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At least 37 records · Page 2

Materials Data on MoC by Materials Project

MoC is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Mo4+ is bonded to six C4- atoms to form a mixture of edge, face, and corner-sharing MoC6 octahedra. The corner-sharing octahedra tilt angles range from 0–46°. There are three shorter (2.18 Å) and three longer (2.23 Å) Mo–C bond lengths. There are two inequivalent C4- sites. In the first C4- site, C4- is bonded to six equivalent Mo4+ atoms to form a mixture of edge and corner-sharing CMo6 octahedra. In the second C4- site, C4- is bonded to six equivalent Mo4+ atoms to form a mixture of distorted edge and corner-sharing CMo6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 2°.

36 MATERIALS SCIENCE↗

Materials Data on MoC by Materials Project

MoC is Zincblende, Sphalerite structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Mo4+ is bonded to four equivalent C4- atoms to form corner-sharing MoC4 tetrahedra. All Mo–C bond lengths are 2.03 Å. C4- is bonded to four equivalent Mo4+ atoms to form corner-sharing CMo4 tetrahedra.

36 MATERIALS SCIENCE↗

Modification of the Coordination Environment of Active Sites on MoC for High-Efficiency CH 4 Production

Modulating the coordination environment of active sites on catalyst surfaces is crucial to developing effective catalysts and controlling catalysis, but it is highly challenging. Guided by our first-principles calculations, we experimentally accomplish the modification of the coordination environment of active sites on MoC nanoparticle surfaces by anchoring pyridinic N atom rings of holey graphene on Mo atoms. The rings produce electrostatic forces that enable the tuning of the Mo sites' affinity to reaction intermediates, which passivates Mo hollow sites, activates Mo top sites and reduces the over-adsorption of OH on the Mo active sites, as predicted by the calculations. The atomic-level modification is well confirmed by atomic-resolution imaging, high-resolution electron tomography, synchrotron soft X-ray spectroscopy and operando electrochemical infrared spectroscopy. Consequently, the Faradaic efficiency for CO 2 reduction to CH 4 is enhanced from 16% to 89%, a record high efficiency so far, in aqueous electrolyte. Meantime, it also exhibits a negligible activity loss over 50 h.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Real-time test of MOCS algorithm during Superflux 1980

A remote sensing experiment was conducted in which success depended upon the real-time use of an algorithm, generated from MOCS (multichannel ocean color sensor) data onboard the NASA P-3 aircraft, to direct the NOAA ship Kelez to oceanic stations where vitally needed sea truth could be collected. Remote data sets collected on two consecutive days of the mission were consistent with the sea truth for low concentrations of chlorophyll a. Two oceanic regions of special interest were located. The algorithm and the collected data are described.

Grew, G. W.↗

Mars Global Surveyor MOC Images

Images of several dust devils were captured by the Mars Orbiter Camera (MOC) during its global geodesy campaign. The images shown were taken two days apart, May 13, 1999 and May 15, 1999. Dust devils are columnar vortices of wind that move across the landscape and pick up dust. They look like mini tornadoes.

Source record↗

Small Crater Populations on Mars: Studies of MOC Images

Populations of small martian craters can now be studied using MOC images. The smallest craters record aspects of the crater production and resurfacing history that could not be observed previously. Examples from a number of terrains are shown.

Plaut, J. J.↗

Characterization of MER Landing Sites Using MOC and MOLA

The MOC images for MER are compared with MOLA data to characterize and locate each image. MOLA profiles show that Hematite remains benign, Melas and Isidis are rougher, and Athabasca and Gusev have regions of significant small scale topography. Additional information is contained in the original extended abstract.

Anderson, F. S.↗

Mars: Detaching of the Free Water Signature (FWS) Presence Regions on the Base of HEND/ODYSSEY Data and Their Correlation with Some Permafrost Features from MOC Data

The first results from global mapping of the neutron albedo from Mars by HEND instrument have shown the noticeable deficit of both the epithermal (EN) and the fast (FN) neutrons counts rate in the high latitudes regions of both hemispheres of the planet. The deficit is indicative for high enriching of the surface regolith by hydrogen, which may correspond to amount of any water phases and forms. The objectives of our study are the spatial and temporal variations of the free water (ice) signature in the Martian surface layer on the base of HEND/ODYSSEY data and their correlation with spatial spreading of some permafrost features, mapped on the base of MOC images. For the study we used the results of the global mapping (pixel 5 x5 ) of EN and FN albedo, realized by HEND/ODYSSEY in the period from 17 February to 10 December 2002 year.

