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At least 37 records · Page 2

Passive continuous variable quantum key distribution scheme using a thermal source

A passive continuous variable quantum key distribution scheme, where Alice splits the output of a thermal source into two beams, measures one locally and transmits the other mode to Bob after applying attenuation. A secure key can be established based on measurements of the two beams without the use of a random number generator or an optical modulator.

Qi, Bing↗

Estimating soil thermal inertia profiles from the passive equilibration of a temperature probe: Supporting data and code

This dataset contains measurements of soil thermal properties and organic layer thickness at three field sites on the Seward Peninsula near Nome, Alaska, USA. Code is also provided for estimation of soil thermal properties from temperature data, including a forward heat transfer mode, a library of simulated temperature data, and an inversion scheme to retrieve thermal properties from temperature measurements (Lamb et al., 2025). This dataset and code is published in support of the manuscript “Estimating Soil Thermal Inertia Profiles from the Passive Equilibration of a Temperature Probe” by Lamb et al., 2025, in which an experimental thermal measurements technique is developed. The dataset contains measurements of soil thermal properties and organic layer thickness obtained with an industry standard thermal properties analyzer and direct observations, as well as data generated using the experimental technique to estimate thermal properties and soil structure from temperature observations. All data is reported in .csv format, and all code is written in Python 3.7 using standard packages. This research was performed as a part of the NGEE Arctic project, which aims to advance model predictions of arctic carbon cycle responses to a changing climate over the 21st Century.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Estimating Soil Thermal Inertia Profiles From the Passive Equilibration of a Temperature Probe

Knowledge of the distribution of soil thermal properties is important for understanding subsurface hydrological and biogeochemical processes. This study describes and evaluates quick thermal profiling (QTP), a new measurement technique aimed at providing rapid, depth-resolved measurements of soil thermal inertia at numerous locations across the landscape. A cylindrical probe with temperature sensors at multiple depths is quickly inserted into the ground, and soil thermal inertia is estimated from how quickly the probe temperature equilibrates with the soil. To this end, a finite volume heat transfer model is used to generate temperature equilibration time series across combinations of controlling factors, and a gridded search inversion approach is applied to infer soil thermal inertia. Field tests in the Arctic indicate that QTP measurements have a minimum uncertainty of 0.14 J m −2 K −1 s −1/2 and covary with dual-probe heat pulse thermal analyzer measurements (concordance correlation coefficient = 0.56) with a root-mean-square error of 0.40 J m −2 K −1 s −1/2 . Besides demonstrating the value of QTP for estimating thermal inertia, this study identifies various sources of measurement uncertainty, particularly probe-soil contact resistance and frictional heating. Further, analysis of soil samples indicates that thermal inertia can be used to estimate thermal conductivity and dry bulk density in the studied area, although such inferences are highly site-specific. Overall, the QTP method holds promise to generate thermal inertia data products and to complement other characterization approaches for advancing understanding of soil properties across far more locations than is currently possible.

Lamb, J. R. [Lawrence Berkeley National Laboratory↗

Quantum key distribution using a thermal source

A passive continuous-variable quantum key distribution scheme, where Alice splits the output of a thermal source into two spatial modes, measures one locally and transmits the other mode to Bob after applying attenuation. A secure key can be established based on measurements of the two modes without the use of a random number generator or an optical modulator.

97 MATHEMATICS AND COMPUTING↗

Theory of the thermionic current beyond the traditional space charge limit enabled by trapped ions in the virtual cathode

We show that trapped ions in virtual cathode potential wells can raise the transmitted current of emitted electrons into a plasma much closer to the full emission than is predicted by cathode sheath theories without trapped ions. The transmitted current is controlled by the well barrier voltage, which must adjust to balance the creation of low-energy ions within the well, and their loss. Our model considers the case of a plasma-facing cathode where trapped ions are created passively via charge-exchange collisions and lost passively via thermal leakage over the well. We quantify these rates and estimate the current in terms of system parameters for thermionic emission into a plasma with several cathode geometries. A general prediction is that the current as a function of emitted flux does not saturate at the traditional space charge limit (the onset of a well) but can reach far higher values until the trapped ion balance breaks down, causing instability. The maximum stable current depends on parameters but in principle can be arbitrarily high if active techniques are used to manipulate the trapped ion balance. We conclude that major improvements in plasma technologies with hot cathodes might be achieved by optimizing the current enhancement enabled by trapped ions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Modular thermal and radiation shielding with passive heat removal

A housing assembly configured to house a reactor is disclosed. The housing assembly includes a plurality of modular walls configured to surround the reactor and a passive temperature control system. The plurality of modular walls includes a first modular wall. The passive temperature control system is coupled to the first modular wall. The passive temperature control system is configured to transfer heat between the reactor and an area around the housing assembly.

