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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Specific Gamma-Ray Dose Constants with Current Emission Data

The specific gamma-ray dose constant represents the gamma effective dose rate due to a point source of unit activity of a given nuclide at 1 m. New tabulations of specific gamma-ray dose constants have been made using current gamma emission data from the SCALE 6.2.3 software package and International Commission on Radiological Protection Publication 107, combined with the effective dose per fluence conversion coefficients (antero-posterior orientation) of International Commission on Radiological Protection Publication 116. SCALE data cover 1,264 nuclides, and International Commission on Radiological Protection Publication 107 data include 1,192 nuclides, with only 777 nuclides in common between the two sets.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Canopy cover and microtopography control precipitation-enhanced thaw of ecosystem-protected permafrost

Abstract Northern high-latitudes are projected to get warmer and wetter, which will affect rates of permafrost thaw and mechanisms by which thaw occurs. To better understand the impact of rain, as well as other factors such as snow depth, canopy cover, and microtopography, we instrumented a degrading permafrost plateau in south-central Alaska with high-resolution soil temperature sensors. The site contains ecosystem-protected permafrost, which persists in unfavorable climates due to favorable ecologic conditions. Our study (2020–2022) captured three of the snowiest years and three of the four wettest years since the site was first studied in 2015. Average thaw rates along an across-site transect increased nine-fold from 6 ± 5 cm yr −1 (2015–2020) to 56 ± 12 cm yr −1 (2020–2022). This thaw was not uniform. Hummock locations, residing on topographic high points with relatively dense canopy, experienced only 8 ± 9 cm yr −1 of thaw, on average. Hollows, topographic low points with low canopy cover, and transition locations, which had canopy cover and elevation between hummocks and hollows, thawed 44 ± 6 cm yr −1 and 39 ± 13 cm yr −1 , respectively. Mechanisms of thaw differed between these locations. Hollows had high warm-season soil moisture, which increased thermal conductivity, and deep cold-season snow coverage, which insulated soil. Transition locations thawed primarily due to thermal energy transported through subsurface taliks during individual rain events. Most increases in depth to permafrost occurred below the ∼45 cm thickness seasonally frozen layer, and therefore, expanded existing site taliks. Results highlight the importance of canopy cover and microtopography in controlling soil thermal inputs, the ability of subsurface runoff from individual rain events to trigger warming and thaw, and the acceleration of thaw caused by consecutive wet and snowy years. As northern high-latitudes become warmer and wetter, and weather events become more extreme, the importance of these controls on soil warming and thaw is likely to increase.

54 ENVIRONMENTAL SCIENCES↗

Design Principles for Efficient and Stable Water Splitting Photoelectrocatalysts

Photoelectrochemical water splitting is a promising avenue for sustainable production of hydrogen used in the chemical industry and hydrogen fuel cells. The basic components of most photoelectrochemical water splitting systems are semiconductor light absorbers coupled to electrocatalysts, which perform the desired chemical reactions. A critical challenge for the design of these systems is the lack of stability for the majority of desired semiconductors under operating water splitting conditions. One strategy to address this issue is to protect the semiconductor by covering it with a stabilizing insulator layer, creating a metal–insulator–semiconductor (MIS) architecture, which has demonstrated improved stability. In addition to enhanced stability, the insulator layer may significantly affect the electron and hole transfer, which governs the recombination rates. Furthermore, the insertion of an insulator layer leads to the introduction of additional insulator/electrocatalyst and insulator/semiconductor interfaces. These interfaces can impact the system’s performance significantly, and they need to be carefully engineered to optimize the efficiencies of MIS systems. In this Account, we describe our recent progress in shedding light on the critical role of the insulator and the interfaces on the performance of MIS systems. We discuss our findings by focusing on the concrete example of planar n-type Si protected by a HfO 2 insulator layer and coupled to a Ni or Ir electrocatalyst that performs the oxygen evolution reaction, one of the water splitting half-reactions. To improve our fundamental understanding of the insulator layer, we precisely control the HfO 2 insulator thickness using atomic layer deposition (ALD), and we perform a series of rigorous electrochemical experiments coupled with theory and modeling. We demonstrate that by tuning the insulator thickness, we can control the flux and recombination of photogenerated electrons and holes to optimize the generated photovoltage. Despite optimizing the thickness, we find that the maximum generated photovoltage in MIS systems is often significantly lower than the upper performance limit, i.e., there are additional losses in the system that could not be addressed by optimizing the insulator thickness. We identify the sources of these losses and describe strategies to minimize them by a combination of improving the semiconductor light absorption, removing nonidealities associated with interfacial defects, and finding alternative insulators with improved charge carrier selectivity. Finally, we quantify the improvements that can be obtained by implementing these specific strategies. Our collective work outlines strategies to analyze MIS systems, identify the sources of efficiency losses, and optimize the design to approach the fundamental performance limits. Furthermore, these general approaches are broadly applicable to photoelectrochemical materials that utilize sunlight to produce value-added chemicals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

