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Rising atmospheric moisture escalates the future impact of atmospheric rivers in the Antarctic climate system

Abstract Despite their relative rarity, atmospheric rivers are key contributors to the surface mass balance of Antarctica. However, the future role of atmospheric rivers in modulating Antarctic sea-level contributions is a major area of uncertainty. Here, we leverage high-resolution climate simulations to show that Antarctic atmospheric rivers are highly sensitive to future increases in atmospheric moisture, leading to a doubling of atmospheric river frequencies and 2.5 × increase in precipitation from 2066–2100 under present-day thresholds for atmospheric river detection. However, future precipitation impacts are critically dependent on the detection threshold: accounting for moisture increases in the threshold produces smaller, regional changes in atmospheric river frequency, primarily resulting from an eastward shift in the polar jet maximum wind speeds. Our results underscore the importance of using large ensembles to quantify Antarctic atmospheric river responses to variability in projected moisture, which may not be captured when using only a few ensemble members.

Environmental Sciences & Ecology

Dates and rates of loess deposition and soil formation on the Snake River Plain, Idaho, USA

Loess-paleosol sequences in eolian deposits on the Snake River Plain, Idaho, western United States, preserve records of late Pleistocene to Holocene glacial-interglacial cycles. Here, we examine climate-driven changes in the timing and rate of loess accretion, soil formation, and pedogenic carbonate accumulation in the eastern and central Snake River Plain. High rates of loess deposition often correspond with dry, cold, and windy conditions and/or high sediment supply, while soil formation indicates landscape stability. Optically stimulated luminescence dating of four loess-soil sequences provides a record of the timing of loess deposition, and radiocarbon dating ( 14 C) of soil inorganic carbon provides ages for soil formation and pedogenic carbonate precipitation. On the central Snake River Plain, marine isotope stage (MIS) 3 is marked by loess deposition between ca. 50 ka and 33 ka, and pedogenic carbonate accumulation between ca. 42 ka calibrated years before present (cal. B.P.) and 31 ka cal. B.P. During MIS 2, loess deposition between ca. 21 ka and 15 ka is contemporaneous with pedogenic carbonate precipitation. MIS 2 is characterized by diffuse pedogenic carbonate formation and rapid loess accumulation. Both the eastern and central Snake River Plain study sites experienced high rates of loess deposition during MIS 2; however, the eastern Snake River Plain had almost three times faster rates of loess accumulation (0.56−0.63 m/k.y. from ca. 25 ka to 17 ka) as compared to the central Snake River Plain (0.18−0.26 m/k.y. from ca. 21 ka to 15 ka). During MIS 1, loess deposition on the central Snake River Plain ca. 11 ka was coincident with pedogenic carbonate formation ca. 10 ka cal. B.P. MIS 3 and MIS 1 are characterized by A horizons and well-developed Bk horizons, indicating soil stability and lower rates of loess accumulation during these intervals. Finally, this study highlights the role of late Quaternary−scale climatic variability on rates and amounts of soil inorganic carbon storage.

Geosciences

The Relationship of Hydrology in the Green River to Colorado Pikeminnow Populations

The Federally listed Colorado Pikeminnow (CP) (Ptychocheilus Lucius) has been declining in the Green River Basin over the last 20 years. Muth et al. (2000) recommended flows and temperatures to benefit endangered fish species downstream of Flaming Gorge Dam on the Green River. The recommendations identified a range of flows during the base flow period (flows that occur after the annual snowmelt runoff period, usually from early summer to the following spring) that were intended to benefit CP. The recommendations indicated that the mean flow for the summer–winter period should be established each year on the basis of anticipated hydrologic conditions, but adjustments could be made if hydrologic conditions change. Flow should gradually decline from peak flow to base flow, with the base flow reached by early to middle summer (depending on hydrologic conditions) and maintained through February. The rate of decline should depend on rates of decline in Yampa River flows and the recommended rates of decline for dam releases. No specific recommendations were made for base flow variation in Reach 1, but variation around the annual mean base flow should be restricted to achieve recommended levels of variation in Reach 2 (middle Green River) (Table 5.5 in Muth et al. 2000). Implementation of the flow and temperature recommendations served as the proposed action for an EIS on Flaming Gorge Dam operations. A Biological Assessment of the impacts on endangered species of implementing the recommendations was prepared and a Biological Opinion that called for development of a study plan to examine the effects of implementation. Projects to address this evaluation were identified in the Green River Study Plan and have been conducted since then. The purpose of the Study Plan was to identify and recommend to the Recovery Program those monitoring or research projects necessary for implementation and evaluation of the flow and temperature recommendations. Those projects included studies to evaluate the anticipated effects of implementing the recommendations (including potential adverse effects identified in the 2006 Biological Opinion) and studies to examine recognized uncertainties of the recommendations. A new recovery program summer base flow study plan was approved in September of 2020 to evaluate stable and elevated summer base flows below Flaming Gorge Dam intended to benefit CP spawning and rearing success. Anecdotal observations suggest CP production may have been higher in years prior to flow restrictions for endangered fish. Based on long-term CP monitoring data in the Green River, Bestgen and Hill (2016) concluded that CP would benefit from higher summer baseflows (1,700-3,000 ft 3 /sec) with flows above or below associated with lower abundance of age-0 CP. Therefore, flexibility in the ROD is currently being utilized to establish higher stable summer base flows in an attempt create more advantageous conditions for spawning and rearing CP. These fish recovery flows are restrictive to WAPA in the summer months, therefore it is necessary to conduct an analysis of historic river data relationships to CP abundance to better understand if the recommended fish flows (elevated and stable base flows) are necessary for fish recovery.

