Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “SN”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Surface Sn(IV) Hydrolysis Improves Inorganic Sn–Pb Perovskite Solar Cells

Cesium tin-lead (Sn-Pb) perovskites are exceptional for their combined capabilities in unlocking ideal bandgaps for solar cells and mitigating the stability issue faced by their hybrid organic-inorganic counterparts. But the development of high-performance solar cells using these materials is retarded by their inherent high density of detrimental Sn(IV) defects. Herein, we demonstrate a sequential surface treatment method, which entails a Sn(II) halide treatment to displace the buried Sn(IV) ions underneath the film surface, followed by a H 2 O treatment to hydrolyze the displaced Sn(IV) ions. The surface treatment induces chemical and microstructural reconstructions that significantly improve the optoelectronic properties and stability of perovskites. As a result, a power conversion efficiency of 16.79% and a T 90 stability of 958 h are achieved, topping all previously reported performance parameters for inorganic Sn-Pb PSCs. This achievement further shortens the performance gap between all-inorganic and hybrid organic- inorganic Sn-Pb PSCs with sub-1.4 eV bandgaps.

14 SOLAR ENERGY↗
DOE OSTI2025

Stability Frontiers in the AM 6 X 6 Kagome Metals: The Ln Nb 6 Sn 6 ( Ln :Ce–Lu,Y) Family and Density-Wave Transition in LuNb 6 Sn 6

The kagome motif is a versatile platform for condensed matter physics, hosting rich interactions between magnetic, electronic, and structural degrees of freedom. In recent years, the discovery of a charge density wave (CDW) in the AV 3 Sb 5 superconductors and structurally-derived bond density waves (BDW) in FeGe and ScV 6 Sn 6 have stoked the search for new kagome platforms broadly exhibiting density wave (DW) transitions. Here, in this work, we evaluate the known AM 6 X 6 chemistries and construct a stability diagram that summarizes the structural relationships among the >125 member family. Subsequently, we introduce our discovery of the broader LnNb 6 Sn 6 (Ln:Ce–Nd,Sm,Gd–Tm,Lu,Y) family of kagome metals and an analogous DW transition in LuNb 6 Sn 6 . Our X-ray scattering measurements clearly indicate a (1/3, 1/3, 1/3) ordering wave vector (√$\bar{3}$ x √$\bar{3}$ x $3$ superlattice) and diffuse scattering on half-integer L-planes. Our analysis of the structural data supports the “rattling mode” DW model proposed for ScV 6 Sn 6 and paints a detailed picture of the steric interactions between the rare-earth filler element and the host Nb–Sn kagome scaffolding. We also provide a broad survey of the magnetic properties within the HfFe 6 Ge 6 -type LnNb 6 Sn 6 members, revealing a number of complex antiferromagnetic and metamagnetic transitions throughout the family. This work integrates our new LnNb 6 Sn 6 series of compounds into the broader AM 6 X 6 family, providing new material platforms and forging a new route forward at the frontier of kagome metal research.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1992

Analysis of the photospheric epoch spectra of type 1a supernovae SN 1990N and SN 1991T

This paper presents an LTE analysis of the photospheric epoch optical and IUE UV spectra of the recent Type Ia supernovae SN 1990N and SN 1991T. It is found that SN 1990N has matter moving as fast as 40,000 km/s, while SN 1991T has matter moving as fast as 20,000 km/s. The exponential density profile with e-folding velocity of 3160 km/s suggested by deflation and delayed/late-detonation explosion models is adequate for calculating fits to the observed spectra. Findings on the iron peak elements suggest that in both SNe some nuclear burning continues into the outer ejecta or the newly synthesized elements are mixed into the outer ejecta. The observed spectra of SN 1990N are consistent with a composition of the inner envelope like that of model W7. Intermediate-mass elements with abundances higher than solar are probably in the outer ejecta of both SNe, while silicon, sulfur, and calcium are underabundance in SN 1991T relative to SN 1990N by factors of order 3, 3, and 120, respectively.

