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At least 37 records · Page 2

Machine learning modeling and model predictive control of a closed-circuit reverse osmosis system

Closed-circuit reverse osmosis (CCRO) offers a flexible and energy-efficient alternative to conventional reverse osmosis by operating in a semi-batch mode that recycles brine, enabling higher recovery rates and reduced specific energy consumption (SEC). However, developing accurate, system-level dynamic models for CCRO remains challenging due to its nonlinear, multi-phase operation and sensitivity to variable feed water conditions. Traditional modeling approaches, such as NARMAX (nonlinear autoregressive moving average with exogenous inputs), often struggle to generalize across varying inlet feed concentrations, necessitating frequent parameter re-estimation and limiting their utility for real-time control applications. To address these limitations, we developed a long short-term memory (LSTM) neural network model trained on an extensive experimental data set from a CCRO pilot plant. The model accepts three inputs, feed flow rate, recirculation flow rate, and initial feed conductivity, and predicts three key outputs: reject conductivity, feed pump power draw, and recirculation pump power draw. We validated the LSTM model against experimental data, demonstrating its ability to distinguish between different feed conductivities and adapt to variable flow rates. Subsequently, we incorporated the LSTM model within a nonlinear model predictive control (MPC) scheme and conducted closed-loop simulations to optimize the integrated SEC (iSEC). In conclusion, the results project up to a 6% reduction in iSEC by using MPC to optimize performance over the entire experiment duration, without requiring any random excitation for data collection or parameter re-estimation.

Desalination↗

Energy requirements of the switchable polarity solvent forward osmosis (SPS-FO) water purification process

A model was developed to estimate the process energy requirements of a switchable polarity solvent forward osmosis (SPS FO) system for water purification from aqueous NaCl feed solution concentrations ranging from 0.5 to 4.0 molal at an operational scale of 480 m3/day (feed stream). The model indicates recovering approximately 90% of the water from a feed solution with NaCl concentration similar to seawater using SPS FO would have total equivalent energy requirements between 2.4 and 4.3 kWh per m 3 of purified water product. The process is predicted to be competitive with current costs for disposal/treatment of produced water from oil and gas drilling operations. As a result, once scaled up the SPS FO process may be a thermally driven desalination process that can compete with the cost of seawater reverse osmosis.

15 GEOTHERMAL ENERGY↗

Optimization-based modeling and analysis of brine reflux osmotically assisted reverse osmosis for application toward zero liquid discharge systems

Significant amounts of high-salinity wastewater generated by water-intensive industrial activities such as shale oil and gas production have raised serious environmental concerns in recent years. Existing and emerging desalination technologies offer promise to manage these high salinity wastewater streams while simultaneously producing fresh water that could be diverted for beneficial uses. Osmotically assisted reverse osmosis (OARO) is one such emerging desalination technology capable of handling hypersaline brines and achieving high recoveries. However, rigorous modeling and analysis is needed to evaluate the process performance, energy consumption, and treatment cost of various OARO configurations. Here, this work presents detailed modeling and analysis of brine-reflux OARO (BR-OARO) system and compares it with other commonly discussed configurations, including cascading osmotically mediated reverse osmosis (COMRO), consecutive loop OARO, and split feed counterflow RO, through a cost optimization-based framework. We analyze and compare the treatment costs, membrane area, specific energy consumption, and design parameters of the aforementioned configurations with the ultimate goal of achieving zero liquid discharge (ZLD). The results indicate that the BR-OARO system with treatment cost of 5.1 US $/m 3 of produced water with 10% salinity outperforms other configurations in terms of number of stages needed, treatment cost, membrane area, and energy consumption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Impact of large-scale effects on mass transfer and concentration polarization in Reverse Osmosis membrane systems

