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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Process for preparing liquid metal electrical contact device

The parts of an electrical contact device are treated by sputter etching to remove the parent metal oxide. Prior to exposure of the electrodes to any oxygen, a sacrificial metal is sputter deposited on the parts. Preferably this sacrificial metal is one that oxidizes slowly and is readily dissolved by the liquid metal. The sacrificial metal may then be removed from unwanted areas. The remainder of the ring and the probe to be wet by the liquid metal are submerged in the liquid metal or the liquid metal is flushed over these areas, preferably while they are being slightly abraded, unitl all the sacrificial material on these portions is wet by the liquid metal. In doing so the liquid metal dissolves the sacrificial metal and permanently wets the parent metal. Preferred materials used in the process and for the electrodes of electrical contact devices are high purity (99.0%) nickel or AISI type 304 stainless steel for the electrical contact devices, gallium as the liquid metal, and gold as the sacrificial material.

Lovell, R. R.↗
NASA NTRS1963

Liquid Metals for Aerospace Electric-Power Systems

Liquid metals and their properties, as applied to space electric-power systems, are discussed as possible heat-transfer and thermodynamic working fluids. Representative liquid metals—lithium, sodium, potassium, NaK-78, lead, and bismuth — tare discussed and compared. Space power requirements are listed and used as a basis for evaluating the potentialities of the liquid metals.

Heat transfer↗
NASA NTRS1972

Investigation of a liquid-metal magnetohydrodynamic power system.

Liquid-metal magnetohydrodynamic power conversion is being investigated for nuclear-electric propulsion. A liquid-metal MHD converter has no moving mechanical parts and requires a heat source temperature of only 1300 K. Cycle efficiencies of 5% to 8% for single-stage converters and 10% for multistage converters appear attainable. The specific weight of a 240 kWe MHD power plant has been estimated as 30 kg/kWe with shielding for unmanned science missions.

Elliott, D. G.↗
NASA NTRS1986

Heat-Powered Pump for Liquid Metals

Proposed thermoelectromagnetic pump for liquid metal powered by waste heat; needs no battery, generator, or other external energy source. Pump turns part of heat in liquid metal into pumping energy. In combination with primary pump or on its own, thermoelectric pump circulates coolant between reactor and radiator. As long as there is decay heat to be removed, unit performs function.

Campana, R. J.↗
NASA NTRS1993

Thermophysical properties of simple liquid metals: A brief review of theory

In this paper, we review the current theory of the thermophysical properties of simple liquid metals. The emphasis is on thermodynamic properties, but we also briefly discuss the nonequilibrium properties of liquid metals. We begin by defining a 'simple liquid metal' as one in which the valence electrons interact only weakly with the ionic cores, so that the interaction can be treated by perturbation theory. We then write down the equilibrium Hamiltonian of a liquid metal as a sum of five terms: the bare ion-ion interaction, the electron-electron interaction, the bare electron-ion interaction, and the kinetic energies of electrons and ions. Since the electron-ion interaction can be treated by perturbation, the electronic part contributes in two ways to the Helmholtz free energy: it gives a density-dependent term which is independent of the arrangement of ions, and it acts to screen the ion-ion interaction, giving rise to effective ion-ion pair potentials which are density-dependent, in general. After sketching the form of a typical pair potential, we briefly enumerate some methods for calculating the ionic distribution function and hence the Helmholtz free energy of the liquid: monte Carlo simulations, molecular dynamics simulations, and thermodynamic perturbation theory. The final result is a general expression for the Helmholtz free energy of the liquid metal. It can be used to calculate a wide range of thermodynamic properties of simple metal liquids, which we enumerate. They include not only a range of thermodynamic coefficients of both metals and alloys, but also many aspects of the phase diagram, including freezing curves of pure elements and phase diagrams of liquid alloys (including liquidus and solidus curves). We briefly mention some key discoveries resulting from previous applications of this method, and point out that the same methods work for other materials not normally considered to be liquid metals (such as colloidal suspensions, in which the suspended microspheres behave like ions screened by the salt solution in which they are suspended). We conclude with a brief discussion of some non-equilibrium (i.e., transport) properties which can be treated by an extension of these methods. These include electrical resistivity, thermal conductivity, viscosity, atomic self-diffusion coefficients, concentration diffusion coefficients in alloys, surface tension and thermal emissivity. Finally, we briefly mention two methods by which the theory might be extended to non-simple liquid metals: these are empirical techniques (i.e., empirical two- and three-body potentials), and numerical many-body approaches. Both may be potentially applicable to extremely complex systems, such as nonstoichiometric liquid semiconductor alloys.

Stroud, David↗
NASA NTRS2003

Liquid-Metal-Fed Pulsed Plasma Thrusters

Liquid metal propellants may provide a path toward more reliable and efficient pulsed plasma thrusters (PPTs). Conceptual thruster designs which eliminate the need for high current switches and propellant metering valves are described. Propellant loading techniques are suggested that, at least in principle, show promise to increase propellant utilization, dynamic, and electrical efficiency. Experimental results from a prototype electromagnetically-pumped propellant feed system, and experiments in the initiation of arc discharges in liquid metal droplets, are presented.