54 ENVIRONMENTAL SCIENCES

Increasing phosphorus loss despite widespread concentration decline in US rivers

The loss of phosphorous (P) from the land to aquatic systems has polluted waters and threatened food production worldwide. Systematic trend analysis of P, a nonrenewable resource, has been challenging, primarily due to sparse and inconsistent historical data. Here, we leveraged intensive hydrometeorological data and the recent renaissance of deep learning approaches to fill data gaps and reconstruct temporal trends. We trained a multitask long short-term memory model for total P (TP) using data from 430 rivers across the contiguous United States (CONUS). Trend analysis of reconstructed daily records (1980–2019) shows widespread decline in concentrations, with declining, increasing, and insignificantly changing trends in 60%, 28%, and 12% of the rivers, respectively. Concentrations in urban rivers have declined the most despite rising urban population in the past decades; concentrations in agricultural rivers however have mostly increased, suggesting not-as-effective controls of nonpoint sources in agriculture lands compared to point sources in cities. TP loss, calculated as fluxes by multiplying concentration and discharge, however exhibited an overall increasing rate of 6.5% per decade at the CONUS scale over the past 40 y, largely due to increasing river discharge. Results highlight the challenge of reducing TP loss that is complicated by changing river discharge in a warming climate.

Science & Technology - Other Topics

15-minute Parker River gap-filled tide height and salinity data, PIE LTER, Plum Island Sound, MA (2014–2023), for ELM PFLOTRAN modeling

This dataset contains 15-minute tide height and salinity data from the Typha site along the Parker River, part of the Plum Island Ecosystems Long Term Ecological Research (PIE LTER) site in Plum Island Sound, Massachusetts (MA) 2014-2023. Tide height (in NAVD88) was compiled from measurements conducted at the mouth of Plum Island Sound and corrected for time lags. Gap-filling of missing periods were done by fitting tidal constituents to the time series. Salinity was measured (and is stored on ESS DIVE ) in 2022 and 2023 using HOBO U24-002 conductivity loggers. River discharge is the most important control on tidal river water salinity at the location (Vallino & Hopkinson, 1998). An artificial neural network was trained to predict river water salinity at the location using Parker River discharge (USGS station 01101000, Parker River at Byfield, MA) and gap-filled salinity observations from a long-term monitoring station ca. 3km downstream from the Typha site (LTER station ‘Middle Road’) as input variables to create continuous time series information. The data set was used in the spin up and simulations of a land surface model coupled to a biogeochemical reaction network (ELM PFLOTRAN) assessing impacts of hydrology and salinity input on methane fluxes in 2022 and 2023 (Sulman et al., 2024). Metadata files ELMPFLOTRAN_tide_salinity_dd.csv and ELMPFLOTRAN_tide_salinity_flmd.csv provide details on site location, data variables, and QA/QC methods .

54 ENVIRONMENTAL SCIENCES

Modeling the microplastic distribution along the Delaware River Estuary: Accumulation patterns and hydrodynamic influences

Microplastic pollution is an escalating environmental concern, particularly in densely populated estuary regions, where it poses significant threats to aquatic life and human health. The dispersion patterns of microplastic particles along estuaries are influenced and complicated by multiple environmental factors such as river flow, tidal mixing, salt intrusion, and estuarine circulation. This study examines the accumulation and dispersion patterns by modeling three typical classes of microplastics in the Delaware River Estuary: synthetic fibers, sinking plastic films, and rising plastic pellets. Our findings reveal specific areas with high microplastic accumulation for each type. Notably, the upper estuary regions exhibit significant retention of rising microplastics, associated with a region with reduced along-thalweg velocities downstream of Trenton, NJ and upstream of Philadelphia, PA. Conversely, synthetic fibers and sinking plastic films accumulate in the flow convergence zone near the bottom salinity front, typically downstream of Philadelphia. All of the microplastic accumulation hot spot locations are controlled by the balance of river discharge and salinity intrusions. During the dry season, microplastic accumulation hot spots shift upstream in the estuary, whereas in the wet season, the strong river discharge pushes them downstream. Furthermore, on the other hand, tidal mixing, settling, and resuspension processes strongly impact the spreading of microplastics along the river.

