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Computerized method of interpreting low resolution mass spectra in organic chemical analysis, describing inference maker program applications and results
Airborne lidar provides timely updated maps for monitoring forest change at high resolution but it has been little used for that purpose due to the scarcity of long-term time-series over a common area. The NASA Jet Propulsion Laboratory Airborne Snow Observatory (ASO) is a landscape-level monitoring system that provides ongoing multi-year remote sensing measurements over mountainous ecosystems to primary quantify snow volume and dynamics. It collects low-resolution lidar data (~1.5 pt/m2) with a nominal weekly frequency up to 12 times a year with measurements that span 2013-2017 over 12 mountain watersheds across the western US that currently face ecological threads. In this work, we present a method to automatically register ASO weekly low-resolution lidar point clouds in order to calculate spatially consistent datasets (~12 pt/m2) adapted to fine scale forestry studies. We test the method using 12 lidar datasets acquired over the Tuolumne River Basin (Sierra Nevada, California) in the spring and summer of 2014. On average, the ASO lidar system provides accurate measurements in terms of geolocation (0.38m and 0.12m for the horizontal and vertical dimension, respectively) but some datasets are biased up to 1.38m and 0.53m, respectively. Our registration method successfully corrected for systematic bias improving the 3D geometry of forest point clouds.
Fourier transformation compensation for spectral averaging error reduction in low resolution spectroradiometry
An alternative optical thermometry technique that utilizes the low-resolution (order 10(exp 1)/cm) pure-rotational spontaneous Raman scattering of air is developed to aid single-shot multiscalar measurements in turbulent combustion studies. Temperature measurements are realized by correlating the measured envelope bandwidth of the pure-rotational manifold of the N2/O2 spectrum with a theoretical prediction of a species-weighted bandwidth. By coupling this thermometry technique with conventional vibrational Raman scattering for species determination, we demonstrate quantitative spatially resolved, single-shot measurements of the temperature and fuel/oxidizer concentrations in a high-pressure turbulent Cf4-air flame. Our technique provides not only an effective means of validating other temperature measurement methods, but also serves as a secondary thermometry technique in cases where the anti-Stokes vibrational N2 Raman signals are too low for a conventional vibrational temperature analysis.
Low-resolution ultraviolet spectra were obtained for six early-type stars in 1972 December, using an Ebert spectrometer mounted in the service module of the Apollo 17 spacecraft. The spectrometer scanned from 1180 A to 1680 A, with a speed that varied with wavelength according to a program chosen for lunar studies. Spectral resolution was 11 A. The ultraviolet absolute calibration of the instrument was determined by comparison with National Bureau of Standards calibrated photodiodes, and is believed known to plus or minus 10 percent. The absolute intensities are in good general agreement with the observations of other stars and with the predictions of stellar model-atmosphere calculations.
This document describes the design and operation of a low resolution radar data recording system for precipitation measurements. This system records a full azimuth scan on seven track magnetic tapes every five minutes. It is designed to operate on a continuous basis with operator intervention required only for changing tape reels and calibration.
We present low-resolution VLT spectroscopy of the aftergiow position of the gamma ray bursts 991216, 011211, 021211 and 030328. The spectmm of GRB 991216 shows two probable absorption systems at z = 0.80 and z = 1.02, where the highest redshift most likely reflects the distance to the host galaxy. A third, more uncertain, system may be detected at z = 0.77. HST imaging of the field obtained 4 months later, show two amorphous regions of emission, one at the projected OT position, the presumed host galaxy at z = 1.02, and the other 0"6 away. All significant lines in the spectrum of GRB 011211 are identified with lines originating in a single absorption system at z = 2.142 plus or minus 0.002, the redshift of the GRB 011211 host galaxy. We also detect Lya in the host, for which we fit a neutral hydrogen column density of log N(HI)=20.4 plus or minus 0.2, which indicates that it is a damped Lya system. For GRB021211, we detect a single emission line in a spectrum tens of days after the burst, which we identify as [OII] at z = 1.006. The galaxy l"5 away from the afterglow location has z = 0.800, and is therefore unrelated to the GRB. Finally, for GRB030328 at least two absorption systems are required to explain all significant lines: one at z = 1.522, the likely redshift of the GRB, and the other at z = 1.295. For the latter system we only detect two lines, and we consider the reality of this system to be uncertain.
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Progress on a low-resolution survey of primitive C-class asteroids continues using new equipment (and its associated problems) to understand aqueous alteration in the solar system. Additional information is contained in the original extended abstract.
A catalogue is presented of all the low-resolution IUE spectra of dwarf novae and nova-like stars that were recorded until the end of 1987. All spectra have been reduced, and are displayed, in a homogeneous way. In addition to details about these data, to the extent available, their position in the outburst light curves is given, physical information about each system, and a comprehensive list of references for published observations in all wavelength ranges.
The feasibility of real time digital processing of synthetic aperture radar data for Venus orbiting imaging radar low resolution modes was investigated. First, it is shown that range migration is not a problem for these modes. Then, under the assumption of no range migration, fast Fourier transform implementations for accomplishing both range and azimuth correlation in real time are shown to be feasible with current technology.
