Ionization potential of O sub 2.
Ionization potential, dissociation energy and electron affinity for molecular oxygen
SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Ionization potential, dissociation energy and electron affinity for molecular oxygen
Ultraviolet absorption spectra of oxygen in liquid and crystalline argon and nitrogen
A series of YBa2Cu(3-x)MxO(7-y) (M=Al,Zn and Sn) single phase samples were prepared, and the measurements of the crystal structure, oxygen content, electric resistivity, thermoelectric power, Mossbauer spectrum, XPS and superconductivity were performed. The experimental results of X ray powder diffraction, Mossbauer spectrum and oxygen content show that the Zn(2+) and the Al(3+) occupy the Cu(2) site in Cu-O planes and the Cu(1) site in Cu-O chains respectively, but the Sn(4+) occupies both the Cu(1) sites. As regards the properties in superconducting state, both the Zn(2+) and the Al(3+) depress T(sub c) strongly, but the Sn(4+) does not. As for the electronic transport properties in normal state, the system doped by Al(3+) displays a rapid increase of resistivity and some electron localization-like effects, and the thermoelectric power enhances obviously; the series contained Zn(2+) almost shows no changes of electric resistivity but the sign of the thermoelectric power is reversed. Other results are given and briefly discussed.
Ultraviolet spectra of the tropical oxygen nightglow in the range of 830 to 1850 A (in first order) at 3 A resolution were obtained with the Hopkins Ultraviolet Telescope in December 1990. The data are presented which were obtained on a setting celestial target as the zenith angle of the line-of-sight varied from 77 to 95 deg. The dominant features in the spectrum (other than geocoronal hydrogen) are O I 1304 and 1356 and the radiative recombination continuum near 911 A. The continuum is resolved and found to be consistent with an electron temperature in the range 1000-1250 K. The observed ratio of the brightness of O I 1356 to the continuum suggests that O(+)-O(-) mutual neutralization contributes about 40 percent to the 1356 A emission. The dependence of the optically thin emissions on zenith angle is consistent with a simple ionospheric model. Weak O I 989 emission is also detected, but there is no evidence for any similarly produced atomic nitrogen emissions.
Photospheric abundances of C, N and O of an evolved halo Population 2 star, the field horizontal-branch star HD 109995, based on observations of ultraviolet resonance or low excitation lines are presented. The logarithmic abundance ratio with respect to the Sun O/Fe = +1.5 is substantially higher than previously determined values for Pop. 2 red giants or RR Lyrae stars, but agrees well with a derived value from the OI infrared triplet. This may be direct evidence of Tinsley's (1979) scenario of localized sharply rising interstellar oxygen abundances immediately following bursts of massive star formation. Star HD 109995 may have formed from such highly oxygen-enriched material prior to its dilution by gas with the pre-burst composition. The ratio C/N = -1.3 may reflect the composition of material from which the star formed or CN processing within the star during its evolution.
Explore the source record for details and available documents.
Ultraviolet and optical spectra data are presented for the oxygen-rich supernova remnant 1E 0102-7219 in the SMC. These UV data are the first to seriously constrain the UV emission from an oxygen-rich remnant. Emission lines of O I, forbidden O II, semiforbidden O III, semiforbidden O IV, C IV, forbidden Ne IV, and Mg II have been unambiguously detected in the UV. Shock models for material with abundances appropriate to massive stellar ejecta are calculated, and a number of differences between these models and the observations are found. The UV lines are observed to be weaker relative to optical lines than expected from models. Models of photoionization by the remnant's X-ray emission are calculated, and these provide a better qualitative match to the observed spectra. Approximate abundances in the ejecta are derived and the implications these have for the precursor star are discussed.
