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Optical and Mechanical Designs of the Multi-band SWIR Receiver for the Lunar Flashlight CubeSat Mission
Mapping and quantifying lunar water ice addresses one of NASA’s Strategic Knowledge Gaps to understand the lunar resource potential for future human exploration of the Moon. Lunar Flashlight is an innovative NASA CubeSat mission dedicated to mapping water ice in the permanently-shadowed and occasionally-sunlit regions in the vicinity of the lunar South Pole. Lunar Flashlight will acquire these measurements from lunar orbit using a multi-band laser reflectometer composed of an optical receiver aligned with four lasers emitting different wavelengths in the shortwave infrared spectral region between 1 µm and 2 µm. The receiver measures the laser radiance reflected from the lunar surface in each spectral band and continuum/absorption reflectance band ratios are then analyzed to quantify water ice concentration in the illuminated spot. The receiver utilizes a 70×70-mm, aluminum, off-axis paraboloidal mirror with a focal length of 70 mm, which collects the incoming light onto a single, 2 mm diameter InGaAs detector with a cutoff wavelength of 2.4 µm. We present the optical and mechanical designs of the receiver, including its optimization for rejection of solar stray-light from outside its intended field of view. This highly mass- and volume-constrained instrument payload will demonstrate several firsts, including being one of the first instruments onboard a CubeSat performing science measurements beyond low Earth orbit and the first planetary mission to use multi-band active reflectometry from orbit.
The Lunar Flashlight CubeSat Instrument: A Compact SWIR Laser Reflectometer to Quantify and Map Water Ice on the Surface of the Moon
The Lunar Flashlight (LF) mission will send a CubeSat to lunar orbit via NASA’s Space Launch System (SLS) test flight. The LF spacecraft will carry a novel instrument to quantify and map water ice harbored in the permanently shadowed craters of the lunar South Pole. The LF instrument, an active multi-band reflectometer which employs four high power diode lasers in the 1-2 μm infrared band, will measure the reflectance of the lunar surface near water ice absorption peaks. We present the detailed instrument design and system engineering required to deploy this instrument within very demanding CubeSat resource allocations.
Drone-Acquired Short-Wave Infrared (SWIR) Imagery in Landscape Archaeology: An Experimental Approach
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SWIR LED-based dual comb spectroscopy for high value gas detection, STL-038-21, Year 1 of 2
Presentation to be presented during the Site-Directed Research and Development (SDRD) program FY 2021 review meeting (Webex), September 22–23, 2021.
SWIR Led-based Dual Comb Spectroscopy for High Value Gas Detection Project #: 22-061 Year 2 of 2
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SWIR LED-Based Dual Comb Spectroscopy for High Value Gas Detection
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SWIR LED-Based Dual Comb Spectroscopy for High Value Gas Detection
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Enabling the Assimilation of CrIS Shortwave Infrared Observations in Global NWP at NOAA. Part II: OSEs and Results
The assimilation of data from hyperspectral infrared sounders in global data assimilation systems has historically been focused on observations in the longwave infrared (LWIR) region of the spectrum (650-1100 cm−1), despite the often concurrent availability of measurements from the shortwave infrared (SWIR) region of the spectrum (2150-2550 cm−1), because issues (like solar effects) have generally prevented the assimilation of SWIR observations. Recent advances in radiative transfer models have worked to address some of the previous challenges in simulating SWIR observations, and the assimilation of SWIR data (e.g. from potential future small-satellites) is now a feasible prospect. Still, a better understanding of how these observations perform in a data assimilation system and impact resulting analyses and NWP forecasts is necessary. In this study, the value of SWIR observations in global NWP is assessed by assimilating SWIR observations from the Cross-track Infrared Sounder (CrIS) in NOAA’s Global Data Assimilation System (GDAS). The methodologies used to enable the assimilation of these observations, including the implementation of a scene-dependent observation error and the enhancement of quality control procedures, are discussed, as are the results of Observing System Experiments (OSEs) conducted to evaluate the impact of assimilating SWIR observations on forecast skill. The overall results show that SWIR assimilation produces similar forecast impacts to LWIR assimilation. The ability to demonstrate that the assimilation or SWIR observations in NWP is a realistic prospect may help to shape future constellations of small-satellites to serve as a beneficial complement to the current constellation if hyperspectral IR sounders.
