Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “La”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Silica-Aerogel Composites Opacified with La(0.7)Sr(0.3)MnO3

As part of an effort to develop improved lightweight thermal-insulation tiles to withstand temperatures up to 1,000 C, silica aerogel/fused-quartz-fiber composite materials containing La0.7Sr0.3MnO3 particles as opacifiers have been investigated as potentially offering thermal conductivities lower than those of the otherwise equivalent silica-aerogel composite materials not containing La(0.7)Sr(0.3)MnO3 particles. The basic idea of incorporating opacifying particles into silica-aerogels composite to reduce infrared radiative contributions to thermal conductivities at high temperatures is not new: it has been reported in a number of previous NASA Tech Briefs articles. What is new here is the selection of La(0.7)Sr(0.3)MnO3 particles as candidate opacifiers that, in comparison with some prior opacifiers (carbon black and metal nanoparticles), are more thermally stable. The preparation of a composite material of the present type includes synthesis of the silica-aerogel component in a sol-gel process. The La(0.7)Sr(0.3)MnO3 particles, made previously in a separate process, are mixed into the sol, which is then cast onto fused-quartz-fiber batting. Then the aerogel-casting solution is poured into the mold, where it permeates the silica fiber felt. After the sol has gelled, the casting is aged and then subjected to supercritical drying to convert the gel to the final aerogel form. The separate process for making the La(0.7)Sr(0.3)MnO3 particles begins with the slow addition of corresponding proportions of La(CH3COOH)3, Mn(CH3COOH)3, and Sr(NO3)2 to a solution of H2O2 in H2O. The solution is then peptized by drop-wise addition of NH4OH to obtain a sol. Next, the sol is dried in an oven at a temperature of 120 C to obtain a glassy solid. The solid is calcined at 700 C to convert it to La(0.7)Sr(0.3)MnO3. Then La(0.7)Sr(0.3)MnO3 particles are made by ball-milling the calcined solid. The effectiveness of La(0.7)Sr(0.3)MnO3 particles as opacifiers and thermal-conductivity reducers depends on the statistical distribution of particle sizes as well as the relative proportions of La(0.7)Sr(0.3)MnO3 and aerogel. For experiments performed thus far, samples of aerogel/fiber composites were formulated to have, variously, silica target density of 0.07 or 0.14 g/cu cm and to contain 30 percent of La(0.7)Sr(0.3)MnO3 in average particle size of 0.3 or 3 microns. The thermal conductivities of the samples containing the 3 micron La(0.7)Sr(0.3)MnO3 particles were found to be lower than those of the samples containing the 0.3 micron La(0.7)Sr(0.3)MnO3 particles. The optimum particle size is believed to be between 1 and 5 microns.

Rhine, Wendell↗
NASA NTRS2018

Tandem LA-ICP-MS & LIBS; A New Micro-Analytical Technique for the Measurement of Every Element in the Periodic Table

Laser Ablation ICP-MS (LA-ICP-MS) has been widely accepted as a microanalytical technique for in-situ trace (ppb) elemental analysis on the micron scale in a variety of geologic materials. LA-ICP-MS (single or multi-collector) provides both elemental and isotopic measurements critical for a wide range of geological research by generating a fine grained aerosol (nm scale) during the laser ablation event and delivering that aerosol to the ICP ion source of the mass spectrometer via an inert carrier gas. LA-ICP-MS, however, suffers from limitations in analyzing high ionization potential elements as well as elements subject to atmospheric and argon based interferences. LA-ICP-MS also has limitations in analyzing major elements due to detector saturation. An alternative laser ablation technique, Laser Induced Breakdown Spectroscopy (LIBS), employs an optical spectrometer integrated into the laser ablation system that analyzes the laser induced plasma at the sample surface across the entire optical spectrum for emission lines of every element in the periodic table. Elements that are difficult or impossible to measure with LA-ICP-MS are now possible to analyze with LIBS down to low ppm levels with CCD and/or ICCD detection. We introduce a new laser based technique, “Tandem LA-LIBS”, that combines LA for ICP-MS and LIBS into one integrated laser ablation system. This system has the effect of expanding the elemental coverage and the dynamic range of the laser ablation experiment as measurements from ppb to % level matrix elements can now be analyzed in a single ablation experiment. We present both femtosecond and nanosecond Tandem LA-LIBS quantitative and qualitative data on wide range of geological materials for those elements that are difficult or impossible by traditional LA-ICP-MS techniques such as F, H, O, N, C, S, halogens, etc. We also demonstrate that the simultaneous measurement of trace, minor and major elements are now possible in a single laser ablation experiment with Tandem LA-LIBS technology.