Delaware River Estuary

Impacts of Alternative Operations and Renewable Energy Deployment on Columbia River Hydropower

The Columbia River Treaty Tribes in the Pacific Northwest - the Nez Perce, Umatilla, Warm Springs, and Yakama - hold treaty-reserved fishing rights for the Columbia River, one of the world's most productive salmon rivers and a critical resource for these tribes. However, the tribes have expressed that current operating regimes of hydropower dams throughout the Columbia River Basin (CRB) do not fully account for tribal fishing rights and have negatively impacted fish populations. Four tribes acting together through the Columbia River Inter-Tribal Fish Commission (CRITFC)'s 2022 Energy Vision stated that current power system models often do not fully account for the many constraints faced by hydropower facilities in the CRB. As the deployment of variable renewable energy (VRE) like solar and wind continues to increase, power system flexibility will become increasingly important. As a result, there is a growing need to better understand the true capabilities of the hydropower generation fleet while accurately accounting for ecological constraints (Northwest Power and Conservation Council 2022). Understanding hydropower's role in a future grid with a higher share of VRE can inform water resources planning to address ecological needs. The goal of this study is to examine the impacts of alternative hydropower operation rules and weather variability on hydropower generation and grid operations in VRE and transmission infrastructure deployment scenarios. The study evaluates how hydropower scheduling practices can reduce ecological impacts to the region's salmon populations. More specifically, the study examines the impact of today's dam water release rules (called "adjusted base water rules" in this study) and new, ecologically informed water release rules (called "ecosystem water rules" in this study) on two VRE scenarios (current renewable energy levels and higher renewable energy levels) using six weather years for each scenario (2008-2013). CRITFC developed the ecosystem water rules, which capture a portion of the changes they recommend for CRB hydropower operations. These analyses use a water resource planning model (OASIS) and a production cost model (PLEXOS) to simulate CRB reservoir cascade and Western Interconnection power grid operation.

13 HYDRO ENERGY

CRiSPPy: An advanced hydropower scheduling tool for the Colorado River Storage Project

The Western Area Power Administration (WAPA) plays a vital role in delivering reliable and cost-effective hydroelectric power to millions of customers across the western United States. The Colorado River Storage Project (CRSP) carries out WAPA’s mission in Arizona, Utah, Colorado, New Mexico, Nevada, Wyoming and Texas. Achieving this mission requires effective management of the Colorado River system, and depends on the use of advanced analytical tools and modeling methodologies. For many years, CRSP has relied on the Generation and Transmission Maximization Superlite (GTMax SL) model for its mid-term and long-term hydroscheduling needs. However, the evolving energy market, power system operations, environmental rules, and hydrology conditions, coupled with advancements in computational capabilities, have necessitated the development of a more modern and robust solution. This report introduces the Colorado River Storage Project Python-based (CRiSPPy) model, a new, advanced hydropower scheduling tool developed to address CRSP ever-evolving challenges. CRiSPPy represents a significant leap forward in our ability to model and optimize the operation of the Colorado River system. It incorporates state-of-the-art optimization algorithms, enhanced data management capabilities, and an advanced graphical user interface, providing WAPA CRSP personnel with unprecedented insights and decision-making support. This document details the development, capabilities, and implementation of CRiSPPy. It is intended to serve as a comprehensive resource for WAPA staff, stakeholders, and anyone interested in the future of hydropower scheduling in the Colorado River Basin. We are confident that CRiSPPy will enhance WAPA's mission while adapting to the challenges of a dynamic and increasingly complex environment. The version of CRiSPPy described in this report is the version 2.3. New versions of CRiSPPy will be developed as the tool keeps evolving to address CRSP challenges.

