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All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Modeling and Impact of Solar Energetic Particles in the Heliosphere and Geospace

Understanding the radiation environment due to solar energetic particles in the heliosphere and the Earth’s magnetosphere is a challenging and practically important task. Exposure to energetic particles often leads to malfunctions and unexpected failures of electronics onboard spacecraft. The most vulnerable are exploratory missions when outside of the Earth’s magnetosphere. Geomagnetic field deflects Solar Energetic Particles (SEPs) moving through geospace though some of these particles propagate to LEO and have a high penetrating capability, thus producing significant radiation hazards for human spaceflight. Solar energetic particles also have an essential effect on the composition and dynamics of the Earth’s atmosphere. Precipitating SEPs enhance the atmospheric concentration of NOx and HOx, which play a crucial role in the ozone balance in the middle atmosphere by destroying odd oxygen through catalytic reactions. Numerical modeling of the radiation environment due to SEPs in the inner heliosphere and geospace is a multifold problem. That includes simulating 1) solar wind dynamics and the interplanetary magnetic field, 2) global modeling of the Earth’s magnetosphere, and 3) modeling transport and acceleration of SEPs in the inner heliosphere and geospace. The lecture will outline the key physical processes that control the behavior of SEPs in the heliosphere and geospace, along with the contemporary numerical methods used for their modeling. It will primarily focus on describing the SEP population in geospace across different altitudes, ranging from Low Earth Orbit (LEO) through Medium Earth Orbit (MEO) and Geostationary Orbit (GEO), up to the magnetopause, while considering the realistic geomagnetic field. Additionally, the lecture will cover how the SEP population in geospace varies in response to geomagnetic activity. This includes the temporal trapping of SEPs in geospace and the reduction of the rigidity cutoff during geomagnetic storms.

solar energetic particles↗
NASA NTRS1976

NO sub X destruction by CO in NO sub X to NO converters of chemiluminescent NO analyzers

An instrument modification for chemiluminescent NO - NOx analyzers was developed which minimizes the NOx destruction in the NOx to NO converters of NO analyzers due to high concentrations of CO. This mechanism causes the NO analyzers to indicate incorrect NOx concentrations when the analyzers are operated in the NOx analysis mode. The modification is applicable to analyzers in which the detection chamber is evacuated.

Summers, R. L.↗
DOE OSTI2025

SCILLA nitrogen oxide (NOx) airborne data

Nitrogen oxides mixing ratios in ppb are measured using a Teledyne API Model T200UP. The analyzer uses chemiluminescence to determine NO concentration. Alternating measurement of the concentrations of total NOx (NO + NO2) and just NO are made by directing the sample through a blue light converter that photolyzes NO2 to NO and bypassing it, respectively, with the NO2 concentration calculated as the difference between the two. Sampled air was pulled from above the Naval Postgraduate School’s (NPS) Twin Otter aircraft through a rear-facing, ¼” OD PFA Teflon tube. The sample stream was split between several other gas analyzers (CO, O3, and H2O) and an oxidation flow reactor. The NO, NO2, and NOx mixing ratios were recorded once per minute.

NOx concentration↗
NASA NTRS2001

Sources, Sinks, and the Distribution of OH in the Lower Stratosphere

Extensive measurement campaigns by the NASA ER-2 research aircraft have obtained a nearly pole-to-pole database of the species that control HOx (OH + HO2) chemistry. The wide dynamic range of these in situ measurements provides an opportunity to demonstrate empirically the mechanisms that control the HOx system. Measurements in the lower stratosphere show a remarkably tight correlation of OH concentration with the solar zenith angle (SZA). This correlation is nearly invariant over latitudes ranging from 70 S to 90 N and all seasons. An analysis of the production and loss of HOx in terms of the rate determining steps of reaction sequences developed by Johnston and Podolske and Johnston and Kinnison is used to clarify the behavior of the system and to directly test our understanding of the system with observations. Calculations using in situ measurements show that the production rate of HOx is proportional to O3 and ultraviolet radiation flux. The loss rate is proportional to the concentration and the partitioning of NOy (reactive nitrogen) and the concentration of HO2. In the absence of heterogeneous reactions, the partitioning of NOy is controlled by O3 and NOx and the concentration of HO2 is controlled by NOy and O3, so that the removal rate of OH is buffered against changes in the correlation of O3 and NOy. The heterogeneous conversion of NO2 to HNO3 is not an important net source of HO, because production and removal sequences are nearly balanced. Changes in NOy partitioning resulting from heterogeneous chemistry have a large effect on the loss rates of HOx, but little or no impact on the measured abundance of OH. The enhanced loss rates at high NO2/HNO3 are offset in the data set examined here by enhanced production rates resulting from increased photolysis rates resulting from the decreased O3 column above the ER-2.