LA-ICP-MS↗
NASA NTRS2023

Multiyear La Niña Events and Multiseason Drought in the Horn of Africa

One of the primary sources of predictability for seasonal hydroclimate forecasts are sea surface temperatures (SSTs) in the tropical Pacific, including El Niño–Southern Oscillation. Multiyear La Niña events in particular may be both predictable at long lead times and favor drought in the bimodal rainfall regions of East Africa. However, SST patterns in the tropical Pacific and adjacent ocean basins often differ substantially between first- and second-year La Niñas, which can change how these events affect regional climate. Here, we demonstrate that multiyear La Niña events favor drought in the Horn of Africa in three consecutive seasons [October–December (OND), March–May (MAM), OND]. But they do not tend to increase the probability of a fourth season of drought owing to the sea surface temperatures and associated atmospheric teleconnections in the MAM long rains season following second-year La Niña events. First-year La Niñas tend to have both greater subsidence over the Horn of Africa, associated with warmer waters in the west Pacific that enhance the Walker circulation, and greater cross-continental moisture transport, associated with a warm tropical Atlantic, as compared to second-year La Niñas. Both the increased subsidence and enhanced cross-continental moisture transport favors drought in the Horn of Africa. Our results provide a physical understanding of the sources and limitations of predictability for using multiyear La Niña forecasts to predict drought in the Horn of Africa.

Climate variability↗
NASA NTRS2024

High Precision and Spatial Resolution Chemical Interrogation of Planetary Materials Using fs-LA/LIBS in Tandem With Multi-Collector ICP-MS

Combining femtosecond laser ablation (fs-LA) with laser-induced breakdown spectroscopy (LIBS), together with multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS), can provide remarkable insights into the composition, structure, and therefore geologic history of planetary materials and their terrestrial analogs. Using the Applied Spectra iX-fs-Tandem LA-LIBS Instrument and the Nu SP1700 MC-ICP-MS housed within the Center for Isotope Cosmochemistry and Geochronology at NASA Johnson Space Center, we present preliminary tandem fs-LA-(MC)-ICP-MS/LIBS measurements of planetary analog materials. The synergistic integration of fs-LA-LIBS offers high spatial resolution elemental mapping, enabling the identification of microscale variations within samples. Simultaneously, the MC-ICP-MS can deliver precise isotopic analyses, and integrating the two datasets yields a wealth of geochemical information for a given sample. LA-based chemical mapping experiment designs are contingent on the information sought (i.e., quantitative, or semi-quantitative) and the preferred or available volume of material removed for the analysis. For example, occasionally, there are significant limitations in the depth of ablation due to the sample value, the amount of material available, or simply the need to coordinate with other in-situ techniques. In these limited sample scenarios, the “depth-controlled” chemical maps allow for precise post-mapping ion-polishing of the sample, while the isotopic and elemental maps can be used for targeting future analyses (e.g., conventional LA analyses, SIMS analyses, and micro milling for solution ICP-MS/TIMS). The emerging methodology will establish a powerful tool for investigation of astromaterials and materials returned by future planetary sample science missions.