Improvements of On-orbit Characterization of Terra MODIS Short-wave Infrared Spectral Bands Out-of-Band Responses
The short-wave infrared (SWIR) bands (5-7, 26) of Terra MODIS, which are co-located with the mid-wav e infrared (MWIR) bands (20-25) on the short and mid-wave infrared (SMIR) Focal Plane Assembly (FPA),have a known issue related to 5.3 μm out-of-band (OOB) thermal leak and electronic crosstalk that was identified prelaunch. As a result, a crosstalk correction algorithm was designed and implemented in the MODIS Level 1B (L1B) calibration. Shortly after the Terra launch, extensive efforts were under taken to help characterize and mitigate the impact due to the OOB response and crosstalk on the SWIR on-orbit calibration and, consequently, the associated L1Bdata products. In addition, special night time day mode (NTDM) operations have been regularly scheduled to derive the crosstalk correction coefficients. Since MODIS does not have a spectral band centered at 5.3 μm, its band 28 (7.325 μm) was chosen as the surrogate sending band to simulate the OOB radiances at 5.3 μm. This was largely based on the measurements from the MODIS Airborne Simulator (MAS) spectrometer field campaigns in the early months after the Terra launch. In the case of Aqua MODIS, the magnitude of the SWIR crosstalk was much smaller and band 25 (4.52 μm) was found to be more effective as the sending band for the crosstalk correction. In recent years, the Terra MODIS photovoltaic (PV) long-wave infrared (LWIR) bands (27-30)electronic crosstalk has increased considerably, especially after the spacecraft safe-mode event occurred in February2016. This accentuated degradation in the PV LWIR performance has also impacted the performance of the SWIR crosstalk correction and thus its calibration and data quality. In this paper, we examine the use of band 25 as the sending band for the Terra MODIS SWIR crosstalk correction and compare its performance with that based on band 28 as the sending band. Results indicate an improvement of on-orbit gain stability for the SWIR calibration and reduced detector to detector and sub-frame to sub-frame striping in the calibrated L1B imagery, especially during the period when the PV LWIR electronic crosstalk has become more severe. This approach has been implemented in the forward production of Terra MODIS Collection 6 and Collection 6.1,starting from July 2019, and is planned to be used for the future reprocessing of MODIS L1B and to help improve the mission-long reflectance calibration and trending stability of the SWIR bands.
Evaluation of Shortwave Infrared Atmospheric Correction for Ocean Color Remote Sensing of Chesapeake Bay
The NASA Moderate Resolution Imaging Spectroradiometer onboard the Aqua platform (MODIS-Aqua) provides a viable data stream for operational water quality monitoring of Chesapeake Bay. Marine geophysical products from MODIS-Aqua depend on the efficacy of the atmospheric correction process, which can be problematic in coastal environments. The operational atmospheric correction algorithm for MODIS-Aqua requires an assumption of negligible near-infrared water-leaving radiance, nL(sub w)(NIR). This assumption progressively degrades with increasing turbidity and, as such, methods exist to account for non-negligible nL(sub w)(NIR) within the atmospheric correction process or to use alternate radiometric bands where the assumption is satisfied, such as those positioned within shortwave infrared (SWIR) region of the spectrum. We evaluated a decade-long time-series of nL(sub w)(lambda) from MODIS-Aqua in Chesapeake Bay derived using NIR and SWIR bands for atmospheric correction. Low signal-to-noise ratios (SNR) for the SWIR bands of MODIS-Aqua added noise errors to the derived radiances, which produced broad, flat frequency distributions of nL(sub w)(lambda) relative to those produced using the NIR bands. The SWIR approach produced an increased number of negative nL(sub w)(lambda) and decreased sample size relative to the NIR approach. Revised vicarious calibration and regional tuning of the scheme to switch between the NIR and SWIR approaches may improve retrievals in Chesapeake Bay, however, poor SNR values for the MODIS-Aqua SWIR bands remain the primary deficiency of the SWIR-based atmospheric correction approach.