Hanisco, T. F.↗
NASA NTRSDate not supplied

Global Burden of Tropospheric Ozone: Effects of Particulate Nitrate Photolysis and Assimilation of NO2 Measurements

Tropospheric ozone is a major pollutant, a greenhouse gas, and the primary source of the hydroxyl radical. It is largely produced in situ from the oxidation of CO and volatile organic compounds in the presence of nitrogen oxides (NOx=NO+NO2). Global atmospheric chemistry models generally underestimate NOx and CO concentrations in the northern hemisphere away from source regions, which would lead to an underestimate in the tropospheric ozone burden. Here we evaluate the tropospheric ozone simulation in the GEOS-Chem model (version 14) using observations from satellite, aircraft, and ozonesondes. We include GEOS-Chem simulations conducted in the standard offline mode, as well as in the online mode within the NASA GEOS earth system model which forms the basis for the GEOS Composition Forecasts (GEOS-CF). In both configurations, GEOS-Chem underestimates ozone concentrations in the northern midlatitude free troposphere in spring and summer. We find that we can improve the ozone simulation by including an additional NOx source over the oceans from particulate nitrate photolysis on sea salt aerosols at rates inferred from field studies over the Atlantic Ocean. We investigate whether further improvements in the ozone simulation can be achieved by assimilating satellite measurements of NO2 from the Ozone Monitoring Instrument (OMI) and CO from the Measurement of Pollution in the Troposphere (MOPITT) instruments.

tropospheric ozone↗
DOE OSTI2024

EPCAPE-PT-LANL Measurements: NO/NOx Analyzer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: NO2/NO/NOx Monitor (2B-Technology) Header: - NO2_2B[ppb]: Concentration of nitrogen dioxide (NO2) measured at the time of the sampling, expressed in parts per billion. - NO_2B[ppb]: Concentration of nitric oxide (NO) measured at the time of the sampling, expressed in parts per billion. - NOx_2B[ppb]: Total concentration of nitrogen oxides (NOx, which includes NO and NO2) measured at the time of the sampling, expressed in parts per billion.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2009

Emission control system

Methods and apparatus utilizing hydrogen peroxide are useful to reduce SOx and mercury (or other heavy metal) emissions from combustion flue gas streams. The methods and apparatus may further be modified to reduce NOx emissions. Continuous concentration of hydrogen peroxide to levels approaching or exceeding propellant-grade hydrogen peroxide facilitates increased system efficiency. In this manner, combustion flue gas streams can be treated for the removal of SOx and heavy metals, while isolating useful by-products streams of sulfuric acid as well as solids for the recovery of the heavy metals. Where removal of NOx emissions is included, nitric acid may also be isolated for use in fertilizer or other industrial applications.

Parrish, Clyde F.↗
DOE OSTI2026

Measured Indoor Nitrogen Oxides in Homes with a Child with Asthma and Gas or Induction Electric Cooking

The Cooking Energy and Ventilation Impacts on Children's Asthma (CEVICA) study is a randomized control trial investigating the effects of replacing gas with induction electric ranges in the homes of children with asthma in California's San Joaquin Valley. Indoor air quality parameters and respiratory health indicators were measured over 2-week intensive at Baseline and after consecutive 3-month study phases, with half getting electric cooking at the start of Phase 1 and others in Phase 2. Indoor air measurements included time-integrated NO 2 and NO X by passive sampler and time-resolved NO 2 by electrochemical sensors. In the first 40 homes, data were collected during 61 intensives for gas cooking and 55 for induction. Cooking was identified using temperature sensors above the cooktop. Pollutant events were identified from sharp rises in concentrations Time integrated NOX species were lower with electric cooking, with mean differences of 14.2 ppb for NO 2 (95% CI: 9.6, 18.7; p < 0.001), 55.6 ppb for NO X (95% CI: 30.4, 80.9; p < 0.001), and 41.5 ppb for derived NO (95% CI: 19.7, 63.2; p < 0.001). A paired, within home analysis showed larger reductions in Group 2 (gas to induction) than Group 1 that remained electric across Phase 1 and Phase 2 for NO 2 (mean difference in As of 10.5 ppb; 95% CI: 5.6, 15.4; p < 0.001), NO X (32.3 ppb; 95% CI: 10.0, 54.5; p=0.007), and derived NO (21.8 ppb; 95% CI: 3.6, 40.0; p=0.022). Compared to electric cooking, gas had much higher rates of associated NO 2 events, and larger above-baseline NO 2 peaks. These preliminary results are consistent with prior findings that shifting to induction cooking can substantially lower indoor NO 2 compared with gas cooking.