Jacob B Setera↗
NASA NTRS2011

The International Summer School on Land Cover Change and Hydroclimate of the La Plata Basin

The La Plata Basin (LPB) in southern South America has been subject to land cover and land use changes (LCLUCs) since colonial times and with an accelerated rate in the last decades and over extensive areas. The work of Ameghino even suggested that there were relations between those land use changes and the frequency of droughts and floods in the region. Despite this early knowledge, not much is known of the potential impacts of LCLUC on the hydroclimate of the La Plata basin. Besides, over the last century much of the La Plata Basin has had a reported increase in precipitation and heavy rains, and these changes along with an increase in population growth - have resulted in more adverse effects from flooding. To draw attention to these issues, during two weeks in November 2009 the International Summer School on Land Cover Change and Hydroclimate of the La Plata Basin was organized at the grounds of the Itaip Hydropower Plant in Brazil. The school was the result of the combination of interests between the La Plata Basin Regional Hydroclimate Project, the Inter-American Institute for Global Change Research (IAI), and the International Hydroinformatics Center (IHC) in Itaip . LPB is an umbrella project endorsed by the Global Energy and Water Cycle Experiment (GEWEX) and the Climate Prediction and Variability (CLIVAR), both of the World Climate Research Programme (WCRP). LPB has made a priority to train young scientists and promote interdisciplinary collaborations in areas related to Climate, Hydrology, Ecology and Agriculture. The IAI, with a similar agenda, was a natural partner to develop this Summer School, which in turn benefited from Itaipu s interest in relating with the scientific community of neighboring countries. The choice of location (Itaip Technological Park) was made so that participants could relate research usually done at academic institutions to applications and operations at one of the largest hydropower plants in the world. The school was attended by 45 advanced graduate students and young scientists with different backgrounds from seven countries, including less technically advanced ones in the region..

Berbery, Ernesto Hugo↗
NASA NTRSDate not supplied

LA-8 Computational Analysis and Validation Studies Using FlightStream

With the emerging market of Urban Air Mobility and the associated unique new flight vehicles with the capability of vertical takeoff and landing, design tools need to be calibrated to assist in the development of these new flight vehicle concepts. Distributed electric propulsion (DEP) covers these vehicles with high-energy flow from the array of motors, which leads to extensive propulsion/airframe interaction effects. With limited experimental data of vehicles using DEP and vehicle operation across a large range of angles of attack, including post-stall conditions, there is a lack of validated design tools to advance new vehicle concepts that have blown wings and operate in multiple flight modes. Although some CFD tools can handle the integration of multiple propulsors and unique geometries, the computational time with a full vehicle is extraordinary. FlightStream, a surface vorticity flow solver that can run in a fraction of the time of other CFD methods, has been evaluated using the Langley Aerodrome No. 8 (LA-8) vehicle as a test case. The LA-8 vehicle is a DEP tandem tilt-wing research vehicle that was designed, built, and tested at NASA Langley Research Center. The LA-8 design features both high-performance and high-technical risks aspects. The vehicle has gone through extensive design of experiments wind tunnel testing in the NASA Langley 12-Foot Low-Speed Wind Tunnel in order to capture all modes of operation. In addition, the LA-8 vehicle has undergone wind tunnel testing with and without propellers, which contributes to the validation of FlightStream for aerodynamic performance in blown and unblown wing cases. This study shows that FlightStream can produce trends and magnitudes of the lift and drag coefficients similar to the data collected from the wind tunnel testing of LA-8. The test cases were both blown and unblown wing cases and with and without high lift control surface deflections.

Steven Curtis Geuther↗
NASA NTRS1991

Theoretical study of the bonding of Sc, Y, and La singly charged and dipositive ions to C2H2, C2H4, and C3H6

The interaction of the Sc and Y singly-charged and dipositive ions with C2H2, C2H4, and C3H6 is studied using electronic structure calculations that include high levels of electron correlation. These results are compared with comparable calculations performed previously for La(+) and La(2+). For C2H2 and C2H4, all three metal ions insert into the C-C pi bond, making a three-membered ring. The optimal structures for the MC3H6(+) ions all involve rearrangement to make a four-membered ring. The strength of the metal-ligand bond for the singly charged ions follows the order La greater than Sc equal to about Y. In contrast, the bonds involving the dipositive ions are electrostatic, so that the binding energy increases as the size of the ion decreases, leading to the trend Sc greater than Y greater than La.

