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Geology Before Pluto: Pre-Encounter Considerations

Pluto, its large satellite Charon, and its four known satellites represent the first trans-Neptunian Kuiper Belt objects populating the outer-most solar system beyond the gas giant planets to be studied in detail from a spacecraft (New Horizons). A complete picture of the solar nebula, and solar system formation cannot be confidently formulated until representatives of this group of bodies at the edge of solar space have been examined. The Pluto system is composed of unique lunar- and intermediate-sized objects that can tell us much about how objects with volatile icy compositions evolve. Modeling of the interior suggests that geologic activity may have been to some degree, and observations of frost on the surface could imply the need for a geologic reservoir for the replenishment of these phases. However, the putative indicators of Pluto's geologic history are inconclusive and unspecific. Detailed examination of Pluto's geologic record is the only plausible means of bridging the gap between theory and observations. In this talk I will examine the potential importance of these tentative indications of geologic activity and how specific spacecraft observations have been designed and used to constrain the Pluto system's geologic history. The cameras of New Horizons will provide robust data sets that should be immanently amenable to geological analysis of the Pluto System's landscapes. In this talk, we begin with a brief discussion of the planned observations by New Horizons' cameras that will bear most directly on geological interpretability. Then I will broadly review major geological processes that could potentially operate of the surfaces of Pluto and its moons. I will first survey exogenic processes (i.e., those for which energy for surface modification is supplied externally to the planetary surface): impact cratering, sedimentary processes (including volatile migration) and the work of wind. I will conclude with an assessment of prospects for endogenic activity in the form of tectonics and cryo-volcanism.

Pluto

Spectroscopy of Pluto, 380-930 Nm at Six Longitudes

We have obtained spectra of the Pluto-Charon pair (unresolved) in the wavelength range 380-930 nm with resolution approx..450 at six roughly equally spaced longitudes. The data were taken in May and June, 2014, with the 4.2-m Isaac Newton Telescope at Roque de Los Muchachos Observatory in the Canary Islands, using the ACAM (auxiliary-port camera) in spectrometer mode, and using two solar analog stars. The new spectra clearly show absorption bands of solid CH4 at 620, 728, and 850-910 nm, which were known from earlier work. The 620-nm CH4 band is intrinsically very weak, and its appearance indicates a long optical path-length through the ice. This is especially true if it arises from CH4 dissolved in N2 ice. Earlier work (Owen et al. Science 261, 745, 1993) on the near-infrared spectrum of Pluto (1-2.5 microns) has shown that the CH4 bands are shifted to shorter wavelengths because the CH4 occurs as a solute in beta-phase crystalline N2. The optical path-length through the N2 crystals must be on the order of several cm to produce the N2 band observed at 2.15 microns. The new spectra exhibit a pronounced red slope across the entire wavelength range; the slope is variable with longitude, and differs in a small but significant way from that measured at comparable longitudes by Grundy & Fink (Icarus 124, 329, 1996) in their 15-year study of Pluto's spectrum (500-1000 nm). The new spectra will provide an independent means for calibrating the color filter bands on the Multispectral Visible Imaging Camera (MVIC) (Reuter et al. Space Sci. Rev. 140, 129, 2008) on the New Horizons spacecraft, which will encounter the Pluto-Charon system in mid-2015. They will also form the basis of modeling the spectrum of Pluto at different longitudes to help establish the nature of the non-ice component(s) of Pluto's surface. It is presumed that the non-ice component is the source of the yellow-red coloration of Pluto, which is known to be variable across the surface.