Fang, Yi↗
NASA NTRS1980

Comparison of measured ozone in southeastern Virginia with computer predictions from a photochemical model

Data for one day of the 1977 southeastern Virginia urban plume study are compared with computer predictions from a traveling air parcel model using a contemporary photochemical mechanism with a minimal description of nonmethane hydrocarbon (NMHC) constitution and chemistry. With measured initial NOx and O3 concentrations and a current separate estimate of urban source loading input to the model, and for a variation of initial NMHC over a reasonable range, an ozone increase over the day is predicted from the photochemical simulation which is consistent with the flight path averaged airborne data.

Wakelyn, N. T.↗
NASA NTRS2004

Surface-Satellite Measurements for Atmospheric Radiative Transfer (SMART)and Chemical, Optical and Microphysical Measurements of In-Situ Troposphere (COMMIT) Research Activities

The GSFC SMART consists of a suite of remote sensing instruments, including many commercially available radiometers, spectrometer, interferometer, and three in-house developed inskuments: micro-pulse lidar (MPL), scanning microwave radiometer (SMiR), and sun-sky-surface photometer (S(sup 3)). SMART cover the spectral range from UV to microwave, and passive to active remote sensing. This is to enrich the EOS-like research activities (i.e., EOS validation, innovative investigations, and long-term local environmental observations). During past years, SMART has been deployed in many NASA supported field campaigns to collocate with satellite nadir overpass for intercomparisons, and for initializing model simulations. Built on the successful experience of SMART, we are currently developing a new ground-based in-situ sampling package, COMMIT, including measurements of trace gases (CO, SO2, NOx, and O3,) concentrations, fine/coarse particle sizers and chemical composition, single- and three-wavelength nephelometers, and surface meteorological probes. COMMIT is built for seeking a relationship between surface in-situ measurements and boundary layer characteristics. This is to enrich EOS-like research on removing boundary layer signal from the entire column from space observation - to deduce the stable (less variability) free-troposphere observations. The COMMIT will try its best to link the chemical, microphysical, and optical properties of the boundary layer with radiation. The next major activities for SMART-COMMIT are scheduled for 2004-2006 in BASE-ASIA and EAST-AIRE. The expected close collaboration of BASE-ASIA with various research projects in Asia (i.e., ABC in South Asia, led by Ramanathan et al.; EAST-AIRE in East Asia, led by Li et al.; and APEX in Northeast Asia, led by Nakajima et al.) will definitely provide a better understanding of the impact of the biomass burning and air pollutants on regional-to-global climate, hydrological and carbon cycles, and tropospheric chemistry in Asia.

Tsay, Si-Chee↗
NASA NTRS2016

Production of Peroxy Nitrates in Boreal Biomass Burning Plumes over Canada During the BORTAS Campaign

The observations collected during the BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites (BORTAS) campaign in summer 2011 over Canada are analysed to study the impact of forest fire emissions on the formation of ozone (O3 and total peroxy nitrates (sigma)PNs, (sigma)ROONO2. The suite of measurements on board the BAe-146 aircraft, deployed in this campaign, allows us to calculate the production of O3 and of (sigma)PNs, a long-lived NOx reservoir whose concentration is supposed to be impacted by biomass burning emissions.In fire plumes, profiles of carbon monoxide (CO), which is a well-established tracer of pyrogenic emission, show concentration enhancements that are in strong correspondence with a significant increase of concentrations of (sigma)PNs, where as minimal increase of the concentrations of O3 and NO2 is observed. The (sigma)PN and O3 productions have been calculated using the rate constants of the first- and second-order react Pions of volatile organic compound (VOC) oxidation. The (sigma)PN and O3 productions have also been quantified by 0-D model simulation based on the Master Chemical Mechanism. Both methods show that in fire plumes the average production of (sigma)PNs and O3 are greater than in the background plumes, but the increase of (sigma)PN production is more pronounced than the O3 production. The average (sigma)PN production in fire plumes is from 7 to 12 times greater than in the background, whereas the average O3 production in fire plumes is from 2 to 5 times greater than in the background. These results suggest that, at least for boreal forest fires and for the measurements recorded during the BORTAS campaign,fire emissions impact both the oxidized NOy and O3;but (1)(sigma)PN production is amplified significantly more thanO3 production and (2) in the forest fire plumes the ratio between the O3 production and the (sigma)PN production is lower than the ratio evaluated in the background air masses, thus confirming that the role played by the (sigma)PNs produced during biomass burning is significant in the O3 budget. The implication of these observations is that fire emissions in some cases, for example boreal forest fires and in the conditions reported here, may influence more long-lived precursors of O3than short-lived pollutants, which in turn can be transported and eventually diluted in a wide area.

