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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Visualizing Flow Over Parametric Surfaces Using Line Integral Convolution

Line Integral Convolution (LIC) is a powerful technique for imaging and animating vector fields. We extend the LIC paradigm in three ways: (1) The existing technique is limited to vector fields over a regular Cartesian grid. We extend it to vector fields over parametric surfaces, such as those found in curvilinear grids, used in computational fluid dynamics simulations; (2) Periodic motion filters can be used to animate the flow visualization. When the flow lies on a parametric surface, however, the motion appears misleading. We explain why this problem arises and show how to adjust the LIC algorithm to handle it; (3) We introduce a technique to visualize vector magnitudes as well as vector direction. Cabral and Leedom have suggested a method for variable-speed animation, which is based on varying the frequency of the filter function. We develop a different technique based on kernel phase shifts which we have found to show substantially better results. Our implementation of these algorithms utilizes texture-mapping hardware to run in real time, which allows them to be included in interactive applications.

Forssell, Lisa↗
NASA NTRS2023

Trajectory Design and Early Mission Operations for the Lunar IceCube Mission

The Lunar IceCube (LIC) mission, a Next Space Technologies for Exploration Partnerships (NSTEP) program selection, was launched as a rideshare onboard Artemis-I on November 16th 2022, and deployed into a high energy lunar flyby trajectory. The final destination of the mission was a polar elliptical lunar orbit from which it could conduct spectroscopy observations of the lunar surface; however, a near rectilinear halo orbit (NRHO) was planned to be used as a staging orbit that divided the lunar transfer and low-thrust spiral phases of the mission. This paper presents the process used to design the LIC transfer trajectory from the high-energy deployment state to a 9:2 synodic resonance NRHO. Additional analyses performed, to assess the critical deployment to lunar flyby phase of the trajectory and to generate recovery trajectories following a loss of contact with the spacecraft, are described as well. Lessons learned from working on the LIC mission are presented to inform the design of similar future CubeSat missions.

Robert E Pritchett↗
DOE OSTI2021

Controlling MoO 2 and MoO 3 phases in MoO x /CNTs nanocomposites and their application to anode materials for lithium-ion batteries and capacitors

Molybdenum oxides (MoO 2 and MoO 3 ) are attractive anode materials for Li- and Na- ion batteries. Although there have been extensive studies on them individually, systematic and comparative studies are still lacking. Here, we demonstrate a facile and straightforward synthesis method to control the phase and oxidation state in the MoO x /CNTs nanocomposites via hydrothermal reaction followed by heat-treatment. By changing the gas atmosphere during the annealing process, well-dispersed MoO 2 /CNTs and MoO 3 /CNTs nanocomposites are formed without altering their overall morphology. This strategy enables us to investigate the true structure-property correlation of MoO x /CNTs nanocomposites by comparing the structure and electrochemical properties of MoO 2 /CNTs and MoO 3 /CNTs. When tested as anode materials for lithium-ion batteries, both HT-MoO 2&3 /CNTs electrodes show much-improved cycling stability and rate performance compared to the rod-shaped bulk MoO 3 electrode. In situ Mo K-edge x-ray absorption spectroscopy (XAS) has been further employed to compare and elucidate Li + storage mechanisms of both electrodes. When employed to the negative electrode of a high-power lithium-ion capacitor (LIC), the LIC full-cell composed of HT-MoO 3 /CNTs negative and activated carbon positive electrodes demonstrates impressive energy and power densities (~ 90 Wh kg –1 with 2000 W kg –1 ) and excellent cycling stability (96.8 % capacity retention after 300 cycles), revealing the versatility of the MoO x /CNTs electrodes in energy applications.

25 ENERGY STORAGE↗
DOE OSTI2021

Homoleptic Perchlorophenyl “Ate” Complexes of Thorium(IV) and Uranium(IV)

