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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Anomalous lattice thermal conductivity increase with temperature in cubic GeTe correlated with strengthening of second-nearest neighbor bonds

Understanding thermal transport mechanisms in phase change materials is critical to elucidating the microscopic picture of phase transitions and advancing thermal energy conversion and storage. Experiments consistently show that cubic phase germanium telluride (GeTe) has an unexpected increase in lattice thermal conductivity with rising temperature. Despite its ubiquity, resolving its origin has remained elusive. In this work, we carry out temperature-dependent lattice thermal conductivity calculations for cubic GeTe through efficient, high-order machine-learned models and additional corrections for coherence effects. We corroborate the calculated phonon properties with our inelastic X-ray scattering measurements. Our calculated lattice thermal conductivity values agree well with experiments and show a similar increasing trend. Through additional bonding strength calculations, we propose that a major contributor to the increasing lattice thermal conductivity is the strengthening of second-nearest neighbor interactions. The findings herein serve to deepen our understanding of thermal transport in phase-change materials.

36 MATERIALS SCIENCE↗
NASA NTRS2004

Accurate Calculation of Oscillator Strengths for CI II Lines Using Non-orthogonal Wavefunctions

Non-orthogonal orbitals technique in the multiconfiguration Hartree-Fock approach is used to calculate oscillator strengths and transition probabilities for allowed and intercombination lines in Cl II. The relativistic corrections are included through the Breit-Pauli Hamiltonian. The Cl II wave functions show strong term dependence. The non-orthogonal orbitals are used to describe the term dependence of radial functions. Large sets of spectroscopic and correlation functions are chosen to describe adequately strong interactions in the 3s(sup 2)3p(sup 3)nl (sup 3)Po, (sup 1)Po and (sup 3)Do Rydberg series and to properly account for the important correlation and relaxation effects. The length and velocity forms of oscillator strength show good agreement for most transitions. The calculated radiative lifetime for the 3s3p(sup 5) (sup 3)Po state is in good agreement with experiment.

Tayal, S. S.↗
NASA NTRS1991

Effect of Fiber Strength on the Room Temperature Tensile Properties of Sic/Ti-24Al-11Nb

SCA-6 SiC fibers of known strength were incorporated into SiC/Ti-24Al-11Nb (at. percent) composites and the effect of fiber strength variability on room temperature composite strength was investigated. Fiber was etched out of a composite fabricated by the powder cloth technique and the effect of the fabrication process on fiber strength was assessed. The strength of the composite was directly correlated with the strength of the as-received fiber. The strength of composite plates containing mixed fiber strengths was dominated by the lower strength fiber. Fabrication by the powder cloth technique resulted in only a slight degradation of fiber strength. The strength of the composite was found to be overestimated by the rule of mixtures strength calculation. Examination of failed tensile specimens revealed periodic fiber cracks and the failure mode was concluded to be cumulative. With the variation in fiber strength eliminated, the composite UTS was found to have a positive correlation with volume fraction of fiber.