biomass burning↗
NASA NTRSDate not supplied

Energetic Particles in Geospace: Origin, Dynamics, and Modeling

This presentation explores the origins and dynamics of energetic particles—specifically solar energetic particles (SEPs) and galactic cosmic rays (GCRs) - within the heliosphere and Earth's magnetosphere. We will discuss the fundamental physical processes governing their transport and acceleration in the heliosphere, including interactions with the solar wind and the interplanetary magnetic field. The penetration of these particles into Earth's magnetosphere is examined, emphasizing how the geomagnetic field influences their propagation across the magnetosphere. Key phenomena such as the temporal trapping of SEPs in geospace, reductions in rigidity cutoff during geomagnetic storms, and the enhancement of atmospheric NOx and HOx concentrations - which affect the ozone balance through catalytic reactions—are discussed. The presentation also outlines contemporary numerical modeling techniques used to simulate SEPs and GCRs, providing insights into their complex behaviors under varying geomagnetic conditions.

solar energetic particles↗
NASA NTRS1980

A model of CO-CH4 global transport/chemistry. I - Chemistry model

A simplified chemistry model was developed to incorporate the CO-CH4 chemistry into the global transport model of these compounds. CO is important because of its effects on atmospheric chemistry and is partly responsible for controlling the hydroxyl radical (OH) concentration in the troposphere. The model includes the photodissociation rate coefficients expressed as functions of solar zenith angle and altitude, and it was applied to determine the sensitivity of the OH concentration to trace gaseous species, such as NOx, O3, and H2O. Also, the concentrations and diurnal variations of OH and HO2, and the contribution of individual reactions to OH generation and consumption were calculated.

Peters, L. K.↗
NASA NTRS1981

A diagnostic model for studying daytime urban air quality trends

A single cell Eulerian photochemical air quality simulation model was developed and validated for selected days of the 1976 St. Louis Regional Air Pollution Study (RAPS) data sets; parameterizations of variables in the model and validation studies using the model are discussed. Good agreement was obtained between measured and modeled concentrations of NO, CO, and NO2 for all days simulated. The maximum concentration of O3 was also predicted well. Predicted species concentrations were relatively insensitive to small variations in CO and NOx emissions and to the concentrations of species which are entrained as the mixed layer rises.

Brewer, D. A.↗
DOE OSTI2026

Biochemical Conversion of Herbaceous Biomass to Renewable Diesel: Biorefinery Marginal Air Quality Impacts and Comparison to Feedstock Production

This study assesses the air quality impacts of an advanced biorefinery that produces renewable diesel blendstock (RDB) from lignocellulosic biomass via aerobic respiration (Davis et al. 2022) by estimating fine particulate matter (PM2.5) impacts from biorefinery emissions. It continues a prior analysis that used a geospatial assessment to identify source regions for biomass feedstocks and studied the impact of feedstock production emissions on air quality (Thind et al. 2022). Thind et al. (2022) identified RDB biorefineries that can use corn stover feedstocks of 2,000; 5,200; and 9,100 dry metric tons per day (DMT/day), based in Iowa, and suggested 7 unique counties can serve as hosts for a biorefinery that draws biomass feedstock from neighboring counties. Given 13 unique county-biorefinery size combinations and two waste lignin end uses at the biorefinery (lignin as a fuel for electricity generation and lignin for pellet production), the air-quality-related sustainability aspects of each of these 26 scenarios are assessed by estimating the annual average impacts of biorefinery emissions on the dispersion and formation of secondary PM2.5 in the atmosphere using a novel reduced-complexity air quality model called the Intervention Model for Air Pollution (InMAP). The 26 biorefinery design combinations help capture how a biorefinery's emissions of air pollutants and their resulting impact on local and regional air quality are influenced by the magnitude of production scale, lignin utilization strategy, and location of a proposed biorefinery. Methods developed in Thind et al. (2022) are applied to estimate the constraints on primary PM2.5 and secondary PM2.5 precursor emissions based on compliance with U.S. Environmental Protection Agency's (EPA's) annual primary National Ambient Air Quality Standard (NAAQS) of PM2.5 (i.e.12.0 micrograms per cubic meter (microgram/m3)) at downwind receptors of a biorefinery. Incremental PM2.5 concentrations caused by the emission of biorefining corn stover into RDB are assessed and compared to those of corn stover production. To illuminate which upstream supply chain stage of renewable diesel production contributes most to air quality impacts, marginal PM2.5 concentrations are compared between both stages at multiple downwind air quality monitor locations. In addition, through a hotspot analysis, we identify the primary contributing factors of emissions within the feedstock production and biorefinery stage operations. In doing so, we provide insights for improving the air pollutant emission-related sustainability of advanced lignocellulosic biofuel production.

