Phonon-induced splitting of exciton lines in MgO and BeO.
Exciton line splitting in MgO and BeO induced by exciton-phonon coupling, comparing splitting with longitudinal optical phonon energy
Loh, E.↗
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Relation of the catalytic activity of MgO to its electron energy states.
Surface UV irradiated MgO powder catalytic activity for hydrogen-deuterium exchange reaction
Harkins, C. G.↗
Exciton spectra of CaO and MgO.
CaO and MgO reflectance spectra measurements at high resolution and at low temperature including exciton spectra at 25 K, obtaining fine structure
Walker, W. C.↗
The formation of defect centers in MgO
Defect F centers formation in MgO, discussing optical absorption bands, oscillator strengths, luminescence band, impurity centers, etc
Kroes, R. L.↗
Coloration of MgO single crystals by low energy protons - A function of selected defects
MgO single crystals dominant coloration in solar spectral region by electron hole pair diffusion, trapping and recombination
Berggren, C. C.↗
Reaction constants in the system Fe-MgO-SiO2-O2 at 1 atm between 900 and 1300 C - Experimental results
Thermodynamic equilibrium constants of Fe-MgO-SiO2-O2 system reactions at one atmosphere and 900-1300 C
Williams, R. J.↗
O(minus 2) grain boundary diffusion and grain growth in pure dense MgO
Grain growth behavior in fully dense compacts of MgO of very high purity was studied, and the results compared with other similar behaving materials. The activation energy for the intrinsic self-diffusion of Mg(2minus) is discussed along with the grain boundary diffusion of O(2minus). Grain boundary diffusion of O(2minus) is proposed as the controlling mechanism for grain growth.
Kapadia, C. M.↗
Adsorption of Ar on a nonuniform MgO surface
Data are presented for the adsorption of Ar and N2 on a strongly heterogeneous MgO surface at 84 K and for Ar at a range of temperatures between 130 and 250 K. The high-temperature data are analyzed according to a model which separates the contributions to the potential into bulk and surface terms, providing a method for the determination of the surface area from parameters characteristic of the bulk material. A solid-gas energy parameter and parameters indicating the strength of the impurity sites are also evaluated.
Hinman, D. C.↗
In situ investigation of the mobility of small gold clusters on cleaved MgO surfaces
The mobility of small clusters of gold (about 10 A in diameter) on electron-beam-cleaved MgO surfaces was studied by in situ transmission electron microscopy under controlled vacuum and temperature conditions. During the first 10 min following a deposition at room temperature, over 10 per cent of the crystallites moved over short distances (about 20 A) discontinuously, with a velocity greater than 150 A/sec. Eighty per cent of the mobility events were characterized by the avoidance of proximity of other crystallites, and this was tentatively explained as the result of repulsive elastic forces between the interacting crystallites.
Metois, J. J.↗
In situ oxygen conditioning of /001/ MgO thin film substrates for film growth studies by electron microscopy
It was found that the in situ treatment of 001-plane single-crystal films of MgO (prepared by epitaxial growth from the vapor phase) at high temperatures with a jet of oxygen will produce a surface that is almost equivalent, for epitaxial studies, to surfaces with the same orientation prepared by vacuum cleavage of bulk single crystals. The effectiveness of the process is demonstrated by its impact on the epitaxy of silver.
Moorhead, R. D.↗
An SCF and MCSCF description of the low-lying states of MgO
The paper presents the multiconfiguration-self-consistent (MCSCF) and configuration state functions (CSF) for the low-lying electronic states of MgO. It was shown that simple description of these states was possible provided the 1 Sigma(+) states are individually optimized at the MCSCF level, noting that the 1(3 Sigma)(+) and 2(1 Sigma)(+) states which nominally result from the same electron occupation are separated energetically. The molecular orbitals obtained at this level of approximation should provide a useful starting point for extended configuration interaction calculations since they have been optimized for the particular states of interest.
Bauschlicher, C. W., Jr.↗
On the low-lying states of MgO. II
Using a double zeta plus polarization basis set of Slater orbitals, full valence MCSCF (FVMCSCF) calculations were performed for the low-lying states of MgO. For each state the FVMCSCF calculations were used to identify the important configurations which are then used in the MCSCF calculation and subsequently as references in a single and double excitation CI calculation. This approach is found to treat all states equivalently, with the maximum error in the computed transition energies and equilibrium bond lengths of 800/cm and approximately 0.03 A, respectively. The b 3 Sigma + state which has yet to be characterized experimentally is predicted to have a transition energy of approximately 8300/cm and a bond length of 1.79 A. A spectroscopic analysis of the potential curves indicates that their shapes are in quite reasonable agreement with the range of experimental results.