Here, we present well-resolved computational fluid dynamics simulations of a large-scale reverse osmosis membrane-spacer configuration (1 m). Our computational model solves the flow and transport equations with variable solute-dependent properties. We utilize a high resolution computational mesh to resolve all relevant length scales associated with spacer-induced mixing and thin concentration boundary layers. An important contribution of this work is the development of a modified mass-transfer correlation that accounts for the development of the concentration boundary layer along the channel. A set of 2D axisymmetric simulations were performed for a spiral wound module layer with varying cross-flow conditions and spacer diameters which indicate a significant entrance length effect for concentration profile development at lower flow rates while mixing effects dominate at higher flow rates. The mass-transfer correlations at higher flow rates compare well with published correlations while a surrogate model for Sherwood number was obtained that depends on an additional similarity variable that accounted for entrance length effects at lower flow rates. Finally, a large-scale membrane-spacer design relevant to high-pressure reverse osmosis is studied with a non-uniform arrangement of spacers, which indicate a substantial saving in pressure drop (~40%) compared to traditional uniformly spaced pattern with minor variations (~2%) in concentration polarization, product water quality (~1%) and water recovery (~7%) compared to a uniform spacer pattern.

97 MATHEMATICS AND COMPUTING↗

Tuning Fabrication Factors for Reduced Graphene Oxide Forward Osmosis Membranes

Forward osmosis (FO) may serve as a near-zero energy approach for wastewater management and selective chemical enrichment with an appropriate FO membrane. There is a need for novel FO membranes with better physical stability, chemical compatibility, and enhanced reverse flux selectivity. In this work, we have systematically studied a variety of factors for fabricating thermally reduced graphene oxide (RGO) FO filtration membranes and have demonstrated that with a comparable water flux, the RGO membranes have an exceptionally large reverse flux selectivity with 1.5 M sodium sulfate draw solution, about 7 times larger than that of cellulose triacetate membranes under the same testing condition. The interlayer spacing of the membranes can be fine-tuned by varying temperatures, so that the free interlayer spacing is less than 0.7 nm after exposure to water. The RGO-based membranes offer a few advantages with high reverse flux selectivity, mechanical robustness with strong adhesion to nylong support membranes without damage after FO tests and tape peel tests, and enhanced chromate and chlorine resistance. Finally, we have further demonstrated that in the FO processes, one can concentrate waste brine while simultaneously harvesting the osmotic energy as electricity, offering potential applications of forward osmosis-based osmotic batteries for powering electronic devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evaluating Pretreatment Strategies with Modeling for Reducing Scaling Potential of Reverse Osmosis Concentrate: Insights from Ion Exchange and Activated Alumina

Reverse osmosis concentrate (ROC) treatment is critical for enhancing water recovery and minimizing concentrate volume for disposal, especially in regions facing water scarcity. This study investigates the application of ion exchange (IX) resins and activated alumina (AA) as pretreatment strategies to mitigate scaling in ROC due to high concentrations of total dissolved solids, hardness (Ca 2+ and Mg 2+ ), and silica. Through a series of Langmuir isotherms, continuous column experiments, and model simulation, two types of strong acid cation IX resins and three types of strong base anion IX resins alongside three types of AA were evaluated. Results indicate that AA exhibits superior performance in silica removal, achieving up to a 65% reduction and maintaining performance for up to 800 bed volume without reaching saturation. Model simulation of a secondary reverse osmosis treating ROC after the IX and AA pretreatment indicated an additional water recovery of ~70% using antiscalants. This study demonstrates the potential for achieving higher water recovery while also identifying opportunities for pretreatment improvement. Challenges such as the limited IX capacity treating ROC, which requires frequent regeneration and increases operational costs, along with the restricted regeneration capacity of AA, underscore the importance of innovation. These findings emphasize the critical need for developing advanced materials and optimized strategies to further enhance the efficiency of ROC treatment processes.

