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Quantum Sensing using Geometrical Phase in Qubit-Oscillator Systems

We present a quantum sensing protocol for coupled qubit-oscillator systems that surpasses the standard quantum limit (SQL) by exploiting a geometrical phase. The signal is encoded in the geometrical phase that is proportional to the area enclosed in oscillator phase space. This area is amplified through squeezing, enabling sensitivities beyond the SQL. Our method is independent of oscillator's initial state, amenable to sensing with high-temperature or logical error-corrected states. The protocol shows robustness to qubit Markovian noise and preserves its state-independence, underscoring its practicality for next-generation quantum metrology. We demonstrate application to force sensing beyond the SQL in longitudinally coupled systems, and to high-precision measurements of couplings and pulse calibration surpassing SQL in dispersively coupled circuit quantum electrodynamics (cQED) architectures.

Suri, Nishchay [LBNL, Berkeley]

A Strategic Lens on Quantum Sensing for Space Applications

As classical technologies approach their theoretical power limits, quantum technologies, including computing, communications, and sensing, are often credited as the next science and engineering revolution. Quantum sensors are the basis of quantum computing and communications technologies, but also have unique uses for security, medical, and space-related applications. Regarding NASA’s agency goals, quantum sensing can improve climate change monitoring, enable navigations systems for deep space, and enhance fundamental astrophysics research. This report outlines the findings from an independent intern project on the ways NASA can strategically invest in quantum sensing technologies. This report also outlines policy barriers to developing the technology, largely related to communication difficulties, unfamiliarity with quantum, and lengthy approval processes. The information on tools and challenges relevant to quantum technology was gathered from literature reviews, online research, and discussions with NASA individuals. This report concludes with strategic recommendations to answer the question: what policies should NASA implement to effectively research and develop quantum sensing technologies?

Holland Frieling

Molecular Diradical Spin Qubits in a Crystalline Host as a Platform for Quantum Sensing

Doping a luminescent tris(2,4,6-trichlorophenyl)methyl diradical m (TTM) 2 into a host crystal of its diamagnetic precursor m (HTTM) 2 creates a molecular color center with enhanced optical-spin interface properties important for quantum sensing. Optical polarization of the |T 0 ⟩ sublevel of the diradical triplet ground state is achieved by spin-selective intersystem crossing from the |T + ⟩ and |T – ⟩ sublevels of the triplet excited state at ambient and cryogenic temperatures. Coherent spin control of m (TTM) 2 doped into m (HTTM) 2 using pulsed optically detected magnetic resonance (ODMR) spectroscopy results in a 10-fold improvement in ODMR contrast over that observed for randomly oriented m (TTM)2 using continuous-wave ODMR. The diradical doped crystal powders achieve spin coherence times of 2.8, 3.4, and 7.4 μs at 294, 85, and 5 K, respectively. The diradical photoluminescence is sensitive to weak applied magnetic fields independent of temperature, excitation wavelength, and dopant concentration, providing a promising pathway toward robust quantum sensing of anisotropic magnetic fields under ambient conditions.

crystal structure

High-precision chemical quantum sensing in flowing monodisperse microdroplets

A method is presented for high-precision chemical detection that integrates quantum sensing with droplet microfluidics. Using nanodiamonds (ND) with fluorescent nitrogen-vacancy (NV) centers as quantum sensors, rapidly flowing microdroplets containing analyte molecules are analyzed. A noise-suppressed mode of optically detected magnetic resonance is enabled by pairing controllable flow with microwave control of NV electronic spins, to detect analyte-induced signals of a few hundredths of a percent of the ND fluorescence. Using this method, paramagnetic ions in droplets are detected with low limit-of-detection using small analyte volumes, with exceptional measurement stability over >10 3 s. In addition, these droplets are used as microconfinement chambers by co-encapsulating ND quantum sensors with various analytes such as single cells, suggesting wide-ranging applications including single-cell metabolomics and real-time intracellular measurements from bioreactors. Important advances are enabled by this work, including portable chemical testing devices, amplification-free chemical assays, and chemical imaging tools for probing reactions within microenvironments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Quantum Sensing and Communications Being Developed for Nanotechnology

An interdisciplinary quantum communications and sensing research effort has been underway at the NASA Glenn Research Center since the summer of 2000. Researchers in the Communications Technology, Instrumentation and Controls, and Propulsion and Turbomachinery Divisions have been working together to study and develop techniques that use the principle of quantum entanglement (QE). This work is supported principally by the Nanotechnology Base R&T program at Glenn. As applied to communications and sensing, QE is an emerging technology that holds promise as a new and innovative way to communicate faster and farther, and to sense, measure, and image environmental properties in ways that are not possible with existing technology. Quantum entangled photons are "inseparable" as described by a wave function formalism. For two entangled photons, the term "inseparable" means that one cannot describe one photon without completely describing the other. This inseparability gives rise to what appears as "spooky," or nonintuitive, behavior because of the quantum nature of the process. For example, two entangled photons of lower energy can be created simultaneously from a single photon of higher energy in a process called spontaneous parametric down-conversion. Our research is focused on the use of polarization-entangled photons generated by passing a high-energy (blue) photon through a nonlinear beta barium borate crystal to generate two red photons that have orthogonal, but entangled, polarization states. Although the actual polarization state of any one photon is not known until it is measured, the act of measuring the polarization of one photon completely determines the polarization state of its twin because of entanglement. This unique relationship between the photons provides extra information about the system. For example, entanglement makes it easy to distinguish entangled photons from other photons impinging on a detector. For many other applications, ranging from quantum computation and information to quantum sensing, the entanglement property is critical.

