marine carbon dioxide removal monitoring: a case study

Several unknowns remain surrounding marine Carbon Dioxide Removal (mCDR) monitoring, reporting, and verification (MRV) practices and capabilities. Current in-situ sensor technology is limited (primarily pH and pCO 2 ), requiring calculations and assumptions to estimate changes in carbonate chemistry parameters, including total alkalinity (TA). Considering that cost, energy consumption, and accuracy of commercial sensors can vary by orders of magnitude, understanding how well existing sensors perform in an mCDR context is important for this emerging community. Likewise, documenting sensor limitations and how relatively simple models can optimize sensor deployments will improve MRV efforts and support protocol development. Here we (1) compare performance a variety of commercially available sensors in a blind mesocosm experiment simulating ocean alkalinity enhancement (OAE), and how sensor performance impacted carbonate chemistry estimates; (2) evaluate if sensors can distinguish the OAE signal from natural variability during a small scale OAE field test in Sequim Bay, WA, USA, and (3) use an idealized ocean biogeochemistry model to explore optimal sensor network design based on (1) and (2). Our mesocosm results indicate that correctly constraining pH uncertainty will be critical for accurate TA estimates with current sensor technology compared to the less impactful variation caused by uncertainty in pCO 2 (pH data that are presented throughout are reported on the total scale (pH T ) unless otherwise noted). Our pilot field test demonstrated that sensors were capable of distinguishing mCDR signatures from natural variability under optimal real-world conditions. Idealized modeling simulations of the field test showed that a range of sparse and dense (3 to 100) sensors sampling areas of detectable increases will underestimate the net change in surface pH by at least 35–55%, at both realistic and highly elevated alkalinity input levels. We also highlight the limitations of current sensing technology for MRV, and the importance of ocean biogeochemistry models as critical tools for predicting when and where mCDR signals will be detectable using available sensors. Overall, our findings suggest that commercially available pCO 2 sensors and some pH sensors will form an important backbone for mCDR MRV tasks, though complete MRV characterization will require these data to be used in combination with other tools.

OAE↗

Gallium Oxide Heterojunction Diodes for 400 °C High‐Temperature Applications

β ‐Ga 2 O 3 ‐based semiconductor devices are expected to have significantly improved high‐power and high‐temperature performance due to its ultrawide bandgap of close to 5 eV. However, the high‐temperature operation of these ultrawide‐bandgap devices is usually limited by the relatively low 1–2 eV built‐in potential at the Schottky barrier with most high‐work‐function metals. Herein, heterojunction p ‐NiO/n‐ β ‐Ga 2 O 3 diodes fabrication and optimization for high‐temperature device applications are reported, demonstrating a current rectification ratio ( I ON / I OFF ) of more than 10 6 at 410 °C. The NiO heterojunction diode can achieve higher turn‐on ( V ON ) voltage and lower reverse leakage current compared to the Ni‐based Schottky diode fabricated on the same single‐crystal β ‐Ga 2 O 3 substrate, despite charge transport dominated by interfacial recombination. Electrical characterization and device modeling show that these advantages are due to a higher built‐in potential and additional band offset. These results suggest that heterojunction p–n diodes based on β ‐Ga 2 O 3 can significantly improve high‐temperature electronic device and sensor performance.

Sohel, Shahadat H.↗

Distributed Temperature Monitoring of Tundish Refractory Lining Using Optical Fiber Sensors

Distributed temperature monitoring can provide useful insights into the thermal conditions in the continuous caster tundish that can affect operating stability and cast quality, such as preheat conditions, superheat uniformity, fill height, and refractory wear. In the current study, fiber optic sensors were embedded into the refractory lining of a lab-scale tundish to record the temperature profiles during dry-out, preheating, and direct molten steel exposure to demonstrate sensor performance. Additional trials were performed with fiber optic sensors embedded in an industrial tundish used in production. Furthermore, the results demonstrate that fiber optic sensors using Rayleigh technology can provide accurate distributed temperature measurements in refractory lined vessels and provide useful information about the process.