The reaction of AnCl 4 (DME) n (An = Th, n = 2; U, n = 0) with 5 equiv of LiC 6 Cl 5 in Et 2 O resulted in the formation of homoleptic actinide-aryl “ate” complexes [Li(DME) 2 (Et 2 O)] 2 [Li(DME) 2 ][Th(C 6 Cl 5 ) 5 ] 3 ([Li][1]) and [Li(Et 2 O) 4 ][U(C 6 Cl 5 ) 5 ] ([Li][2]). Similarly, the reaction of AnCl 4 (DME)n (An = Th, n = 2; U, n = 0) with 3 equiv of LiC 6 Cl 5 in Et 2 O resulted in the formation of heteroleptic actinide-aryl “ate” complexes [Li(DME) 2 (Et 2 O)][Li(Et 2 O) 2 ][ThCl 3 (C 6 Cl 5 ) 3 ] ([Li][3]) and [Li(Et 2 O) 3 ][UCl 2 (C 6 Cl 5 ) 3 ] ([Li][4]). Density functional calculations show that the An–C ipso σ-bonds are considerably more covalent for the uranium complexes vs the thorium analogues, in line with past results. Additionally, good agreement between experiment and calculations is obtained for the 13 C ipso NMR chemical shifts in [Li][1] and [Li][3]. Here, the calculations demonstrate a deshielding by ca. 29 ppm from spin–orbit coupling effects originating at Th, which is a direct consequence of 5f orbital participation in the Th–C bonds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Effects of catholyte aging on high-nickel NMC cathodes in sulfide all-solid-state batteries

Sulfide solid-state electrolytes (SSEs) in all-solid-state batteries (SSBs) are recognized for their high ionic conductivity and inherent safety. The LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) cathode offers a high thermodynamic potential of approximately 3.8 V vs. Li/Li + and a theoretical specific capacity of 200 mA h g −1 . However, the practical utilization of NMC811 in sulfide SSBs faces significant interfacial challenges. The oxidation instability of sulfide solid electrolytes against NMC811 and the formation of the cathode electrolyte interphase (CEI) during cycling lead to degradation and reduced cell performance. Volumetric changes in NMC during lithiation and de-lithiation can also cause detachment from sulfide electrolytes or internal particle cracking. Despite extensive galvanostatic cycling studies to address the issues, the calendar life of sulfide SSBs remains poorly understood. Here, we systematically studied the effects of four different catholytes on the calendar aging of LiNbO 3 (LNO)-coated NMC811, including Li 6 PS 5 Cl (LPSCl), Li 3 InCl 6 –Li 6 PS 5 Cl (LIC–LPSCl), Li 3 YCl 6 –Li 6 PS 5 Cl (LYC–LPSCl), and Li 10 GeP 2 S 12 (LGPS). Our results indicate that LPSCl provides optimal capacity retention when stored at high state-of-charge (SOC) at room temperature, but the LIC–LPSCl cathode shows significant capacity degradation and chemical incompatibility. We also established an effective electrochemical calendar aging testing protocol to simulate daily usage, enabling quick inference of the calendar life of SSBs. In conclusion, this new testing approach accelerates materials selection strategies for high-nickel NMC composite cathodes in sulfide SSBs.

25 ENERGY STORAGE↗
DOE OSTI2021

A laser inverse Compton scattering diagnostic to study runaway electron dynamics during tokamak disruptions

The goal is to design a new diagnostic based on laser inverse Compton scattering (LICS) to study the dynamics of runaway electron formation and their subsequent loss during triggered disruptions in DIII-D. It is known that better measurements of the runaway electron population, throughout the evolution of a disruption, is critical for mitigating the impact of energetic electron beams especially in high plasma current discharges such as those in reactor relevant burning plasmas. The goal of the LICS approach being designed for DIII-D is to measure the timeresolved spatial profile and energy distribution of the runaway electrons while they are in the core of the tokamak plasma. During the last year, a code was developed to simulate the signals from a new laser scattering diagnostic for DIII-D, which will measure the relativistic electron population expected in DIII-D after disruptions triggered by argon pellet injection.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1996

Enhanced Line Integral Convolution with Flow Feature Detection

The Line Integral Convolution (LIC) method, which blurs white noise textures along a vector field, is an effective way to visualize overall flow patterns in a 2D domain. The method produces a flow texture image based on the input velocity field defined in the domain. Because of the nature of the algorithm, the texture image tends to be blurry. This sometimes makes it difficult to identify boundaries where flow separation and reattachments occur. We present techniques to enhance LIC texture images and use colored texture images to highlight flow separation and reattachment boundaries. Our techniques have been applied to several flow fields defined in 3D curvilinear multi-block grids and scientists have found the results to be very useful.

Lane, David↗
NASA NTRS1999

Which Way Is the Flow?

