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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Challenging Issues for On-orbit Calibration in the VIS and NIR

On-orbit calibration of Earth-observing sensors in the VIS and NIR spectral regions is usually performed using the sensors on-board devices such as internal lamp(s) or solar diffuser plate(s) to provide calibration parameters. For sensors with no (or with less reliable) on-board calibrators, lunar calibration or ground validation approaches are often used. Each of these has its own set of problems that need to be fully addressed in order to support high quality on-orbit calibration and characterization. Some science products, such as Ocean color, may impose more stringent requirements that demand greater calibration precision. This paper uses MODIS as an example to illustrate challenging issues involved in VIS and NIR on-orbit calibration. It focuses on the solar diffuser (SD) calibration approach, including the effects due to SD BRF, SD attenuation screen(s), and earthshine. The impact of optics (solar diffuser and scan mirror) on-orbit degradation, including changes in the sensor s response versus scan angle (RVS), on the calibration and subsequent data quality is also discussed.

Xiong, X.↗
NASA NTRS2005

Phase 2 of Comparative NIR Detector Characterization for NGST

In accordance with NASA Grant and Cooperative Agreement Handbook, 1260.75 (c) (3), enclosed please find a citation of publications resulting from research for the above referenced grant entitled, "Phase II of Comparative NIR Detector Characterization for NGST." This list can also be accessed at http://idtl.stsci.edu/publications.htm. This project was completed with the failure of two Rockwell NIR detectors. The originally proposed measurements could not be completed.

Figer, Donald↗
NASA NTRS2016

Assessment of SNPP VIIRS VIS NIR Radiometric Calibration Stability Using Aqua MODIS and Invariant Surface Targets

The first Visible Infrared Imaging Radiometer Suite (VIIRS) is onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite. As a primary sensor, it collects imagery and radiometric measurements of the land, atmosphere, cryosphere, and oceans in the spectral regions from visible (VIS) to long-wave infrared. NASA's National Polar-orbiting Partnership (NPP) VIIRS Characterization Support Team has been actively involved in the VIIRS radiometric and geometric calibration to support its Science Team Principal Investigators for their independent quality assessment of VIIRS Environmental Data Records. This paper presents the performance assessment of the radiometric calibration stability of the VIIRS VIS and NIR spectral bands using measurements from SNPP VIIRS and Aqua MODIS simultaneous nadir overpasses and over the invariant surface targets at the Libya-4 desert and Antarctic Dome Concordia snow sites. The VIIRS sensor data records (SDRs) used in this paper are reprocessed by the NASA SNPP Land Product Evaluation and Analysis Tool Element. This paper shows that the reprocessed VIIRS SDRs have been consistently calibrated from the beginning of the mission, and the calibration stability is similar to or better than MODIS. Results from different approaches indicate that the calibrations of the VIIRS VIS and NIR spectral bands are maintained to be stable to within 1% over the first three-year mission. The absolute calibration differences between VIIRS and MODIS are within 2%, with an exception for the 0.865-m band, after correction of their spectral response differences.

Wu, Aisheng↗
NASA NTRS2012

Near-Infrared (NIR) Raman Spectroscopy of Precambrian Carbonate Stromatolites with Post-Depositional Organic Inclusions

Raman spectroscopy has promising potential for future Mars missions as a non-contact detection technique for characterizing organic material and mineralogy. Such a capability will be useful for selecting samples for detailed analysis on a rover and for selecting samples for return to Earth. Stromatolites are important evidence for the earliest life on Earth and are promising targets for Mars investigations. Although constructed by microorganisms, stromatolites are organo-sedimentary structures that can be large enough to be discovered and investigated by a Mars rover. In this paper, we report the Raman spectroscopic investigations of the carbonate mineralogy and organic layering in a Precambrian (;1.5 Gyr old) stromatolite from the Crystal Spring Formation of Southern California. Ultraviolet (UV: 266 nm), visible (514 nm, 633 nm), and near-infrared (NIR: 785 nm, 1064 nm) Raman spectra are presented. We conclude that 1064 nm excitation is the optimal excitation wavelength for avoiding intrinsic fluorescence and detecting organic carbon within the carbonate matrix. Our results confirm that NIR Raman spectroscopy has important applications for future Mars missions.

Tanaka, Zuki↗
NASA NTRS2018

Fabrication and Characterization of a NIR-FIR Dichroic for the Infrared Interferometer BETTII

BETTII is a balloon-borne far infra-red (FIR: 30-100 µm) interferometer that also uses a near-infrared (NIR: 1-2.5 µm) channel for fine pointing sensing using stars. We have developed an inductive grid dichroic to divide the incoming beam into two components, by reflecting FIR light and transmitting NIR light. The dichroic is fabricated using focused electron beam technology to produce a 1 µm period, 100 nm width metal grid on a sapphire substrate in order to have high reflectance for FIR wavelengths. Here we discuss the design and the detailed manufacturing process for such a dichroic. The transmission and reflectance characteristics are also presented. We discuss them in context of the BETTII requirements.