Bauschlicher, Charles W., Jr.↗
NASA NTRS2020

Thermal Analysis, Compressibility, and Decomposition of Synthetic Bastnäsite-(La) to Lanthanum Oxyfluoride

Understanding basic material properties of rare earth element (REE) bearing minerals such as their phase stability and equations of state can assist in understanding how economically viable deposits might form. Bastnäsite is the most commonly mined REE bearing mineral. We synthesized the lanthanum-fluoride end member, bastnäsite-(La) (LaCO3F), and investigated its thermal behavior and decomposition products from 298 K to 1173 K under ambient pressure conditions through thermogravimetric analysis, differential scanning calorimetry, evolved gas analysis, and high temperature powder X-ray diffraction. We also investigated the compressibility of bastnäsite-(La) via single crystal X-ray diffraction in diamond anvil cells at an ambient temperature up to 11.3 GPa and from 4.9 GPa to 7.7 GPa up to 673 K. At ambient pressure, bastnäsite-(La) was stable up to 598 K in air, where it decomposed into CO2 and tetragonal γ-LaOF. Above 948 K, cubic α-LaOF is stable. High temperature X-ray diffraction data were used to fit the Fei thermal equation of state and the thermal expansion coefficient α(sub 298) for all three materials. Bastnäsite-(La) was fit from 298 K to 723 K with V(sub 0) = 439.82 Å(exp 3), α(sub 298) = 4.32 × 10(exp -5) K(exp -1), a(sub 0) = −1.68 × 10(exp -5) K(exp -1), a(sub 1) = 8.34 × 10(exp -8) K(exp -1), and a(sub 2) = 3.126 K(exp -1). Tetragonal γ-LaOF was fit from 723 K to 948 K with V(sub 0) = 96.51 Å(exp 3), α(sub 298) = 2.95×10(exp -4) K(exp -1), a(sub 0) = −2.41×10(exp -5) K(exp -1), a(sub 1) = 2.42×10(exp -7) K(exp -1), and a(sub 2) = 41.147 K(exp -1). Cubic α-LaOF was fit from 973 K to 1123 K with V(sub 0) = 190.71 Å(exp 3), α(sub 298) = −1.12×10(exp -5) K(exp -1), a(sub 0) = 2.36×10(exp -4) K(exp -1), a(sub 1) = −1.73 × 10(exp -7) K(exp -1), and a(sub 2) = −17.362 K(exp -1). An ambient temperature third order Birch–Murnaghan equation of state was fit with V(sub 0) = 439.82 Å(exp 3), K(sub 0) = 105 GPa, and K’ = 5.58.

Bastnäsite↗
NASA NTRS2021

The Impact and Recovery of Asteroid 2018 LA

The June 2, 2018 impact of asteroid 2018 LA over Botswana is only the second asteroid detected in space prior to impacting over land. Here, we report on the successful recovery of meteorites. Additional astrometric data refine the approach orbit and define the spin period and shape of the asteroid. Video observations of the fireball constrain the asteroid's position in its orbit and were used to triangulate the location of the fireball's main flare over the Central Kalahari Game Reserve. Twenty-three meteorites were recovered. A consortium study of eight of these classifies Motopi Pan as an HED polymict breccia derived from howardite, cumulate and basaltic eucrite, and diogenite lithologies. Before impact, 2018 LA was a solid rock of ~156 cm diameter with high bulk density ~2.85 g cm^(−3), a relatively low albedo pV ~ 0.25, no significant opposition effect on the asteroid brightness, and an impact kinetic energy of ~0.2 kt. The orbit of 2018 LA is consistent with an origin at Vesta (or its Vestoids) and delivery into an Earth-impacting orbit via the ν6 resonance. The impact that ejected 2018 LA in an orbit toward Earth occurred 22.8 ± 3.8 Ma ago. Zircons record a concordant U-Pb age of 4563 ± 11 Ma and a consistent 207Pb/206Pb age of 4563 ± 6 Ma. A much younger Pb-Pb phosphate resetting age of 4234 ± 41 Ma was found. From this impact chronology, we discuss what is the possible source crater of Motopi Pan and the age of Vesta's Veneneia impact basin.