Nguyen, Quang-Viet

How Quantum Sensing Will Help Solve GPS Denial in Warfare

The U.S. military’s ability to posture, deter, and prevail in future conflicts may rest on the quantum sensing position, navigation, and timing (PNT) capabilities that are currently being developed. Heavy reliance on GPS signals for PNT has become a critical vulnerability for the U.S. military. Meanwhile, the conflict in Ukraine has demonstrated that GPS denial and electronic warfare (EW) is now a key component of modern combat and satellite-guided munitions are reportedly being rendered ineffective. The Department of Defense (DOD) is focusing on upgrading GPS to use stronger, military-specific signals, which will still be vulnerable to EW and anti-satellite capabilities. A more diverse and resilient alternate-PNT strategy is needed to ensure mission success.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF

Quantum Sensing and Communications Being Developed for Nanotechnology

An interdisciplinary quantum communications and sensing research effort for application in microdevices has been underway at the NASA Glenn Research Center since 2000. Researchers in Glenn's Instrumentation and Controls, Communications Technology, and Propulsion and Turbomachinery Divisions have been working together to study and develop techniques that utilize quantum effects for sensing and communications. The emerging technology provides an innovative way to communicate faster and farther using less power and to sense, measure, and image environmental properties in ways that are not possible with existing technology.

Lekki, John D.

The Laser Interferometer Space Antenna (LISA): Current plans and prospects for quantum sensing in future space-based gravitational wave observatories

ESA’s third large class mission is a space-based gravitational wave observatory with NASA as a partner. This talk will describe the current plans for this mission, including the expected science, the instrument design, and a schedule for the development and launch. The noise floor of the system will be described and opportunities for improvement, including possible applications os quantum sensing and measurement techniques.

Jeff Livas

Quantum sensing of paramagnetic analytes by nanodiamonds in levitated microdroplets and aqueous solutions

Nanodiamonds (ND) hosting negatively charged nitrogen-vacancy (NV-) color centers have received attention for applications in magnetic field, electric field, chemical, and bio-sensing. The versatility of these probes is their excellent room-temperature optical and spin properties, along with their small size, functionalized surfaces and resistance to bleaching, making them ideal as nanoscopic sensors in picoliter volumes (e.g. single cells, but also microcompartments and aerosols). For quantitative ND-NV- sensing of paramagnetic analytes in such contexts, however, there remains an incomplete understanding of how factors related to the aqueous phase environment control detection efficiency. To address this, optically detected magnetic resonance (ODMR) is measured in bulk macroscale solutions and single levitated microdroplets as a function of Gd+3 concentration (340 nM to 1.5 mM), nanodiamond size, pH, competitor ions, and ligands. The ODMR response to [Gd+3] is found to be nonlinear, and pH, ND and sample volume dependent; indicating the detection of Gd+3 requires efficient adsorption of the analyte to the diamond surface. Langmuir adsorption isotherms embedded in a quantitative photophysical model links the ODMR response to adsorption thermodynamics of Gd+3. The equilibrium constant for Gd+3 adsorption to a carboxylated ND surface is determined to be (1 ± 0.5) x 105 M-1 corresponding to a free energy of adsorption of (-28 ± 1) kJ mol-1. These results provide general insight into how complex aqueous and microscale environments impact nanodiamond based quantum sensing modalities, and portend their application as quantitative chemical sensors in microenvironments.

Brown, Emily K

Quantum sensing for emerging energy technologies

The ability to exploit quantum phenomena has enabled sensing technologies with detection limits below the classical limit. Sensors with applications in energy discovery, production, transportation, and consumption can be enhanced through quantum or hybrid quantum-classical sensors. Here, in this Review, we provide an overview of commercial and emerging quantum sensor platforms and their opportunity areas specific to advanced energy technologies. Key examples include: power grid-enhancing-technologies, where quantum magnetometers can detect powerline and transformer faults; electric vehicle-to-grid applications, where chip-scale atomic clocks can enable grid synchronization; and carbon capture and storage, where quantum gravimeters and single-photo LiDAR can detect microscopic leaks. Quantum sensor deployment requires further research into miniaturization and ruggedization for field deployment, cost-reduction, and workforce development. The maturation of clean energy technologies and quantum sensors provide opportunities for synergy, with the integration of quantum sensors into advanced energy technologies maximizing their security, reliability, and efficiency.