An ultrathin solid-state electrolyte film coated on LiNi 0.8 Co 0.1 Mn 0.1 O 2 electrode surface for enhanced performance of lithium-ion batteries

We report layered Ni-rich oxide is a promising cathode material for lithium-ion batteries (LIBs) of high energy density, yet its poor electrochemical stability induced by electrode-electrolyte interfacial degradation has still needed to be addressed. Surface coating is one of the powerful techniques to tackle this issue, nevertheless, it has been extensively used on particle but not electrode regarding a larger area of protection. Herein, we have covered a nano-scaled layer of lithium phosphorus oxynitride (LiPON) on the electrode level of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM) surface and found lower impedance, longer cycle life, and better safety for treated battery. Most notably, such an NCM-LiPON based 1.3 Ah pouch cell delivers an energy density of 364.4 Wh kg -1 (based on positive and negative materials), along with the retention of 80.0% over 745 cycles at 0.5 C-rate, which is 1.3 times longer than the bare one. This results from modification of both superficial cathode-electrolyte interphase (CEI) and structure stabilization of general particle surface, therefore, role of conformal coating upon electrode surface should be highlighted.

36 MATERIALS SCIENCE↗

Frequency-domain hot-wire sensor and 3D model for thermal conductivity measurements of reactive and corrosive materials at high temperatures

High temperature solids and liquids are becoming increasingly important in next-generation energy and manufacturing systems that seek higher efficiencies and lower emissions. Accurate measurements of thermal conductivity at high temperatures are required for the modeling and design of these systems, but commonly employed time-domain measurements can have errors from convection, corrosion, and ambient temperature fluctuations. Here, we describe the development of a frequency-domain hot-wire technique capable of accurately measuring the thermal conductivity of solid and molten compounds from room temperature up to 800 °C. Therefore, by operating in the frequency-domain, we can lock into the harmonic thermal response of the material and reject the influence of ambient temperature fluctuations, and we can keep the probed volume below 1 µl to minimize convection. The design of the microfabricated hot-wire sensor, electrical systems, and insulating wire coating to protect against corrosion is covered in detail. Furthermore, we discuss the development of a full three-dimensional multilayer thermal model that accounts for both radial conduction into the sample and axial conduction along the wire and the effect of wire coatings. The 3D, multilayer model facilitates the measurement of small sample volumes important for material development. A sensitivity analysis and an error propagation calculation of the frequency-domain thermal model are performed to demonstrate what factors are most important for thermal conductivity measurements. Finally, we show thermal conductivity measurements including model data fitting on gas (argon), solid (sulfur), and molten substances over a range of temperatures.

47 OTHER INSTRUMENTATION↗

Observations Regarding Commonly Available Materials for Face Shield Emulated-Personal Protective Equipment

The Center for Disease Control has recommended that to reduce potential exposure to COVID-19 the public should wear cloth face coverings in public settings where other social distancing measures are difficult to maintain. These face coverings and other Emulated-Personal Protective Equipment (E-PPE) can be made by using Commonly Available Materials (CAMs). As E-PPE recommendations continue to flood the media, a Sandia COVID-19 LDRD effort, the Sandia E-PiPEline Team, systematically evaluated E-PPE design options considering their effectiveness, durability, build difficulty, build cost, and comfort. Using qualitative and semi-quantitative evaluation tools, results of the investigation are presented here to provide guidelines for home and office construction of E-PPE.

