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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Optical properties and photoexcitation of a novel liquid form of soluble polyacetylene

Optical absorption, fluorescence emission, Raman scattering, and time-resolved emission experiments are reported on a new liquid form of soluble polyacetylene. This liquid consists of separate polyene chains, grown on activated sites of a polybutadiene chain. The depolarization ratios as well as the time-resolved spectrum of the secondary emission were measured. The relevant spectral features are discussed and analyzed in terms of the lack of interchain interactions which characterize the polymer in solution.

Tubino, R.↗
NASA NTRS1989

Fluorescence from photoexcitation of C2H2 at 50-106 nm

The photoabsorption and fluorescence cross sections of C2H2 were measured in the 50-106 nm region using synchrotron radiation as a light source. Fluorescence observed at several excitation wavelengths was dispersed to identify the fluorescing species that are excited C2H, C2, CH, H, and possibly C2H2. The photodissociation process of C2H2 leading to the formation of fluorescing species is discussed. The C2 (C-A) emission observed at 92.3 and 95.5 nm is produced by the molecular elimination process associated with superexcited state(s). Fluorescence spectra from the two-photon excitation of C2H2 at 157.5 and 193 nm were also observed and compared with those of single-photon excitation at the equivalent excitation energies.

Han, J. C.↗
NASA NTRS1990

Fluorescence from photoexcitation of Cl2 at 50 to 105 nm

The photoabsorption and fluorescence cross sections of Cl2 were measured in the 50 to 105 nm region. Excitation of Cl2 in the 90 to 109 nm region emits two UV bands with peaks at 258 and 307 nm. The emission bands are attributed to the Cl2(D' to A') transition that is produced by the energy transfer from Cl*(4P 5/2) to Cl2. The Cl2(+)(A to X) emission band is produced at the excitation wavelengths shorter than 89 nm.

Ma, Guang↗
NASA NTRS1989

Fluorescence from photoexcitation of C2H5OH by vacuum ultraviolet radiation

The photoabsorption and fluorescence cross sections of C2H5OH have been measured in the 46-200 nm region. Fluorescence is dispersed to identify the emission systems, which are mainly OH(A-X), CH(A,B-X), and the H Balmer series. The photodissociation processes that produce the observed emissions are discussed.

Han, J. C.↗
NASA NTRS1990

Fluorescence from photoexcitation of Cl2 at 50 to 105 nm

The photoabsorption and fluorescence cross sections of Cl2 were measured in the 50 to 105 nm region. Excitation of Cl2 in the 90 to 109 nm region emits two UV bands with peaks at 258 and 307 nm. The emission bands are attributed to the Cl2 (D' to A') transition that is produced by the energy transfer from metastable Cl (4P 5/2) to Cl2. The Cl2(+) (A to X) emission band is produced at the excitation wavelengths shorter than 89 nm.

Ma, Guang↗
NASA NTRS1996

Investigation of Oxygen-Induced Quenching of Phosphorescence in Photoexcited Aromatic Molecules by Positron Annihilation Spectroscopy

Platinum OctaEthyl Porphyrin (Pt.OEP) is an efficient phosphor under ultraviolet excitation. The phosphorescent triplet state P(T(Sup 1)) is readily quenched by the oxygen O2 molecules. This phenomenon is being utilized as the basis for global air pressure measurements in aerodynamic facilities at various laboratories. The exact mechanism by which O2 molecules quench the P(T(Sup 1) approaches P(S(Sub O)) transitions is still unknown. The diamagnetic singlet states P(S(Sub n)), which feed P(T(Sub 1)) states via intersystem crossings, would presumably not be affected by O2. It must be only the magnetic P(T(Sub 1)) states, which can interact with the paramagnetic O2 molecules, that are affected. However, our positron lifetime and Doppler broadening studies suggest the formation of O2P(S(Sub n)), complexes which can also eventually reduce the population of the P(T(Sub 1)) states (i.e., quench phosphorescence). This reduction is possible because higher triplet states in (Pt.OEP) are admixed with the P(S(Sub 1)), states via spin orbit interactions. The experimental procedures and the results of various measurements are presented in this paper.

Singh, Jag J.↗
NASA NTRS2020

High Resolution Photoexcitation Measurements Exacerbate the Long-Standing Fe XVII Oscillator Strength Problem

For more than 40 years, most astrophysical observations and laboratory studies of two key soft x-ray diagnostic 2p - 3d transitions, 3C and 3D, in Fe XVII ions found oscillator strength rations f(3C)/f(3D) disagreeing with theory, but uncertainties had precluded definitive statements on this much studied conundrum. Here, we resonantly excite these lines using synchrotron radiation at PETRA III, and reach, at a millionfold lower photon intensities, a 10 times higher spectral resolution, and 3 times smaller uncertainty than earlier work. Our final result of f(3C)/f(3D) = 3.09(8)(6) supports many of the earlier clean astrophysical and laboratory observations, while departing by five sigmas from our own newest large-scale ab initio calculations, and excluding all proposed explanations, including those invoking nonlinear effects and population transfers.