Spectroscopy

Tholins as Coloring Agents on Pluto and Other Icy Solar System Bodies

Tholins are refractory organic solids of complex structure and high molecular weight, with a wide range of color ranging from yellow and orange to dark red, and through tan to black. They are made in the laboratory by energy deposition (photons or charged particles) in gases and ices containing the simple molecules (e.g., N2, CH4, CO) found in planetary atmospheres or condensed on planetary surfaces. They are widely implicated in providing the colors and albedos, particularly in the region 0.3-1.0 microns, of several outer Solar System bodies, including Pluto, as well as aerosols in planetary atmospheres such as Titan. Recent color images of Pluto with the New Horizons spacecraft show concentrations of coloring agent(s) in some regions of the surface, and apparent near-absence in other regions. Tholins that may to some degree represent surface chemistry on Pluto have been synthesized in the laboratory by energetic processing of mixtures of the ices (N2, CH4, CO) known on Pluto's surface, or the same molecules in the gas phase. Details of the composition and yield vary with experimental conditions. Chemical analysis of Pluto ice tholins shows evidence of amides, carboxylic acids, urea, carbodiimides, and nitriles. Aromatic/olefinic, amide, and other functional groups are identified in XANES analysis. The ice tholins produced by e- irradiation have a higher concentration of N than UV ice tholins, with N/C approx. 0.9 (versus approx. 0.5 for UV tholins) and O/C approx.0.2. Raman spectra of the electron tholin show a high degree of structural disorder, while strong UV fluorescence indicates a large aromatic content. EUV photolysis of a Pluto gaseous atmosphere analog yields pale yellow solids relatively transparent in the visual, and with aliphatic CH bonds prominent in IR spectra. This or similar material may be responsible for Pluto's hazes.

Tholins

(abstract) The Impactor Flux in the Pluto-Charon System

The impactor flux on Pluto and Charon consists of long-period comets from the Oort cloud passing through the region, and intermediate-period comets evolving inward to (or outward from) short-period orbits. The source of the intermediate-period comets is likely an extended disk of remnant planetesimals beyond the orbit of Neptune, commonly referred to as the Kuiper belt, though the Oort cloud may be an additional source of some short-period comets. The Pluto-Charon system actually circulates within the Kuiper belt, and with an aphelion of 49.3 AU, moves through a region where remnant planetesimal orbits would likely be stable over the age of the solar system. The recent discovery of two objects at Kuiper belt distances, 1992 QB 1 and 1993 FW, and the fact that the orbit determined for 1992 QB 1 is likely of low eccentricity and low inclination, have provided strong observational evidence for the Kuiper belt. Weisman et al (1989) showed that, for the expected number of objects in the Kuiper belt necessary to provide the short-period comet flux, cometary cratering on Pluto and Charon is dominated by Kuiper belt comets. We will provide updated estimates of the numbers, based on an improved understanding of Oort cloud and Kuiper belt dynamics since 1989, and on improved estimates for the radii and masses for Pluto and Charon. Because Pluto and Charon actually penetrate the stable region of the Kuiper belt beyond 40 AU, expected cratering rates for the pair are substantially higher than for Triton, which is located at the inner edge of the Kuiper belt. However, the Pluto-Charon system is tidally evolved and this may have led to resurfacing events at various times in its history. Thus, detailed predictions of the integrated crater density or comparisons with Triton are not very meaningful without a knowledge of that history. Differences in the suspected compositions of Pluto and Charon may also lead to different surface rheologies and thus, different retention times for cratered surfaces.

Pluto

Mass-radius relationships and constraints on the composition of Pluto

With the new upper limit of Pluto's mass, an upper limit for Pluto's density of 1.74 g/cu cm has been found. Assuming Pluto to be 100% methane, available methane density data can be used to set a lower limit of 0.53 g/cu cm on Pluto's density, thus placing an absolute upper limit of 1909 km on the radius and a lower limit of 0.32 on the albedo. The results of 280 computer models covering a wide range of composition ratios of rock, water ice, and methane ice are reported. Limits are placed on Pluto's silicate content, and a simple spacecraft method for determining Pluto's water content from its density and moment of inertia is given. The low thermal conductivity and strength of solid methane suggest rapid solid-state convection in Pluto's methane layer.

Lupo, M. J.