Continuous Caster↗

Microengineering Pressure Sensor Active Layers for Improved Performance

Abstract Pressure sensors play an integral role in a wide range of applications, such as soft robotics and health monitoring. In order to meet this demand, many groups microengineer the active layer—the layer that deforms under pressure and dictates changes in the output signal—of capacitive, resistive/piezoresistive, piezoelectric, and triboelectric pressure sensors in order to improve sensor performance. Geometric microengineering of the active layer has been shown to improve performance parameters such as sensitivity, dynamic range, limit of detection, and response and relaxation times. There are a wide range of implemented designs, including microdomes, micropyramids, lines or microridges, papillae, microspheres, micropores, and microcylinders, each offering different advantages for a particular application. It is important to compare the techniques by which the microengineered active layers are designed and fabricated as they may provide additional insights on compatibility and sensing range limits. To evaluate each fabrication method, it is critical to take into account the active layer uniformity, ease of fabrication, shape and size versatility and tunability, and scalability of both the device and the fabrication process. By better understanding how microengineering techniques and design compares, pressure sensors can be targetedly designed and implemented.

Ruth, Sara Rachel Arussy↗

NREL Hydrogen Sensor Testing Laboratory

The NREL Sensor Laboratory supports the HFTO's mission for the safe and efficient implementation of hydrogen as an energy carrier. Sensors are a critical element for a facility safety system by providing an early indication of unintended releases. Sensors can be used in process control applications (e.g., FQ verification). The Sensor Laboratory provides developers and end-users with an unbiased resource to validate sensor performance to application requirements. The Sensor Laboratory facilitates deployment through support of codes and standards development and safety research. The Sensor Laboratory supports advanced strategies for early leak detection.

detection↗

Comparative Analysis of Capacitive Sensors with Different Geometrical layouts for Cable Insulation Degradation Detection

This paper presents a comparative analysis between an Interdigital Capacitor (IDC) sensor and a Serpentine Capacitive (SRC) sensor. The effects of electrode layouts on sensor performance are studied by means of finite element simulation where the geometrical dimensions (except electrode length) and material characteristics of both sensors are identical. Conformal IDC and SRC sensors with equal sensor area are modeled on a cable surface. The simulation results show a tradeoff between IDC and SRC sensors in terms of sensitivity and penetration depth. The SRC sensor shows 13.3% increase in sensitivity and 16.8% increase in capacitance compared to the IDC sensor, though the electric field penetration depth of the SRC sensor is 18.8% lower than the IDC sensor. In addition, the effects of change in electrode width, inter-electrode gap, and number of electrodes on SRC and IDC sensor comparative performance are evaluated.

Interdigital Capacitance, Serpentive Capacitive Se↗

Skipper-CCD sensors for the Oscura experiment: requirements and preliminary tests

Oscura is a proposed multi-kg skipper-CCD experiment designed for a dark matter (DM) direct detection search that will reach unprecedented sensitivity to sub-GeV DM-electron interactions with its 10 kg detector array. Oscura is planning to operate at SNOLAB with 2070 m overburden, and aims to reach a background goal of less than one event in each electron bin in the 2–10 electron ionization-signal region for the full 30 kg-year exposure, with a radiation background rate of 0.01 dru.[1 dru (differential rate unit) corresponds to 1 event/kg/day/keV.] In order to achieve this goal, Oscura must address each potential source of background events, including instrumental backgrounds. In this work, we discuss the main instrumental background sources and the strategy to control them, establishing a set of constraints on the sensors' performance parameters. We present results from the tests of the first fabricated Oscura prototype sensors, evaluate their performance in the context of the established constraints and estimate the Oscura instrumental background based on these results.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Evaluate the impact of sensor accuracy on model performance in data-driven building fault detection and diagnostics using Monte Carlo simulation

