Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “MAGNESIUM”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

A magnesium–sodium hybrid battery with high operating voltage

Here, we report a high performance magnesium-sodium hybrid battery utilizing a magnesium-sodium dual-salt electrolyte, a magnesium anode, and a Berlin green cathode. The cell delivers an average discharge voltage of 2.2 V and a reversible capacity of 143 mA h g –1 . We also demonstrate the cell with an energy density of 135 W h kg –1 and a high power density of up to 1.67 kW kg –1 .

25 ENERGY STORAGE↗
DOE OSTI2011

The TMS Magnesium Committee: Committed to the Advancement of Global Magnesium Technology

The TMS Magnesium Committee was established in the year 2000 as a spin-off of the Reactive Metals Committee, triggered by the strong global growth of magnesium being used in a variety of structural lightweight applications since the mid-1990’s. Since then the committee has seen a distinct development in terms of size, participation and focus. The article at hand outlines this development by recapitulating the output of its two main activities: the annual Magnesium Technology Symposia and the JOM Special Issues dedicated to magnesium research and development. Further records on the Magnesium Committee are available from the committee homepage (accessible through http://members.tms.org).

36 MATERIALS SCIENCE↗
DOE OSTI2016

Solid state cathode materials for secondary magnesium-ion batteries that are compatible with magnesium metal anodes in water-free electrolyte

With high elemental abundance, large volumetric capacity, and dendrite-free metal deposition, magnesium metal anodes offer promise in beyond-lithium-ion batteries. However, the increased charge density associated with the divalent magnesium-ion (Mg{sup 2+}), relative to lithium-ion (Li{sup +}) hinders the ion-insertion and extraction processes within many materials and structures known for lithium-ion cathodes. As a result, many recent investigations incorporate known amounts of water within the electrolyte to provide temporary solvation of the Mg{sup 2+}, improving diffusion kinetics. Unfortunately with the addition of water, compatibility with magnesium metal anodes disappears due to forming an ion-insulating passivating layer. In this short review, recent advances in solid state cathode materials for rechargeable magnesium-ion batteries are highlighted, with a focus on cathode materials that do not require water contaminated electrolyte solutions for ion insertion and extraction processes. - Graphical abstract: In this short review, we present candidate materials for reversible Mg-battery cathodes that are compatible with magnesium metal in water-free electrolytes. The data suggest that soft, polarizable anions are required for reversible cycling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1927

The Corrosion of Magnesium and of the Magnesium Aluminum Alloys Containing Manganese

The extensive use of magnesium and its alloys in aircraft has been seriously handicapped by the uncertainties surrounding their resistance to corrosion. This problem has been given intense study by the American Magnesium Corporation and at the request of the Subcommittee on Materials for Aircraft of the National Advisory Committee for Aeronautics this report was prepared on the corrosion of magnesium. The tentative conclusions drawn from the experimental facts of this investigation are as follows: the overvoltage of pure magnesium is quite high. On immersion in salt water the metal corrodes with the liberation of hydrogen until the film of corrosion product lowers the potential to a critical value. When the potential reaches this value it no longer exceeds the theoretical hydrogen potential plus the overvoltage of the metal. Rapid corrosion consequently ceases. When aluminum is added, especially when in large amounts, the overvoltage is decreased and hydrogen plates out at a much lower potential than with pure magnesium. The addition of small amount of manganese raises the overvoltage back to practically that of pure metal, and the film is again negative.

Boyer, J A↗
DOE OSTI2024

A weakly ion pairing electrolyte designed for high voltage magnesium batteries

High-voltage rechargeable magnesium batteries (RMBs) are potential alternatives to lithium-ion batteries owing to the low cost and high abundance of magnesium. However, the parasitic reactions of the latter with many electrolytes greatly hinders the stability and kinetics of Mg plating/stripping. Here we report a new and easily accessible solvent-designed electrolyte, which effectively solves the difficulty of ion pair dissociation and facilitates fast nanoscale Mg nucleation/growth using simple Mg(TFSI)2 as the salt, enabling a facile interfacial charge transfer process. Dendrite-free Mg plating/stripping is maintained for over 7000 hours (∼10 months) at a practical areal capacity of 2 mA h cm−2. The high-voltage stability of these electrolytes is demonstrated by benchmarking with polyaniline||Mg full cells with an operating voltage up to 3.5 V that exhibit stable cycling at a 2C rate with 99% coulombic efficiency after 400 cycles. This work opens up new frontiers in coupling low-cost electrolytes with next-generation high-voltage cathode materials for fast-charging RMBs with long life and high energy densities.