Leveraging hyperspectral phenotyping for accurate, non-destructive prediction of metabolite profiles in poplar under drought stress
Accurately predicting drought tolerance in woody perennial bioenergy crops is critical for sustainable biomass production under fluctuating precipitation. Hyperspectral imaging (HSI) in the visible-near-infrared (VNIR) and shortwave-infrared (SWIR) ranges offers a promising approach for predicting plant biochemical traits, yet its application in metabolite profiling remains underexplored. We integrated VNIR+SWIR HSI with untargeted metabolomics to investigate drought-induced metabolic shifts in Populus leaves from eight Populus genotypes. Metabolite profiling identified 127 compounds, with 73 showing significant drought responses spanning amino acids (AA), carbohydrates (CHO), phenolic glycosides (PG), organic acids (OA), fatty acids and alcohols (FA), terpenes (T), phenolic metabolites (P), and unclassified metabolites. Spectral analysis revealed consistently higher reflectance across VNIR and SWIR wavelengths in drought-stressed plants, corresponding with increased accumulation of AA and reduced CHO and PG levels. Least absolute shrinkage and selection operator (LASSO) regression modeling identified robust spectral predictors of metabolite concentrations, associating VNIR wavelengths (500–700 nm) predominantly with AA and P, whereas SWIR wavelengths (1680–1700 nm) reliably predicted CHO, OA, and T. Several stable spectral-metabolite associations persisted across the two watering regimes (drought vs. well-watered), highlighting their potential as spectral biomarkers for non-destructive stress monitoring. Minimal genotype-specific variation suggests that observed spectral and metabolic responses were driven primarily by environmental factors, likely reflecting limited genetic diversity among the commercial Populus genotypes examined. This work establishes VNIR+SWIR hyperspectral imaging as a powerful, non-destructive phenotyping tool for precision monitoring and targeted improvement of drought resilience in bioenergy crops.
Shortwave‐Infrared‐Emitting Nanoprobes for CD8 Targeting and In Vivo Imaging of Cytotoxic T Cells in Breast Cancer
Checkpoint immunotherapy has made great strides in the treatment of solid tumors, but many patients do not respond to immune checkpoint inhibitors. Identification of tumor‐infiltrating cytotoxic T cells (CTLs) has the potential to stratify patients and monitor immunotherapy responses. In this study, the design of cluster of differentiation (CD8 + ) T cell‐targeted nanoprobes that emit shortwave infrared (SWIR) light in the second tissue‐transparent window for noninvasive, real‐time imaging of CTLs in murine models of breast cancer is presented. SWIR‐emitting rare‐earth nanoparticles encapsulated in human serum albumin are conjugated with anti‐CD8α to target CTLs with high specificity. CTL targeting is validated in vitro through binding of nanoprobes to primary mouse CTLs. The potential for the use of SWIR fluorescence intensity to determine CTL presence is validated in two syngeneic mammary fat pad tumor models, EMT6 and 4T1, which differ in immune infiltration. SWIR imaging using CD8‐targeted nanoprobes successfully identifies the presence of CTLs in the more immunogenic EMT6 model, while imaging confirms the lack of substantial immune infiltration in the nonimmunogenic 4T1 model. In this work, the opportunity for SWIR imaging using CD8‐targeted nanoprobes to assess CTL infiltration in tumors for the stratification and monitoring of responders to checkpoint immunotherapy is highlighted.