Jeffery, David J.↗
DOE OSTI2020

Over 11% Efficient Eco-Friendly Kesterite Solar Cell: Effects of S-Enriched Surface of Cu2ZnSn(S,Se)4 Absorber and Band Gap Controlled (Zn,Sn)O Buffer

For high efficiency kesterite Cu2ZnSn(S,Se)4 (CZTSSe) solar cell, CdS thin film was usually used as a buffer layer. However, due to the toxicity of Cd and pollution problems involved from the solution-based chemical bath deposition, eco-friendly high efficiency CZTSSe solar cell with Cd-free buffer is necessary. As an Cd-free buffer layer, we investigated (Zn,Sn)O (ZTO) film deposited by sputtering method. In order to achieve high power conversion efficiency, we controlled energy band gaps of CZTSSe absorber as well as ZTO buffer, which was required to optimize conduction band offset (CBO) between the absorber and the buffer and to increase open circuit voltage (Voc) and fill factor (FF). The CBO was optimized by controlling the band gap of ZTO. By varying the Sn/(Zn + Sn) ratio and its deposition temperature, band gap of ZTO was successfully adjusted. Experimental and computational calculation results showed that solar cell performance was strongly affected by the CBO between absorber and buffer. Besides CBO matching, larger band gap of ZTO improved short circuit current density (Jsc) with enhanced external quantum efficiency value in blue photon spectrum range. As an additional way to improve power conversion efficiency of solar cell, band graded CZTSSe absorber was developed by using spray-based two-step process. The sprayed CZTSSe film was engineered to have S-enriched surface, which makes surface band gap widened and surface passivated, and resultantly increases Voc, Jsc and fill factor (FF). By controlling band gaps of both CZTSSe absorber and ZTO buffer, we obtained 11.22% environment-friendly CZTSSe solar cell without MgF2 anti-reflection coating.

(Zn↗
DOE OSTI2024

Magneto-transport study on Sn-rich Sn 1–x Ge x thin films enabled by CdTe buffer layer

α-Sn, generally known as gray tin, has attracted significant scientific interest due to its potential to host novel topological phases. Studying the transport properties of α-Sn thin films grown on the InSb substrate has been challenging, as the InSb substrate also significantly contributes to the transport properties. In this article, we report a novel approach to epitaxially grow α-Sn thin films on an InSb substrate with a resistive buffer layer of CdTe. Thin films of α–Sn 1–x Ge x (x = 0, 0.025) alloy of 15 nm thickness have been grown using molecular beam epitaxy. The high quality of the samples has been determined through high-resolution x-ray diffraction. The CdTe buffer layer has high resistance and acts as an insulating virtual substrate, which significantly suppresses contribution from InSb. Magnetotransport measurements show clear Shubnikov–de Hass oscillations in α–Sn 1–x Ge x (x = 0, 0.025) thin films. A change in oscillation frequency is observed upon alloying with Ge, implying a modification in the electronic structure and demonstrating the effectiveness of the CdTe buffer layer approach. Furthermore, this work provides a new approach that enables the electronic transport characterization of the α–Sn 1–x Ge x alloy system, which enables the study of the topological quantum states using electronic transport and their device applications.

36 MATERIALS SCIENCE↗
NASA NTRS1983

The infrared echo of a type II supernova with a circumstellar dust shell - Applications to SN 1979c and SN 1980k

Merrill (1980) and Telesco et al. (1981) have reported observations according to which supernovae developed a thermal infrared excess about 7-9 months after visual maximum. The two supernovae involved are SN 1979c in NGC 4321 and SN 1980k in NGC 6946. The infrared behavior of these supernovae is almost identical to that observed in several novae. The present investigation is concerned with the question whether the thermal infrared radiation from SN 1979c and SN 1980k could have been emitted by dust particles which were present in a circumstellar shell prior to the supernova event. The obtained results confirm the suggestion of Bode and Evans (1980) that the thermal emission from SN 1979c may have originated from preexisting dust present in a circumstellar shell and heated up by the UV-visual output of the supernova. The thermal infrared emission from SN 1980k may have a similar origin.