36 MATERIALS SCIENCE↗

Doubling protected land area may be inefficient at preserving the extent of undeveloped land and could cause substantial regional shifts in land use

Abstract Projection of land use and land‐cover change is highly uncertain yet drives critical estimates of carbon emissions, climate change, and food and bioenergy production. We use new, spatially explicit land availability data in conjunction with a model sensitivity analysis to estimate the effects of additional land protection on land use and land cover. The land availability data include protected land and agricultural suitability and is incorporated into the Moirai land data system for initializing the Global Change Analysis Model. Overall, decreasing land availability is relatively inefficient at preserving undeveloped land while having considerable regional land‐use impacts. Current amounts of protected area have little effect on land and crop production estimates, but including the spatial distribution of unsuitable (i.e., unavailable) land dramatically shifts bioenergy production from high northern latitudes to the rest of the world, compared with uniform availability. This highlights the importance of spatial heterogeneity in understanding and managing land change. Approximately doubling the current protected area to emulate a 30% protected area target may avoid land conversion by 2050 of less than half the newly protected extent while reducing bioenergy feedstock land by 10.4% and cropland and grazed pasture by over 3%. Regional bioenergy land may be reduced (increased) by up to 46% (36%), cropland reduced by up to 61%, pasture reduced by up to 100%, and harvested forest reduced by up to 35%. Only a few regions show notable gains in some undeveloped land types of up to 36%. Half of the regions can reach the target using only unsuitable land, which would minimize impacts on agriculture but may not meet conservation goals. Rather than focusing on an area target, a more robust approach may be to carefully select newly protected land to meet well‐defined conservation goals while minimizing impacts to agriculture.

54 ENVIRONMENTAL SCIENCES↗

Securing Grid Communications Infrastructure: Addressing Gaps Beyond NERC CIP Facility Perimeters

The North American electric grid relies on a complex communications infrastructure that extends beyond facility perimeters traditionally covered by NERC Critical Infrastructure Protection (CIP) standards. While CIP requirements have significantly strengthened cybersecurity within Electronic Security Perimeters, many operational communications—such as those between control centers, substations, and third-party networks—fall outside current regulatory scope. As grid modernization introduces new technologies and connectivity models, these external pathways present evolving security challenges. This brief explores the nature of these challenges, including emerging attack vectors and supply chain considerations, and highlights how ongoing grid transformation increases exposure to sophisticated threats. It outlines practical strategies and policy options to complement existing standards, such as expanding secure communications practices, enhancing supply chain transparency, and fostering collaboration among federal, state, and industry stakeholders. Near-term actions like encryption, authentication, and contractual safeguards can help reduce risk while longer-term frameworks are developed to ensure resilient and secure grid operations.

24 - POWER TRANSMISSION AND DISTRIBUTION↗

E-PiPEline: Quick to Market Emulated-PPE using Commonly Available Materials

The Center for Disease Control has recommended the public to wear cloth face coverings in public settings that reduce potential exposure to COVID-19 where other social distancing measures are difficult to maintain (e.g., grocery stores and pharmacies) especially in areas of significant community based transmission. These face coverings and other Emulated-Personal Protective Equipment (EPPE) can be made by using Commonly Available Materials (CAMs). As part of the Sandia COVID-19 LDRD effort (funded under the Materials Science Investment Area), the Sandia E-PiPEline task evaluated E-PPE design options for face coverings and face shields considering their effectiveness, durability, build difficulty, build cost, and comfort. Observations from this investigation are presented here to provide guidelines for home construction of E-PPE. This executive summary includes a brief roadmap of the analysis methodology, two one-page handouts geared to be distributed to the public at large (one for E-PPE face coverings and one for E-PPE face shields), and additional observations regarding the potential solutions for E-PPE face coverings and face shields included to further support the one-page handouts.