On the global distribution of Pluto's atmosphere

The present investigation is relevant to the study of Pluto's current global and diurnal radiation balance. Strong gravitational tides are suggested by Charon's close proximity to Pluto (approximately 20,000 km) and Charon's large relative mass (roughly 0.25 Pluto's mass). Thus, the Pluto-Charon system replaces the earth-moon system as the best known example of a double planet. Methane is the only gas positively detected in Pluto's atmosphere. The tendency of the whole atmosphere to bulge preferentially toward the subsolar point as a result of the solar heating of the suface is considered, taking into account the longitudinal and the latitudinal tide. It is concluded that near perihelion, Pluto's atmosphere is essentially uniform over Pluto's surface. Its heat capacity by virtue of the heat of condensation is large enough that eclipses and the diurnal variation of insolation cause negligible freezing out of atmospheric gases.

Trafton, L.

Dynamics of Pluto and Charon

The dynamics of the Pluto-Charon system are reviewed from a historical perspective. Although Pluto's orbit crosses Neptune's, an intricate system of nested resonances keeps these planets apart. Pluto's orbit is apparently chaotic as well. Pluto always keeps the same face turned toward Charon, and vice versa. Tides also damp Charon's orbital eccentricity and inclination. Precession of Pluto's orbital plane causes Pluto's obliquity to vary periodically from formally prograde to retrograde. Pluto is probably an original member of the Solar system, but not an escaped satellite of Neptune.

Dobrovolskis, Anthony R.

A new determination of radii and limb parameters for Pluto and Charon from mutual event lightcurves

Over the past several years Pluto-Charon mutual events have yielded progressively more accurate estimates of Charon's orbital elements and the radii of Pluto and Charon (e.g., Buie, Tholen, and Horne, 1992). Analysis of the 1988 stellar occultation by Pluto indicates a radius for Pluto that is about 4%, or 50 km, larger than the mutual event radius of 1151 km. One possible explanation for the discrepancy is that the mutual event modeling treats Pluto and Charon as uniformly bright disks. If they are limb-darkened, the mutual event fits could underestimate their radii. In this paper we use an independent mutual event data set (Young and Binzel, 1992) to fit for Pluto and Charon's radii in a manner independent of either object's limb profile or albedo distribution. Our least-squares solution indicates that Pluto's radius is 1164 +/- 22.9 km and Charon's radius is 621 +/- 20.6 km.

Young, Eliot F.

Mirages and the nature of Pluto's atmosphere

We present model occultation lightcurves demonstrating that a strong thermal inversion layer at the base of Pluto's stratosphere can reproduce the minimum flux measured by the Kuiper Airborne Observatory (KAO) during the 1988 occultation of a star by Pluto. The inversion layer also forms the occultation equivalent of a mirage at a radius of 1198 km, which is capable of hiding tropospheres of significant depth. Pluto's surface lies below 1198 km, its radius depending on the depth of the troposphere. We begin by computing plausible temperature structures for Pluto's lower atmosphere, constrained by a calculation of the temperature of the atmosphere near the surface. We then trace rays from the occulted star through the model atmosphere, computing the resultant bending of the ray. Model light curves are obtained by summing the contribution of individual rays within the shadow of Pluto on Earth. We find that we can reproduce the KAO lightcurve using model atmospheres with a temperature inversion and no haze. We have explored models with tropospheres as deep as 40 km (implying a Pluto radius of 1158 km) that reproduce the suite of occultation data. Deeper tropospheres can be fitted to the data, but the mutual event radius of 1150 km probably provides a lower bound. If Pluto has a shallow or nonexistent troposphere, its density is consistent with formation in the solar nebula with modest water loss due to impact ejection. If the troposhere is relatively deep, implying a smaller radius and larger density, significant amounts of water loss are required.

Stansberry, J. A.