Trupiano, Anthony G.↗

Amidination of ligands for chemical and field-effect passivation stabilizes perovskite solar cells

Surface passivation has driven the rapid increase in the power conversion efficiency (PCE) of perovskite solar cells (PSCs). However, state-of-the-art surface passivation techniques rely on ammonium ligands that suffer deprotonation under light and thermal stress. We developed a library of amidinium ligands, of interest for their resonance effect–enhanced N–H bonds that may resist deprotonation, to increase the thermal stability of passivation layers on perovskite surfaces. This strategy resulted in a >10-fold reduction in the ligand deprotonation equilibrium constant and a twofold increase in the maintenance of photoluminescence quantum yield after aging at 85°C under illumination in air. Here, implementing this approach, we achieved a certified quasi–steady-state PCE of 26.3% for inverted PSCs; and we report retention of ≥90% PCE after 1100 hours of continuous 1-sun maximum power point operation at 85°C.

Yang, Yi↗

Report on Thermal Cycling Testing and Bimaterial Weld Development for a Passively Actuated Materials Surveillance Test Article

This report describes the continuation and conclusion of a thermal cycling test program designed to evaluate a family of passively actuated material surveillance test articles. Additionally, the report details a preliminary study of bimetallic welding between 316 stainless steel and TZM (tungsten-zirconium-molybdenum) alloy. The test program was ultimately successful in demonstrating the basic viability of the passively actuated test article concept as well as specifically validating the procedures developed to size specimens to mimic the mechanical response of operating components. The report discusses and summarizes the results of the complete test program which tested samples for more than 1,000 controlled thermal cycles. The weld development program included both stir friction and electron beam joining. The stir friction welding was ultimately successful, while the electron beam welding would require additional development. Ultimately, these test programs pave the way for implementing a materials surveillance program in future molten salt reactors (MSRs). The report conclusions outline a plan for transforming the research and developed described here into a definite set of practices and procedures for a surveillance program at a future operating reactor.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Entrainment, Detrainment, and Dilution of Dry and Moist Atmospheric Thermals

Here this study examines the entrainment, detrainment, and dilution of dry and moist (cloud) atmospheric thermals in large-eddy simulations. In a neutrally stable environment (with respect to dry dynamics), moist thermals have an increase in radius R with thermal height z t (α ≡ dR/dz t ) about 4 times smaller compared to dry thermals when density stratification is considered and ~2.4 times smaller without density stratification (i.e., applying the Boussinesq approximation). An analytic expression relating α to several dimensionless parameters is derived from the thermal impulse–circulation relation to clarify the factors impacting α. This expression shows that the difference in buoyancy structure between moist and dry thermals, with buoyancy concentrated in the central cores of moist thermals owing to latent heating, explains their smaller spreading rates. Individual contributions of entrainment and detrainment are analyzed using a direct parcel-based approach in the simulations. Moist thermals have similar fractional detrainment but much smaller fractional entrainment rates compared to dry thermals, consistent with the differences in α. Despite having smaller α, moist thermals are similarly dilute (quantified by a passive tracer) as dry thermals because of their greater mixing efficiency with the environment. Thus, moist thermals are substantially dilute but expand much less in size/volume as they rise compared to dry thermals. The α values for moist thermals in (dry) neutral and statically stable environments are similar, but fractional entrainment and especially detrainment rates are greater in the stable environment. Large detrainment rates are associated with a breakdown of the broader thermal vortex ring structure, especially with low environmental relative humidity, attributed in part to evaporation and buoyancy reversal.