Electron-ion collisions↗
NASA NTRS1992

Impulsive phase Fe K-alpha emission in a flare of 1989 March

Evidence for enhanced Fe K-alpha line emission that is coincident (to within 15 s) of an intense hard X-ray (greater than 50 keV) burst is presented on the basis of observations of the Fe K-alpha soft X-ray line made with the SMM. Three different models for explaining the K-alpha enhancement are investigated, namely, photoexcitation by soft X-ray thermal bremsstrahlung radiation from an isothermal source, collisional excitation by nonthermal thick-target electrons, and photoexcitation by a nonthermal hard X-ray flux distribution which extends with a power-law spectrum down to the Fe K-alpha ionization threshold at 7.1 keV. It is found that, to within the limits of isothermal temperature and emission measure set by soft X-ray observations, the thermal photoexcitation model cannot reproduce satisfactorily the intensity of enhanced K-alpha emission during the hard X-ray impulsive phase. The impulsive phase K-alpha flux exceeds that predicted by the thermal photoexcitation model by about 3 sigma. The implications of these results for the nonthermal interpretation of impulsive hard X-ray bursts in solar flares are discussed.

Zarro, D. M.↗
NASA NTRS1985

A method for analysis of blackbody diatomic-triatomic lasers

A formalism is developed for analysis of performance of direct blackbody and blackbody transfer lasers. Application to the CO/CO2 system is made. Three cases are treated: (1) Photoexcited triatomic laser; (2) Photoexcited diatomic-triatomic laser; and (3) Photoexcited diatomic mixing triatomic laser. Each is treated in a transverse flow geometry as illustrated. It is seen from the analysis that the mixing laser configuration has many advantages in that CO can achieve high excitation densities so that high power can be achieved on a relatively small scale.

Wilson, J. W.↗
NASA NTRS1987

Quantitative photoabsorption and fluorescence spectroscopy of H2S and D2S at 49-240 nm

Photoabsorption and fluorescence cross sections of H2S and D2S were measured in the 49-240 nm region using synchrotron radiation as a light source. Fluorescence from photoexcitation of H2S appears at 49-97 nm, but not in the long wavelength region. Fluorescence spectra were dispersed, and used to identify the emitters to be H2S(+) (A), SH(+)(A), and H(n greater than 2). The fluorescence quantum yield is about 6 percent. Photoexcitation of D2S at 49-96 nm produces fluorescence with a quantum yield of about 5 percent. The emitters are identified from the fluorescence spectra to be D2S(+)(A), SD(+)(A), and D(n greater than 2). The Franck-Condon factors for the SH(+) and SD(+) (A-X) transitions were determined. The SD(A-X) fluorescence was observed from photoexcitation of D2S at 100-151 nm, for which the fluorescence cross section and quantum yield were measured.

Lee, L. C.↗
NASA NTRS1991

Photoabsorption and photodissociation of molecules important in the interstellar medium

The photoabsorption, photodissociation, and fluorescence cross sections of interstellar molecules are measured at 90 to 250 nm. These quantitative optical data are needed for the understanding of the formation and destruction processes of molecules under the intense interstellar UV radiation field. Research covering the following topics is presented: (1) fluorescences from photoexcitation of CH4, CH3OH, and CH3SH; (2) NO gamma emission from photoexcitation of NO; (3) photoexcitation cross sections of aromatic molecules; (4) IR emission from UV excitation of HONO2; (5) IR emission from UV excitation of benzene and methyl-derivitives; and (6) IR emission from UV excitation of polycyclic aromatic hydrocarbon molecules.

Lee, Long C.↗
NASA NTRS1995

The neutral oxygen spectrum. 2: Pumping by hydrogen Lyman-beta under the optically thin condition: A first application to the classical novae

A calculation, employing a detailed model of neutral oxygen, is carried out to give fluorescent line intensities expected in a long-proposed photoexcitation by accidental resonance (PAR) process in which hydrogen Lyman-beta photoexcites the oxygen spectrum. The results pertain to the optically thin case but provide an upper limit to the fluorescent intensities which can be attained. They are applied to analyze line ratios involving the strong 8446 A line observed in classical novae during the diffusion-enhanced and Orion phases. Operation of the PAR process in the novae is verified. It is found that photoexcitation rates in the ejecta reach values greater than 0.1/sec, corresponding to hydrogen Lyman-beta radiation field intensities greater than 1250 ergs/cm/sec/sr.