Dhabal, Arnab↗
DOE OSTI2025

Shifting the MLCT of d 6 metal complexes to the red and NIR

Light-active d 6 -coordination compounds hold great promise for light energy conversion, sensors and therapeutic applications. However, the activity in the red-to-NIR spectral region is highly desirable to convert solar light more efficiently, use low-cost red-light sources and activate these chromophores in biological tissue environment. Due to their versatility, tunability and broad intense absorption, d 6 -coordination compounds with metalto-ligand charge transfer (MLCT) transitions are especially interesting. This review article offers a comprehensive collection of strategies to tune MLCT excited states in d 6 metal complexes and gives insights on group 6 to group 9 transition metals and their respective state-of-the-art MLCT engineering towards red-shifted absorption and emission properties with long-lived excited states. Strategies comprise lowering the π* level of the ligands, destabilizing and mixing of the metal-based HOMO, switching within a group of transition metals, matrix effects and insights into dealing with excited state deactivation in the context of the energy gap law.

Metal to ligand charge transfer (MLCT)↗
NASA NTRS2014

Observation of Mountain Lee Waves with MODIS NIR Column Water Vapor

Mountain lee waves have been previously observed in data from the Moderate Resolution Imaging Spectroradiometer (MODIS) "water vapor" 6.7 micrometers channel which has a typical peak sensitivity at 550 hPa in the free troposphere. This paper reports the first observation of mountain waves generated by the Appalachian Mountains in the MODIS total column water vapor (CWV) product derived from near-infrared (NIR) (0.94 micrometers) measurements, which indicate perturbations very close to the surface. The CWV waves are usually observed during spring and late fall or some summer days with low to moderate CWV (below is approx. 2 cm). The observed lee waves display wavelengths from3-4 to 15kmwith an amplitude of variation often comparable to is approx. 50-70% of the total CWV. Since the bulk of atmospheric water vapor is confined to the boundary layer, this indicates that the impact of thesewaves extends deep into the boundary layer, and these may be the lowest level signatures of mountain lee waves presently detected by remote sensing over the land.

satellite remote sensing↗
DOE OSTI2026

UV–Vis–NIR Reflectance Spectroscopy and Chemometrics for Monitoring Pu Directly on an Ion Exchange Column

Here, we present a fiber-optic UV–vis–NIR reflectance spectroscopy method for direct, noninvasive monitoring of Pu(IV) in a glass ion exchange column during dynamic loading and elution in a glovebox. A movable probe enables spatially resolved spectral acquisition along the column axis, capturing distinct features associated with Pu(IV) nitrate complexes during loading and free ions during elution. Principal component analysis was applied to extract the dominant spectral variance and resolve relative concentration profiles without requiring precise knowledge of optical penetration depth or species identity. This in situ approach reveals spatial gradients and speciation dynamics in real time, which provides actionable insight into Pu(IV) ion migration, resin saturation, and breakthrough behavior under evolving flow conditions. The method offers a practical, fiber-compatible strategy to monitor glass column–based separations for Pu and other lanthanides or actinides and to characterize metal–resin interactions in flow-through systems.

actinide↗
DOE OSTI2025

Above the Energy Gap Law: Heavy Chalcogenide Substitution in NIR II-Emissive Diradicaloid Qubits

Near-infrared (NIR, 700–1700 nm)- and telecom (∼1260–1625 nm)-emissive molecules are good candidates for biological imaging and quantum sensing applications, respectively; however, bright low energy emission is rare due to exponentially increasing nonradiative decay rates in these regions, a phenomenon known as the energy gap law. Recent literature has emphasized the importance of minimizing skeletal modes to prevent increased nonradiative decay rates, but most organic lumiphores in these regions utilize large, conjugated scaffolds containing many C═C modes. Here we report a compact, telecom-emissive scaffold, tetrathiafulvalene-2,3,6,7-tetraselenate, or TTFts, that displays remarkable air, water, and acid stability, exhibits record quantum yields and brightness values, and retains quantum coherence under ambient conditions. These properties are enabled through methodical selenium substitution, which bathochromically shifts emission while shifting skeletal vibrations to lower energies. This new scaffold validates heavy heteroatom substitution strategies and establishes a new class of bright telecom emitters and robust qubits.

biological imaging↗
DOE OSTI2025

Fiber-Coupled Multipass NIR Sensor for In Situ, Real-Time Water Vapor Outgassing Monitoring