Draper, S. L.↗
NASA NTRS2016

Designing the Next Generation of Human Spacecraft

Lunar Space Station Common Module: A new concept for a module for a lunar space station attempts to reduce the module's mass by abandoning the traditional rack structure currently used on the ISS for the mounting of internal hardware and replacing it with a core structure. By using this design, the pressure shell will not have to carry the loads resulting from the internal mass. I worked with another intern to create the initial design for the module, with him focusing on the core and myself focusing on the pressure shell. To start, I was given the shell overall dimensions and material and tasked with sizing the wall thickness and placing stiffeners such that the shell could withstand the required loads. At the same time, I had to keep the mass to a minimum to keep the overall module within the allowable launch mass. Once I had done initial sizing based on pressure loads, I combined the pressure shell with the inner core to perform optimization of the design. Currently, the design involves circumferential stiffeners along the entire length of the pressure shell with longitudinal stiffeners on either end. In addition, extra wall thickness was added around each of the hatches. At this stage, the design shows a comparable mass to a more traditional design, but we are hopeful that, through optimization, we will be able to reduce the mass even further. There is currently a patent pending for the module design, for which I am listed as a co-inventor. ALON Material Testing: I was given samples of aluminum oxynitride (ALON) that had been impacted by a previous intern on which to perform residual strength tests as part of a plan to approve them for space use. Before testing, I measured the pucks and their damages using a ruler and optical micrometer in order to verify that the puck dimensions were within the tolerances set by the test guidelines and that the damages had not grown when the pucks were thinned. The test was a ring-ring test, which used two concentric rings to place the ring in axisymmetric bending, with the puck set up so that the damaged side was always in tension. Though I was unable to do the setup of the test or run the load machine due to a period of changing test procedures, I was able to observe the testing and perform the data collection. The pucks behaved as expected, breaking at the damage, as did the strengths calculated from the data, being lower than for the unimpacted pucks and having less scatter between the puck values. The attached image is of myself during the ALON strength testing. Over the course of my internship, I was able to learn much more about real-life structural analysis and about the behavior of materials, and it confirmed my previous interest in structural analysis. At the same time, due to the opportunities offered to interns, I was able to learn a lot about mission control, and, in doing so, I developed a second interest in working in mission control. In addition, being able to meet the people here and learn about the type of work NASA does made me want to come back to work for NASA full time.

Simmons, Emily↗
NASA NTRS1972

UK-5 Van Allen belt radiation exposure: A special study to determine the trapped particle intensities on the UK-5 satellite with spatial mapping of the ambient flux environment

Vehicle encountered electron and proton fluxes were calculated for a set of nominal UK-5 trajectories with new computational methods and new electron environment models. Temporal variations in the electron data were considered and partially accounted for. Field strength calculations were performed with an extrapolated model on the basis of linear secular variation predictions. Tabular maps for selected electron and proton energies were constructed as functions of latitude and longitude for specified altitudes. Orbital flux integration results are presented in graphical and tabular form; they are analyzed, explained, and discussed.

Stassinopoulos, E. G.↗
DOE OSTI2023

Effects of Accident Thermal Loading on In-Plane Shear Behavior of Steel-Plate Composite Walls

Structural walls in safety-related nuclear facilities are required to be designed for seismic and accident thermal (due to postulated high-energy pipe break events) loading combination. Current U.S. and international codes provide limited guidance for analysis and design of walls for this loading combination. This paper describes the experimental results and observations from tests conducted on a laboratory-scale (1:4 to 1:5) test unit representing steel-plate composite (SC) walls subjected to combined in-plane (seismic) and accident thermal loading. The test unit was subjected to surface temperatures of up to 450°F in combination with cyclic in-plane loading. Results of similar experiments recently conducted in Japan are also summarized (with surface temperatures up to 570°F). Surface heating combined with the low thermal conductivity and high specific heat of concrete resulted in nonlinear thermal gradients through the thickness of the specimens. These nonlinear thermal gradients and the associated self- or internal restraint led to extensive concrete cracking. This concrete cracking reduced the initial and secant stiffness of the specimens. The initial stiffness of the heated specimens reduced to 30 to 40% of the initial stiffness of the control (unheated) specimen. The secant stiffness of the heated specimens reduced up to 50% of the secant stiffness of the control (unheated) specimen. However, the in-plane shear strength of the heated SC specimens was still approximately 10 to 30% greater than the nominal in-plane shear strength calculated, for the limit state of steel plate von Mises yielding, using AISC N690 equations and measured material properties. Evaluation of the experimental results and observations suggests that the in-plane shear strength of SC walls subjected to typical accident surface temperatures (up to 570°F) can be estimated conservatively using the current provisions of AISC N690. The stiffness for accident thermal loading combinations can be considered to reduce from cracked composite stiffness at ambient temperature to fully cracked—that is, steel-only stiffness as the surface temperature increases up to typical accident value.