Kuzmin, R. O.↗

The Diversity of Martian Volcanic Features as Seen in MOC Images and MOLA Topographic Data

This project focused on the evolution of the summit areas of Martian volcanoes. By using data collected from the Mars Orbiter Camera (MOC) and Mars Laser Altimeter (MOLA) instruments, we tried to better understand the diversity of constructional volcanism on Mars, and hence further understand eruption processes. We investigated the styles of volcanism on the major volcanic constructs (Olympus, Arsia, Pavonis, and Ascraeus Montes), and also studied the role of magma-volatile interactions within the shallow subsurface of these volcanoes and the surrounding areas. Theoretical models for internal processes within volcanoes, including the thermal influences of dike intrusions on pre-existing volatiles, were developed based on our identification of landform distributions. Our work provided new insights into the diversity of volcanism on Mars, and the distribution of Martian volatiles in space and time. Highlights of our results include: 1) The identification of large ash deposits at the summit of Arsia Mons; 2) The study of a large flank eruption on Elysium Mons and the estimation of the effusion rate needed to produce the observed lava channel; 3) The quantitative description of dike intrusion into volatile-rich terrain to explain the origin of Hrad Vallis; 4) The identification of constructional ridges on top of very young lava flows from Olympus Mons, with the interpretation that these ridges were formed by very recent phreatomagmatic eruptions; and 5) The characterization of the dimensions and slope distributions on 18 volcanic edifices on Mars.

Mouginis-Mark, Peter J.↗

Yearly Comparisons of the Mars North Polar Cap: 1999, 2001, and 2003 MOC Observations

The seasonal cycle of the martian north polar cap has been studied since the time of William Herschel, who published the first quantitative observations of the seasonal recession of the polar caps in 1784. Ground-based observations made after Herschel were summarized by Slipher in 1962. More recent ground-based observations of the north polar cap have been done by Iwasaki et al. Mariner 9 and Viking also made north polar observations. Cantor et al. used Hubble Space Telescope observations between 1990 and 1997 to determine several north polar recessions and Lambert albedos of the cap. Mars Global Surveyor went into orbit around Mars in September 1997. The wide-angle cameras on the Mars Orbiter Camera (MOC) acquire images of the entire planet every day at a resolution of approx. 7.5 km/pixel in both red (575 nm - 625 nm) and blue (400 nm - 450 nm) bandpasses (WAR and WAB). Some polar cap observations were acquired during the aerobraking (AB) and science phasing (SPO) of MGS before systematic mapping began in March, 1999 at Ls = 110 .

Benson, J. L.↗

MOC Automation with GMSEC and the Generic Extendable Message Utility (GEMU)

Automation has become critical for ground systems, improving efficiency and reliability while reducing costs across mission operations. The Goddard Mission Services Evolution Center (GMSEC) software suite has played a significant role in enabling this automation, leveraging its publish/subscribe paradigm through a message bus architecture to facilitate seamless communication and data flow. Historically, the GMSEC suite, through components like Criteria Action Table (CAT) has been pivotal in automating ground system capabilities. However, as technology advances, limitations in automation with CAT have emerged, creating an opportunity to enhance ground system automation through the introduction of GEMU. This new GMSEC component brings new capabilities and addresses specific automation constraints that CAT could not overcome, allowing for more sophisticated, flexible, and efficient message processing. GEMU, at its core, is designed to accelerate the development of custom GMSEC-compliant applications. It enables users to construct automated message processing pipelines quickly, supporting both drag-and-drop web-based configuration and scripting through a simple domain-specific language. This advancement not only simplifies the process but also reduces the time needed for implementing automated solutions. This presentation will outline GEMU’s potential value in improving mission operations automation. It will highlight the benefits of transitioning from CAT to GEMU and offer insights into how GEMU can drive operational efficiencies. We will also provide an overview of the automation capabilities of GEMU and its potential impact on mission operations centers (MOCs).

GMSEC↗

Transient MOC with frequency transform and DSA on unstructured mesh

We present an implementation of the transient method of characteristics (MOC) with isotropic time derivatives, accelerated by diffusion synthetic acceleration (DSA). The fully implicit frequency transform method is used to solve the transient problem with analytic precursor integration. The code works on meshes composed of almost any of the commonly used non-curvilinear finite element types, and can handle the deformation of geometry in time-dependent transport calculations. We present results of a continuous Fourier analysis for the transient multigroup DSA problem, and representative benchmarking results are presented for the C5G7-TD benchmark in 2D showing reasonable performance and agreement compared to other codes. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