54 ENVIRONMENTAL SCIENCES↗

Futures for electrochromic windows on high performance houses in arid, cold climates

This study investigates high performance electrochromic windows used on a passive house and residential dwelling to IECC 2021 (i.e., IECC dwelling). In the lab, the electrochromic film switches transmitted solar heat gain coefficient (SHGC) from 0.09 to 0.7 and visible transmittance from 0.15 to 0.82 with power consumption of 1.23 W/m 2 during switching times less than 3 minutes. We extrapolate these results to a window assembly. Building energy models of the houses were evaluated in Santa Fe, New Mexico. A Monte Carlo analysis for 2020, 2040, 2060, and 2080 was conducted for Shared Socioeconomic Pathways 2-4.5, 3-7.0, and 5-8.5. Cases with and without the electrochromic windows and with and without electricity were used to determine energy use intensity and hours beyond thermal safety thresholds. The passive house showed 1.3-3.1% mean energy savings and the IECC dwelling 4.4-5.1% with electrochromic efficiency benefits growing into the future for both cases. Even so, overall savings decrease into the future for the passive house, due to growth in cooling load being dominant, conversely overall energy savings increase into the future for the IECC dwelling due to heating loads being dominant. For thermal resilience, the passive house exhibited a mean percent decrease of 0.02-0.31% hours in the extreme caution (i.e., > 32.2 °C, ≤ 39.4 °C) range while the IECC dwelling exhibited 0.38-4.38%. The study therefore shows that electrochromic windows will have smaller benefits for the passive house in comparison to the IECC dwelling. The relationship between electrochromic windows is shown to have a complex relationship between house efficiency and climate change by these results.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Loop Thermosyphon Enhanced Solar Collector

A two-phase loop thermosyphon solar collector was developed to transfer thermal energy efficiently and passively from a concentrated solar collector to a thermal desalination process. The two-phase flow in the loop thermosyphon is driven by a difference in gravitational pressure head between the liquid return line and the two-phase riser located between the evaporator and condenser. A numerical model incorporating mass, energy, and pressure drop balances was developed to predict system performance and use as a design tool. Three iterations of loop thermosyphon solar collectors were designed, fabricated, and tested to validate the numerical analysis and demonstrate system integration. Additionally, a novel solar receiver design was evaluated based on volumetric absorption of the concentrated sunlight by an optically absorptive two-phase working fluid. Life tests were performed to evaluate the working fluid thermal stability and resistance to ultraviolet degradation. A glass receiver tube and associated glass-to-metal junctions were developed. Finally, a full-scale loop thermosyphon was integrated with a parabolic trough solar collector and tested on-sun.

14 SOLAR ENERGY↗

Counterintuitive Catalytic Reactivity of the Aluminum Oxide “Passivation” Shell of Aluminum Nanoparticles Facilitating the Thermal Decomposition of exo -Tetrahydrodicyclopentadiene (JP-10)

High energy density aluminum nanoparticles (AlNP) have been at the center of attention as additives to hydrocarbon jet fuels like exo-tetrahydrodicyclopentadiene (JP-10, C 10 H 16 ) aiming at a superior performance of volume-limited air-breathing propulsion systems. However, a fundamental understanding of the ignition and combustion chemistry of JP-10 in presence of AlNPs has been elusive. Exploiting an isomer-selective comprehensive identification of the decomposition products in a newly designed high temperature chemical microreactor coupled to vacuum ultraviolet photoionization, we reveal an active low temperature heterogeneous surface chemistry commencing at 650 K involving the alumina (Al 2 O 3 ) shell. Contrary to textbook knowledge of an “inactive alumina surface”, this unconventional reactivity, where oxygen is transferred from alumina to JP-10, leads to generating cyclic, oxygenated organics like phenol (C 6 H 5 OH) and 2,4-cyclopentadiene-1-one (C 5 H 4 O) - key tracers of an alumina-mediated interfacial chemistry. Furthermore, this counterintuitive reactivity transforms our knowledge on the (catalytic) processes of alumina-coated AlNPs on the molecular level.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High-fidelity Experiments of Turbulent Buoyant Jets from Simultaneous Particle Image Velocimetry and Laser Induced Fluorescence