Dwek, E.↗
DOE OSTI2022

Atomic layer epitaxy of kagome magnet Fe 3 Sn 2 and Sn-modulated heterostructures

Magnetic materials with kagome crystal structure exhibit rich physics, such as frustrated magnetism, skyrmion formation, topological flat bands, and Dirac/Weyl points. Until recently, most studies on kagome magnets have been performed on bulk crystals or polycrystalline films. Here, we report the atomic layer molecular beam epitaxy synthesis of high-quality thin films of topological kagome magnet Fe 3 Sn 2 . The structural and magnetic characterization of Fe 3 Sn 2 on epitaxial Pt(111) identifies highly ordered films with c-plane orientation and an in-plane magnetic easy axis. Studies on the local magnetic structure by anomalous Nernst effect imaging reveal in-plane oriented micrometer size domains. Superlattice structures consisting of Fe 3 Sn 2 and Fe 3 Sn are also synthesized by atomic layer molecular beam epitaxy, demonstrating the ability to modulate the sample structure at the atomic level. The realization of high-quality films by atomic layer molecular beam epitaxy opens the door to explore the rich physics of this system and investigate novel spintronic phenomena by interfacing Fe 3 Sn 2 with other materials.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Spectra of two very old supernovae - SN 1986J and SN 1980K

Spectra are presented for SN 1986J in NGC 891, observed 4 and 7 years after the explosion, and SN 1980K, observed 9 years after maximum light. A narrow-line and a broad-line component are noted in SN 1986J; these are respectively attributed to a circumstellar shell and the actual stellar interior (without hydrogen). SN 1980K continues to emit in very broad lines. Comparison with earlier observations suggests that this SN halted its exponential flux decline in the early 1980s, and is currently emitting at a constant rate. In both SNs studies, the identity of the energy source which sustains emission remains uncertain.

Leibundgut, Bruno↗
DOE OSTI2023

Direct analysis of the broad-line SN 2019ein: connection with the core-normal SN 2011fe

Type Ia supernovae (SNe Ia) are important cosmological probes and contributors to galactic nucleosynthesis, particularly of the iron group elements. To improve both their reliability as cosmological probes and to understand galactic chemical evolution, it is vital to understand the binary progenitor system and explosion mechanism. The classification of SNe Ia into Branch groups has led to some understanding of the similarities and differences among the varieties of observed SNe Ia. Branch groups are defined by the pseudo-equivalent widths of the two prominent Si ii lines, leading to four distinct groups: core-normal (CN), shallow-silicon, cool, and broad-line (BL). However, partly due to small sample size, little work has been done on the BL group. We perform direct spectral analysis on the pre-maximum spectra of the BL SN 2019ein, comparing and contrasting to the CN SN 2011fe. Both SN 2019ein and SN 2011fe were first observed spectroscopically within 2 d of discovery, allowing us to follow the spectroscopic evolution of both SNe in detail. We find that the optical depths of the primary features of both the CN and BL SNe are very similar, except that there is a Doppler shift between them. We further examine the BL group and show that for nine objects with pre-maximum spectra in the range (–6)–(–2) d with respect to B-maximum all the emission peaks of the Si ii λ6355 line of BL are blueshifted pre-maximum, suggesting a possible classification criterion.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Rapidity distributions of Z = 1 isotopes and the nuclear symmetry energy from Sn+Sn collisions with radioactive beams at 270 MeV/nucleon

The rapidity distributions of hydrogen isotopes emitted from central collisions of neutron-rich 132 Sn+ 124 Sn and neutron-deficient 108 Sn+ 112 Sn systems at 270 MeV/nucleon were investigated at RIKEN-RIBF. The data are compared with antisymmetrized molecular dynamics (AMD) calculations and the rapidity distributions can be reproduced after adjusting the in-medium nucleon-nucleon cross sections. The double ratios between the two reaction systems taken for the relative yields of deuteron to proton (d/p) and triton to proton (t/p) are further examined in the midrapidity domain, where the adjustments in the AMD calculations do not affect much on them. The d/p and t/p double ratios at midrapidity agree well with the ratio of the system neutron numbers and its squared value, respectively, and the rapidity dependence of these double ratios is consistent with a picture of partial mixing of colliding nuclei. By comparing with the AMD model which shows a strong symmetry energy dependence of the t/p double ratio, the experimental result in the midrapidity domain favors the calculation with a symmetry-energy slope parameter around L = 46 MeV rather than L = 108 MeV.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2026