A description is given of a development of computer analysis of low-resolution chromatographic-mass spectrometric data, which provides a preliminary classification of an unknown spectrum as a listing of candidate classes of compounds. This procedure, referred to as COMSOC (Classification of Mass Spectra on Computers), operates by converting an incoming unknown mass spectrum into a simplified key word which is then compared with each of the key words held in its reference file. The advantages of COMSOC in characterizing complex mixtures are emphasized.
Abundances of neon and sulfur for 95 H II regions whose spectra were measured by the IRAS Low Resolution Spectrometer (LRS) are determined; and theoretical implications of the neon ionization level and the sulfur-to-neon abundance ratio are discussed. The abundances show a distinct gradient of Ne/H with respect to Galactocentric radius RG, and a smaller gradient for S/H. The neon ionization is high only for sources with both low neon abundance and high luminosity. It is concluded that, due to the fact that the luminosities observed are so high compared to those predicted for the zero-age main sequence star, the most luminous H II regions are probably excited by several stars or a cluster of stars. The observed ionization of neon shows that the effective temperatures of the exciting stars cannot be more than 40,000 K, with an alternative explanation that 04 and 03 stars have Lyman continuum spectra cooler than the 45,000 - 50,000 K effective temperatures that are found for their visible and UV spectra.
Two bodies in the Solar System exhibit high-temperature active volcanism: Earth and Io. While there are important differences in the eruptions on Earth and Io, in low-spatial-resolution data (corresponding to the bulk of available and foreseeable data of Io), similar styles of effusive and explosive volcanism yield similar thermal flux densities. For example, a square metre of an active pahoehoe flow on Io looks very similar to a square metre of an active pahoehoe flow on Earth. If, from observed thermal emission as a function of wavelength and change in thermal emission with time, the eruption style of an ionian volcano can be constrained, estimates of volumetric fluxes can be made and compared with terrestrial volcanoes using techniques derived for analysing terrestrial remotely-sensed data. In this way we find that ionian volcanoes fundamentally differ from their terrestrial counterparts only in areal extent, with Io volcanoes covering larger areas, with higher volumetric flux. Io outbursts eruptions have enormous implied volumetric fluxes, and may scale with terrestrial flood basalt eruptions. Even with the low-spatial resolution data available it is possible to sometimes constrain and classify eruption style both on Io and Earth from the integrated thermal emission spectrum. Plotting 2 and 5 m fluxes reveals the evolution of individual eruptions of different styles, as well as the relative intensity of eruptions, allowing comparison to be made from individual eruptions on both planets. Analyses like this can be used for interpretation of low-resolution data until the next mission to the jovian system. For a number of Io volcanoes (including Pele, Prometheus, Amirani, Zamama, Culann, Tohil and Tvashtar) we do have high/moderate resolution imagery to aid determination of eruption mode from analyses based only on low spatial-resolution data.
Two FORTRAN computer programs for the interpretation of low resolution mass spectra were prepared and tested. One is for the calculation of the molecular isotopic distribution of any species from stored elemental distributions. The program requires only the input of the molecular formula and was designed for compatability with any computer system. The other program is for the determination of all possible combinations of atoms (and radicals) which may form an ion having a particular integer mass. It also uses a simplified input scheme and was designed for compatability with any system.
Using IRAS COADDed images, candidates are suggested for the exciting stars of Herbig-Haro objects from the Reipurth and Graham sample. The IRAS low-resolution spectrometer provides spectra for 20 of the 46 candidate stars so far identified as exciting young, unevolved H-H systems. These reveal 10-micron silicate absorption features, or are too red to show detectable flux near 10 microns. The histogram of bolometric luminosities for 46 young Herbig-Haro exciting stars has a median of 13 solar luminosities and a mode between 16 and 32 solar luminosities. Although the enlarged sample of known exciting stars has more of the higher luminosity objects than an earlier sample, the histogram still represents a generally low-luminosity distribution.
High resolution images of non-spherical objects, such as Viking images of Phobos and the anticipated Galileo images of Gaspra, lend themselves to conventional planetary cartographic procedures: control network analysis, stereophotogrammetry, image mosaicking in 2D or 3D, and airbrush mapping. There remains the problem of a suitable map projection for bodies which are extremely elongated or irregular in shape. Many bodies will soon be seen at lower resolution (5-30 pixels across the disk) in images from speckle interferometry, the Hubble Space Telescope, ground-based radar, distinct spacecraft encounters, and closer images degraded by smear. Different data with similar effective resolutions are available from stellar occultations, radar or lightcurve convex hulls, lightcurve modeling of albedo variations, and cometary jet modeling. With such low resolution, conventional methods of shape determination will be less useful or will fail altogether, leaving limb and terminator topography as the principal sources of topographic information. A method for shape determination based on limb and terminator topography was developed. It has been applied to the nucleus of Comet Halley and the jovian satellite Amalthea. The Amalthea results are described to give an example of the cartographic possibilities and problems of anticipated data sets.
The use of low-dispersion IUE spectra is investigated to deduce properties of chromospheres in Zeta-Aur binaries. This approach, obviously, has the advantage of allowing the study of stars somewhat fainter than the classical systems. As expected, the column density of absorbers along the line of sight can be determined rather well, from the shape and extent of line extinction. The turbulent velocity of the gas can be found by comparing the strength of Fe II features with Ly-Alpha. In addition, it may be possible in some cases to determine a crude excitation temperature, although the effects of temperature on low-dispersion IUE spectra are generally quite subtle.