60 APPLIED LIFE SCIENCES↗

California Energy Systems for the 21st Century (CES-21) Program, CRADA TC02200 (Final Report)

The following report representsthe culmination of a five-year Cybersecurity Research and Development (R&D) program performed by California’s Investor-Owned Utilities (IOUs) and Lawrence Livermore National Laboratory (LLNL) and funded by the IOUs’ electricity ratepayers as authorized by California Legislation and the California Public Utilities Commission (CPUC). The cybersecurity R&D, which was intensely technical in nature, was broken into three major workstreams: 1. The development of a modeling & simulation platform, to explore the potential effects of various threat and response scenarios at grid scale; 2. The establishment of a physical testbed with separate substation instances from each of the IOUs, to evaluate threats and responses on actual substation equipment; 3. The development of a research package consisting of several capabilities to support the industry’s evolution towards automated threat response and other next-generation cybersecurity techniques Throughout the program, there was extensive collaboration between the program team and national laboratories, federal departments, academic institutions and industry organizations. Several of the tools developed through the program have been made available to the open source community, to enable faster adoption and continued development of important cybersecurity capabilities. While this program began to develop much of the foundation for automated threat response, much work remains to be done, and this report recommends a series of next steps. While the Executive Summary below has been simplified as much as possible, the very technical nature of the subject matter would make further reduction difficult without causing meaning to be lost. Due to the sensitive nature of the research, some topics are intentionally covered at a high level to protect the research and therefore the electric grid and customers of California and the Nation. For further detail, clarification or questions we suggest discussion with the program team.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Quench conditioning device. Vibrational quench conditioning

Recently a new type of device, capacitor-based, aiming to eliminate or reduce superconducting magnet training was developed and tested at FNAL. I’ll review its main characteristics and principles of operation, make relevant comparisons and conclusions. Separately, I’ll discuss somewhat similar concepts based on induced vibrations in magnets, but I’ll extend this topic to cover both training reduction and quench protection. Those will be discussed at conceptual level, arguing about feasibility of such an approach and the need for more focused research on the topic, including simulations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Intense infrared lasers for strong-field science

The advent of chirped-pulse amplification in the 1980s and femtosecond Ti:sapphire lasers in the 1990s enabled transformative advances in intense laser–matter interaction physics. Whereas most of experiments have been conducted in the limited near-infrared range of 0.8–1 μm, theories predict that many physical phenomena such as high harmonic generation in gases favor long laser wavelengths in terms of extending the high-energy cutoff. Significant progress has been made in developing few-cycle, carrier-envelope phase-stabilized, high-peak-power lasers in the 1.6–2 μm range that has laid the foundation for attosecond X ray sources in the water window. Even longer wavelength lasers are becoming available that are suitable to study light filamentation, high harmonic generation, and laser–plasma interaction in the relativistic regime. Long-wavelength lasers are suitable for sub-bandgap strong-field excitation of a wide range of solid materials, including semiconductors. In the strong-field limit, bulk crystals also produce high-order harmonics. In this review, we first introduce several important wavelength scaling laws in strong-field physics, then describe recent breakthroughs in short- (1.4–3 μm), mid- (3–8 μm), and long-wave (8–15 μm) infrared laser technology, and finally provide examples of strong-field applications of these novel lasers. Furthermore, some of the broadband ultrafast infrared lasers will have profound effects on medicine, environmental protection, and national defense, because their wavelengths cover the water absorption band, the molecular fingerprint region, as well as the atmospheric infrared transparent window.