Short-Wave Infrared Upconverting Nanoparticles
Optical technologies enable real-time, noninvasive analysis of complex systems but are limited to discrete regions of the optical spectrum. While wavelengths in the short-wave infrared (SWIR) window (typically, 1700-3000 nm) should enable deep subsurface penetration and reduced photodamage, there are few luminescent probes that can be excited in this region. Here, we report the discovery of lanthanide-based upconverting nanoparticles (UCNPs) that efficiently convert 1740 or 1950 nm excitation to wavelengths compatible with conventional silicon detectors. Screening of Ln3+ ion combinations by differential rate equation modeling identifies Ho3+/Tm3+ or Tm3+ dopants with strong visible or NIR-I emission following SWIR excitation. Experimental upconverted photoluminescence excitation (U-PLE) spectra find that 10% Tm3+-doped NaYF4 core/shell UCNPs have the strongest 800 nm emission from SWIR wavelengths, while UCNPs with an added 2% or 10% Ho3+ show the strongest red emission when excited at 1740 or 1950 nm. Mechanistic modeling shows that addition of a low percentage of Ho3+ to Tm3+-doped UCNPs shifts their emission from 800 to 652 nm by acting as a hub of efficient SWIR energy acceptance and redistribution up to visible emission manifolds. Parallel experimental and computational analysis shows rate equation models are able to predict compositions for specific wavelengths of both excitation and emission. These SWIR-responsive probes open a new IR bioimaging window, and are responsive at wavelengths important for vision technologies.
A Framework Based on 2-D Taylor Expansion for Quantifying the Impacts of Subpixel Reflectance Variance and Covariance on Cloud Optical Thickness and Effective Radius Retrievals Based on the Bispectral Method
The bispectral method retrieves cloud optical thickness (τ) and cloud droplet effective radius (re) simultaneously from a pair of cloud reflectance observations, one in a visible or near-infrared (VIS/NIR) band and the other in a shortwave infrared (SWIR) band. A cloudy pixel is usually assumed to be horizontally homogeneous in the retrieval. Ignoring subpixel variations of cloud reflectances can lead to a significant bias in the retrieved τ and re. In the literature, the retrievals of τ and re are often assumed to be independent and considered separately when investigating the impact of subpixel cloud reflectance variations on the bispectral method. As a result, the impact on τ is contributed only by the subpixel variation of VIS/NIR band reflectance and the impact on re only by the subpixel variation of SWIR band reflectance. In our new framework, we use the Taylor expansion of a two-variable function to understand and quantify the impacts of subpixel variances of VIS/NIR and SWIR cloud reflectances and their covariance on the τ and re retrievals. This framework takes into account the fact that the retrievals are determined by both VIS/NIR and SWIR band observations in a mutually dependent way. In comparison with previous studies, it provides a more comprehensive understanding of how subpixel cloud reflectance variations impact the τ and re retrievals based on the bispectral method. In particular, our framework provides a mathematical explanation of how the subpixel variation in VIS/NIR band influences the re retrieval and why it can sometimes outweigh the influence of variations in the SWIR band and dominate the error in re retrievals, leading to a potential contribution of positive bias to the re retrieval. We test our framework using synthetic cloud fields from a large-eddy simulation and real observations from Moderate Resolution Imaging Spectroradiometer. The predicted results based on our framework agree very well with the numerical simulations. Our framework can be used to estimate the retrieval uncertainty from subpixel reflectance variations in operational satellite cloud products and to help understand the differences in τ and re retrievals between two instruments.
