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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Vibrational and Electronic Energy Transfer and Dissociation of Diatomic Molecules by Electron Collisions

At high altitudes and velocities equal to or greater than the geosynchronous return velocity (10 kilometers per second), the shock layer of a hypersonic flight will be in thermochemical nonequilibrium and partially ionized. The amount of ionization is determined by the velocity. For a trans atmospheric flight of 10 kilometers per second and at an altitude of 80 kilometers, a maximum of 1% ionization is expected. At a velocity of 12 - 17 kilometer per second, such as a Mars return mission, up to 30% of the atoms and molecules in the flow field will be ionized. Under those circumstances, electrons play an important role in determining the internal states of atoms and molecules in the flow field and hence the amount of radiative heat load and the distance it takes for the flow field to re-establish equilibrium. Electron collisions provide an effective means of transferring energy even when the electron number density is as low as 1%. Because the mass of an electron is 12,760 times smaller than the reduced mass of N2, its average speed, and hence its average collision frequency, is more than 100 times larger. Even in the slightly ionized regime with only 1% electrons, the frequency of electron-molecule collisions is equal to or larger than that of molecule-molecule collisions, an important consideration in the low density part of the atmosphere. Three electron-molecule collision processes relevant to hypersonic flows will be considered: (1) vibrational excitation/de-excitation of a diatomic molecule by electron impact, (2) electronic excitation/de-excitation, and (3) dissociative recombination in electron-diatomic ion collisions. A review of available data, both theory and experiment, will be given. Particular attention will be paid to tailoring the molecular physics to the condition of hypersonic flows. For example, the high rotational temperatures in a hypersonic flow field means that most experimental data carried out under room temperatures are not applicable. Also, the average electron temperature is expected to be between 10,000 and 20,000 K. Thus only data for low energy electrons are relevant to the model.

Huo, Winifred M.

Measuring Thermodynamic Properties of Metals and Alloys With Knudsen Effusion Mass Spectrometry

This report reviews Knudsen effusion mass spectrometry (KEMS) as it relates to thermodynamic measurements of metals and alloys. First, general aspects are reviewed, with emphasis on the Knudsen-cell vapor source and molecular beam formation, and mass spectrometry issues germane to this type of instrument are discussed briefly. The relationship between the vapor pressure inside the effusion cell and the measured ion intensity is the key to KEMS and is derived in detail. Then common methods used to determine thermodynamic quantities with KEMS are discussed. Enthalpies of vaporization, the fundamental measurement, are determined from the variation of relative partial pressure with temperature using the second-law method or by calculating a free energy of formation and subtracting the entropy contribution using the third-law method. For single-cell KEMS instruments, measurements can be used to determine the partial Gibbs free energy if the sensitivity factor remains constant over multiple experiments. The ion-current ratio method and dimer-monomer method are also viable in some systems. For a multiple-cell KEMS instrument, activities are obtained by direct comparison with a suitable component reference state or a secondary standard. Internal checks for correct instrument operation and general procedural guidelines also are discussed. Finally, general comments are made about future directions in measuring alloy thermodynamics with KEMS.

Copland, Evan H.

Polarization observables in double neutral pion photoproduction

Abstract Measurements of target asymmetries and double-polarization observables for the reaction "Equation missing"<#comment/>are reported. The data were taken with the CBELSA/TAPS experiment at the ELSA facility (Bonn University) using the Bonn frozen-spin butanol ($$\hbox {C}_4\hbox {H}_9$$ C 4 H 9 OH) target, which provided transversely polarized protons. Linearly polarized photons were produced via bremsstrahlung off a diamond crystal. The data cover the photon energy range from "Equation missing"<#comment/>to "Equation missing"<#comment/>and nearly the complete angular range. The results have been included in the BnGa partial wave analysis. Experimental results and the fit agree very well. Observed systematic differences in the branching ratios for decays of "Equation missing"<#comment/>and$${\varDelta ^*}$$ Δ ∗ resonances are attributed to the internal structure of these excited nucleon states. Resonances which can be assigned to SU(6)$$\times $$ × O(3) two-oscillator configurations show larger branching ratios to intermediate states with non-zero intrinsic orbital angular momenta than resonances assigned to one-oscillator configurations.

