Engineering PapersSearch

SEARCH · Engineering Papers

Results for “Nd”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2

The isotopic composition of Nd in different ocean masses

The paper examines the isotopic composition of Nd in marine environments. The Sm-Nd data for authigenic ferromanganese sediments indicate that the Atlantic, Pacific, and Indian Oceans have a distinct range in Nd isotopic composition characteristics of each ocean basin and reflect the dissolved load of Nd in the water mass. Measurements of the Nd isotopic seawater composition of seawater indicate that the rare earth elements (REE) in ferromanganese sediments are derived by direct precipitation of these elements out of seawater. It is believed that the Nd isotopic variations in these sediments represent true variations in the dissolved Nd isotopic composition which reflect the age and (Sm-147)/(Nd-144) ratios of the continental masses sampled believed to be the major source of REE in seawater.

Piepgras, D. J.

Blackbody absorption efficiencies for six lamp pumped Nd laser materials

Utilizing high resolution spectra, the absorption efficiencies for six Nd laser materials were calculated as functions of the effective blackbody temperature of the lamp and laser crystal size. The six materials were Nd:YAG, Nd:YLF, Nd:Q-98 Glass, Nd:YVO4, Nd:BEL, and Nd:Cr:GSGG. Under the guidelines of this study, Nd:Cr:GSGG's absorption efficiency is twice the absorption efficiency of any of the other laser materials.

Cross, Patricia L.

Efficiency of Nd laser materials with laser diode pumping

For pulsed laser-diode-pumped lasers, where efficiency is the most important issue, the choice of the Nd laser material makes a significant difference. The absorption efficiency, storage efficiency, and extraction efficiency for Nd:YAG, Nd:YLF, Nd:GSGG, Nd:BEL, Nd:YVO4, and Nd:glass are calculated. The materials are then compared under the assumption of equal quantum efficiency and damage threshold. Nd:YLF is found to be the best candidate for the application discussed here.

Barnes, Norman P.

Sm-Nd Isotopic Systematics of Troctolite 76335

A study of the Sm-Nd isotopic systematics of lunar Mg-suite troctolite 76335 was undertaken to further establish the early chronology of lunar magmatism. Because the Rb-Sr isotopic systematics of similar sample 76535 yielded an age of 4570 +/- 70 Ma [2, lambda = 1.402 x 10(exp -11)], 76335 was expected to yield an old age. In contrast, the Sm-Nd and K-Ar ages of 76535 indicate that the sample is approximately 4260 Ma old, one of the youngest ages obtained for a Mg-suite rock. This study establishes the age of 76335 and discusses the constraints placed on its petrogenesis by its Sm-Nd isotope systematics. The Sm-Nd isotopic system of lunar Mg-suite troctolite 76335 indicates an age of 4278 +/- 60 Ma with an initial epsilon (sup 143)(sub Nd) value of 0.06 +/- 0.39. These values are consistent with the Sm-Nd isotopic systematics of similar sample 76535. Thus, it appears that a robust Sm-Nd age can be determined from a highly brecciated lunar sample. The Sm-Nd isotopic systematics of troctolites 76335 and 76535 appear to be different from those dominating the Mg-suite norites and KREEP basalts. Further analysis of the Mg-suite must be completed to reveal the isotopic relationships of these early lunar rocks.

Edmunson, J.