Peter Jenniskens↗
NASA NTRS2021

The Impact and Recovery of Asteroid 2018 LA

The June 2, 2018 impact of asteroid 2018 LA over Botswana is only the second asteroid detected in space prior to impacting over land. Here, we report on the successful recovery of meteorites. Additional astrometric data refine the approach orbit and define the spin period and shape of the asteroid. Video observations of the fireball constrain the asteroid’s position in its orbit and were used to triangulate the location of the fireball’s main flare over the Central Kalahari Game Reserve. Twenty-three meteorites were recovered. A consortium study of eight of these classifies Motopi Pan as an HED polymict breccia derived from howardite, cumulate and basaltic eucrite, and diogenite lithologies. Before impact, 2018 LA was a solid rock of ~156 cm diameter with high bulk density ~2.85 g cm(exp -3), a relatively low albedo p(sub v) ~0.25, no significant opposition effect on the asteroid brightness, and an impact kinetic energy of ~0.2 kt. The orbit of 2018 LA is consistent with an origin at Vesta (or its Vestoids) and delivery into an Earth-impacting orbit via the m6 resonance. The impact that ejected 2018 LA in an orbit toward Earth occurred 22.8 ± 3.8 Ma ago. Zircons record a concordant U-Pb age of 4563 ± 11 Ma and a consistent 207Pb/206Pb age of 4563 ± 6 Ma. A much younger Pb-Pb phosphate resetting age of 4234 ± 41 Ma was found. From this impact chronology, we discuss what is the possible source crater of Motopi Pan and the age of Vesta’s Veneneia impact basin.

Peter Jenniskens↗
NASA NTRS2023

The Triple-Dip La Niña of 2020–22: Updates to the Correlation of ENSO With the Termination of Solar Cycles

The Sun provides the energy required to sustain life on Earth and drive our planet’s atmosphere. However, establishing a solid physical connection between solar and tropospheric variability has posed a considerable challenge across the spectrum of Earth-system science. Over the past few years a new picture to describe solar variability has developed, based on observing, understanding and tracing the progression, interaction and intrinsic variability of the magnetized activity bands that belong to the Sun’s 22-year magnetic activity cycle. A solar cycle’s fiducial clock does not run from the canonical min or max, instead resetting when all old cycle polarity magnetic flux is cancelled at the equator, an event dubbed the “termination” of that solar cycle, or terminator. In a recent paper, we demonstrated with high statistical significance, a correlation between the occurrence of termination of the last five solar cycles and the transition from El Niño to La Niña in the Pacific Ocean, and predicted that there would be a transition to La Niña in mid 2020. La Niña did indeed begin in mid-2020, and endured into 2023 as a rare “triple dip” event, but some of the solar predictions made did not occur until late 2021. This work examines what went right, what went wrong, the correlations between El Niño, La Niña and geomagnetic activity indices, and what might be expected for the general trends of large-scale global climate in the next decade.

Robert J Leamon↗
NASA NTRS1994

Geosat-derived sea level and surface current anomalies in the equatorial Pacific during the 1986-1989 El Nino and La Nina