Photoionization and absorption cross sections measured for nitrogen and oxygen at wavelengths below 1100 angstroms
At the time of the recent sunspot minimum in 1987 when the cosmic-ray intensity within the heliosphere was a maximum, Pioneer 10(P10) was at a radial distance of approximately 42 AU. The solar modulation parameter Phi is estimated to have reached a minimum value of approximately 150 MV at P10 at that time, as compared with a minimum value of approximately 500 MV at the Earth. Thus P10 is in a sense effectively approximately 0.7 of the way to the heliospheric modulation boundary whatever its physical distance in astronomical units. Accordingly, the spectra of the various cosmic-ray species are much nearer to the interstellar spectra than any spectra ever before measured. We have therefore examined the penetrating high energy telescope (HET) data from P10 for a 2.5 yr period around 1987 to obtain a statistically accurate spectrum of oxygen nuclei over the energy range from 90 to 450 MeV/nucleon for comparison with a 'reference' interstellar spectrum. A similar spectrum is derived for helium nuclei. These two spectra and their ratios constitute important 'reference' spectra for all of the heavier cosmic-ray nuclei. The cosmic-ray source ratio required to explain the observed He/O ratio, when a full Galactic propagation calculation is carried out including secondary He-4 and He-3 production, is 15.9. The implications of this very low ratio and a comparison with the He/O ratio measured at high energies are discussed.
Intensity measurements on molecular oxygen Herzberg I system emitting in afterglow of microwave discharge, noting dependence of transition moment on internuclear distance
Near infrared spectroscopy (NIRS) is commonly used to measure muscle oxygenation during exercise and recovery. Current NIRS algorithms do not account for variation in water content and optical pathlength during exercise. The current effort attempts to validate a newly developed NIRS algorithm during rhythmic handgrip exercise and recovery. Six female subjects, aver age 28 +/- 6 yrs, participated in the study. A venous catheter was placed in the retrograde direction in the antecubital space. A NIRS sensor with 30 mm source-detector separation was placed on the flexor digitorum profundus. Subjects performed two 5-min bouts of rhythmic handgrip exercise (2 s contraction/1 s relaxation) at 15% and 30% of maximal voluntary contraction. Venous blood was sampled before each bout, during the last minute of exercise, and after 5 minutes of recovery. Venous oxygen saturation (SvO2) was measured with a I-stat CG-4+ cartridge. Spectra were collected between 700-900 nm. A modified Beer's Law formula was used to calculate the absolute concentration of oxyhemoglobin (HbO2), deoxyhemoglobin (Hb) and water, as well as effective pathlength for each spectrum. Muscle oxygen saturation (SmO2) was calculated from the HbO2 and Hb results. The correlation between SvO2 and SmO2 was determined. Optical pathlength and water varied significantly during each exercise bout, with pathlength increasing approximately 20% and water increasing about 2%. R2 between blood and muscle SO2 was found to be 0.74, the figure shows the relationship over SvO2 values between 22% and 82%. The NIRS measurement was, on average, 6% lower than the blood measurement. It was concluded that pathlength changes during exercise because muscle contraction causes variation in optical scattering. Water concentration also changes, but only slightly. A new NIRS algorithm which accounts for exercise-induced variation in water and pathlength provided an accurate assessment of muscle oxygen saturation before, during and after exercise.
Electron paramagnetic resonance spectra of oxygen chemisorption by reduced titanium dioxide
Dayglow green line and possible excitation mechanisms such as photodissociation and dissociative recombination of oxygen
Rydberg series from resonances in continuous photoionization absorption of molecular oxygen near 500 angstroms
Diurnal and latitudinal variations in 6300 angstrom nightglow intensity determined along Pacific coast of South America, noting relation between location of antisolar point and equatorial midnight enhancement
Oxygen IV transition multiplet relative intensities for measuring decay rates, using triply ionized emitters
UV auroral spectrum atomic oxygen, nitrogen and molecular nitrogen electron impact excited emission calculations compared to rocket observations
Radio wave propagation in the 40 to 140 GHz band through the first hundred kilometers of the atmosphere is strongly influenced by the microwave spectrum of oxygen (O2-MS). A unified treatment of molecular attenuation and phase dispersion is formulated. Results of molecular physics are translated into frequency, temperature, pressure, and magnetic field dependencies of a complex refractive index. The intensity distribution of the O2-MS undergoes several changes with increasing altitude. The influence of water vapor is discussed. Examples of computer plots are given as a function of altitude for homogeneous, zenith, and tangential path geometries. Molecular resonances of minor atmospheric gases are discussed briefly.