Physics

Shock wave properties of anorthosite and gabbro

Huyoniot data on San Gabriel anorthosite and San Marcos gabbro to 11 GPA are presented. Release paths in the stress-density plane and sound velocities are reported as determined from partial velocity data. Electrical interference effects precluded the determination of accurate release paths for the gabbro. Because of the loss of shear strength in the shocked state, the plastic behavior exhibited by anorthosite indicates that calculations of energy partitioning due to impact onto planetary surfaces based on elastic-plastic models may underestimate the amount of internal energy deposited in the impacted surface material.

Boslough, M. B.

Transient Analysis Used to Study Thermal Radiation Effects in Single and Composite Semitransparent Layers

In a continuing in-house program at the NASA Lewis Research Center, analytical and numerical methods are being developed to apply radiative analysis to predict transient temperature distributions and heat flows in partially transmitting materials. Results have been obtained for a single plane layer, and a transient analysis is being developed for a two-layer composite where each layer has a different refractive index. Because the ceramic refractive indices are larger than one, internal reflections are produced at the surfaces and at the internal interface. Reflections tend to distribute energy within a layer, and this affects the transient temperature distributions.

Source record

BMINN: Learning chemical potentials and parameters from voltage data for multi-phase battery modeling

Free-energy landscapes and chemical potentials govern the dynamics of phase transitions, transport, and stability in functional materials, yet they remain experimentally inaccessible under realistic operating conditions. Here we introduce a Bayesian model-integrated neural network (BMINN) that embeds physics-based formulations of non-autonomous partial differential-algebraic equations into probabilistic learning. This approach reconstructs hidden thermodynamics directly from macroscopic current-voltage data, providing quantitative access to metastable states, staging transitions, and energy barriers without synchrotron probes. Demonstrated on lithium-graphite electrodes, BMINN recovers full Gibbs free-energy landscapes with fidelity validated against operando X-ray diffraction. The framework generalizes across dynamical regimes, enabling accurate voltage prediction, internal state estimation, and inference of governing parameters. Beyond batteries, BMINN exemplifies a broadly applicable strategy for learning missing physics in multiphase, non-equilibrium systems, offering a new pathway to uncover hidden thermodynamic functions across condensed matter and materials physics.

25 ENERGY STORAGE

Glucose determination in human aqueous humor with Raman spectroscopy

It has been suggested that spectroscopic analysis of the aqueous humor of the eye could be used to indirectly predict blood glucose levels in diabetics noninvasively. We have been investigating this potential using Raman spectroscopy in combination with partial least squares (PLS) analysis. We have determined that glucose at clinically relevant concentrations can be accurately predicted in human aqueous humor in vitro using a PLS model based on artificial aqueous humor. We have further determined that with proper instrument design, the light energy necessary to achieve clinically acceptable prediction of glucose does not damage the retinas of rabbits and can be delivered at powers below internationally acceptable safety limits. Herein we summarize our current results and address our strategies to improve instrument design. 2005 Society of Photo-Optical Instrumentation Engineers.

Spectrum Analysis, Raman/methods

Tidal Disruptions of Main-sequence Stars. IV. Relativistic Effects and Dependence on Black Hole Mass

Using a suite of fully relativistic hydrodynamic simulations applied to main-sequence stars with realistic internal density profiles, we examine full and partial tidal disruptions across a wide range of black hole mass( MM105 105BH7)and stellar mass (MM0.33) as larger MBH leads to stronger relativistic effects. For fixed Må, as MBH increases, the ratio of the maximum pericenter distance yielding full disruptions (t) to its Newtonian prediction rises rapidly, becoming triple the Newtonian value for= ́MM510BH7, while the ratio of the energy width of the stellar debris for full disruptions to the Newtonian prediction decreases steeply, resulting in a factor of 2 correction at= ́MM510BH7. We provide approximate formulae that express the relativistic corrections of both t and the energy width relative to their Newtonian approximate estimates. For partial disruptions, we find that the fractional remnant mass for a given ratio of the pericenter to t is higher for larger MBH. These results have several implications. As MBH increases above~M107, the cross section for complete disruptions is suppressed by competition with direct capture. However, the cross-section ratio for partial to complete disruptions depends only weakly on MBH. The relativistic correction to the debris energy width delays the time of peak mass-return rate and diminishes the magnitude of the peak return rate. ForMM10BH7, the MBH-dependence of the full disruption cross section and the peak mass-return rate and time is influenced more by relativistic effects than by Newtonian dynamics.