13 HYDRO ENERGY

Wind River Experimental Forest Subcanopy Tower Information Sheet

Wind River was one of three sites that collected 3d sonic anemometer data for an ICOS subcanopy observation study. The three sites were defined by the following features and terrain: a deciduous broadleaf forest in flat terrain (Lanžhot, Czech Republic), a coniferous forest in mountainous terrain (Renon, Italy), and a tall conifer forest in mountain-valley terrain (Wind River, USA). The Wind River subcanopy towers were deployed in a high LAI, old-growth evergreen conifer forest and collected approximately 11 months of data. The site is an ecologically rich temperate rainforest in the western Cascade Mountains, and the biological carbon sink and source strength has been measured since 1998 using eddy covariance on the top of a 74 m tall flux tower (currently called the Wind River NEON tower). Additionally, forest inventory records date back to the 1920s. In 2024, four subcanopy towers were installed near the Wind River NEON tower to measure wind flow in the understory canopy layer for better understanding canopy flow coupling and decoupling in the subcanopy and how this affects the interpretation of overstory fluxes. The subcanopy tower installation was done by Lawrence Livermore National Laboratory and Washington State University (WSU) with collaborations from the University of Utah and the National Ecological Observatory Network (NEON).

54 ENVIRONMENTAL SCIENCES

Staying Current: A Community Readiness Framework for Marine Energy Applied to River Current Energy in Alaska

Marine energy-including wave, tidal, and river current energy-can provide a local energy source for rural and remote communities. Marine energy has the potential to bolster self-sufficiency and create economic opportunities while preserving ecological integrity. Communities may be interested in deploying, testing, and advancing these early-stage technologies to meet their needs. However, limited capacity, workforce constraints, and other barriers can challenge development. To better understand a community's interest in and preparedness for marine energy, we developed a suite of 150 'metrics of readiness.' Organized across seven categories-technical, social, environmental, strategic, governance, economic, financial-and 29 subcategories, the metrics provide a holistic perspective beyond the technical aspects of an energy device. We conducted a desktop application of the metrics of readiness for Igiugig, Alaska. The metrics were applied retrospectively for two points in time: before (2009) and after (2018) in-stream testing of a river current energy device. By documenting changes among categories and subcategories of the metrics, our results show the evolving nature of community readiness for river current energy. They also illustrate how our interdisciplinary framework captures the investment in environmental effects research and commitment to strategic planning that occurred in Igiugig. In future applications, we envision the framework could be used to foster public engagement in marine energy, collaborate with communities in project development, shape capacity building activities, prioritize investments, and inform research needs. While our study focuses on enabling river current energy in Alaska, the metrics of readiness have the potential to inform implementation of other renewable technologies with communities in new geographies.

13 HYDRO ENERGY

Dataset: "Widespread Drought-driven Declines in Streamflows and Water quality in the Upper Colorado River Basin (1998-2022)"