Enabling the Assimilation of CrIS Shortwave Infrared Observations in Global NWP at NOAA. Part I: Background and Methods
Radiance observations from Earth-observing satellites have a significant positive impact on numerical weather prediction (NWP) forecasts, but some spectral regions are not fully exploited. Observations from hyperspectral infrared (IR) sounders in the longwave region (650-1100 cm -1 ), for instance, are routinely assimilated in many NWP models, but observations in the shortwave region (2155-2550 cm -1 ) are not. Each of these regions provides information on the temperature structure of the atmosphere, but the shortwave IR (SWIR) region is considered challenging to assimilate due to noise equivalent delta temperature (NEDT) that is highly variable depending on scene brightness temperature and to phenomena that are difficult to model, like non-Local Thermodynamic Equilibrium (NLTE) and solar reflectance. With recent advances in small-satellite technology, SWIR temperature sounders may provide an agile and cost-effective complement to the current constellation of IR sounders. Therefore, a better understanding of the use and impact of SWIR observations in data assimilation for NWP is warranted. In part one of this study, as presented here, the amount of unique information (as determined by Empirical Orthogonal Decomposition (EOD)) made available to a data assimilation system by Cross-track Infrared Sounder (CrIS) SWIR observations is reviewed, recent advancements to the Community Radiative Transfer Model (CRTM) for the simulation of CrIS shortwave radiances are tested, and enhancements to NOAA’s Global Data Assimilation System (GDAS) for the assimilation of CrIS SWIR observations are implemented and evaluated. Part two of this study, which seeks to assess the value of assimilating shortwave IR observations in global NWP, is also introduced.
Volatile Element Evidence of Local MORB Mantle Heterogeneity Beneath the Southwest Indian Ridge, 48°–51°E
Abstract The mantle source beneath the Southwest Indian Ridge (SWIR) reflects a complex history of contamination. Magmatic volatile contents are vital tracers of these kinds of heterogeneities, which may fractionate otherwise constant volatile/non‐volatile elemental ratios, such as the H 2 O/Ce ratio. Although several studies have recently used trace element and isotopic data to address mantle source heterogeneity and magmatic processes at SWIR 48°–51°E region, volatile element constraints provide a valuable test of models for the origins of mantle heterogeneities in this region. Here, we present new data for nine rare basaltic glass samples from the 48°–51°E region, which enable careful assessment of the effects of primary versus secondary processes on the glass volatile contents. These samples are strongly affected by variable extents of carbon degassing, and shallow assimilation of Cl‐rich fluid, but also reveal consistently high H 2 O/Ce ratios (458.8 ± 14.9), among the highest in MORBs, that cannot be explained by late‐stage secondary processes, crustal assimilation, or simple melting of peridotite mantle at variable depths. Instead, the high H 2 O/Ce ratios are features of the mantle source composition. The 48°–51°E region is notably more depleted in highly incompatible trace elements relative to other regions of the SWIR, although this depletion is not apparent in H 2 O, which is similarly abundant throughout the SWIR. We link the high H 2 O/Ce ratios in these glasses with other trace element characteristics diagnostic of subduction and fluid addition, suggesting that the mantle source reflects signatures of a refractory mantle residue that previously melted within a subduction zone.
NGC 4314. I - Visible and short-wavelength infrared surface photometry of the nucleus and bar
BVI (TI CCD) and JHK (University of Texas IR Camera) surface photometry of NGC 4314, an SB (rs)ap anemic spiral with a nuclear ring containing recent star formation, is presented. The shortwave IR (SWIR) frames reveal a nuclear bar of length 2 arcsec at PA of 0 deg. The nuclear ring and associated dust were detected in all SWIR color indices. A nuclear spiral was detected in the visible and SWIR just exterior to the ring. Extremely low-amplitude spiral-shaped deficits were found in the stellar distribution in the SWIR in this same region. These are attributed to dust, since CO is detectable at or near these locations. Average minor-axis profiles show this galaxy to have a nuclear bulge obeying the de Vaucouleurs r exp 1/4 law for values in the range 2-7 arcsec. The extinction and scattering characteristics of dust near the sites of recent star formation in the nuclear ring are discussed.