Taeho Ryu

Intermediate energy nucleon-deuteron elastic scattering

The adequacy of a multiple scattering description of nucleon-deuteron scattering at intermediate energy is examined. Although the multiple-scattering series is expected to converge slowly, model calculations indicate that the higher-order multiple-scattering terms contribute only to the low-order partial waves. The first two terms, nucleon exchange and single scattering, are assumed to describe the high-order partial waves completely. It is assumed that the deuteron is coupled only to the nucleon channel and that the internal structure is adequately defined by a nonrelativistic wave function.

Wilson, J. W.

HdsaLib

HdsaLib performs hyper-differential sensitivity analysis in optimization problems that are constrained by partial differential equation problems. The software aids researchers in understanding the impact of uncertainties on their optimization models. The tool has been applied for use in ice sheet modeling, fluid flow modeling, atmospheric tracer transport modeling, and subsurface flow modeling. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

van Bloemen Waanders, Bart [Sandia National Lab. (

Diffusivity in turbulent fluid containing two dominant scales, and compressible shear layer according to a kinetic theory

The solution of the two nonequilibrium-degree kinetic equation was first determined for the effective length scale and turbulence energy for a spatially homogeneous turbulence field with two characteristic length scales, where the source for one family of eddies exists. This solution was applied to the evaluation of the eddy diffusivity in the combustion chamber of an internal combustion engine. The result was compared with another existing solution. This was carried out to demonstrate the feasibility of obtaining an effective length-scale equation within the context of the kinetic theory. A formulation and partial solution of the compressible plane shear layer are also presented.

Chung, P. M.

Design of the High Energy Astronomy Observatory /HEAO/ power subsystem

Observatory power is generated by a partially deployable solar array which is modularized to facilitate adaptation to three missions having different power requirements. Three nickel-cadmium batteries are controlled independently from dedicated modular chargers to increase subsystem adaptability and decrease sensitivity to temperature differences between batteries. Battery level redundancy is employed, enabling mission completion with two of three battery/charger combinations operational. Bus voltage limiting is accomplished by a modularized shunt regulator which can survive any single part failure and meet all mission requirements. Relatively low shunt electronics power dissipation internal to the observatory is achieved by sequenced operation of linear shunt segments which are coupled to a large area resistive shunt radiator. Summaries of solar array, battery and subsystem breadboard test results are provided.

Reppucci, G. M.

Wind Turbine Sound Setbacks and Supply Curves: Ordinances and Extrapolated Trends, 110 Hub Height, 130 Rotor Diameter