This data package contains the associated data and scripts for Nagamoto, E., Ombadi, M., Ciulla, F. et al. Widespread drought-driven declines in streamflows and water quality in the Upper Colorado River Basin during 1998-2022. Commun Earth Environ 7, 734 (2026). https://doi.org/10.1038/s43247-026-03890-5. This purpose of this study was to investigate the impact of the 21st century drought on water quantity and quality at catchments throughout the Upper Colorado River Basin (UCRB). We used stream flow, water temperature, specific conductance, air temperature, precipitation, and catchment attribute data for over 200 sites in the UCRB, collected from the National Water Information System using Basin3D (Varadharajan, 2023), GAGESII (Falcone, 2010), and the Google Earth Engine. We identified years of severe drought between 1998 and 2022 using the Standardized Precipitation Evaporation Index (SPEI), then calculated the relative change percentage of the stream flow, water temperature, and specific conductance from drought versus non-drought years. We used the attribute information from GAGESII to investigate what physical traits of catchments are associated streamflow vulnerability (greater relative change) or resilience to drought. We used land cover data from the National Land Cover Database (USGS, 2024) to assess any changes to physical attributes that may not be represented in the static attributes information in GAGESII. To increase data availability, we modeled stream temperature using methods from Willard, 2023. While the study period is water years 1998 to 2022, the raw water quantity and quality data extends to 1950 and the meteorological data extends to 1980. The data and code can be downloaded via the UCRB_drought.zip. Within the zip, the files are organized as follows: - INPUTS: Contains all input data used in UCRB_Drought_Workflow.ipynb - OUTPUTS: Contains all intermediate data created from UCRB_Drought_Workflow.ipynb as well as final products including the calculated Standardized Evapotranspiration Index (SPEI) - climatic_variables: The code used to collect meteorologic data from Google Earth Engine - feature_importance: The code used for the catchment attributes analysis - preprocessing: Code used in UCRB_Drought_Workflow_Preprocessing.ipynb - pyeto: Code used in UCRB_Drought_Workflow_Preprocessing.ipynb - calculations: Code used in UCRB_Drought_Workflow_Impacts.ipynb - plotting: Code used in UCRB_Drought_Workflow_Impacts.ipynb - README.md - UCRB_Drought_Workflow_Preprocessing.ipynb: The code used to prep raw data for the analysis - UCRB_Drought_Workflow_Impact.ipynb: The code which uses the prepped raw data for analysis, and plots all figures - requirements_ucrb-drought_v2.yml: The requirements file to create a virtual environment and Jupyter Lab kernel to run the code The INPUTS folder is organized into the following major directories and sub-directories. The "RDC_WT_SC_RAW" folder contains raw data for streamflow, water temperature, and specific conductance in a ".h5" file. The "NLCD_RAW" folder contains ".csv" files with annual land cover percentages for counties within the UCRB. The "MET_RAW" folder contains a ".csv" file with monthly meteorological data (air temperature and precipitation) for the sites in the UCRB which was obtained from code in the climatic_variables folder. The "GAGESII" folder contains ".csv" files with physical catchment attribute variables for catchments across the country. The "WT_LSTM_data" folder contains ".csv" files with calculated WT (Willard, 2023) and the associated RMSEs. The "Upper_Colorado_River_Basin_Boundary" folder contains geographic data including a shapefile for plotting in the UCRB_Drought_Workflow.ipynb. The "RESERVOIRS_RAW" folder contains ".csv" files for each reservoir in the UCRB with daily reservoir storage. There are also two files in the INPUTS folder that have combined reservoir storage data and reservoir metadata. The OUTPUTS folder is organized into the following major directories and sub-directories. The "RDC_WT_SC_data" folder contains a folder "Water_year" with the associated cleaned data, metadata, and data availability information in ".csv" files, a folder "Median_Relchange" with the relative change comparing drought to non-drought years in ".csv" files, and a folder "Peak95_Min5_Relchange" that has ".csv" files for the relative change in peak (95th %) and minimum (5th %) variables. The "NLCD_data" folder contains the difference in land cover from the beginning to end of the study period and the percentage of the county that is within UCRB bounds can be found in Nagamoto et al (2025)). The "MET_data" folder contains separated monthly air temperature and precipitation data and the calculated PET in ".csv" files. The "SPEI_data" folder contains ".csv" files with calculated SPEI values (one restricted to the study period and the other with information from the entire MET data period). The "Paper_Tables" folder contains two ".csv" files containing site information and data availability and information about the GAGESII trait aggregated categories. The base directory includes the file “flmd.csv” for a list and description of all files and the file “dd.csv” for data dictionaries. Scripts for preprocessing, analysis, and figure generation are located in the associated GitHub repository found at [https://github.com/iNAIADS/drought-impacts/tree/develop/UCRB-drought]. UPDATE 1: Title and code file updated to match submitted manuscript 10-15-2025. UPDATE 2: Code and data files updated to match revised manuscript 3-4-2026. UPDATE 3: Code and data files updated to match revised manuscript 6-7-2026. ** NOTE: DD and FLMD have not been updated yet. UPDATE 4: Added associated Manuscript information and DD and FLMD have been updated. To cite this code, please use the following BibTeX: @misc{nagamoto2025drought, author = {Emily Nagamoto and Fabio Ciulla and Mohammad Ombadi and Jared Willard and Rosemary Carroll and Charuleka Varadharajan}, title = {Dataset: "Widespread Drought-driven Declines in Streamflows and Water quality in the Upper Colorado River Basin (1998-2022)"}, year = {2025}, doi = {10.15485/2551894}, publisher = {ESS-DIVE Repository}, url = {https://data.ess-dive.lbl.gov/datasets/doi:10.15485/2551894} }

54 ENVIRONMENTAL SCIENCES

Data for Unraveling the Drivers of Water Shortage across Spatial Scales and Sectors in Colorado's West Slope River Basins

Results from Sunkara et al. submitted to Earth's Future. All code to reproduce the experiment and make the figures can be found here: https://github.com/ssaiveena/Sunkara-etal_2025_WestSlope For a detailed guide to data in this repository, see the README.txt file. Shortage output from .xdd files generated by StateMod was compressed into .parquet files in the Uncertain_scenarios folder. Reservoir output from .xre files can be found in the "Reservoir" directory within the Uncertain_scenarios folder. We adopted the CDSS naming convention: cm = Upper Colorado River Basin gm = Gunnison River Basin ym = Yampa River Basin wm = White River Basin sj = Southwest Basin