43 PARTICLE ACCELERATORS↗

The regulation of the cell wall by glycosylphosphatidylinositol-anchored proteins in Arabidopsis

A polysaccharides-based cell wall covers the plant cell, shaping it and protecting it from the harsh environment. Cellulose microfibrils constitute the cell wall backbone and are embedded in a matrix of pectic and hemicellulosic polysaccharides and glycoproteins. Various environmental and developmental cues can regulate the plant cell wall, and diverse glycosylphosphatidylinositol (GPI)-anchored proteins participate in these regulations. GPI is a common lipid modification on eukaryotic proteins, which covalently tethers the proteins to the membrane lipid bilayer. Catalyzed by a series of enzymic complexes, protein precursors are post-translationally modified at their hydrophobic carboxyl-terminus in the endomembrane system and anchored to the lipid bilayer through an oligosaccharidic GPI modification. Ultimately, mature proteins reach the plasma membrane via the secretory pathway facing toward the apoplast and cell wall in plants. In Arabidopsis, more than three hundred GPI-anchored proteins (GPI-APs) have been predicted, and many are reported to be involved in diverse regulations of the cell wall. In this review, we summarize GPI-APs involved in cell wall regulation. GPI-APs are proposed to act as structural components of the cell wall, organize cellulose microfibrils at the cell surface, and during cell wall integrity signaling transduction. Besides regulating protein trafficking, the GPI modification is potentially governed by a GPI shedding system that cleaves and releases the GPI-anchored proteins from the plasma membrane into the cell wall.

59 BASIC BIOLOGICAL SCIENCES↗

Protection of U.S. streams is insufficient to safeguard stream diversity and prevent habitat impairment

Despite covering a small portion of Earth’s surface, streams support a disproportionate amount of biodiversity. Here, we measure progress against the Global Biodiversity Framework 30×30 protection target for streams within the conterminous U.S., in terms of quantity, representation, and effectiveness of habitat protection under primarily land-based protection strategies. We evaluated the geophysical and biogeographical diversity of streams falling under protection measures. Additionally, we expose a paradox of streams being protected yet simultaneously impaired from human disturbances. Without considering impairment, approximately 30% of streams are currently protected through land-based conservation of their local or upstream watersheds; when considering impairment, only 9% to 28% of streams are truly protected from disturbances depending on impairment thresholds and protection criteria. Furthermore, despite protection approaching 30×30 targets, only 5% of the most prevalent physical stream habitat types are protected. We provide a targeted protection strategy, overcoming the impairment paradox and ensuring adequate representation of streams.

Biogeography↗

2022 Climate Change Vulnerability Assessment and Resilience Plan Summary

Los Alamos National Laboratory (LANL, or the Laboratory) produced a Vulnerability Assessment and Resilience Plan (VARP) following Department of Energy (DOE) Guidance to assess and manage climate change related risks to the Laboratory’s assets and operations. This is a condensed summary of the Laboratory’s 2022 VARP – the full version of the document is not publicly available at this time. The VARP was led by the Pollution Prevention (P2) Program in the Environmental Protection and Compliance Division (EPC-DO) and covers the entirety of the 36-square-mile LANL site in Los Alamos, New Mexico. A Steering Committee, composed of representatives from the three main Laboratory Directorates and the Los Alamos Field Office, identified real property Critical Assets based on their Mission Dependency Index (MDI) scores. LANL used MDI scores of 70 and above, which are considered Mission-Critical, to generate a list of 141 Critical Asset facilities.

54 ENVIRONMENTAL SCIENCES↗

Impact of Inverter-Based Resources on Grid Protection: A Review of Negative-Sequence Current Generation

The increasing integration of inverter-based resources (IBRs) in power grids poses challenges to traditional protection systems, primarily due to their different fault current signatures compared to conventional synchronous generators. Unlike synchronous generators whose fault response is dictated by their physical design, IBRs exhibit a wide range of fault characteristics due to manufacturer-specific control algorithms and settings. This dependence on proprietary control schemes makes modeling IBR behavior during faults significantly more complex, especially considering the rapid evolution of inverter technology and the diverse control strategies employed. While much research has focused on the positive-sequence current injections of IBRs during symmetrical faults, the understanding of negative-sequence current generation during non-symmetrical faults remains limited. This report provides an overview of current research on IBRs' negative-sequence current generation during unbalanced faults and its impact on protection schemes based on negative-sequence components. It covers both type III wind turbines and full-size converter-based IBRs. Additionally, this report reviews strategies for grid-forming controlled inverters to generate negative-sequence current during unbalanced faults, in addition to grid-following controlled ones.

24 POWER TRANSMISSION AND DISTRIBUTION↗