activated alumina↗

SWITCHABLE POLARITY SOLVENTS AS DRAW SOLUTES FOR FORWARD OSMOSIS

Switchable polarity solvents (SPS), mixtures of carbon dioxide, water, and tertiary amines, are presented as viable forward osmosis (FO) draw solutes allowing a novel SPS FO process. In this study substantial osmotic strengths of SPS are measured with freezing point osmometry and were demonstrated to induce competitive ?uxes at high salt concentrations on a laboratory-scale FO unit utilizing a ?at sheet cellulose triacetate (CTA) membrane. Under the experimental conditions the SPS degrades the CTA membrane; however experiments with polyamide reverse osmosis (RO) membranes display stability towards SPS. Once the draw is diluted the major fraction of the switchable polarity solvent can be mechanically separated from the puri?ed water after polar to nonpolar phase shift induced by introduction of 1 atm carbon dioxide to 1 atm of air or nitrogen with mild heating. Trace amounts of SPS can be removed from the separated water with RO in a process that avoids solution concentration polarization. The separated nonpolar phase can be regenerated to a full strength draw and recycled with the re-addition of 1 atm of carbon dioxide.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Unraveling the mysteries of the thin film composite reverse osmosis membrane

A recent article in Science by Culp, Kumar, Gomez, and colleagues introduces a new approach to characterizing reverse osmosis thin film composite membranes to provide critical insights into understanding how polymer membrane microstructure affects water permeability. Such approaches offer a degree of microstructure characterization that has up until now been unavailable to the membrane science community. Here, combined with modeling of water diffusion coefficient in the polymer membrane itself, this effort has begun to answer decades-old questions about how polyamide reverse osmosis membranes function.

McCutcheon, Jeffrey R.↗

X-ray Scattering Studies of Reverse Osmosis Materials

Scarcity of freshwater is becoming a world crisis. In a recent annual risk report, the World Economic Forum lists it in their greatest global risk category. Currently, about four billion people live under conditions of severe water scarcity for at least one month out of the year [1]. Increasing water use efficiency is thus essential. However, this alone will not be able to provide adequate drinking water to meet the world’s needs. The process of preparing drinking water from seawater and brackish water involves many stages, the final and most expensive of which is typically reverse osmosis (RO). Reverse osmosis processes operate by forcing water across a semi-permeable membrane by applying a pressure greater than the osmotic pressure of the feed solution (seawater, Π ≈ 28 bar = 400 psi), thereby separating the water from any dissolved ions and impurities (rejection > 99%). The flux of water through the membrane is directly proportional to the amount of pressure applied above the osmotic pressure; however, the energy consumption is related to the total pressure. According to the American Membrane Technology Association, the amount of energy required to desalinate seawater with current technologies is 2.5 to 3.5 kWh/m 3 of water. RO materials have been tuned, modified, and optimized extensively since their initial discovery through an Edisonian approach. Despite immense technological progress [2, 3], many basic scientific questions remain on the molecular structure of RO membranes. Overall, in this report, we demonstrate that synchrotron X-ray scattering methods offer the possibility of improving our fundamental understanding of RO materials.

36 MATERIALS SCIENCE↗

Evaluating the Techno-Economic Feasibility of Forward Osmosis Process Utilizing Low Grade Heat: Applications in Power Plant Water, Wastewater, and Reclaimed Water Treatment