Climate Change

Summary of Savannah River Site FY23 Salt Waste Qualification Data

The Savannah River National Laboratory (SRNL) analyzed samples from Savannah River Site (SRS) Waste Tanks 41H and 21H to support qualification of Salt Waste Processing Facility (SWPF) Waste Batches 8 and 9 for processing (the FY23 Salt Batch Qualification samples). These Tanks (i.e. 41H and 21H) are blend tanks for feed to SWPF. None of the samples displayed any unusual or unexpected characteristics such as large amounts of solids, floating solids, or unusual color. Characterization of these samples confirmed similar chemical composition and characteristics to previous salt waste batches. The results for Batches 8 and 9 were provided by SRNL to Savannah River Mission Completion (SRMC), the Liquid Waste Operations subcontractor at SRS, as External Sample Results (Laboratory Information Management System (LIMS)) Reports. Additionally, a separate technical memo was issued by SRNL to report re-test data for Batch 8 for Cs-137 for filtered samples only which were run at the request of SWPF. For Batch 9, a set of samples was also analyzed in parallel by the SWPF-Analytical Laboratory (SWPF-AL). The SWPF-AL data is included herein for comparison with the SRNL data where applicable. The analytical results (both rapid, typically 4 weeks, and long term, typically 8 weeks) for Batches 8 and 9 are now summarized and discussed in this technical report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W

Stock-specific spatial overlap among seabird predators and Columbia River juvenile Chinook Salmon suggests a mechanism for predation during early marine residence

Abstract Objective Because predation is thought to be the primary source of natural mortality for juvenile salmon first entering the ocean, we sought to identify regions where, on average, stock-specific spatial overlap between the distribution of threatened and endangered juvenile Chinook Salmon Oncorhynchus tshawytscha and abundant fish-eating seabirds (common murres Uria aalge and sooty shearwaters Ardenna grisea) suggests the greatest potential for ocean predation risk to juvenile Chinook Salmon. Methods The relative abundance and spatial distribution of seabird predators and juvenile Chinook Salmon were quantified as part of long-term ecosystem surveys during May 2003–2012 and June 2003–2022. Genetic stock identification methods were used to assign individual fish to their respective stock groups. Stock-specific species distribution models then generated maps and indices of average annual spatial overlap between predators and prey within the survey area. Result There is unequivocal evidence for spatial overlap between common murres, sooty shearwaters, and five genetic groups of interior and lower Columbia River juvenile Chinook Salmon. We found strongly positive (≥0.70) spatial correlations between predator and prey densities in both May and June, although spatial overlap was, in general, greater during May. The region of highest spatial overlap occurred on the inner continental shelf between the Columbia River mouth (46.2°N) and Grays Harbor (47.0°N), a region at the beginning of the juvenile salmon migratory pathway that is strongly affected by freshwater outflow from the river. Conclusion Our findings support the idea that ocean avian predation during early marine residence has the potential to affect marine survival of juvenile Chinook Salmon and should be further investigated to better inform and implement ecological models and possible recovery actions for Chinook Salmon populations of the Columbia River basin.

Zamon, Jeannette E.

Longitudinal Patterns in Nitrate Revealed Through Drone‐Based Measurements in an Agriculturally Influenced Midwestern U.S. River

Nitrate concentrations in streams and rivers in the Midwestern United States are often elevated, reflecting the predominance of agriculture in the surrounding landscape. Recent advances in technology, including surface water drones and more precise sensors, provide opportunities to investigate nitrate dynamics with high spatial and temporal resolution. We deployed an aquatic drone, the AquaBOT, in a sixth-order, agriculturally influenced river to examine longitudinal patterns in water quality. Our goal was to measure the spatial and temporal heterogeneity in nitrate and nitrate removal processes and determine the influence of tributary inputs on main stem chemistry. We navigated the drone along a 12-km reach of the Des Moines River (Iowa, USA) nine times between June 2021 and August 2022. Across the deployments, mean nitrate concentration was positively related to discharge and was nearly two orders of magnitude higher in spring than summer. We observed contrasting patterns in main stem nitrate, which decreased downstream during some runs (e.g., 3.1–2.7 mg N L −1 in June 2021), demonstrating net nitrate uptake along the reach, and remained constant on other dates. Similarly, tributaries to the Des Moines had a varied influence on riverine nitrate. Tributaries either increased or decreased main stem nitrate concentrations depending on the tributary and the date. Nitrate removal rates were spatially and temporally variable but showed some consistency at the subreach (2 km) scale, with two subreaches often showing elevated rates of nitrate removal across dates. In conclusion, our study reveals nuanced heterogeneity in nitrate dynamics of the Des Moines River despite the homogeneity of agricultural land cover in the watershed.

