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N2O is Cyanogen Chloride-derived structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of four hydroxylamine, o-amino- molecules. N1+ is bonded in a single-bond geometry to one O2- atom. The N–O bond length is 1.20 Å. O2- is bonded in a linear geometry to two equivalent N1+ atoms.
NO2 is beta Polonium structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ~{n}-(hydroxyamino)peroxyhydroxylamine molecules. N is bonded in a water-like geometry to two O atoms. There is one shorter (1.16 Å) and one longer (1.66 Å) N–O bond length. There are two inequivalent O sites. In the first O site, O is bonded in a water-like geometry to one N and one O atom. The O–O bond length is 1.39 Å. In the second O site, O is bonded in a single-bond geometry to one N atom.
N2O3 is alpha Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia molecules and four nitric acid molecules.
N2O is Cinnabar structured and crystallizes in the trigonal P3_121 space group. The structure is zero-dimensional and consists of three nitrogen molecules and three water molecules.
NO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen nitric acid molecules. N is bonded in a trigonal planar geometry to three O atoms. All N–O bond lengths are 1.25 Å. There are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one N atom. In the second O site, O is bonded in a single-bond geometry to one N atom. In the third O site, O is bonded in a single-bond geometry to one N atom.