Accurate models of turbulent buoyant flows are essential for the design of nuclear reactors thermal hydraulics and passive safety systems. However, available models fail to fully capture the physics of turbulent mixing when buoyancy becomes predominant with respect to momentum. Therefore, high-fidelity experiments of well-controlled fundamental flows are needed to develop and validate more accurate models. We performed experiments of positive and negative turbulent buoyant jets, both in uniform and stratified environments, with the aim of understanding the thermal hydraulics of turbulent mixing with variable density and providing high-fidelity data for the development and validation of turbulence models. Non-intrusive, simultaneous Particle Image Velocimetry and Laser Induced Fluorescence measurements were carried out to acquire instantaneous velocity and concentration fields on a vertical section parallel to the axis of a jet in the self-similar region. The Refractive Index Matching method was applied to measure high-resolution buoyant jets with up to 8.6% density difference. These data are free of the typical errors that characterize optical measurements of buoyancy driven flows (e.g., natural and mixed convection) where the refractive index of the fluid is inhomogeneous throughout the measurement domain. Turbulent statistics and entrainment of buoyant jets in uniform and stratified environments are presented. These data are compared with non-buoyant jets in uniform environment, as a reference to investigate the effects of buoyancy and stratification on turbulent mixing. The results will be used for the assessment of current turbulence models and as basis for the development of a new one that captures turbulent mixing.

42 ENGINEERING↗

Overview of IMPACT Data Acquisition System and Data Reduction Process

This report documents the development of the data acquisition system (DAS) and data reduction methodologies for the Irradiated Material Property Accelerated Characterization Test (IMPACT) experiment at the Advanced Test Reactor (ATR). The IMPACT experiment is designed to enable in-pile measurement of thermal conductivity in metallic nuclear fuels, specifically U-10Zr, using an instrumented thermal conductivity probe. The DAS supports both passive temperature monitoring and active thermal interrogation of the probe through controlled AC and DC excitation. Significant modifications to laboratory-scale systems were required to accommodate the higher resistance paths associated with the in-pile application. Custom electronics and relay-controlled measurement sequencing were developed to enable the measurement and sufficient power delivery to the sensing region. A reduced-order, axisymmetric thermal model based on the thermal quadrupoles method is presented to support data interpretation. This model enables efficient evaluation of transient heat transfer behavior and facilitates solution of the inverse problem required to extract thermal properties from measured signals. Multiple boundary condition formulations are discussed to address varying experimental time scales and geometries. Additionally, machine learning techniques are introduced to support data reduction and improve confidence in inverse solutions. Convolutional neural networks are applied to identify the presence of gas gaps and other evolving geometric features that significantly impact thermal response during irradiation. These efforts contribute to the broader integration of digital twin frameworks and real-time modeling capabilities within the Advanced Fuels Campaign.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Energy and Comfort Impacts of High Performance Facades in Office Buildings

Building facades have a major effect on energy use, occupant comfort, and well-being. Yet adoption of high-performance facades is often slowed by limited data and unclear cost benefits. To address this gap, Oak Ridge National Laboratory, in collaboration with the Facade Tectonics Institute, conducted whole-building energy simulations to evaluate fenestration technologies for small and medium office buildings across three weather locations: hot (Tampa, Florida, weather zone 2A), mixed (New York, New York, weather zone 4A), and cold (Rochester, Minnesota, weather zone 6A). The simulations included parametric variations in window-to-wall ratio (30%–70%), U-values (0.1–1 Btu/h∙ft 2 ∙°F), solar heat gain coefficients (0.2–0.8), and solar control strategies and devices (e.g., interior shades and switchable glazing). Performance metrics included annual cooling, heating, and total heating, ventilation and air-conditioning (HVAC) energy use intensity, as well as nonenergy factors such as useful daylight illuminance, glare frequency, and thermal comfort during typical office hours (8 a.m.–6 p.m.). Results indicate that cooling energy consumption is most sensitive to solar heat gain coefficient (SHGC) in hot weather, whereas heating energy consumption is strongly influenced by U-value in cold weather. Total HVAC reflects these trade-offs, showing up to 60% difference for a window in total HVAC energy use intensity between different combinations of U-value and SHGC. Daylight dimming generally reduces cooling loads but can increase heating demands in colder locations. Interior solar shades improve useful daylight and reduce discomfort glare, whereas switchable glazing delivers the largest cooling reductions in hot weather but may increase heating loads in winter by limiting passive solar gains. Thermal comfort improves with lower window-to-wall ratios and lower SHGC in hot locations and with lower U-values in cold locations.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