This work presents the recent development of a fiber-coupled multipass near-infrared (NIR) gas sensor used to monitor water vapor desorption of small material coupons. The gas sensor design employs a White cell topology to maximize the optical path length over a compact, hand-size footprint. Water vapor concentrations are quantified over a large dynamic range by simultaneously applying wavelength modulation and tunable diode laser absorption spectroscopy techniques. A custom headspace optimized for material desorption experiments is assembled using commercially available vacuum chamber components. We provide in situ measurements of water vapor desorption from two geometries of the industrially important silicone elastomer Sylgard-184 as a case study for sensor viability. To corroborate the results, the gas sensor data are compared to numerical simulations based on a triple-mode diffusion–sorption model, consisting of Henry, Langmuir, and Pooling modes.

gas sensor↗
NASA NTRS1997

A new network of faint calibration stars from the near infrared spectrometer (NIRS) on the IRTS

The point source extraction and calibration of the near infrared spectrometer (NIRS) onboard the Infrared Telescope in Space (IRTS) is described. About 7 percent of the sky was observed during a one month mission in the range of 1.4 micrometers to 4 micrometers. The accuracy of the spectral shape and absolute values of calibration stars provided by the NIRS/IRTS were validated.

Freund, Minoru M.↗
NASA NTRS2004

Comparative NIR Detector Characterization for NGST

List of publications for final perfomance report are: Detectors for the JWST Near-Infrared Spectrometer Rauscher, B.J., Strada, P., Regan, M.W., Figer, D.F., Jakobsen, P., Moseley, H.S., & Boeker, T. 2004, SPIE Detectors for the JWST Near-Infrared Spectrometer Rauscher, B.J., Strada, P., Regan, M.W., Figer, D.F., Jakobsen, P., Moseley, H.S., & Boeker, T. 2004, AAS, 203, 124.07 Independent Testing of JWST Detector Prototypes Figer, D.F., Rauscher, B. J., Regan, M. W., Morse, E., Balleza, J., Bergeron, L., & Stockman, H. S. 2003 , SPIE, 5 167 The Independent Detector Testing Laboratory and the NGST Detector Program Figer, D.F., Agronin, M., Balleza, J., Barkhouser, R., Bergeron, L., Greene, G. R., McCandliss, S. R., Rauscher, B. J., Reeves, T., Regan, M. W., Sharma, U., Stockman, H. S. 2003, SPIE, 4850,981 Intra-Pixel Sensitivity in NIR Detectors for NGST Sharma, U., Figer, D.F., Sivaramakrishnan, A., Agronin, M., Balleza, J., Barkhouser, R., Bergeron, L., Greene, G. R., McCandliss, S. R., Rauscher, B. J., Reeves, T., Regan, M. W., Stockman, H. S. 2003, SPIE, 4850,1001 NIRCAM Image Simulations for NGST Wavefiont SensinglPS A. Sivaramakrishnan, D. Figer, H. Bushouse, H. S. Stockman (STScI),C. Ohara , D. Redding (JPL), M. Im (IPAC), & J. Offenberg (Raytheon) 2003, SPIE, 4850,388 Ultra-Low Background Operation of Near-Infrared Detectors for NGS Rauscher, B. J., Figer, D. F., Agronin, M., Balleza, J., Barkhouser, R., Bergeron, L., Greene, G. R., McCandliss, S. R., Reeves, T., Regan, M. W., Sharma, U., Stockman, H. S. 2003, SPIE, 4850,962 The Independent Detector Testing Laboratory and the JWST Detector Program Figer, D.F. et a1.2003, AAS201, #131.05

Greenhouse, Matthew↗
NASA NTRS2008

Tetravalent chromium doped laser materials and NIR tunable lasers

A method is described to improve and produce purer Cr.sup.4+-doped laser materials and lasers with reduced co-incorporation of chromium in any other valence states, such as Cr.sup.3+, Cr.sup.2+, Cr.sup.5+, and Cr.sup.6+. The method includes: 1) certain crystals of olivine structure with large cation (Ca) in octahedral sites such as Cr.sup.4+:Ca.sub.2GeO.sub.4, Cr.sup.4+:Ca.sub.2SiO.sub.4, Cr.sup.4+:Ca.sub.2Ge.sub.xSi.sub.1-xO.sub.4 (where 0<x<1), and/or 2) high-temperature solution growth techniques that enable the growth of the crystals below the temperature of polymorphic transitions by using low melting point solvent based on oxide, fluoride and/or chloride compounds. Purer Cr.sup.4+-doped laser materials are characterized by a relatively high concentration of Cr.sup.4+-lasing ion in crystalline host that makes these materials suitable for compact high power (thin disk/wedge) NIR laser applications.