Kastner, S. O.↗
NASA NTRS1974

Thermally-restorable optical degradation and the mechanism of current transport in Cu2S-CdS photovoltaic cells

The photovoltaic properties of single-crystal Cu2S-CdS heterojunctions have been investigated as a function of heat treatment by detailed measurements of the dependence of short-circuit current on photon energy, temperature, and the state of optical degradation or enhancement. A coherent picture is formulated for the relationship between enhancement and optical degradation, and their effect on the transport of short-circuit photoexcited current and dark, forward-bias current in the cell. Optical degradation in the Cu2S-CdS cell is shown to be closely identical to optical degradation of lifetime in a homogeneous CdS:Cd:Cu crystal, indicating that the CdS:Cu layer near the junction interface controls carrier transport in the cell. It is proposed that both the photoexcited short-circuit current and the dark, forward-bias current are controlled by a tunneling-recombination process through interface states.

Fahrenbruch, A. L.↗
NASA NTRS1975

G2.4 + 1.4, a supernova remnant or ring nebula around a peculiar star

G2.4 + 1.4 is a probable nonthermal radio source and an optical nebula which appears to be a supernova remnant (SNR). It also contains an O VI sequence star of great excitation. We present new radiofrequency-continuum and (nil) H 92 alpha observations, optical spectroscopy, and Fabry-Perot scanner observations of the nebula. The object distance (possibly 5 kpc), origin of gas kinematics (possibly SNR expansion), and mode of excitation of the gas (possibly photoexcitation and/or shock wave) remain uncertain. We discuss the possible roles of the O VI star as 'runaway' in an SNR, as a source of photoexcitation, and as an ejector of a 'counterfeit' SNR.

Johnson, H. M.↗
NASA NTRS1980

Solar-pumped gas laser development

A survey of gas properties through detailed kinetic models led to the identification of critical gas parameters for use in choosing appropriate gas combinations for solar pumped lasers. Broadband photoabsorption in the visible or near UV range is required to excite large volumes of gas and to insure good solar absorption efficiency. The photoexcitation density is independent of the absorption bandwidth. The state excited must be a metastable state which is not quenched by the parent gas. The emission bandwidth must be less than 10 A to insure lasing threshold over reasonable gain lengths. The system should show a high degree of chemical reversibility and an insensitivity to increasing temperature. Other properties such as good quantum efficiency and kinetic efficiency are also implied. Although photoexcitation of electronic vibrational transitions is considered as a possible system if the emission bands sufficiently narrow, it appears that photodissociation into atomic metastables is more likely to result in a successful solar pumped laser system.

Wilson, J. W.↗
NASA NTRS1983

The solar O III spectrum. II - Longer wavelengths, line widths, and the He II Lyman alpha radiation field

The solar O III spectrum above 900 A is analyzed, including several visible and infrared lines which are important in nebular studies. The dependence of the line intensities on the rate of photoexcitation by He Ly-alpha is determined, and the observability of these lines in the solar spectrum is studied. The impact approximation is employed to calculate the expected line widths of the stronger solar O III lines. The photoexciting field at 304 A calculated from the observed intensities of the O III lines below 900 A (Bhatia et al., 1982) is compared with the field predicted by a recent model (Avrett et al., 1976). It is shown that additional radiation trapping must be present beyond that given by this model.

Kastner, S. O.↗
NASA NTRS1984

On Bowen enhancement of the N III spectrum under solar and nebular conditions

Expected enhancement of the N III emission-line spectrum by the Bowen He II to O III to N III resonant photoexcitation process is computed using a six-configuration model. Preliminary comparisons with available solar and nebular observations indicate that the process may play only a small role, although photoexcitation quenching of the N III and O III far-infrared fine-structure lines is noted as a possibly important mechanism. Some features are discussed in connection with the nebular emission at 1750 A, which is suggested as an indicator of excitation class for planetary nebulae.

Kastner, S. O.↗
NASA NTRS1985

Measurements of HO2 chemical kinetics with a new detection method

In this research program, HO2 was detected by the OH(A-X) photofragment from dissociative excitation of HO2 at 147 nm. This detection method was applied to measure the reaction rate constant of HO2 + O3. This reaction rate constant is needed for the understanding of stratospheric chemistry. Since C12 was used in the flow system, photoexcitation of C12 may produce fluorescence to interfere with the measurements. Thus, the photoexcitation process of C12 in the vacuum ultraviolet region was also examined in this research period using synchrotron radiation as a light source. The research results are summarized.

Lee, L. C.↗