54 ENVIRONMENTAL SCIENCES

Geochemical Phosphorus Sequestration in Tundra Soils Impedes Delivery of Bioavailable Phosphorus to the Kuparuk River, Alaska, USA: Implications for the Broader Arctic Region

Long-term river monitoring of the Kuparuk River (North Slope, Alaska, USA) confirms significant increases in solutes that are indicative of active layer thickening due to thawing permafrost. However, there is no evidence of an increase in total dissolved phosphorus (TDP) or soluble reactive phosphorus (SRP), the nutrient that limits primary production in this and similar rivers in the region. Here, we show that Mehlich-3 extractable iron (Fe) and aluminum (Al) in active layer soils impart high P geochemical sorption capacities across a range of landscape features that we would expect to promote lateral movement of water and solutes to headwater streams in our study watershed. Reanalysis of a recently published pan-Arctic soils database that includes active layer and permafrost soil samples suggests that this high P sorption capacity could be common in other parts of the Arctic region. We conclude that soil minerals enhance P retention on hillslopes and propose pedogenic secondary Fe and Al minerals may continue to retain P in these soils and limit biological productivity in the adjacent river even as active layer thickening increases potential P mobility in the watershed. We suggest that similar interactions may occur in other areas of the Arctic where comparable geochemical conditions prevail.

Sutor, Frederick W. [Univ. of Vermont, Burlington,

A Comparative Study of Physics‐Informed and Data‐Driven Neural Networks for Compound Flood Simulation at River‐Ocean Interfaces: A Case Study of Hurricane Irene

Simulating compound flooding (CF) at the river-ocean interface within large-scale Earth System Models (ESMs) presents significant challenges due to complex interactions between river discharge, storm surge, and tides. This study assesses the comparative advantages of physics-informed and data-driven machine learning (ML) approaches for enhancing local ESM performance. We systematically compare data-driven neural network models (i.e., CNNs, U-Net, Long Short-Term Memory (LSTM), Gated Recurrent Unit), and physics-informed neural network (PINN) models, including vanilla PINN and a finite-difference-based PINN (FD-PINN). Specifically, FD-PINN is introduced to enhance computational efficiency, accelerating vanilla PINNs by ∼6.5 times while improving accuracy. To enhance data-driven model training, a new data-generation approach is developed to sample historical fluvial and coastal flood events, which ensures a robust data set for extreme event prediction. The models are evaluated using a realistic one-dimensional river domain extracted from an ESM's river mesh and the Hurricane Irene event as an independent test case. Results show that FD-PINN achieves accurate predictions with significantly reduced computational costs relative to vanilla PINNs. Among data-driven models, the best overall performance is achieved by a CNN-LSTM hybrid, which balances accuracy and efficiency. While a fully connected CNN (CNN-FC) provides the best accuracy, it incurs high computational cost. Architectures lacking strong temporal modeling tend to underperform on unseen events. These findings highlight the importance of sequence-aware designs for robust generalization. This study reveals the trade-offs between physics-informed and data-driven models and proposes an adaptive hybrid framework for integrating ML into ESMs to enhance local flood simulations.

Earth Systems Modeling

Cation Data for the East River Watershed, Colorado (2014-2025)