Bauschlicher, C. W., Jr.↗
Modelling Equilibrium and Fractional Crystallization in the System MgO-FeO-CaO-Al2O3-SiO2
A mathematical modelling technique for use in petrogenesis calculations in the system MgO-FeO-CaO-Al2O3-SiO2 is reported. Semiempirical phase boundary and elemental distribution information was combined with mass balance to compute approximate equilibrium crystallization paths for arbitrary system compositions. The calculation is applicable to a range of system compositions and fractionation calculations are possible. The goal of the calculation is the computation of the composition and quantity of each phase present as a function of the degree of solidification. The degree of solidification is parameterized by the heat released by the solidifying phases. The mathematical requirement for the solution of this problem is: (1) An equation constraining the composition of the magma for each solid phase in equilibrium with the liquidus phase, and (2) an equation for each solid phase and each component giving the distribution of that element between that phase and the magma.
Herbert, F.↗
The emission of atoms and molecules accompanying fracture of single-crystal MgO
The emission of particles due to deformation and fracture of materials has been investigated. The emission of electrons (exoelectron emission), ions, neutral species, photons (triboluminescence), as well as long wavelength electromagnetic radiation was observed; collectively these emissions are referred to as fractoemission. This paper describes measurements of the neutral emission accompanying the fracture of single-crystal MgO. Masses detected are tentatively assigned to the emission of H2, CH4, H2O, CO, O2, CO2, and atomic Mg. Other hydrocarbons are also observed. The time dependencies of some of these emissions relative to fracture are presented for two different loading conditions.
Dickinson, J. T.↗
Efficient second harmonic generation of a diode-laser-pumped CW Nd:YAG laser using monolithic MgO:LiNbO3 external resonant cavities
56-percent efficient external-cavity-resonant second-harmonic generation of a diode-laser pumped, CW single-axial-mode Nd:YAG laser is reported. A theory of external doubling with a resonant fundamental is presented and compared to experimental results for three monolithic cavities of nonlinear MgO:LiNbO3. The best conversion efficiency was obtained with a 12.5-mm-long monolithic ring cavity doubler, which produced 29.7 mW of CW, single-axial model 532-nm radiation from an input of 52.5 mW.
Kozlovsky, William J.↗
Efficient monolithic MgO:LiNbO3 singly resonant optical parametric oscillator
A monolithic MgO:LiNbO3 singly resonant optical parametric oscillator (OPO) was operated as both a standing-wave and a ring-geometry resonator. The OPO was pumped by the second harmonic of an amplified single-mode diode-laser-pumped Nd:YAG laser. Pump depletions of greater than 60 percent were observed when pumping four times greater than the 35-W threshold. The OPO output at the resonant signal tuned with temperature from 834 to 958 nm, while the corresponding idler tuned from 1.47 to 1.2 microns. The spectral characteristics of the OPO signal output and the relative merits of a standing wave versus a ring geometry are discussed.
Kozlovsky, W. J.↗
Pomozdino - An anomalous, high-MgO/FeO, yet REE-rich eucrite
A new chemical analysis and petrographic data for the Pomozdino basaltic achondrite are presented. Earlier indications that Pomozdino is a eucrite and that it is a monomict breccia with an anomalous, REE-rich, yet high-MgO/FeO bulk composition, are confirmed. Characteristics such as texture, composition, and REE concentration are examined and compared to those in other publications. A model for the origin of this meteorite, as a partial cumulate with an uncommonly high content of trapped liquid, is found to be preferable. Two alternatives of the origin are suggested, one of which implies that the parent melt is roughly similar in composition to Stannern. The other considers Pomozdino as a possible primary partial melt, derived from a source region far more magnesian than generally envisaged for the sources of primary eucritic partial melts. It is concluded that at least some Stannern-like eucrites were involved in fractional crystallization, and thus do not represent primary partial melts.
Warren, P. H.↗
Absolute and relative nonlinear optical coefficients of KDP, KD(asterisk)P, BaB2O4, LiIO3, MgO:LiNbO3, and KTP measured by phase-matched second-harmonic generation
Both absolute and relative nonlinear optical coefficients of six nonlinear materials measured by second-harmonic generation are discussed. A single-mode, injection-seeded, Q-switched Nd:YAG laser with spatially filtered output was used to generate the 1.064-micron fundamental radiation. The following results were obtained: d36(KDP) = 0.38 pm/V, d36(KD/asterisk/P) = 0.37 pm/V, (parallel)d22(BaB2O4)(parallel) = 2.2 pm/V, d31(LiIO3) = -4.1 pm/V, d31(5 percentMgO:MgO LiNbO3) = -4.7 pm/V, and d(eff)(KTP) = 3.2 pm/V. The accuracy of these measurements is estimated to be better than 10 percent.
Eckardt, Robert C.↗