Equatorial wave dynamics are essential in most oceanic models for reproducing aspects of the El Nino-Southern Oscillation (ENSO) phenomenon. Observational evidence of first baroclinic equatorial Kelvin and first symmetric meridional Rossby waves is found in Geosat-derived sea level anomalies (SLA) and surface zonal current anomalies (ZCA) in the equatorial Pacific ocean during the 1986-1987 El Nino and the ensuing 1988-1989 La Nina. This was made possible after extensive quality control and specific processing of the recently improved Geosat geophysical data records pertaining to the 17-day Exact Repeat Mission. In particular, the processing was made so that the Geosat-derived ZCA best fit near-surface zonal currents from three equatorial moorings at 165 deg E, 140 deg W, and 110 deg W. The Geosat-derived SLA and ZCA are decomposed into first baroclinic equatorial Kelvin and gravest Rossby modes. The emphasis is then put on the chronology of the ZCA at the equator where the currents are the most energetic and where Kelvin and first symmetric Rossby waves explain most of the variance in ZCA, in similar proportion. The 1986-1987 El Nino is mostly characterized by a strong downwelling Kelvin wave in December 1986, a series of downwelling Kelvin waves in March-October 1987, and a strong upwelling Rossby wave in March-September 1987. These waves are consistent with wind forcing, and all give rise to notable eastward ZCA for almost an entire year. During El Nino-La Nina transition period there is the occurrence of two downwelling Rossby waves originating from the eastern Pacific at times of favorable wind forcing. These Rossby waves switch the basin-wide ZCA from eastward to westward, terminating the warm event. Then, the 1988-1989 La Nina shows the generation of a series of upwelling Kelvin waves which are clearly identified in March/April and September/October 1988. These upwelling Kelvin waves are apparently related to the enhencement of the trade wind in the western half of the basin. These waves maintain the basin-wide westward ZCA for more than a year, although the ZCA is slightly reduced ba front of upwelling Rossby waves in phase with the normal seasonal cycle. The Kelvin wave forcing and sign of kelvin wave contribution versus Rossby wave contribution to ZCA in the western Pacific are discussed, and we conclude that neither pleads in favor of the delayed action oscillator mechanism.

Delcroix, Thierry↗
NASA NTRS2002

Satellite-Based Surface Heat Budgets and Sea Surface Temperature Tendency in the Tropical Eastern Indian and Western Pacific Oceans for the 1997/98 El Nino and 1998/99 La Nina

The 1997/98 is a strong El Nino warm event, while the 1998/99 is a moderate La Nina cold event. We have investigated surface heat budgets and sea surface temperature (SST) tendency for these two events in the tropical western Pacific and eastern Indian Oceans using satellite-retrieved surface radiative and turbulent fluxes. The radiative fluxes are taken from the Goddard Satellite-retrieved Surface Radiation Budget (GSSRB), derived from radiance measurements of the Japanese Geostationary Meteorological Satellite 5. The GSSRB covers the domain 40 deg S - 4 deg N, 90 deg E-17 deg W and a period from October 1997 to December 2000. The spatial resolution is 0.5 deg x 0.5 deg lat-long and the temporal resolution is 1 day. The turbulent fluxes are taken from Version 2 of the Goddard Satellite-based Surface Turbulent Fluxes (GSSTF-2). The GSSTF-2 has a spatial resolution of 1 deg x 1 deg lat-long over global Oceans and a temporal resolution of 1 day covering the period July 1987-December 2000. Daily turbulent fluxes are derived from the S S M (Special Sensor Microwave/Imager) surface wind and surface air humidity, and the SST and 2-m air temperature of the NCEP/NCAR reanalysis, using a stability-dependent bulk flux algorithm. The changes of surface heat budgets, SST and tendency, cloudiness, wind speed, and zonal wind stress of the 1997/98 El Nino relative to the1998/99 La Nina for the northern winter and spring seasons are analyzed. The relative changes of surface heat budgets and SST tendency of the two events are quite different between the tropical eastern Indian and western Pacific Oceans. For the tropical western Pacific, reduced solar heating (more clouds) is generally associated with decreased evaporative cooling (weaker winds), and vise versa. The changes in evaporative cooling over-compensate that of solar heating and dominate the spatial variability of the changes in net surface heating. Both solar heating and evaporative cooling offset each other to reduce interannual variability of net surface heating. In addition, the area of increased SST tendency is larger than that of increased net surface heating, due to less solar radiation penetration through the bottom of deeper ocean mixed layer (stronger winds). For the tropical eastern Indian Ocean, enhanced solar heating (less clouds) is generally associated with reduced evaporative cooling (weaker winds). Both solar heating and evaporative cooling reinforce each other to increase interannual variability of net surface heating. In addition, the area of increased SST tendency is smaller than that of increased net surface heating in the southern domain. The relative changes in wind and zonal wind stress indicate more solar radiation penetration through the ocean mixed layer and more northward heat transport by Ocean current from the south to the north Indian Ocean for the El Nino than for the La Nina.