Recovering and using uncoverted heat produced during electric power generation holds potential to significantly improve the efficiency of the electric power industry. One potential use of this low-temperature waste heat is on-site water treatment using waste heat driven processes to comply with the 2015 Effluent Limitation Guidelines for the Steam Electric Generating Sector. Ammonia-carbon dioxide forward osmosis (NH 4 HCO 3 FO) is a two-step waste heat driven process that involves a membrane separation process in which an osmotic pressure gradient created by an NH 4 HCO 3 draw solution is used to pull water across the membrane and a distillation column to regenerate the NH 4 HCO 3 draw solution. In this work we estimate the quantity, quality, and spatio-temporal availability of waste heat produced at U.S. coal, nuclear, and natural gas plants. We combine these estimates of waste heat availability with a techno-economic optimization model of NH 4 HCO 3 FO in order to assess the potential of NH 4 HCO 3 FO to treat flue gas desulfurization (FGD) wastewater, gasification wastewater, and boiler feedwater. We find that in 2012, 18.9 billion GJ of waste heat was discharged from the U.S. coal, natural gas, and nuclear fleet, although only 900 million GJ of waste heat was discharged at temperatures suitable for NH 4 HCO 3 FO. A maximum of 1.9 billion m3/yr of water could be produced using this waste heat to drive a NH 4 HCO 3 FO. The costs of waste heat driven NH 4 HCO 3 FO for FGD and gasification wastewater treatment to zero liquid discharge (ZLD) and boiler feedwater treatment are 2.20-2.40/m 3 and 0.35-0.65/m 3 , respectively. With mechanical vapor compression and crystallization for ZLD wastewater treatment and reverse osmosis for boiler feedwater treatment as the cost benchmark technologies, waste heat driven NH 4 HCO 3 FO is cost competitive for ZLD wastewater treatment, but not boiler feedwater treatment.

20 FOSSIL-FUELED POWER PLANTS↗

Scaling dynamics in low-salt-rejection reverse osmosis for high-salinity produced water desalination: Mechanistic modeling and membrane autopsy

Membrane scaling remains a critical barrier to the reliable operation of desalination systems, particularly for hypersaline produced water (PW) treatment. This study fills the knowledge gap of autopsy-based model validation for PW desalination by elucidating scaling mechanisms in a Low-Salt-Rejection Reverse Osmosis (LSRRO) system through the integration of pilot-scale experimentation and complementary modeling approaches. A semi-empirical modeling framework was developed and applied to a multistage pilot LSRRO system equipped with nanofiltration and RO membranes treating high-salinity PW from the Permian Basin. Water quality analysis showed that total dissolved solids decreased from ~130,000 mg/L to ~1900 mg/L in the permeate, then further reduced to ~300 mg/L by a second-pass RO. Two different thermodynamic modeling approaches were evaluated: the first extends the LSRRO framework by incorporating system complexity and scaling phenomena, whereas the second method explicitly captures concentration polarization in localized supersaturation. Both methods illustrate the tendency for carbonate and sulfate scaling throughout the stages. Membrane autopsies revealed a silica-dominated deposit matrix, localized CaSO 4 at Stage 2, and minor barite/celestite despite their prominence in model predictions. Quantum-chemical calculations indicated silica scaling can be rationalized by favorable adsorption of H 4 SiO 4 on Fe-oxide surfaces (ΔG ≈ −44 kJ/mol), providing a kinetic pathway for interfacial inorganic polymerization even when bulk equilibrium predictions are conservative. Overall, the thermodynamic scaling modeling and membrane autopsy revealed heterogeneous, localized deposits with limited impact on LSRRO performance, while quantum analysis rationalized the thermodynamically unfavorable precipitation formation under bulk equilibrium, reconciling model–autopsy discrepancies. These insights support targeted pretreatment and silica-specific antiscalants to extend membrane lifetime and increase recovery, providing a transferable framework for hypersaline water desalination systems. The combined experimental–computational approach provides new mechanistic insight into scaling in hypersaline membrane systems and establishes a transferable framework for predicting and mitigating scaling in next-generation desalination technologies.

Low-salt-rejection reverse osmosis↗

Polyamide-crosslinked graphene oxide membrane for forward osmosis

We report a novel polyamide-graphene oxide (PA-GO) membrane was synthesized on a polyethersulfone support by first intra-crosslinking GO aggregates via m-xylylenediamine (MXDA) and then inter-crosslinking GO aggregates via trimethyle chloride (TMC). This method allows for the use of hydrophilic, more porous supports in forward osmosis (FO) membranes, thereby lending much flexibility to membrane synthesis and also potentially reducing internal concentration polarization in FO. The elemental composition, morphology, and hydrophilicity of the synthesized PA-GO membrane were characterized to confirm intra- and inter-crosslinking reactions and understand membrane properties. It was found that the mixing temperature of MXDA and GO should be controlled below 20 °C to avoid the formation of large GO aggregates and hence reduce membrane heterogeneity and defects. The performance of the PA-GO membrane was compared with that of a commercial FO membrane using trisodium citrate (TSC), Na 2 SO 4 , and MgCl 2 , respectively, as draw solutes. Under the same osmotic pressure, the water flux of the PA-GO membrane was the highest with TSC as draw solute, moderate with Na 2 SO 4 , and almost zero with MgCl 2 , while the ranking of solute fluxes followed a reverse order, revealing that an effective solute barrier plays an important role in making FO membranes with high water flux and low solute flux.