K2 Precision Lightcurve: Twelve Days in the Pluto-Charon System

The Kepler spacecraft's imaging photometer monitored the Pluto system from October-December 2015 during Campaign 7 of the K2 extended mission. Kepler obtained an unprecedented and fortuitous nearly continuous 12-Pluto day lightcurve from measurements acquired every 30 min using long cadence sampling. This 3-month-long baseline anchors the Pluto+Charon lightcurve near the time of the New Horizons July 2015 encounter, observing at solar phase angles between 1.16° and 1.74°. Long-term modeling of Pluto's lightcurve will ultimately reveal its long-term seasonal variation. K2's combined Pluto+Charon lightcurves measured at this epoch have an average total amplitude of 0.120+/- 0.006, 0.07 magnitudes smaller than the amplitude predicted by a static frost model (Buie and Tholen, 1989) projected from Hubble Space Telescope surface maps (Buie et al., 1992). Subtracting a static Charon lightcurve from the Pluto+Charon K2 lightcurve produces the same results. Likewise, we subtract each rotation model from the model for the first full rotation and find that the average difference of all variations is 0.017 +/- 0.008 magnitudes. Moreover, the difference between the first and last K2 rotation is 0.005 magnitudes, implying that there are no significant changes in the lightcurve during the 3 months of K2 observations. These results are consistent with seasonal transport on Pluto's surface and the predictions of Buratti et al. (2015a). However, a detailed understanding of the surface-atmosphere interactions associated with these phenomena requires decades of monitoring.

Benecchi, S. D.

Prebiotic Chemistry of Pluto

We present the case for the presence of complex organic molecules, such as amino acids and nucleobases, formed by abiotic processes on the surface and in near-subsurface regions of Pluto. Pluto's surface is tinted with a range of non-ice substances with colors ranging from light yellow to red to dark brown; the colors match those of laboratory organic residues called tholins. Tholins are broadly characterized as complex, macromolecular organic solids consisting of a network of aromatic structures connected by aliphatic bridging units (e.g., Imanaka et al.,2004; Materese et al.,2014, 2015). The synthesis of tholins in planetary atmospheres and in surface ices has been explored in numerous laboratory experiments, and both gas- and solid-phase varieties are found on Pluto. A third variety of tholins, exposed at a site of tectonic surface fracturing called Virgil Fossae, appears to have come from a reservoir in the subsurface. Eruptions of tholin-laden liquid H2O from a subsurface aqueous repository appear to have covered portions of Virgil Fossae and its surroundings with a uniquely colored deposit (D.P. Cruikshank, personal communication) that is geographically correlated with an exposure of H2O ice that includes spectroscopically detected NH3 (C.M. Dalle Ore, personal communication). The subsurface organic material could have been derived from presolar or solar nebula processes, or might have formed in situ. Photolysis and radiolysis of a mixture of ices relevant to Pluto's surface composition (N2, CH4, CO) have produced strongly colored, complex organics with a significant aromatic content having a high degree of nitrogen substitution similar to the aromatic heterocycles pyrimidine and purine (Materese et al.,2014, 2015; Cruikshank et al.,2016). Experiments with pyrimidines and purines frozen in H2O-NH3 ice resulted in the formation of numerous nucleobases, including the biologically relevant guanine, cytosine, adenine, uracil, and thymine (Materese et al.,2017). The red material associated with the H2O ice may contain nucleobases resulting from energetic processing on Pluto's surface or in the interior. Some other Kuiper Belt objects also exhibit red colors similar to those found on Pluto and may therefore carry similar inventories of complex organic materials. The widespread and ubiquitous nature of similarly complex organic materials observed in a variety of astronomical settings drives the need for additional laboratory and modeling efforts to explain the origin and evolution of organic molecules. Pluto observations reveal complex organics on a small body that remains close to its place of origin in the outermost regions of the Solar System.

Cruikshank, D. P.