Alfano, Robert R.↗
NASA NTRS2012

High-Contrast NIR Polarization Imaging of MWC480

One of the key predictions of modeling from the IR excess of Herbig Ae stars is that for protoplanetary disks, where significant grain growth and settling has occurred, the dust disk has flattened to the point that it can be partially or largely shadowed by the innermost material at or near the dust sublimation radius. When the self-shadowing has already started, the outer disk is expected to be detected in scattered light only in the exceptional cases that the scale height of the dust disk at the sublimation radius is smaller than usual. High-contrast imaging combined with the IR spectral energy distribution allow us to measure the degree of flattening of the disk, as well as to determine the properties of the outer disk. We present polarimetric differential imaging in H band obtained with Subaru/HiCIAO of one such system, MWC 480. The HiCIAO data were obtained at a historic minimum of the NIR excess. The disk is detected in scattered light from 0".2-1"0 (27.4-137 AU). Together with the marginal detection of the disk from 1998 February 24 by HST / NICMOS, our data constrain the opening half angle for the disk to lie between 1.3 <= Theta <=2.2 deg. When compared with similar measures in CO for the gas disk from the literature, the dust disk subtends only approx 30% of the gas disk scale height (H/R approx 0. 03). Such a dust disk is a factor of 5-7 flatter than transitional disks, which have structural signatures that giant planets have formed.

McElwain, M. W.↗
NASA NTRS2011

Deep UV to NIR Space Telescopes and Exoplanet Coronagraphs: A Trade Study on Throughput, Polarization, Mirror Coating Options and Requirements

The NASA Exoplanet program and the Cosmic Origins program are exploring technical options to combine the visible to NIR performance requirements of a space coronagraph with the general astrophysics requirements of a space telescope covering the deep UV spectrum. Are there compatible options in terms of mirror coatings and telescope architecture to satisfy both goals? In this paper, we address some of the main concerns, particularly relating to polarization in the visible and throughput in the UV. Telescope architectures employing different coating options compatible with current technology are considered in this trade study.

coronagraph↗
NASA NTRS2018

Calibration of the DSCOVR EPIC Visible and NIR Channels using MODIS Terra and Aqua Data and EPIC Lunar Observations

The unique position of the Deep Space Climate Observatory (DSCOVR) Earth Polychromatic Imaging Camera (EPIC) at the Lagrange 1 point makes an important addition to the data from currently operating low Earth orbit observing instruments. EPIC instrument does not have an onboard calibration facility. One approach to its calibration is to compare EPIC observations to the measurements from polar-orbiting radiometers. Moderate Resolution Imaging Spectroradiometer (MODIS) is a natural choice for such comparison due to its well-established calibration record and wide use in remote sensing. We use MODIS Aqua and Terra L1B 1km reflectances to infer calibration coefficients for four EPIC visible and NIR channels: 443, 551, 680 and 780 nm. MODIS and EPIC measurements made between June 2015 and 2016 are employed for comparison. We first identify favorable MODIS pixels with scattering angle matching temporarily collocated EPIC observations. Each EPIC pixel is then spatially collocated to a subset of the favorable MODIS pixels within 25 km radius. Standard deviation of the selected MODIS pixels as well as of the adjacent EPIC pixels is used to find the most homogeneous scenes. These scenes are then used to determine calibration coefficients using a linear regression between EPIC counts/sec and reflectances in the close MODIS spectral channels. We present thus inferred EPIC calibration coefficients and discuss sources of uncertainties. The lunar EPIC observations are used to calibrate EPIC O2 absorbing channels (688 and 764 nm), assuming that there is a small difference between moon reflectances separated by approx.10 nm in wavelength provided the calibration factors of the red (680 nm) and near-IR (780 nm) are known from comparison between EPIC and MODIS.

Geogdzhayev, Igor V.↗
NASA NTRSDate not supplied

Principal Component-Based Radiative Transfer Model (PCRTM) for Hyperspectral Remote Sensors for UV, VVIS, NIR, IR, and FIR Spectral Regions

Fast and accurate radiative transfer models are needed to efficiently process satellite hyperspectral remote sensors. We have developed a Principal Component-based radiative transfer model (PCRTM) which can simulate TOA radiance or reflectance spectra in the cloudy atmosphere for far IR, IR, NIR, VIS, and UV spectral regions quickly and accurately. Multi-scattering of multiple layers of clouds/aerosols is included in the model. Polarization components can also be calculated. The computation speed is 3 to 4 orders of magnitude faster than MODTRAN5, LBLRTM, and VLIDORT. The PCRTM calculated radiance spectra agree with reference RTM calculated radiance spectra very well (0.03 K in IR and 0.05% in solar). Comparisons of the PCRTM model calculations with observed AIRS, CrIS, IASI, NAST-I, and SCIAMACHY data will be presented. The solar-PCRTM has been developed for CLARREO PathFinder (CPF) and has been extensively used for CPF science algorithms. The PCRTM can also be used for many current and future NASA future missions such as EMIT, SBG, TEMPO, and PACE.

pcrtm↗