New Nd-142 Evidence for a Non-Chondritic Composition of the Moon

The coupled Sm-147,146-Nd-143,142 systematics of lunar samples has been extensively studied for estimating the timescale of lunar differentiation. The published datasets yield consistent ages for Nd isotopic closure within the lunar mantle of approx.200 Myr after CAI formation. Although this time constraint is consistent with estimates derived from Hf-W chronometry of the Moon (>60 Myr after CAI formation), there is debate as to whether this age has chronological significance. Furthermore, there are discrepancies regarding the Nd isotope composition of the bulk Moon. Rankenburg et al. obtained a epsilon Nd-142 vs. Sm-147/Nd-144 correlation for lunar samples passing though the chondritic reference value (Sm-147/Nd-144 = 0.1967, epsilon Nd-142 = -0.21), suggesting that the Moon has a chondritic bulk composition. In contrast, the other datasets define a correlation line that passes approx.10-20 ppm above, suggesting that the Moon has a superchondritic Sm-147/Nd-144 (approx.0.206), close to that of the early depleted Earth (EDM). We present new Sm-Nd data for a high-Ti mare basalt (70135), two low-Ti mare basalt (LAP 02205 and MIL 05035) and a KREEPy low-Ti mare basalt (NWA 2977). These data are used to evaluate the significance of the Sm-Nd systematics for constraining the timescale of lunar differentiation and the bulk Nd isotope composition of the Moon.

Nyquist, L.

Repetitive Q-switched operation of x-axis Nd:La2Be2O5

The repetitive Q-switched performances of an x-axis neodymium-doped lanthanum beryllate (Nd:BeL) laser and the current state-of-the-art Nd:YAG laser are compared. Output beam pulse energy, peak power, pulse width, beam divergence and mode pattern were measured for a gold-plated single elliptical cavity using a xenon flashlamp for excitation. The output of the Nd:BeL laser is found to exceed that of the Nd:YAG laser by a factor of two at Q-switched repetition rates on the order of 1 Hz, due to the smaller stimulated emission cross section of the x-axis Nd:BeL. When the repetition rate is increased to 10 Hz, the Nd:BeL output falls to a level three fifths lower than its low-rate value, while Nd:YAG output remained essentially constant. Analysis reveals that the decrease in output may be attributed to a depolarization loss due to thermally induced stress birefringence.

Tucker, A. W.

Comparison of Nd 1.06 and 1.33 micron operation in various hosts

Performances of Nd in various hosts including Nd:YAG, Nd:YLF, Nd:BEL, and Nd:Cr:GSGG were characterized and compared for operation on the nominal 1.06 micron and 1.33 micron transitions. Comparison included continuous mode operation, normal mode operation, Q-switched operation, and gain measurements. Continuous lasing of Nd:Cr:GSGG under lamp pumping is reported for what may be the first time. Characterization included operation with different mirror reflectivities to obtain the internal losses, measurement of the upper laser level lifetime, measurement of the beam quality of the lasers operating under nominally similar circumstances, and measurement of the wavelength. These measurements should provide a comparison of the various Nd hosts under similar circumstances for a wide variety of operational modes and at both wavelengths of interest.

Barnes, Norman P.

Lunar initial Nd-143/Nd-144 - Differential evolution of the lunar crust and mantle

The Sm-Nd evolution of Apollo 15 green glass is discussed. The ICE age (intercept with chondritic evolution) of 3.8 + or - 0.4 eons overlaps the range of reported (Ar-39)-(Ar-40) ages and implies a distinct source region for green glass, characterized by very low and unfractionated REE abundances. Evidence is presented that LINd (lunar initial Nd) is compatible with a 'chondritic'-type Nd isotopic evolution as observed in the Juvinas meteorite. This normalization is used to study the Sm-Nd system of various lunar rock types. The results obtained from a limited number of rocks clearly indicate differential Sm-Nd evolution for the lunar crust and mantle. High-Ti basalts returned by the Apollo 11 and 17 missions were derived from distinct source regions. The Nd-143 evolution in KREEP requires a source region which is clearly distinct from any mantle reservoir.

Lugmair, G. W.