Gemini NorthNIRI Spectra of Pluto and Charon: Simultaneous Analysis of the Surface and Atmosphere

94035We report on our analysis of blended Pluto and Charon spectra over the wavelength range 1.4 to 2.5 m as obtained by the NIRI instrument on Gemini North on June 25-28, 2004. The data have a resolving power () around 1500 and a SNR around 200 per pixel. The observed blended spectra are compared to models that combine absorption from the solid ice on the surface using Hapke theory, and absorption from the gaseous atmosphere. We assume the spectrum is a combination of several spatially separate spectral units: a CH4-rich ice unit, a volatile unit (an intimate mixture of N2, CH4 and CO), and a Charon unit (H2O, ammonia hydrate and kaolinite). We test for the presence of hydrocarbons (i.e. C2H6) and nitriles (i.e. HCN) and examine cases where additional ices are present as either pure separate spatial units, mixed with the CH4-rich unit or part of the volatile unit. We conclude that 2-4 of Plutos surface is covered with pure-C2H6 and our identification of C2H6 is significantly strengthened when absorption due to gaseous CH4 is included. The inclusion of Plutos atmosphere demonstrates that low-resolution, high-SNR observations are capable of detecting Plutos atmosphere during a time when Plutos atmosphere may have been undergoing rapid changes (1988-2002) and no high-resolution spectra were obtained. In particular, we identify features at 1.665 and 2.317 m as the Q-branch of the 23 and 3+4 bands of gaseous CH4, respectively. The later band is also evident in many previously published spectra of Pluto. Our analysis finds it is unnecessary to include 13CO to explain the depth of the 2.405 m, which has been previously suggested to be a spectral blended with C2H6, but we cannot definitively rule out its presence. Funding for this work (Cook) has been provided by a NASA-PATM grant.

Charon

The Dark Side of Pluto

During its departure from Pluto, New Horizons used its LORRI camera to image a portion of Pluto's southern hemisphere that was in a decades-long seasonal winter darkness, but still very faintly illuminated by sunlight reflected by Charon. Recovery of this faint signal was technically challenging. The bright ring of sunlight forward-scattered by haze in the Plutonian atmosphere encircling the nightside hemisphere was severely overexposed, defeating the standard smeared-charge removal required for LORRI images. Reconstruction of the overexposed portions of the raw images, however, allowed adequate corrections to be accomplished. The small solar elongation of Pluto during the departure phase also generated a complex scattered-sunlight background in the images that was three orders of magnitude stronger than the estimated Charon-light flux (the Charon-light flux is similar to the flux of moonlight on Earth a few days before first quarter). A model background image was constructed for each Pluto image based on principal component analysis applied to an ensemble of scattered-sunlight images taken at identical Sun−spacecraft geometry to the Pluto images. The recovered Charon-light image revealed a high-albedo region in the southern hemisphere. We argue that this may be a regional deposit of N2 or CH4 ice. The Charon-light image also shows that the south polar region currently has markedly lower albedo than the north polar region of Pluto, which may reflect the sublimation of N2 ice or the deposition of haze particulates during the recent southern summer.

Pluto

Surface Volatile Composition as Evidence for Hydrothermal Processes Lasting Longer in Triton’s Interior than Pluto’s

Ocean worlds, or icy bodies in the outer solar system that have or once had subsurface liquid water oceans, are among the most compelling topics of astrobiology. Typically, confirming the existence of a subsurface ocean requires close spacecraft observations. However, combining our understanding of the chemistry that takes place in a subsurface ocean with our knowledge of the building blocks that formed potential ocean worlds provides an opportunity to identify tracers of endogenic activity in the surface volatiles of Pluto and Triton. We show here that the current composition of the volatiles on the surfaces and in the atmospheres of Pluto and Triton are deficient in carbon, which can only be explained by the loss of CH4 through a combination of aqueous chemistry and atmospheric processes. Furthermore, we find that the relative nitrogen and water abundances are within the range observed in building block analogs, comets, and chondrites. A lower limit for N/Ar in Pluto's atmosphere also suggests source building blocks that have a cometary or chondritic composition, all pointing to an origin for their nitrogen as NH3 or organics. Triton's lower abundance of CH4 compared to Pluto, and the detection of CO2 at Triton but not at Pluto points to aqueous chemistry in a subsurface ocean that was more efficient at Triton than Pluto. These results have applications to other large Kuiper Belt objects as well as the assessment of formation locations and times for the four giant planets given future probe measurements of noble gas abundances and isotope ratios.