Construction & Building Technology↗
NASA NTRS1928

Mechanical properties of some materials used in airplane construction

Since lightness is desirable in airplane construction, greater stresses must be tolerated than in other kinds of construction. It is therefore necessary to have a more accurate knowledge of the greatest stresses that may occur and of the actual properties of the materials used. The Aeronautic Research Laboratories took the limit of elasticity as the basis of the strength calculations. Many tests were made of different steels, woods, aluminum alloys, and fabrics.

MATERIALS - STRENGTH↗
NASA NTRS1974

Stress-rupture strength and microstructural stability of tungsten-hafnium-carbon-wire reinforced superalloy composites

Tungsten-hafnium-carbon - superalloy composites were found to be potentially useful for turbine blade applications on the basis of stress-rupture strength. The 100- and 1000-hr rupture strengths calculated for 70 vol. % fiber composites based on test data at 1090C (2000F) were 420 and 280 MN/m2 (61,000 and 41,000 psi, respectively). The investigation indicated that, with better quality fibers, composites having 100- and 1000-hr rupture strengths of 570 and 370 MN/m2 (82,000 and 54,000 psi, respectively), may be obtained. Metallographic studies indicated sufficient fiber-matrix compatibility for 1000 hr or more at 1090C (2000F).

Petrasek, D. W.↗
NASA NTRS1972

Predicted trapped particle radiation levels for Tiros-N

Vehicle encountered electron and proton fluxes were calculated for a set of nominal TIROS-N trajectories with new computational methods and new electron environment models. Temporal variations in the electron data were considered and partially accounted for. Estimates of energetic solar proton fluxes are given for the lifetime of the satellite at selected integral energies from 10 to 100 MeV. Field strength calculations were performed with an extrapolated model on the basis of linear secular variation predictions. Orbital flux integration results are presented in graphical and tabular form.

Stassinopoulos, E. G.↗
DOE OSTI2024

Design of a Three-Layer Impactor for Material Strength Measurements at Multi-Megabar Pressures

Off-Hugoniot loading methods for dynamic compression have been a topic of interest for many years as a means of accessing high pressures without melting a material. Simulations and an initial test experiment of a three-layer gas-gun impactor suitable for use in measuring dynamic material strength at multi-megabar pressures are described. As shown through ARES hydrocode simulations, an impactor consisting of a low-, medium-, and high-impedance material, such as TPX, Al, and Ta or Pt, can produce a quasi-isentropic loading path up to 4.6 Mbar pressure with a low homologous temperature (T/T melt = 0.1–0.25). These impactors can also be tailored to create a pressure drive suitable for a Lagrangian sound speed experiment. Simulated in-situ velocities were analyzed to determine the change in calculated strength due to non-uniformity in the impactor, which provides a measure of error sensitivity. An initial test of a three-layer projectile onto a flat target at 4.4 km/s impact velocity is reported. Finally, while the impactor incurred some delamination during firing, the measured sample/window interface velocity generally agrees with the simulated peak velocity and subsequent release, indicating the feasibility of this approach for measuring material strength.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Microstructure and mechanical properties of high Mn-containing ferritic-martensitic alloys exposed to cyclical thermal treatment

Substantial residual tensile stress tends to accumulate in currently available high-Cr ferritic martensitic steels that are subjected to cyclical heat treatment, which leads to premature brittle fracture. By tailoring the alloy composition, this thermal cycling can be exploited to induce a high number density of nanoprecipitates and phase transformations countering residual tensile stresses. In this work, three new variants of ferritic-martensitic steels have been designed with computational thermodynamics to meet the goals of mitigating residual tensile stresses by lowering martensite start temperatures and of enhancing mechanical strength and irradiation sink strength by increasing the number density of nanoprecipitates. Furthermore, ctenast materials were subjected to cyclical heat treatment. The thermally cycled samples were evaluated with mechanical testing and microstructural analysis to identify the optimal composition in which figures of merit include low residual stress and a high density of nanoscale MX (M = metal, X = C/N) precipitates, leading to high yield strength with reasonable ductility. The noticeably higher density of nanoprecipitates in the optimal alloy favor its higher yield strength, which is supported by the microstructure-derived yield strength calculation and precipitation kinetics simulation.