The Early Differentiation History of Mars from W-182-Nd-142 Isotope Systematics in the SNC Meteorites

We report here the results of an investigation of W and Nd isotopes in the SNC (Shergottite-Nakhlite-Chassignite (martian)) meteorites. We have determined that epsilon W-182 values in the nakhlites are uniform within analytical uncertainties and have an average value of approx. 3. Also, while epsilon W-182 values in the shergottites have a limited range (from 0.3-0.7), their epsilon Nd-142 values vary considerably (from -0.2-0.9). There appears to be no correlation between epsilon W-182 and epsilon Nd-142 in the nakhlites and shergottites. These results shed new light on early differentiation processes on Mars, particularly on the timing and nature of fractionation in silicate reservoirs. Assuming a two-stage model, the metallic core is estimated to have formed at approx. 12 Myr after the beginning of the solar system. Major silicate differentiation established the nakhlite source reservoir before approx. 4542 Ma and the shergottite source reservoirs at 4525 [sup +19 sub -21] Ma. These ages imply that, within the uncertainties afforded by the Hf-182-W-182 and Sm-146-Nd-142 chronometers, the silicate differentiation events that established the source reservoirs of the nakhlites and shergottites may have occurred contemporaneously, possibly during crystallization of a global magma ocean. The distinct W-182-Nd-142 isotope systematics in the nakhlites and the shergottites imply the presence of at least three isotopically distinct silicate reservoirs on Mars, two of which are depleted in incompatible lithophile elements relative to chondrites, and the third is enriched. The two depleted silicate reservoirs most likely reside in the Martian mantle, while the enriched reservoir could be either in the crust or the mantle. Therefore, the W-182-Nd-142 isotope systematics indicate that the nakhlites and the shergottites originated from distinct source reservoirs and cannot be petrogenetically related. A further implication is that the source reservoirs of the nakhlites and shergottites on Mars have been isolated since their establishment before approx. 4.5 Ga. Therefore, there has been no giant impact or efficient global mantle convection to thoroughly homogenize the Martian mantle following the establishment of the SNC source reservoirs.

Foley, C. Nicole

Sm-Nd Isotopic Studies of Ureilite Novo Urei

Ureilites are ultramafic (harzburgitic) achondrites composed predominantly of olivine and pyroxenes, abundant carbon (graphites and shock-produced diamonds), some metal and sulfides. These rocks probably represent ultramafic mantles of differentiated parent asteroidal bodies. Age determinations of these rocks by Rb-Sr and Sm-Nd methods have been difficult because of their extremely low abundances of these parent-daughter elements. Nevertheless, Sm-Nd isochron ages were reported for Kenna, Goalpara, MET 78008 and PCA 82506 yielding ages of 3.74+/-0.02 Ga, approx.3.7 Ga, 4.09+/-0.08 Ga, 4.23+/-0.06 Ga, respectively [1-4]. These "young" Sm-Nd ages may represent secondary metasomatism events [1] related to impacts [5], as indicated by the similarly young Ar-39-Ar-40 degassing ages of 3.3-4.1 Ga for ureilites Kenna, Novo Urei and Havero [6]. Alternatively, it has been suggested that these rocks may have been contaminated with terrestrial crustal materials and the isochrons do not have any age significance [2,7]. Indications of old approx.4.56 Ga ages for ureilites were reported from the U-Pb and Sm-Nd model ages for MET 78008 [8]. More reliable evidences for old formation ages of ureilites were reported recently using the short-lived chronometers Hf-182-W-182, Al-26-Mg-26 and Mn-53-Cr-53. The deficits of 182W in ureilites suggest the metal-silicate segregation occurred very early, approx.1-2 Ma after CAI [9]. The Al-26-Mg-26 and Mn-53-Cr-53 studies for a feldspathic lithology [10] and the Mn-53-Cr-53 for olivine- and pyroxene-dominant lithologies [11] in ureilites revealed that they crystallized approx.5.4 Ma after CAI, i.e., at 4563.8+/-0.5 Ma relative to D.Orbigny. In this report, we present Sm-Nd isotopic data for a relatively fresh ureilite, Novo Urei, a rare ureilite fall (1886). We compare these data to Sm-Nd data for other ureilites, and discuss Novo Urei's petrogenesis

Shih, C.-Y.