Solar system formation

Hemispherical color differences on Pluto and Charon

Time-resolved multicolor photometric observations of Pluto-Charon mutual events have been used to derive individual colors for these two bodies and to investigate the degree of color differences between their synchronous facing and opposite hemispheres. Pluto is significantly redder than Charon, where direct measurements of the anti-Charon hemisphere of Pluto and the Pluto-facing hemisphere of Charon yield B-V magnitudes of 0.867 + or - 0.008 and 0.700 + or - 0.010, respectively. Both Pluto and Charon are found to have relatively uniform longitudinal color distributions with 1-sigma upper limits of 2 percent and 5 percent, respectively, for any large-scale hemispherical color asymmetries. Thus, a previous suspicion of a significant color asymmetry on Charon is not confirmed. Instead the data may be attributed to a direct detection of polar caps on Pluto.

Binzel, Richard P.

The albedos of Pluto and Charon - Wavelength dependence

The March 3, 1987 occultation of Charon by Pluto was monitored simultaneously with three telescopes. Each site covered a distinct wavelength interval with the total range spanning 0.44-2.4 microns. Observing the same event ensures an identical sun-Pluto-earth geometry for all three sites, and minimizes the assumptions which must be made to combine results. This spectrophotometry is used to derive the individual geometric albedos of Pluto and Charon over a factor of at least 5 in wavelength. Combining the results with those of Binzel (1988) improved (B - V) color estimates (on the 'Johnson Pluto' system) are obtained for the components of the system at rotational phase 0.75: (Pluto + Charon) = 0.843 +/- 0.006; Pluto alone = 0.866 +/- 0.007; and Charon alone = 0.702 +/- 0.010.

Marcialis, Robert L.

Exploration of Pluto

Two NASA-sponsored cost-constrained mission implementations for the exploration of Pluto are described. One is the Pluto Fast Flyby (PFF) mission, which utilizes an 83 kg spacecraft to be launched in 1998 aboard a Titan IV (Solid Rocket Motor Upgrade)/Centaur) for an about 7-year-long direct trajectory to Pluto, which will carry an integrated CCD-imaging/UV spectrometer, with a possible integrated IR spectrometer. The other is the Pluto-350 spacecraft, weighing about 316 kg, which will carry a broader instrument set, greater redundancy, and which will require greater than 11 year flight time. Pluto-350 will be launched in 2001 aboard a Delta or Atlas, toward earth and Jupiter swingbys to provide the energy to reach Pluto.

Staehle, Robert L.

Masses and densities of Pluto and Charon

We have analyzed HST Wide Field Camera CCD images of Pluto, Charon, and a background star to observe Pluto's barycentric motion and to determine the individual masses and bulk densities of Pluto and Charon. The most fundamental new result was an accurate solution for a previously undetermined parameter, the Charon/Pluto mass ratio q; the new solution is q = 0.0837 +/- 0.0147. Significant accuracy improvements by almost a factor of two were obtained for Charon's orbital semimajor axis, a = 19,405 +/- 86 km and the Pluto system mass of 1.401 +/- 0.019 x 10 exp 8 inverse solar masses. The Pluto and Charon masses were (13.10 +/- 0.24) x 10 exp 24 g and (1.10 +/- 0.18) x 10 exp 24 g, respectively. Computed densities depend strongly on the assumed radius values. The density of Pluto is 2.13 +/- 0.04 g/cu cm and that of Charon is 1.30 +/- 0.23 g/cu cm.

Null, G. W.