The line integral convolution (LIC) technique has been known to be an effective tool for depicting flow patterns in a given vector field. There have been many extensions to make it run faster and reveal useful flow information such as velocity magnitude, motion, and direction. There are also extensions to unsteady flows and 3D vector fields. Surprisingly, none of these extensions automatically highlight flow features, which often represent the most important and interesting physical flow phenomena. In this sketch, a method for highlighting flow direction in LIC images is presented. The method gives an intuitive impression of flow direction in the given vector field and automatically reveals saddle points in the flow.

Kao, David↗
NASA NTRS1997

UFLIC: A Line Integral Convolution Algorithm for Visualizing Unsteady Flows

This paper presents an algorithm, UFLIC (Unsteady Flow LIC), to visualize vector data in unsteady flow fields. Using the Line Integral Convolution (LIC) as the underlying method, a new convolution algorithm is proposed that can effectively trace the flow's global features over time. The new algorithm consists of a time-accurate value depositing scheme and a successive feed-forward method. The value depositing scheme accurately models the flow advection, and the successive feed-forward method maintains the coherence between animation frames. Our new algorithm can produce time-accurate, highly coherent flow animations to highlight global features in unsteady flow fields. CFD scientists, for the first time, are able to visualize unsteady surface flows using our algorithm.

Shen, Han-Wei↗
NASA NTRS2003

Boundary Conditions of the Heliosphere

As described in the Revised Task Statement for this grant (submitted following the award at a reduced budget), my role in these investigations is to focus on the theoretical calculations relevant to the ionization state and dust content of the Local Cloud that surrounds the Solar System. An important motivation for our investigations is to aid in the interpretation of pick-up ion (PUI) and anomalous cosmic ray (ACR) observations which depends on knowledge of the flux of neutral atoms of various elements into the heliosphere. This flux depends on the ionization and elemental abundances of the gas of the Local Cloud. We have made substantial progress in our program to understand the ionization of the Local Cloud. Our steady state photoionization models are remarkably successful in accounting for the ionization observed both by line of sight (column density) observations towards nearby stars and in situ measurements. By lifting some of the simplifying assumptions in our earlier modeling we hope to make further progress in this understanding. In future work on this project we will continue our exploration of photoionization models, focusing on making sense of the differences between the LIC and the BC. In addition we will explore the effects of altered abundances in the hot gas on the ionization and thermal balance in the LIC.

Frisch, Priscilla C.↗
NASA NTRS2010

Introduction to Vector Field Visualization

Vector field visualization techniques are essential to help us understand the complex dynamics of flow fields. These can be found in a wide range of applications such as study of flows around an aircraft, the blood flow in our heart chambers, ocean circulation models, and severe weather predictions. The vector fields from these various applications can be visually depicted using a number of techniques such as particle traces and advecting textures. In this tutorial, we present several fundamental algorithms in flow visualization including particle integration, particle tracking in time-dependent flows, and seeding strategies. For flows near surfaces, a wide variety of synthetic texture-based algorithms have been developed to depict near-body flow features. The most common approach is based on the Line Integral Convolution (LIC) algorithm. There also exist extensions of LIC to support more flexible texture generations for 3D flow data. This tutorial reviews these algorithms. Tensor fields are found in several real-world applications and also require the aid of visualization to help users understand their data sets. Examples where one can find tensor fields include mechanics to see how material respond to external forces, civil engineering and geomechanics of roads and bridges, and the study of neural pathway via diffusion tensor imaging. This tutorial will provide an overview of the different tensor field visualization techniques, discuss basic tensor decompositions, and go into detail on glyph based methods, deformation based methods, and streamline based methods. Practical examples will be used when presenting the methods; and applications from some case studies will be used as part of the motivation.

Kao, David↗
NASA NTRS2019

Lunar Ice Cube: ongoing development of first generation deep space cubesat mission with compact broadband IR spectrometer

Lunar Ice Cube (LIC) is one of 13 6U cubesats that will be deployed by EM1 in cislunar space. LIC along with Lunar Flashlight and LunaH-Map, all focused on the search for volatiles but with very different payloads, will be the first deep space cubesats designed to address goals for both demonstrating new technologies and collecting scientific data. Effectively, as their developments are occurring in parallel, they are acting as prototypes for future deep space cubesats missions. One useful outcome of this experiment is to evolve a working paradigm for the development and operation of compact, cost-capped, standardized (supporting subsystems) spacecraft to serve the needs of diverse user communities.

