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22 records · Page 2

Data-Driven Optimization of Pixelated CdZnTe Spectrometers for Uranium Enrichment Assay

Here, in recent work [Vavrek et al. (2025)], we developed the performance optimization framework spectre-ml for gamma spectrometers with variable performance across many readout channels. The framework uses non-negative matrix factorization (NMF) and clustering to learn groups of similarly-performing channels and sweep through various learned channel combinations to optimize the performance tradeoff of including worse-performing channels for better total efficiency. In this work, we integrate the pyGEM uranium enrichment assay code with our spectre-ml framework, and show that the U-235 enrichment relative uncertainty can be directly used as an optimization target. We find that this optimization reduces relative uncertainties after a 30 -minute measurement by an average of 20%, as tested on six different H3D M400 CdZnTe spectrometers, which can significantly improve uranium non-destructive assay measurement times in nuclear safeguards contexts. Additionally, this work demonstrates that the spect re-ml optimization framework can accommodate arbitrary end-user spectroscopic analysis code and performance metrics, enabling future optimizations for complex Pu spectra.

Gamma-ray detection

A comparative survey of current and proposed tropospheric refraction-delay models for DSN radio metric data calibration

The standard tropospheric calibration model implemented in the operational Orbit Determination Program is the seasonal model developed by C. C. Chao in the early 1970's. The seasonal model has seen only slight modification since its release, particularly in the format and content of the zenith delay calibrations. Chao's most recent standard mapping tables, which are used to project the zenith delay calibrations along the station-to-spacecraft line of sight, have not been modified since they were first published in late 1972. This report focuses principally on proposed upgrades to the zenith delay mapping process, although modeling improvements to the zenith delay calibration process are also discussed. A number of candidate approximation models for the tropospheric mapping are evaluated, including the semi-analytic mapping function of Lanyi, and the semi-empirical mapping functions of Davis, et. al.('CfA-2.2'), of Ifadis (global solution model), of Herring ('MTT'), and of Niell ('NMF'). All of the candidate mapping functions are superior to the Chao standard mapping tables and approximation formulas when evaluated against the current Deep Space Network Mark 3 intercontinental very long baselines interferometry database.

Estefan, J. A.

MIT Haystack Observatory Analysis Center Report

The data from twenty years of the NCEP numerical weather model have been used to calculate the IMF hydrostatic mapping function for several sites distributed in latitude from -66 degrees to +78 degrees. Comparison of heights estimated with the NMF hydrostatic mapping function demonstrates that using NMFh results in height errors at annual and semi-annual periods with amplitudes as large as approximately 8 mm and 4 mm, respectively, when data down to 5 degrees are included. The errors are smallest at the equator and increase towards the poles.

Niell, Arthur

Predicting High‐Resolution Spatial and Spectral Features in Mass Spectrometry Imaging with Machine Learning and Multimodal Data Fusion

Recent advancements in molecular Mass Spectrometry Imaging have sparked interest in integrating high spatial resolution methods with molecular mass-spectrometry-based chemical imaging. Fusion-based algorithms have proven effective in generating high spatial-resolution molecular mass spectra. However, a significant challenge stems from the differing physical mechanisms underlying image generation and data upsampling techniques, potentially leading to discrepancies in integrated information channels. Integrating physical constraints into data processing workflows is essential to tackle this issue. In this study, we propose an innovative approach that merges data from Fourier transform ion cyclotron resonance (FTICR), time-of-flight matrix-assisted laser desorption/ionization, and time-of-flight secondary ion mass spectrometry imaging techniques. By leveraging FT-ICR's unparalleled spectral resolution and ToF-SIMS's exceptional spatial resolution, we achieve submicron spatial resolution, enabling the observation of intact molecular species with remarkable spectral precision. Canonical correlation analysis is employed to incorporate physical constraints. Through sophisticated image processing and machine learning techniques, the results of this fusion hold significant promise for advancing our comprehension of complex systems and unveiling concealed molecular intricacies.

canonical correlation analysis