42 ENGINEERING↗

Delivery of a Solar-Powered Forward Osmosis Seawater Desalination Plant: Trevi’s 500 m3/day Zero-Carbon FO Seawater Desalination Plant at NELHA

This paper presents an account of Trevi’s delivery of a 500 m3/day solar powered forward osmosis (FO) seawater desalination plant at the Ocean Science and Technology Park of the Natural Energy Laboratory of Hawaii Authority (NELHA). The project aimed to demonstrate the viability of solar thermal-powered desalination for agricultural applications through the integration of a 2MW micro-dish solar thermal array with a state-of-the-art FO system. Highlighted in the paper are the three distinct project phases; Planning and Design, System Construction, Installation & Testing followed finally by System Operation and Optimization. Results and decisions which led to the final plant design will be shared, highlighting how Trevi Systems succeeded in producing a zero-carbon FO seawater desalination plant with a projected Levelized Cost of Water (LCOW) estimate competitive with existing carbon-intensive RO technologies (based on some assumptions and the cost of heat which is required for FO.

14 SOLAR ENERGY↗

Fabrication and Characterization of Composite Membranes for the Concentration of Lithium Containing Solutions Using Forward Osmosis

In this study, an energy and highly time efficient, cost effective, and scalable forward osmosis (FO) composite polyvinylidene fluoride (PVDF) membrane is developed to concentrate lithium chloride recovered from naturally occurring geothermal brine resources. Dense thin robust defect-free Kynar-PVDF membranes are fabricated on porous PVDF hollow fiber supports. Various membrane fabrication parameters such as membrane thickness, coating solution concentration, cross-linker concentration, and curing temperature are studied to develop a defect-free dense membrane. Advanced characterization tools such as FIB-SEM, Raman, FTIR spectroscopy, and XRD are used to study the surface and cross-sectional morphology, chemistry of crosslinking, crystallinity and chemical structure of the dense PVDF membrane. FO is utilized to concentrate LiCl in the solution from 36 to 175 g L -1 with an average water transfer rate of 0.450 L m -2 h -1 (LMH) at 85 °C. Furthermore, the membrane showed stable performance for more than 550 h while maintaining the purity of the concentrated lithium chloride solution of >99.99 wt%. Overall, the results suggest that the FO-based technology is an innovative, time and energy efficient approach compared to the conventional technologies for concentration of battery grade LiCl for application in lithium ion batteries and other clean energy technologies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Rejection of low-molecular weight neutral organics is highly sensitive to reverse osmosis system design and operation

A computational model was developed to investigate the significance of system design and operating conditions on the rejection of neutral, low-MW organics by reverse osmosis for potable reuse. Here, the model demonstrated that the decrease in local rejection as net driving pressure decreases is substantially greater for moderately rejected compounds than for highly rejected compounds. At recovery values less than 70%, the local permeate concentration can exceed the pressure vessel feed concentration for moderately rejected compounds. System-level rejection of moderately rejected compounds is likewise substantially more sensitive to operating conditions than highly rejected compounds. The findings highlight a drawback of relying on rejection results from bench-scale testing that operates at low recovery, which invariably has higher rejection than full-scale systems operating at similar pressure. The analysis demonstrates a trade-off in which the low-pressure, high-recovery operation desired for potable reuse systems can be detrimental to the removal of low-MW neutral organics. The removal of low-MW neutral organics can be improved if organics rejection is explicitly evaluated during the design process.