Mason, Paul↗
NASA NTRSDate not supplied

Trajectory Optimization Methods and Applications at NASA Goddard

The process of spacecraft trajectory design frequently incorporates an optimization step in which one or more objectives, such as propellant consumption or time of flight, is minimized. Optimization is especially crucial for low-thrust mission design, due to the need to specify a thrust vector at every instant in time along a trajectory. At NASA's Goddard Space Flight Center (GSFC) a number of open-source tools have been developed for spacecraft trajectory optimization that utilize direct shooting and collocation methods. These tools have been effectively applied to cislunar, libration point, and interplanetary mission design for the Lunar IceCube, SWFO, and DAVINCI missions, among others. This presentation outlines the theory underlying these optimization tools along with the details of their application to several trajectory design problems, with a focus on the Lunar IceCube (LIC) mission. The LIC mission required a low-thrust trajectory from a high-energy deployment state to a lunar orbit, and its limited control authority necessitated the use of optimization tools and low-energy trajectory design techniques. The tools discussed demonstrate how the use of optimization methods expands mission capabilities and enables transformational science.

Robert Pritchett↗
DOE OSTI2024

AB-G0W0: A practical G0W0 method without frequency integration based on an auxiliary boson expansion

Common G0W0 implementations rely on numerical or analytical frequency integration to determine the G0W0 self-energy, which results in a variety of practical complications. Recently, we have demonstrated an exact connection between the G0W0 approximation and equation-of-motion quantum chemistry approaches [J. Tölle and G. Kin-Lic Chan, J. Chem. Phys. 158, 124123 (2023)]. Based on this connection, we propose a new method to determine G0W0 quasiparticle energies, which completely avoids frequency integration and its associated problems. To achieve this, we make use of an auxiliary boson (AB) expansion. We name the new approach AB-G0W0 and demonstrate its practical applicability in a range of molecular problems.

Chemistry↗
DOE OSTI2021

Comprehensive Insights into Nucleation, Autocatalytic Growth, and Stripping Efficiency for Lithium Plating in Full Cells

Synchrotron high-energy X-ray diffraction is used to enable nondestructive detection and quantification of heterogeneous lithium plating in working batteries. In this study a LiNi 0.5 Mn 0.3 Co 0.2 O 2 /graphite pouch cell was operated under 6C fast-charge rate for greater than 1200 cycles. The magnitude and spatial distribution of lithium plating, lithium stripping, and the effect of metallic lithium deposition on lithium intercalation into graphite were quantified. Fully intercalated graphite (LiC 6 ) was detected after discharge with a lateral distribution closely correlated with lithium plating, which can be used as a higher-sensitivity indicator for lithium plating. Over an extended cycle life, the overall metallic lithium concentration followed a sigmoidal curve indicating two-stage continuous nucleation and autocatalytic growth. The lithium stripping efficiency underwent an exponential decay as a function of cycle life as the buildup of metallic lithium hindered the efficient dissolution back into the electrolyte. The findings provide direct insights into the characteristics of lithium plating and stripping under realistic fast-charge conditions.

25 ENERGY STORAGE↗
DOE OSTI2020

Spatial dynamics of lithiation and lithium plating during high-rate operation of graphite electrodes

The principal inhibitor of fast charging lithium ion cells is the graphite negative electrode, where favorable conditions for lithium plating occur at high charge rates, causing accelerated degradation and safety concerns. The local response of graphite, both at the electrode and particle level, when exposed to fast charging conditions of around 6C is not well understood. Consequently, the conditions that lead to the onset of lithium plating, as well as the local dynamics of lithium plating and stripping, have also remained elusive. Here, we use high-speed (100 Hz) pencil-beam X-ray diffraction to repeatedly raster along the depth of a 101 μm thick graphite electrode in 3 μm steps during fast (up to 6C) charge and discharge conditions. Consecutive depth profiles from separator to current collector were each captured in 0.5 seconds, giving an unprecedented spatial and temporal description of the state of the electrode and graphite's staging dynamics during high rate conditions. The electrode is preferentially activated near the separator, and the non-uniformity increases with rate and is influenced by free-energy barriers between graphite's lithiation stages. The onset of lithium plating and stripping was quantified, occurring only within the first 15 μm from the separator. The presence of lithium plating changed the behavior of the underlying graphite, such as causing co-existence of LiC 6 and graphite in the fully discharged state. Finally, the staging behavior of graphite at different rates was quantified, revealing a high dependency on rate and drastic hysteresis between lithiation and delithiation.

25 ENERGY STORAGE↗