Stimulated-emission cross section at 1064 and 1342 nm in Nd:YVO4

The stimulated-emission cross sections at 1064 and 1342 nm in Nd:YVO4 were determined by measurement of laser thresholds as a function of output mirror reflectivity. Small samples of Nd:YVO4 and Nd:YAG were end pumped at room temperature with a CW 514.5-nm argon ion laser in an almost identical geometrical arrangement which permitted comparative values to be obtained. Assuming that the pumping quantum efficiency of Nd:YVO is similar to that of Nd:YAG, the stimulated-emission cross sections obtained for the 1064- and 1342-nm transitions were respectively 12 x 10 to the -19th and 6.0 x 10 to the -19th/sq cm.

Tucker, A. W.

Rb-Sr and Sm-Nd Study of the D'Orbigny Angrite

D'Orbigny, is a relatively a new angrite find. Angrites are achondrites that show unique mineralogy and typically ancient crystallization ages. D Orbigny has been described extensively by. We have initiated a study of D Orbigny. A Pb-Pb model age of 4559 Ga has been reported. The presence of Pu-244 fission Xe in D Orbigny has also been reported. We present Sm-Nd and Rb-Sr results and a Mn-53-Cr-53 study is in progress. We had expected to find a relatively well-behaved Sm-Nd system, and distinct evidence for the Sm-146-Nd-142 system. Emphasis in this study was placed on the precise measurement of initial Sr-87/Sr-86, since primitive initial Sr-87/Sr-86 may be characteristic of the angrite parent body. Sr isotope measurements were obtained in the recently completed laboratories at JPL, using the ThermoFinnigan Triton mass spectrometer. Due to lower amounts of Nd and Sm, Sm-Nd data were obtained on the Lunatic I spectrometer at Caltech, due to established high ionization techniques, on this instrument using light rare earth oxide ions.

Tonui, E. K.

Rb-Sr And Sm-Nd Ages, and Petrogenesis of Depleted Shergottite Northwest Africa 5990

Northwest Africa (NWA) 5990 is a very fresh Martian meteorite recently found on Hamada du Draa, Morocco and was classified as an olivine-bearing diabasic igneous rock related to depleted shergottites [1]. The study of [1] also showed that NWA 5990 resembles QUE 94201 in chemical, textural and isotopic aspects, except QUE 94201 contains no olivine. The depleted shergottites are characterized by REE patterns that are highly depleted in LREE, older Sm-Nd ages of 327-575 Ma and highly LREE-depleted sources with Nd= +35~+48 [2-7]. Age-dating these samples by Sm-Nd and Rb-Sr methods is very challenging because they have been strongly shocked and contain very low abundances of light rare earth elements (Sm and Nd), Rb and Sr. In addition, terrestrial contaminants which are commonly present in desert meteorites will compromise the equilibrium of isotopic systems. Since NWA 5990 is a very fresh meteorite, it probably has not been subject to significant desert weathering and thus is a good sample for isotopic studies. In this report, we present Rb-Sr and Sm-Nd isotopic results for NWA 5990, discuss the correlation of the determined ages with those of other depleted shergottites, especially QUE 94201, and discuss the petrogenesis of depleted shergottites.

Shih, C. Y.

Inferences about magma sources and mantle structure from variations of Nd-143/Nd-144

Continental flood basalts and mid-ocean ridge (MOR) tholeiitic basalts have distinctly different Nd-143/Nd-144 which may permit a priori distinction between continental and oceanic igneous rocks. Initial Nd-143/Nd-144 of continental igneous rocks through time fall on a Sm/Nd evolution curve with chondritic REE abundance ratio. These observations indicate that many continental igneous rocks are derived from a reservoir with chondritic REE pattern which may represent primary material remaining since the formation of the earth. Oceanic igneous rocks are derived from a different ancient reservoir which has Sm/Nd higher than chondritic. Initial Nd-143/Nd-144 and Sr-87/Sr-86 in young basalts from both oceans and continents show a strong correlation suggesting that Sm-Nd and Rb-Sr fractionation events in the mantle may be correlative and caused by the same process. From this correlation Rb/Sr for the earth is inferred to be 0.029.