Ca Metal Batteries and Sn Anode Alloying: Resolving Misconceptions in Ca–Sn Alloy Formation

Ca metal anode suffers from surface passivation and struggles to effectively plate and strip in conventional Ca electrolytes, making the development of alloy anode for calcium metal battery essential. This work systematically and carefully evaluates the electrochemical formation and feasibility of the Sn anode and its possibility of alloying with Ca using a combination of cyclic voltammetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM/EDS), X-ray diffraction (XRD), and synchrotron transmission X-ray microscopy (TXM). Electrochemical measurements and SEM/EDS analyses indicate apparent Ca alloy formation. However, detailed XRD and TXM characterization reveal substantial lithium-ion involvement when lithium metal is employed as the reference electrode, even in electrolytes with high Ca salt concentrations. These findings highlight a significant risk of misinterpretation: Although limited Ca–Sn alloying may occur, the faster kinetics of Li + can dominate the alloying process, leading to a Li-driven reactions at the Sn anode. In contrast, cells constructed with Ca metal as both reference and counter electrodes exhibit distinct redox features only during the initial cycles, followed by rapid cell failure. The high oxidation currents induce severe Ca passivation, occurring nearly concurrently with Sn dealloying. Overall, this study provides critical insight into the practical limitations and common experimental artifacts associated with Ca metal battery systems and underscores the necessity for rigorous cell design and cautious interpretation when evaluating alloy chemistry in multivalent Ca-based batteries.

36 MATERIALS SCIENCE↗
NASA NTRS1987

High-velocity emission in young supernova remnants: SN 1006 and SN 1572

The paper reports the discovery of broad H-alpha emission from the SN 1006 remnant with a FWHM velocity of 2600 + or - 100 km/s. This emission is similar to that seen in the remnant of SN 1572 which has a FWHM for H-alpha of 1800 km/s. The nonradiative model was used to interpret the line widths and the derived shock velocity was compared with proper motion measurements to derive distances of 1.4-2.1 kpc to SN 1006 and 2.0-2.8 kpc to SN 1572.

Kirshner, Robert↗
NASA NTRS1995

Discovery of Cepheids in NGC 5253: Absolute peak brightness of SN Ia 1895B and SN Ia 1972E and the value of H(sub 0)

Observations of the Hubble Space Telescope (HST) between 1993 May 31 and 1993 July 19 in 20 epochs in the F555W passband and five epochs in the F785LP passband have led to the discovery of 14 Cepheids in the Amorphous galaxy NGC 5253. The apparent V distance modulus is (m-M)(sub AV) = 28.08 +/- 0.10 determined from the 12 Cepheids with normal amplitudes. The distance modulus using the F785LP data is consistent with the V value to within the errors. Five methods used to determine the internal reddening are consistent with zero differential reddening, accurate to a level of E(B-V) less than 0.05 mag, over the region occupied by Cepheids and the two supernovae (SNe) produced by NGC 5253. The apparent magnitudes at maximum for the two SNe in NGC 5253 are adopted as B(sub max) = 8.33 +/- 0.2 mag for SN 1895B, and B(sub max) = 8.56 +/- 0.1 and V(sub max) = 8.60 +/- 0.1 for SN 1972E which is a prototype SN of Type Ia. The apparent magnitude system used by Walker (1923) for SN 1859B has been corrected to the modern B scale and zero point to determine its adopted B(sub max) value.