36 MATERIALS SCIENCE↗
DOE OSTI2021

17-7PH Housing Weld Report FY21

This report presents the work performed for welding 17-7PH stainless steel hemispheres, flanges, and accelerometer blocks. This includes weld development, microhardness measurements, calculated strengths, and distortion measurements after welding and heat treatment. The results of this report are utilized to propose a recommended welding procedure which was implemented for this experiment.

42 ENGINEERING↗
NASA NTRS1976

Absolute oscillator strengths for the iron group - A correction to the data of Warner for the second spectra and a comment on some of the semiempirical results of Kurucz and Peytremann

It has already been shown that the Fe II absolute oscillator strengths (f-values) measured by Warner (1967) contain a systematic error, the magnitude of which depends on the energy of the transition's upper level. The present paper demonstrates that this error affects all of Warner's oscillator strengths for the second spectra of the iron group and develops a correction formula for Warner's results. A comparison of the corrected f-values with other measured f-values for Ti II, V II, and Fe II indicates that the correction improves the usefulness of Warner's data and that the corrected f-values have no large systematic dependence on wavelength, level energy, or line strength. Solar abundances for iron-group elements computed using the original and corrected f-values are compared with recently suggested abundances, and it is found that the corrected f-values yield more consistent results. Semiempirical oscillator strengths calculated by Kurucz and Peytremann (1975) for Fe I, Ti II, and V II are also compared with measured data to evaluate the accuracy of the calculations. It is found that the absolute scales of these results are roughly correct, but some of them are subject to very large errors.

Smith, P. L.↗
NASA NTRS1976

Discrepancy between electron heating and cooling rates derived from Atmosphere Explorer-C measurements

The present theory of electron temperature in the daytime mid-latitude ionosphere is tested by using Atmosphere Explorer-C measurements. In the region below 300 km, where a balance is expected between electron heating by photoelectron impact and electron cooling to ions and neutrals, we find an imbalance in which the cooling rate is consistently higher than the heating rate. The shapes of the altitude profiles also differ substantially. The cooling rate has a sharp peak at about 220 km, while the heating rate exhibits a broad peak about 30 km lower. Improved agreement is achieved at higher altitudes by using an oxygen fine structure loss rate smaller by a factor of 2, based on more recent collision strength calculations. Although this improves the overall agreement of the heating and cooling rates, the shape discrepancy remains, and the new cooling rate falls consistently below the heating rate below 200 km.

Brace, L. H.↗
NASA NTRS1983

Line strength measurements using diode lasers - The nu2 band of H2S

The strengths of 94 lines in the nu2 band of H2S have been measured with an average accuracy of 3 percent using a tunable diode laser. The line strengths are determined from the peak absorption of nearly Doppler-shaped lines. A detailed error analysis of this measurement method is given. Ratios of the measured line strengths to strengths calculated assuming no vibration-rotation interactions are shown to range from as low as 0.057 to as high as 4.71.

Strow, L. L.↗
NASA NTRS1987

A comparison of the C III, O V, F VI, and Ne VII Delta n = 0 (2-2) line emissions from a laboratory plasma with theoretical predictions and astrophysical observations

Spectra of the Delta n = 0 (2-2) transitions of Be I-like ions, C III, O V, F VI, and Ne VII emitted from the TEXT tokamak, were measured with photometrically calibrated instrumentation and compared to the predictions of several models which differ in their treatment of electron impact excitation, using either the distorted wave or R-matrix approach. It was found that the ions from C III to Ne VII were located near the edge of the plasma, at densities between 10 to the 12th and 13th/cu cm. The experimental line ratios were compared with several sets of computations. Agreement is obtained between the experimental data and computations by using the R-matrix technique. This leads to the conclusion that the effect resonances must be included in collision strength calculations, particularly at low nuclear charge. The results show that the line ratios studied may be used with confidence as electron density diagnostics for laboratory or astrophysical plasmas.

Finkenthal, M.↗