This data package contains mean values for cation concentration for water samples taken from the East River Watershed in Colorado. Inductively coupled plasma mass spectrometry (ICP-MS) has been used to measure the concentrations of elements of interest simultaneously for the East River Watershed, Colorado groundwater and surface water samples to inform insights on the biogeochemistry processes within the watershed. The East River is part of the Watershed Function Scientific Focus Area (WFSFA) located in the Upper Colorado River Basin, United States. For samples collected prior to 06-16-2021, the instrumentation, Elan DRC II, PerkinElmer SCIEX, automatically switches among the three models necessary to analyze all 37 elements. These 37 elements include: (1) Lithium (Li), Beryllium (Be), Boron (B), Sodium (Na), Magnesium (Mg), Aluminium (Al), Silicon (Si), Phosphorus (P), Titanium (Ti), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Germanium (Ge), Arsenic (As), Rubidium (Rb), Strontium (Sr), Zirconium (Zr), Molybdenum (Mo), Silver (Ag), Cadmium (Cd), Tin (Sn), Antimony (Sb), Caesium (Cs), Barium (Ba), Europium (Eu), Lead (Pb), Thorium (Th), Uranium (U) using standard model, argon Ar as reaction gas, (2) Potassium (K), Calcium (Ca), Vanadium (V), Chromium (Cr), Manganese (Mn), Iron (Fe) using dynamic reaction cell (DRC) model, ammonia NH3 as reaction gas, and (3) Phosphorus (P) and Selenium (Se) using DRC model, oxygen O2 as reaction gas. Note for the samples with higher concentrations of chloride (Cl-), asenic (As) concentrations were analysed with DRC model (oxygen O2 as reaction gas) to avoid the interference of chloride. For samples collected on and after 06-16-2021, an advanced Agilent 8900 triple quadrupole inductively coupled plasma mass spectrometry system (Agilent 8900 QQQ ICP-MS, Agilent Technologies) has been used to measure the concentrations of interested 36 elements simultaneously for environmental samples, including (1) Lithium (Li), Beryllium (Be) and Boron (B) using standard no gas mode, (2) Sodium (Na), Magnesium (Mg), Aluminium (Al) Phosphorus (P), Potassium (K), Chromium (Cr), Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Germanium (Ge), Arsenic (As), Rubidium (Rb), Strontium (Sr), Zirconium (Zr), Molybdenum (Mo), Silver (Ag), Cadmium (Cd), Tin (Sn), Antimony (Sb), Cesium (Cs), Barium (Ba), Europium (Eu), Lead (Pb), Thorium (Th) and Uranium (U) using standard helium (He) collision mode, (3) Titanium (Ti) and Vanadium (V) using high Energy (HEHe) helium (He) collision mode, and (4) Silicon (Si), Calcium (Ca) and Selenium (Se) using standard H2 reaction mode. All samples were prepared/diluted with 2% (v/v) ultrapure nitric acid in Milli-Q water (18.2 mega ohm-cm), and analyzed under a rigorous quality assurance and quality control (QA/QC) process. This data package contains (1) a zip file (cation_data_2014_2025.zip) containing a total of 5,849 files: 5.848 data files of cation data from across the Lawrence Berkeley National Laboratory (LBNL) Watershed Function Scientific Focus Area (SFA) which is reported in .csv files per location and a locations.csv (1 file) with latitude and longitude for each location; (2) a file-level metadata (v6_20260901_flmd.csv) file that lists each file contained in the dataset with associated metadata; (3) a data dictionary (v6_20260901_dd.csv) file that contains terms/column_headers used throughout the files along with a definition, units, and data type; (4) PDF and docx files for the detemination of Method Detection Limits (MDLs) for ICP-MS PerkinElmer DRC II instrumentation (Detemination_of_Method_Detection_Limits__MDLs__for_ICP_MS__PerkinElmer_Elan_DRC_II__LBL_Bldg74_Lab214D) for samples before November 2021; (5) PDF and docx files for the determination of MDLs for ICP-MS Agilent 8900 QQQ instrumentation (ICP_MS_Analysis_detection_limits_and_QA_QC_WenmingDong_updated_2026-08-06) for samples November 2021 and onward. Missing values within the anion data files are noted as either "-9999" or "0.0" for not detectable (N.D.) data. There are a total of 113 locations containing cation data. Update on 2021-04-11: Added Detemination of Method Detection Limits (MDLs) for ICP-MS document, which can be accessed as a PDF or with Microsoft Word. Update on 2022-06-10: versioned updates to this dataset was made along with these changes: (1) updated cation data for all locations up to 2021-12-31, (2) removal of units from column headers in datafiles, (3) added row underneath headers to contain units of variables, (4) removed suffix and prefix on two variables (“aqberylliumion_asberyllium” and “aqlithiumion_aslithium”), (5) added -9999 for empty numerical cells, and (6) the addition of the file-level metadata (flmd.csv) and data dictionary (dd.csv) were added to comply with the File-Level Metadata Reporting Format. Update on 2022-09-09: Updates were made to reporting format specific files (file-level metadata and data dictionary) to correct swapped file names, add additional details on metadata descriptions on both files, add a header_row column to enable parsing, and add version number and date to file names (v2_20220909_flmd.csv and v2_20220909_dd.csv). Update on 2023-08-08: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-01-05. The file level metadata and data dictionary files were updated to reflect the additional data added. Update on 2024-03-11: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-10-16. Further, revisions to the data files were made to remove incorrect data points (from 1970 and 2001). The reporting format specific files were updated to reflect the additional data added. Updated versions of the PDF and docx files for determination of MDLs for ICP-MS data were added to this dataset for samples starting in November 2021. Update on 2025-05-15: Updates were made to both the data files and reporting format specific files. New available cation data was added, up until the end of WY2024 (September 30, 2024). International Generic Sample Numbers (IGSNs), when registered, were added to the data files. The reporting format specific files were updated to reflect the additional data added. Update on 2026-09-01: Updates were made to both the data files and reporting format specific files. New available cation data was added, up until the end of WY2025 (September 30, 2025). Updated versions, as of 2026-08-06, of the PDF and docx files for determination of MDLs for ICP-MS data were added to this dataset for samples starting in November 2021.

54 ENVIRONMENTAL SCIENCES