Depaolo, D. J.

Sm-Nd-Pu timepieces in the Angra dos Reis meteorite

Isotope ratios and age estimations are presented for the ultramafic pyroxenite Angra dos Reis meteorite. A pyroxene-phosphate internal isochron age of 4.55 plus or minus 0.04 eons was obtained, in agreement with reported Pb-Pb ages. It is suggested that Sm-146 decay led to an increase in the ratio of Nd-142 to Nd-144 in pyroxene, which is greater than the ratio of the Nd isotopes in phosphates. The effect of Pu-244 on the fission xenon components in pyroxene and phosphate is examined. The ratios of Pu-244 to Nd, U-238, and Th-232 are compared for pyroxene and phosphate separates. The exposure age of the meteorite, as obtained by the Kr-81 to Kr-83 method, was found to be 55.5 plus or minus 1.2 million years.

Lugmair, G. W.

Rb-Sr and Sm-Nd chronology and genealogy of mare basalts from the Sea of Tranquility

Rb-Sr and Sm-Nd ages of two Apollo 11 mare basalts, high-K basalt 10072 and low-K basalt 10062, are reported. Rb-Sr, Sm-Nd, and Ar-40-Ar-39 ages are in good agreement and indicate an extensive time interval for filling of the Sea of Tranquility, presumably by thin lava flows, in agreement with similar observations for the Ocean of Storms. Initial Sr and Nd isotopic compositions on Apollo 11 basalts reveal at least two parent sources producing basalts. The Sm-Nd isotopic data demonstrate that low-K and high-Ti basalts from Apollo 11 and 17 derived from distinct reservoirs, while low-Ti Apollo 15 mare basalt sources have Sm/Nd similar to the sources of Apollo 11 basalts. Groupings of mare basalt based on Ti content and on isotopic data do not coincide.

Papanastassiou, D. A.

The Sm-Nd history of KREEP

Sm-Nd whole rock measurements on a variety of KREEP-rich samples from different landing sites are reported. Despite a variation of Nd and Sm concentrations of almost a factor of 3, the Sm-Nd ratios, as well as the Nd-143/Nd-144 values, show an extremely close grouping. No systematic differences between samples from different landing sites are resolved. These results are taken to be indicative of a moon-wide process having been responsible for the generation of the KREEP source reservoir, 4.36 plus or minus 0.06 AE ago, as estimated from model age calculation.

Lugmair, G. W.

Origin and history of the adcumulate eucrite, Moama as inferred from REE abundances, Sm-Nd and U-Pb systematics

The abundances of Sm-Nd and U-Pb isotopes and of rare earth elements (REE) in Moama cumulate eucrite were investigated. The Sm-Nd data plotted on a Nd-143/Nd-144 vs Sm-147/Nd-144 evolution diagram define a line with a slope corresponding to an age of 4.58 plus or minus 0.05 billion years and an initial Nd-143/Nd-144 ratio of about 0.50684. Moama was found to contain the lowest overall trivalent REE abundances, the most light REE-depleted abundance pattern, and largest positive Eu anomaly of any eucrite yet studied. The REE data indicate that Moama could have been derived by about 1 to 5% fractional crystallization from a liquid with REE contents similar to Juvinas, or about 20 to 30% fractional crystallization from a Sioux County-like liquid. The data are consistent with the hypothesis that the Moama, Serra de Mage, and Moore county cumulate meteorites could have been derived from the same parent liquid. Results of the U-Th-Pb study indicate that the majority of the Pb in Moama is of terrestrial origin, and suggest that the meteorite has undergone a minor thermal event causing re-equilibration of the U-Pb system.

Hamet, J.