42 ENGINEERING↗

A Study of Novel Hexavalent Phosphazene Salts as Draw Solutes in Forward Osmosis

Two novel multi-valent salts based on phosphazene chemistry have been synthesized and characterized as forward osmosis (FO) draw solutes. Commercially obtained hexachlorocyclotriphosphazene was reacted with the sodium salt of 4-ethylhydroxybenzoate to yield hexa(4-ethylcarboxylatophenoxy)phosphazene. Hydrolysis, followed by and neutralization with NaOH or LiOH, of the resulting acidic moieties yielded water soluble sodium and lithium phosphazene salts, respectively. Degrees of dissociation were determined through osmometry over the range of 0.05-0.5 m, giving degrees of 3.08-4.95 per mole, suggesting a high osmotic potential. The Li salt was found to be more ionized in solution than the sodium salt, and this was reflected in FO experiments where the Li salt gave higher initial fluxes (~ 7 L/m2h) as compared to the sodium salt (~6 L/m2h) at identical 0.07 m draw solution concentrations at 30 °C. Longer term experiments revealed no detectable degradation of the salts; however some hydrolysis of the cellulose acetate membrane was observed, presumably due to the pH of the phosphazene salt draw solution (pH = ~8).

36 MATERIALS SCIENCE↗

Designing a biocidal reverse osmosis membrane coating: Synthesis and biofouling properties

In this study, a biocidal coating was developed in order to reduce biofouling on a reverse osmosis (RO) membrane using a quaternary ammonium (QA) functionalized polymer. The synthesis of a series of polysulfone (PS) ionomers with QA groups is described, and a method for spraying these QA ionomers as an alcoholic solution, which dried into water insoluble coatings. Contact angle and streaming potential were used to analyze the coating's hydrophilicity and surface charge. Both PS-QA1 and the commercial RO membrane had an apparent contact angle of 68° that increased to 126° for PS-QA12 corresponding to alkyl chain length. A negatively charged particle-probe was used to measure coated and uncoated RO membrane interaction forces. Measured interaction forces correlated strongly with the length of alkyl chains or hydrophobicity of the coated surfaces. Uncoated RO membranes and ones coated with PS-QA were exposed to suspensions of Escherichia coli cells. All four PS-QA coatings showed significant biotoxicity and killed 100% of the E. coli cells, but uncoated RO membranes had metabolically active biofilms. However, coatings tested in a RO crossflow system showed a flux reduction that is attributed to mass transfer resistance due to excessively thick films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Novel graphene quantum dots (GQDs)-incorporated thin film composite (TFC) membranes for forward osmosis (FO) desalination

This paper reports a novel class of thin film composite (TFC) membranes for forward osmosis (FO) desalination. The TFC membranes were fabricated via interfacial polymerization (IP) of aqueous mixture of polyethyleneimine (PEI) and graphene quantum dots (GQDs) with organic solution of trimesoyl chloride (TMC) on modified polyacrylonitrile (PAN) ultrafiltration substrates. The chemical structures and morphologies of the synthesized GQDs and the GQDs-incorporated membranes were studied by various characterization techniques. The synthesized GQDs exhibited a narrow size distribution of 1.0–4.0 nm with an average size of 2.19 nm, and the thickness were one to three graphene layers. The results showed that GQDs nanoparticles were covalently bonded to the polyamide chains. The optimized TFC membrane with 0.050 wt% GQDs loading exhibited quite hydrophilic and neutrally charged membrane surface, along with an enhanced water flux of 12.9 L m –2 h –1 and a comparable reverse salt flux of 1.41 g m –2 h –1 when DI water and 0.5 M MgCl2 were used as the feed solution and the draw solution, respectively. Also, the optimized GQDs-incorporated TFC membrane presented an especially good anti-fouling performance. Furthermore, incorporating the novel graphene nanomaterial into polymer membranes may present its great potential application in desalination, purification and wastewater treatment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