Li, Chang↗
DOE OSTI2024

Structural and chemical evolutions of a magnesium vanadium oxide cathode under electrochemical cycling in magnesium batteries

The design of cathode materials that remain chemically and structurally stable during repetitive ion insertion and extraction poses a significant challenge in developing multivalent batteries. The cycling stability of traditional metal oxide-based cathode is challenged by sluggish diffusion of multivalent cations and parasitic reactivity at interfacial regimes, including the cathode electrolyte interphase layer (CEI). Understanding the reactions at the cathode-electrolyte interface, particularly those induced by non-stoichiometric surface layers, is a crucial design parameter for both cathode materials and electrolytes. Here, in this study, we employed multimodal analysis, including in situ and ex situ X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy (TEM) and electrochemical impedance spectroscopy (EIS) to examine the surface reactions and subsequent structural and chemical evolutions of the CEI on high voltage magnesium vanadium oxide (MgV 2 O 4 ) spinel cathode during the Mg 2+ insertion/extraction processes. The results revealed that the presence of non-stoichiometric surface layers in the magnesium vanadium oxide cathode drive the decomposition of bis(trifluoromethanesulfonyl)imide (TFSI - ) anion, leading to the formation of the CEI layer. The CEI layer could inhibit the Mg 2+ ion transfer processes. Accompanying this reactivity-driven degradation, the magnesium vanadium oxide cathode undergoes pulverization, forming clusters of nanosized particles. This process likely improves cycling ability by creating new intercalation sites and shortening the diffusion pathway for the Mg 2+ cations. This study demonstrates that controlling surface stoichiometry and engineering morphological properties are critical design parameters for high performance cathodes for multivalent batteries.

25 ENERGY STORAGE↗
DOE OSTI2018

Reaction mechanism of magnesium potassium phosphate cement with high magnesium-to-phosphate ratio

Understanding reaction mechanisms of magnesium potassium phosphate (MKP) cement is of significant importance, as it is closely related to the optimum design of MKP cement-based materials. In this study, reaction mechanisms of MKP cements with a high magnesium-to-phosphate (Mg/PO{sub 4}) molar ratio of 8 were investigated at two different water-to-solid (w/s) ratios of 0.5 and 5. The experimental findings show that the use of this high Mg/PO{sub 4} molar ratio suppresses the formation of potassium-free magnesium phosphate hydrates. K-struvite is mainly formed with probably more phosphate than the theoretical value. Moreover, the w/s ratio plays a crucial role on governing the reaction path of MKP cements. The lower w/s ratio (w/s = 0.5) leads to higher potassium concentration and pH value, thus suppressing the formation of intermediate product, Mg{sub 2}KH(PO{sub 4}){sub 2}·15H{sub 2}O, which is formed at the higher w/s = 5. However, it causes the formation of minor amount of brucite at 28 d, which coexists with K-struvite in the paste.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Effect of Composition and Local Environment on CO 2 Adsorption on Nickel and Magnesium Oxide Solid Solutions

CO 2 adsorption energies on the (100) surfaces of a nickel oxide doped with Mg, magnesium oxide doped with Ni, and their 50:50 solid solution were calculated using density functional theory. The composition and atomic arrangement of the adsorption site was varied to understand how the local environment affects CO 2 adsorption and the basicity of the surfaces at the atomic level. The dispersive and electronic contributions to the adsorption energies were quantified, and the results indicate that the variation of the adsorption energy with adsorption site configuration and metal composition is dominated by electronic interactions. Interestingly, for magnesium oxide doped with nickel, a single substitution can create stronger CO 2 binding sites, which implies stronger basic sites, even though nickel oxide is less basic than magnesium oxide. The effect of double substitution at the binding site can be reasonably approximated by summing the effects of single substitutions. Furthermore, this work provides guidance for the preparation of metal oxides with tailored Lewis basicity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2018

Evidence Connecting Mercury's Magnesium Exosphere to Its Magnesium-Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Mercury↗
DOE OSTI2013

Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries

We developed a unique class of air-stable and non-pyrophoric magnesium electrolytes based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg 3 Cl 3 (OR) 2 (THF) 6 ] + [(THF)MgCl 3 ] - . Furthermore we obtained high reversible capacities and good rate capabilities in Mg-Mo 6 S 8 batteries using these new electrolytes at both 20 and 50°C.

25 ENERGY STORAGE↗
NASA NTRS1973

Nondestructive spot test method for magnesium and magnesium alloys

A method for spot test identification of magnesium and various magnesium alloys commonly used in aerospace applications is described. The spot test identification involves color codes obtained when several drops of 3 M hydrochloric acid are placed on the surface to be tested. After approximately thirty seconds, two drops of this reacted acid is transferred to each of two depressions in a spot plate for additions of other chemicals with subsequent color changes indicating magnesium or its alloy.

Wilson, M. L.↗
NASA NTRS2018

Evidence Connecting Mercury's Magnesium Exosphere to its Magnesium-Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Mercury atmosphere↗
NASA NTRS2018

Evidence Connecting Mercury's Magnesium Exosphere to Its Magnesium‐Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Aimee W. Merkel↗