Saha, A.↗
DOE OSTI2021

Crystallization of the P 3 Sn 4 Phase upon Cooling P 2 Sn 5 Liquid by Molecular Dynamics Simulation Using a Machine Learning Interatomic Potential

We performed molecular dynamics simulations to study the crystallization of the P3Sn4 phase from P 2 Sn 5 liquid using a machine learning (ML) interatomic potential with desirable efficiency and accuracy. Our results capture the liquid properties of P 2 Sn 5 at 1300 K, which is well above the melting temperature. The phase separation and crystallization are observed when P 2 Sn 5 liquid is cooled down below 832 and 505 K, respectively. The simulation results are in good agreement with the experimentally observed phase transformation behaviors and provide useful insights into the complex nucleation and crystallization process at the details of atomistic scale. Our work also demonstrated that ML interatomic potentials based on neural network deep learning are robust and capable of accurately describing the energetics and kinetics of complex materials through molecular dynamics simulations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

𝑙-forbidden 𝑀⁢1 strengths near 100 Sn from knockout reactions in Cd and Sn

Neutron knockout reactions on beams of 104,102 Cd and 104 Sn are presented. States in the residual 103,101 Cd and 103 Sn nuclei are populated, including low-lying 7/2 + states of 𝜈⁢𝑔 7/2 character. These states have half-lives ≈ 400 ps due to their low energy and hindered 𝐵⁡(𝑀⁢1;7/2 + →5/2 + ) strengths. The excited-state half-lives were measured using their Doppler-shifted line shapes, and the resulting 𝐵⁡(𝑀⁢1) strengths are compared to valence space in medium similarity renormalization group (VS-IMSRG) calculations. Lastly, the VS-IMSRG calculations underpredict the 𝑙-forbidden 𝑀⁢1 strengths in the 100 Sn region, as well as in other regions of the nuclear chart near 40 Ca and 208 Pb.

90 ≤ A ≤ 149↗
DOE OSTI2021

SN 2019yvq Does Not Conform to SN Ia Explosion Models

We present new photometric and spectroscopic observations of SN 2019yvq, a Type Ia supernova (SN Ia) exhibiting several peculiar properties including an excess of UV/optical flux within days of explosion, a high Si ii velocity, and a low peak luminosity. Photometry near the time of first light places new constraints on the rapid rise of the UV/optical flux excess. Furthermore, a near-infrared spectrum at +173 days after maximum light places strict limits on the presence of H or He emission, effectively excluding the presence of a nearby nondegenerate star at the time of explosion. New optical spectra, acquired at +128 and +150 days after maximum light, confirm the presence of [Ca ii] λ7300 and persistent Ca ii NIR triplet emission as SN 2019yvq transitions into the nebular phase. The lack of [O i]$\lambda 6300$ emission disfavors the violent merger of two C/O white dwarfs (WDs) but the merger of a C/O WD with a He WD cannot be excluded. We compare our findings with several models in the literature postulated to explain the early flux excess including double-detonation explosions, 56 Ni mixing into the outer ejecta during ignition, and interaction with H- and He-deficient circumstellar material. Each model may be able to explain both the early flux excess and the nebular [Ca ii] emission, but none of the models can reconcile the high photospheric velocities with the low peak luminosity without introducing new discrepancies.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1994

X-ray emission from the historical supernovae in the spiral galaxy NGC 6946: SN 1980K and SN 1968D recovered ?

This paper describes a study of the Roentgen Satellite (ROSAT) Position Sensitive Proportional Counter (PSPC) observation of the spiral galaxy NGC 6946 to search for x-ray emission from the six historical supernovae that have occurred in that galaxy. At the age of these supernovae, all could be emitting x rays due to circumstellar interactions. Supernova (SN) 1980K may be present based upon the hardness ratio and the coincidence of an x-ray source with the optical position. Its luminosity agrees with a recent prediction by Chevalier & Fransson. The situation for SN 1968D, apparently recovered in Very Large Array (VLA) data, is less clear due to source confusion, but suggests SN 1968D has not been recovered. Only upper limits are available for the remaining four supernovae that have occurred in this galaxy.

Schlegel, Eric M.↗