This dataset provides a comprehensive set of wind turbine sound setbacks from every residential structure in the contiguous United States (CONUS). A sound setback is defined as the minimum required distance between a residential structure and a hypothetical turbine installation site to ensure that modeled sound levels received at the residence do not exceed local sound ordinances, which are commonly expressed in A-weighted decibels (dBA). Therefore, sound setbacks are a local spatial assessment combining multiple factors, including the sound pressure curve as a function of the observer location (distance and direction) relative to the turbine, local sound regulations, and the geographical distribution of residential structures. The dataset is organized into multiple scenario-based products, detailed as follows: 1. Existing and extrapolated sound setbacks. An existing scenario characterizes sound setbacks only in states or counties that have implemented sound regulations as of 2022. The extrapolated scenarios extend a constant sound threshold to counties that lack explicit sound regulations, with thresholds ranging from 35 to 60 dBA, in 5-dBA increments reflecting the variation observed in current sound ordinances. 2. Sound setbacks in directional and worst scenarios. The directional scenario accounts for the distance and orientation of residential structures relative to a hypothetical turbine location, utilizing the turbine's sound emissions in that specific direction. In contrast, the worst scenario takes loudest sound level at each distance step from the turbine, irrespective of directional considerations, which aligns with current industry practice. 3. Supply curves for Open and Reference Access scenarios. This dataset includes supply curves generated by the reV model, which integrates each of the above sound setbacks into both Open and Reference siting scenarios. In addition, two Open and Reference baselines scenarios were included which do not consider sound setbacks for comparative analysis. All sound setback data are stored in TIF files, with partial maps of the data provided in PNG format. The values in the sound setback raster range from 0 to 1, representing the fraction of developable land within a 90 meter by 90 meter pixel due to sound ordinances. A value of 0 indicates areas where wind energy development is prohibited, while a value of 1 signifies areas fully permissible. The wind turbine parameters used in the sound modeling are based on the land-based turbine from International Energy Agency (IEA), featuring a rated electrical power of 3.4 MW, a rotor diameter of 130 meters, and a hub height of 110 meters. The atmospheric conditions, including wind speed/direction, turbulence, air temperature, relative humidity, and air pressure, that drive the sound generation are obtained from the WIND Toolkit dataset.

Array

Conceptual Thermal Control System Design for a Lunar Surface Habitat

NASA is currently considering a Surface Habitat (SH) to provide 30-60 day habitability for a crew of up to four to explore the Lunar surface at a South Pole location. The SH concept is comprised of an inflatable volume for the habitable space, a metallic airlock and a descent stage with access to a pressurized rover and other surface assets provided through the airlock. A conceptual architecture for the SH Thermal Control System (TCS) is presented with resource estimates. The TCS design employs a dual loop architecture with a water/propylene glycol mix for the internal crew spaces with a freeze tolerant coolant utilized for the external loop. The internal loop is partitioned into low and moderate temperature service with a sublimator available for operational scenarios prior to thermal radiator deployment (or redeployment). Analytical models are utilized to optimize radiator geometry/orientation as well as the TCS internal/external loop architecture. Heritage hardware is utilized for the TCS concept wherever possible and low mass, dust tolerant, deployable/retractable thermal radiators (in partial gravity) present a technology challenge. The TCS must accommodate infrequent eclipse periods lasting up to 100 hours in duration and mitigation strategies to reduce the energy needed to maintain the SH and associated systems above survival temperature limits during this period are explored. Mitigation options include retractable or freezable radiators, other reconfigurable radiator geometries, alternate fluids, re-generable heat exchangers, temperature excursions, thermal energy storage and optimized inflatable optical properties. Finally, TCS sensitivity to SH Electrical Power System (EPS) growth is considered with both operational and dormant impacts quantified.

Thermal Control

Conceptual Thermal Control System Design for a Lunar Surface Habitat

NASA is currently considering a Surface Habitat (SH) to provide 30-60 day habitability for a crew of up to four to explore the Lunar surface at a South Pole location. The SH concept is comprised of an inflatable volume for the habitable space, a metallic airlock and a descent stage with access to a pressurized rover and other surface assets provided through the airlock. A conceptual architecture for the SH Thermal Control System (TCS) is presented with resource estimates. The TCS design employs a dual loop architecture with a water/propylene glycol mix for the internal crew spaces with a freeze tolerant coolant utilized for the external loop. The internal loop is partitioned into low and moderate temperature service with a sublimator available for operational scenarios prior to thermal radiator deployment (or redeployment). Analytical models are utilized to optimize radiator geometry/orientation as well as the TCS internal/external loop architecture. Heritage hardware is utilized for the TCS concept wherever possible and low mass, dust tolerant, deployable/retractable thermal radiators (in partial gravity) present a technology challenge. The TCS must accommodate infrequent eclipse periods lasting up to 100 hours in duration and mitigation strategies to reduce the energy needed to maintain the SH and associated systems above survival temperature limits during this period are explored. Mitigation options include retractable or freezable radiators, other reconfigurable radiator geometries, alternate fluids, re-generable heat exchangers, temperature excursions, thermal energy storage and optimized inflatable optical properties. Finally, TCS sensitivity to SH Electrical Power System (EPS) growth is considered with both operational and dormant impacts quantified.