critical metals

Thresholded quantum sensing with a frustrated Kitaev trimer

We investigate the response of a Ramsey interferometric quantum sensor based on a frustrated, three-spin system (a Kitaev trimer) to a classical time-dependent field (signal). The system eigenspectrum is symmetric about a critical point, |𝒃| = 0, with four of the spectral components varying approximately linearly with the magnetic field and four exhibiting a nonlinear dependence. Under the adiabatic approximation and for appropriate initial states, we show that the sensor's response to a zero-mean signal is such that below a threshold, |𝒃| <⁢ 𝑏 th , the sensor does not respond to the signal, whereas above the threshold, the sensor acts as a detector that the signal has occurred. This thresholded response is approximately omnidirectional. Moreover, when deployed in an entangled multisensor configuration, the sensor achieves sensitivity at the Heisenberg limit. Such detectors could be useful both as stand-alone units for signal detection above a noise threshold and in two- or three-dimensional arrays, analogous to a quantum bubble chamber, for applications such as particle track detection and long-baseline telescopy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC

Quantum Sensing of Displacements with Stabilized Gottesman-Kitaev-Preskill States

We demonstrate how recent protocols developed for the stabilization of Gottesman-Kitaev-Preskill states can be used for the estimation of two-quadrature displacement sensing, with sensitivities approaching the multivariate quantum Cramer-Rao bound. Thanks to the stabilization, this sensor is backaction evading and can function continuously without reset, making it well suited for the detection of itinerant signals. Additionally, we provide numerical simulations showing that the protocol can unconditionally surpass the Gaussian limit of displacement sensing with prior information, even in the presence of realistic noise. Our work shows how reservoir engineering in bosonic systems can be leveraged for quantum metrology, with potential applications in force sensing, waveform estimation, and quantum channel learning.

Labarca, Lautaro [Univ. of Sherbrooke, QC (Canada)

High-dynamic-range quantum sensing of magnons and their dynamics using a superconducting qubit

Magnons, the quanta of collective spin excitations in magnetic materials, may enable functionalities, such as nonreciprocity and transduction in hybrid quantum devices. To assess the potential of such applications, it is necessary to understand magnon dynamics beyond the simple harmonic oscillator regime, where theory predicts effects like population-dependent damping and quantum fluctuations in the form of magnon shot noise. Probing these phenomena requires sensors with high sensitivity and the ability to resolve magnon properties across different excitation regimes. Here, we demonstrate accurate and sensitive detection of magnon population and decay over a wide range of occupation numbers. We use a superconducting qubit to probe magnons in a ferrimagnet over approximately 2000 excitations. Using qubit control and parametrically induced qubit-magnon interactions, we demonstrate few-excitation sensitive detection of magnons with a dynamic range of approximately 30 dB, and are able to accurately resolve their decay with few-ns sensitivity. These capabilities offer a powerful and practical technique for probing magnon dynamics in or beyond the linear regime over a wide range of excitations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC

High sensitivity pressure and temperature quantum sensing in pentacene-doped p-terphenyl single crystals

Quantum sensors’ responsiveness to their physical environment enables detection of variables such as temperature (T), pressure (P), and strain. We present a molecular platform for PT sensing using para-terphenyl crystals doped with pentacene (PDP), leveraging optically detected magnetic resonance (ODMR) of photoexcited triplet electron spins. We observe maximal frequency variations of df/dP=1.8 MHz/bar from 0-8 bar and df/dT=247 kHz/K from 79–330 K, over 1200 times and threefold greater, respectively, than those seen with nitrogen-vacancy centers in diamond and > 85-fold greater pressure sensitivity over the previous record. Density functional theory calculations indicate picometer-level PT-induced molecular orbital shifts are measurable via ODMR. PDP offers additional advantages including high sensor doping levels, narrow ODMR linewidths, high contrast, and low-cost single crystal growth. Overall, this work reports low-cost, optically-interrogated PT sensors and lays the foundation for increased versatility of quantum sensors through synthetic molecular design.

Magnetic properties and materials

H20 Phase Characterization and Icing Mitigation Through Quantum Sensing in Silicon Carbide Non-Metal Defects

The primary focus of aircraft icing research has been on ice accretion on wings for its serious adverse consequences. When icing occurs on a wing, the change in airfoil shape results in a decrease in lift and an increase in drag, leading to potentially fatal accidents. Although the issue was recognized in the 1920s, the icing problem is still an area of ongoing research due to the complexity of the icing phenomena. A much-improved understanding of how certain weather conditions produce different icing characteristics will lead to new mitigation methods and a better quantification of current methods. This can be done by better understanding of the molecular bonding energy produced by ice polytype combinations when interacting with different surface materials in various environments. This work is currently developing both models that more accurately describe the quantum signatures of H2O states (i.e. supercooled, ice, liquid, glass phase...) and chip-based detectors to evaluate these signatures. These sensors utilize ion defects in Silicon Carbide (SiC) as extremely sensitive atomic magnetic detectors. This effort leverages both the decades-long SiC development expertise and infrastructure at NASA Glenn and its growing capabilities in quantum metrology.

Daniel R. Hart