The performance of data-driven fault detection and diagnostics (FDD) is heavily dependent on sensors. However, sensor inaccuracy and sensor faults are pervasive in building operation: inaccurate and missing sensor readings deteriorate FDD performance; sensor inaccuracy will also affect the selection of sensor for data-driven FDD in the model training process, which is another key factor of data-driven FDD performance. Sensor accuracy and sensor selection individually are well-studied research topics in this field, but the impact of sensor accuracy on sensor selection and its further impact on FDD performance has not been evaluated and quantified. In this paper, we developed a novel analysis methodology that comprehensively evaluates sensor fault on sensor selection and FDD accuracy. Monte Carlo simulation is applied to deal with multiple stochastic sensor inaccuracy and provide probabilistic analysis results of the impact of sensor inaccuracy on sensor selection and FDD accuracy. This methodology focuses on the net impact of fault states across a full sensor set. The developed methodology can be used for the early-stage sensor design and operation-stage sensor maintenance. Furthermore, a case study is conducted to demonstrate the analysis methodology using a commercial building model crated to Flexible Research Platform located at Oak Ridge National Laboratory, USA.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Eddy current flow meter model validation with a moving solid rod*

We report that the eddy current flow meter (ECFM) has been used to measure velocities and temperatures of conductive flows, such as liquid metal flows in a nuclear fission reactor. The goal of this paper is to develop a finite element electromagnetic model that can characterize the ECFM sensor performance and validate this finite element model with detailed velocity measurements of a controlled, well-characterized moving conductive solid rod. Both measurements and modeling were performed for various parameters that are important for ECFM performance such as rod velocity, rod material, ECFM sensor coil length, number of sensor coils, applied alternating current (AC) current amplitude, and applied ECFM AC frequency. For all parametric scans, the measurement and modeling agree well in both magnitude and trend. The normalized root-mean-square error between measurement and modeling is less than 10% for all cases. These results suggest that electromagnetic modeling could eventually be used to cost-effectively design future ECFM sensors in arbitrary geometry for more challenging applications such as liquid metal nuclear fission reactors.

47 OTHER INSTRUMENTATION↗

Conceptual Design of Neutron Sensor Qualification Device

The Advanced Sensors and Instrumentation Program at Idaho National Laboratory has been formulating strategies to qualify sensors for use in nuclear environments, particularly in irradiation experiments and advanced reactors. When qualifying neutron sensors for use in high-temperature environments, the wide range of neutron flux levels and representative energy spectra presents significant challenges. This paper discusses the development of the Neutron Sensor Qualification Device (NQD), which is designed to test neutron sensors in high temperature controlled environments with known neutron spectra, addressing the spatial and spectral complexities of neutron fluxes in reactor cores. The proposed NQD will be situated in the exposure room at the Armed Forces Radiobiology Research Institute, thus affording a unique capability to expose sensors to high neutron and gamma fluxes. To achieve thermal control, the device will utilize a radiation-hardened tube furnace, accommodating multiple sensors and neutron activation dosimetry wires. Titanium, iron, and cobalt dosimeter wires are chosen from the American Society for Testing and Materials and International Reactor Dosimetry and Fusion File libraries as references for providing energy-dependent fluence measurements. The design ensures precise sensor positioning to minimize mutual shielding and flux perturbation, which are evaluated via Monte Carlo N particle Transport Code (MCNP) simulations. These simulations have informed the development of guidelines on sensor placement within the NQD. The NQD is essential to the qualification of neutron sensors for advanced reactor technologies. It enables controlled testing of a statistically significant number of sensors, thereby supporting assessments of sensor performance across various neutron flux levels and temperatures. This paper highlights the detailed planning for the NQD prototype, along with its inaugural irradiation (scheduled for fiscal year [FY] 2025). The results from this initial testing will be fundamental in evaluating the device’s performance and establishing measurement uncertainty for in-pile neutron sensor measurements.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