Thermal Control

Load assessment of a wind farm considering negative and positive yaw misalignment for wake steering

Wake steering strategies are employed to increase the overall power production of wind farms by deflecting wakes of upstream turbines away from downstream ones. The gain in net power comes at the expense of increased fatigue loads experienced by downstream turbines. In this work we investigate performance and fatigue loading characteristics of a small farm consisting of five aligned International Energy Agency Wind Technology Collaboration Programme 15 MW wind turbines. A parametric study is performed where, for every wind direction from −20 to 20°, the yaw misalignment angle varies from −25 to 25°. This setup allows us to investigate asymmetries and identify optimal conditions for a given wind direction. In general, we find that positive yaw configurations are preferred and that yaw configurations that result in attractive power differences when compared to a baseline no-yaw scenario (25 %) come with significant increase in fatigue loading (we use the standard deviation and damage-equivalent load (DEL) of the blade-root, low-speed shaft, and tower-base moments as proxies for fatigue load). We find that for any given positive wind inflow angle, yaw angles between −2.5 and 15° yield power differences of 10 %–20 % over a no-yaw baseline, and positive yaw is preferred because of lower fatigue loading. For any given negative wind inflow angles, positive yaw also results in lower magnitudes of standard deviation and DEL for the channels investigated. A small power loss of up to 2 % is observed for some positive yaw angles under negative wind directions (as compared to symmetric negative yaw and positive wind cases), but improvements in terms of loads exceed 25 % and may be enough to justify a positive yaw configuration under negative winds as well. We show that such behavior can be explained by partial waking and the direction of the rotation of the rotor.

17 WIND ENERGY

TalkPipe Writing Assistant

SAND2025-14316O TalkPipe Writing Assistant offers AI assistance, providing help on a point-by-point basis. Authors can start with their own ideas—whether bullet points, partial paragraphs, or phrases—and specify the document type, desired tone, audience, and any other relevant context. As they write, the assistant provides tailored suggestions for each paragraph. They can request high-level concepts, draft a paragraph, or proofread existing text. The large language model (LLM) considers both preceding and following paragraphs to ensure coherence and flow. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

Bauer, Travis [Sandia National Lab. (SNL-CA), Live

Tidal Disruptions of Main-sequence Stars. IV. Relativistic Effects and Dependence on Black Hole Mass

Using a suite of fully relativistic hydrodynamic simulations applied to main-sequence stars with realistic internal density profiles, we examine full and partial tidal disruptions across a wide range of black hole mass (10(exp 5)≤M(BH)/M(ʘ)≤5 x 10(exp 7) and stellar mass (0.3≤M(*)/M(ʘ)≤3) as larger M(BH) leads to stronger relativistic effects. For fixed M( ), as M(BH) increases, the ratio of the maximum pericenter distance yielding full disruptions ( ) to its Newtonian prediction rises rapidly, becoming triple the Newtonian value for M(BH)=5 x 10(exp 7)M(ʘ), while the ratio of the energy width of the stellar debris for full disruptions to the Newtonian prediction decreases steeply, resulting in a factor of 2 correction at M(BH)=5 x 10(exp 7)M(ʘ). We provide approximate formulae that express the relativistic corrections of both R(t) and the energy width relative to their Newtonian approximate estimates. For partial disruptions, we find that the fractional remnant mass for a given ratio of the pericenter to R(t) is higher for larger M(BH). These results have several implications. As M(BH) increases above ~10(exp 7)M(ʘ), the cross section for complete disruptions is suppressed by competition with direct capture. However, the cross-section ratio for partial to complete disruptions depends only weakly on M(BH). The relativistic correction to the debris energy width delays the time of peak mass-return rate and diminishes the magnitude of the peak return rate. For M(BH)≳10(exp 7)M(ʘ), the M(BH)-dependence of the full disruption cross section and the peak mass-return rate and time is influenced more by relativistic effects than by Newtonian dynamics.

Taeho Ryu