Markusic, Thomas↗
NASA NTRS1993

Liquid metal drop ejection

The aim of this project was to demonstrate the possibility of ejecting liquid metals using drop on demand printing technology. The plan was to make transducers for operation in the 100 MHz frequency range and to use these transducers to demonstrate the ability to eject drops of liquid metals such as gallium. Two transducers were made by indium bonding piezoelectric lithium niobate to quartz buffer rods. The lithium niobate plates were thinned by mechanical polishing to a thickness of 37 microns for operation at 100 MHz. Hemispherical lenses were polished in the opposite ends of the buffer rods. The lenses, which focus the sound waves in the liquid metal, had an F-number equals 1. A mechanical housing was made to hold the transducers and to allow precise control over the liquid level above the lens. We started by demonstrating the ability to eject drops of water on demand. The drops of water had a diameter of 15 microns which corresponds to the wavelength of the sound wave in the water. A videotape of this ejection was made. We then used a mixture of Gallium and Indium (used to lower the melting temperature of the Gallium) to demonstrate the ejection of liquid metal drops. This proved to be difficult because of the oxide skin which forms on the surface of the liquid. In some instances, we were able to eject metal drops, however, this was not consistent and reproducible. An experiment was set up at NASA-Lewis to stabilize the process of drop on demand liquid metal ejection. The object was to place the transducer and liquid metal in a vacuum station so that no oxide would form on the surface. We were successful in demonstrating that liquid metals could be ejected on demand and that this technology could be used for making sheet metal in space.

Khuri-Yakub, B. T.↗
NASA NTRS1979

Recent developments in liquid-metal embrittlement

The paper reviews developments in liquid-metal embrittlement of the past 7 years including data on cyclic loading. Embrittlement by solid and liquid metals and by hydrogen has many common features, although the mechanism of embrittler transport differs. Fracture may occur in each type of embrittlement by environmentally assisted shear and by reduced cohesion; embrittlement under cyclic loading has been widely observed, with stress level, temperature, and substrate alloy composition and grain size being the major variables. The degree of embrittlement between any combination of environment (i.e. hydrogen, liquid metal, or solid metal) and substrate depends upon the strength of the interaction with the substrate, the kinetics of embrittler transport, the mutual solubility of embrittler and substrate, and a large number of test and microstructural conditions. A method of calculating the most significant of these variables and the strength of interaction was reviewed and predictions of embrittlement in previously untested couples were made.

Stoloff, N. S.↗
NASA NTRS1975

Analysis of liquid metal embrittlement from a bond energy viewpoint

Absorption induced embrittlement of solid metals by certain liquid metals is analyzed through an Engel-Brewer calculation of the solid-liquid interaction energy, and of the effect of the latter in reducing fracture surface energy. The reduction in fracture surface energy is estimated by comparison of the electronic contribution to the solid-liquid interaction energy with solid-solid bond energy for some 40 liquid-solid couples. Regular solution theory is used to estimate mutual solubility as the relative difference in parameter values. Embrittlement can be predicted by using reduction in fracture surface energy and solubility parameter difference as critical variables. The effect of solute additions to the liquid on the degree of embrittlement is interpreted via the same two variables; the principal effect of solutes is to modify solubility relationships at the solid-liquid interface.

Kelley, M. J.↗
NASA NTRS1973

Solute diffusion in liquid metals

A gas model of diffusion in liquid metals is presented. In this model, ions of liquid metals are assumed to behave like the molecules in a dense gas. Diffusion coefficient of solute is discussed with reference to its mass, ionic size, and pair potential. The model is applied to the case of solute diffusion in liquid silver. An attempt was made to predict diffusion coefficients of solutes with reasonable accuracy.

Bhat, B. N.↗
NASA NTRS1985

Liquid metal cooled reactors for space power applications

The technology basis for evaluation of liquid metal cooled space reactors is summarized. Requirements for space nuclear power which are relevant to selection of the reactor subsystem are then reviewed. The attributes of liquid metal cooled reactors are considered in relation to these requirements in the areas of liquid metal properties, neutron spectrum characteristics, and fuel form. Key features of typical reactor designs are illustrated. It is concluded that liquid metal cooled fast spectrum reactors provide a high confidence, flexible option for meeting requirements for SP-100 and beyond.

Bailey, S.↗
NASA NTRS1993

On the Shape of Liquid Metal Droplets in Electromagnetic Levitation Experiments

We present calculations and measurements on the shape of liquid metal droplets in electromagnetic levitation experiments. A normal stress balance model was developed to predict the shapes of liquid metal droplets that will be obtained in a microgravity experiment to measure the viscosity and surface tension of undercooled metals. This model was tested by calculating the droplet shapes in containerless experiments conducted to determine the surface tension of liquid metals. Inconsistencies associated with the results of a previous paper are elucidated. The computational results of the mathematical model are compared with the results of ground-based experiments for two different metals. The importance of the ratio of electromagnetic skin depth-to-droplet radius to the accuracy of the mathematical model is discussed. A planned alternate approach to modeling the shape by consideration of the entire droplet rather than only the surface is presented. As an example of an application. the influence of the shape on the splitting of the surface oscillation modes of levitated liquid metal droplets is discussed.

Schwartz, E.↗