09 BIOMASS FUELS↗
NASA NTRS2019

Applications of GLM Data for National Climate Assessment (NCA) Studies

The Geostationary Lightning Mapper (GLM) offers a new and exciting way to probe lightning/climate inter-relationships, and therefore supports the National Climate Assessment (NCA) program. In particular, there is a desire to use GLM to estimate lightning nitrogen oxides (LNOx) since trace quantities of NOx affect greenhouse gas concentrations (e.g., ozone).

Koshak, W. J.↗
NASA NTRSDate not supplied

Evaluating the Impact of Agricultural Soil NOx Emissions on Air Quality Using Advanced Satellite, Ground-based, and Model Data

Soil moisture can also influence the concentration of atmospheric trace gases by moderating the emission of nitrogen oxides (NOx = NO + NO2) from agricultural fields. Human activities can play an important role in controlling the available soil moisture depending on irrigation demand and agricultural management. To further complicate matters, nitrogen fertilizer use has also been found to be a significant source of NOx emissions in agricultural areas. In fact, some of the highest emissions have been reported from fertilized soils in high-temperature agricultural regions, such as the Imperial Valley of California. Since NO2 is an important precursor to ozone formation in the troposphere, which is a leading cause of premature death in humans, it is critical to understand how natural and anthropogenic factors contribute to NOx emissions in these areas. O3 pollution is also a growing threat to global food security due to its detrimental impacts on crop production. This work uses a suite of satellite, ground-based, and model data to investigate how agricultural soil NOx emissions from natural (rainfall) and anthropogenic factors (irrigation, nitrogen fertilizer) govern air quality over California. We evaluate the capabilities of using SMAP retrievals and SMAP Land Information System (LIS) output for monitoring irrigation activities over the major agricultural areas of California by conducting intensive analyses of soil moisture and precipitation data. High-resolution trace gas observations from the new generation TROPOspheric Monitoring Instrument (TROPOMI) sensor are used to characterize and monitor the variability of trace gases and air quality conditions associated with soil NOx emissions. We also synthesize satellite, ground-based, and agriculture data to estimate the separate contributions from rainfall, irrigation, and nitrogen fertilizer practices on soil NOx emissions and associated air quality conditions. Finally, unprecedented hourly trace gas retrievals from the NASA Tropospheric Emissions: Monitoring of Pollution (TEMPO) geostationary satellite sensor are used to monitor the diurnal evolution of NO2 and O3 concentrations from soil NOx emissions.

Aaron R Naeger↗
NASA NTRS1979

Launch vehicle effluent measurements during the August 20, 1977, Titan 3 launch at Air Force Eastern Test Range

Airborne effluent measurements within the launch cloud and visible and infrared measurements of cloud physical behavior are discussed. Airborne effluent measurements include concentrations of HCl, Cl2, NO, NOX, and particulates as a function of time during each sampling pass through the exhaust cloud. The particle size distribution was measured for each pass through the cloud. Mass concentration as a function of particle diameter was measured over the size range of 0.05- to 25 micron diameter, and particle number density was measured as a function of diameter over a size range of 0.5 to 7.5 micron. Effluent concentrations in the cloud ranged from about 30 ppm several minutes after launch to about 1 to 2 ppm at 100 minutes. Maximum Cl2 concentrations were about 40 to 55 ppb and by 20 minutes were less than 1.0 ppb. A tabulated listing of the airborne data is given in the appendix. Usable cloud imaging data were limited to the first 16 minutes after launch.

Woods, D. C.↗