Chou, Shu-Hsien↗
NASA NTRS1996

Infrared Optical Properties of La(sub 0.7)Ca(sub 0.3)MnO(sub 3) Epitaxial Films

The reflectance of La(sub 0.7)Ca(sub 0.3)MnO(sub 3) epitaxial films on perovskite substrates with a range of lattice constants is studied in the frequency range of 50 cm(sup -1) - 5000cm(sup -1). The complex dielectric functions of the bare La(sub 0.7)Ca(sub 0.3)MnO(sub 3) films are obtained by modeling the measured reflectivity spectra of the two-layer La(sub 0.7)Ca(sub 0.3)MnO(sub 3)/substrate system with separaately measured dielectric functions of the bare substrate.

lattice distortion epitaxial films lattice polaron↗
NASA NTRS2011

Sol-Gel Synthesis of La(0.6)Sr(0.4)CoO(3-x) and Sm(0.5)Sr(0.5)CoO(3-x) Cathode Nanopowders for Solid Oxide Fuel Cells

Nanopowders of La(0.6)Sr(0.4)CoO(3-x) (LSC) and Sm(0.5)Sr(0.5)CoO(3-x) (SSC) compositions, which are being investigated as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC) with La(Sr)Ga(Mg)O(3-x) (LSGM) as the electrolyte, were synthesized by low-temperature sol-gel method using metal nitrates and citric acid. Thermal decomposition of the citrate gels was followed by simultaneous DSC/TGA methods. Development of phases in the gels, on heat treatments at various temperatures, was monitored by x-ray diffraction. Solgel powders calcined at 550 to 1000 C consisted of a number of phases. Single perovskite phase La(0.6)Sr(0.4)CoO(3-x) or Sm(0.5)Sr(0.5)CoO(3-x) powders were obtained at 1200 and 1300 C, respectively. Morphological analysis of the powders calcined at various temperatures was done by scanning electron microscopy. The average particle size of the powders was approx.15 nm after 700 C calcinations and slowly increased to 70 to 100 nm after heat treatments at 1300 to 1400 C.

Bansal, Narottam P.↗
NASA NTRS2015

Climate Variability Drives Plankton Community Composition Changes: the 2010-2011 El Nino to La Nina Transition Around Australia

The strong La Nina of 2010-2011 provided an opportunity to investigate the ecological impacts of El Nino-Southern Oscillation on coastal plankton communities using the nine national reference stations around Australia. Based on remote sensing and across the entire Australian region 2011 (La Nina) was only modestly different from 2010 (El Nino) with the average temperature declining 0.2 percent surface chlorophyll a up 3 percent and modelled primary production down 14 percent. Other changes included a poleward shift in Prochlorococcus and Synechococcus. Along the east coast, there was a reduction in salinity, increase in nutrients, Chlorophytes and Prasinophytes (taxa with chlorophyll b, neoxanthin and prasinoxanthin). The southwest region had a rise in the proportion of 19-hexoyloxyfucoxanthin; possibly coccolithophorids in eddies of the Leeuwin Current and along the sub-tropical front. Pennate diatoms increased, Ceratium spp. decreased and Scrippsiella spp. increased in 2011. Zooplankton biomass declined significantly in 2011. There was a reduction in the abundance of Calocalanus pavo and Temora turbinata and increases in Clausocalanus farrani, Oncaea scottodicarloi and Macrosetella gracilis in 2011. The changes in the plankton community during the strong La Nina of 2011 suggest that this climatic oscillation exacerbates the tropicalization of Australia.

phytoplankton↗
NASA NTRS2017

Diffusivities of Redox-Sensitive Elements in Basalt vs. Oxygen Fugacity Determined by LA-ICP-MS

Several diffusion experiments were conducted in a piston cylinder device across a range of oxygen fugacities (FMQ-3 FMQ-1.2, FMQ+6) at 1 GPa and 1300 C. This was done to explore the effects of oxygen fugacity (fO2) on diffusivity of redox sensitive trace elements. This allows investigation of how these elements diffuse across the fO2 range encountered in different reservoirs on planets and moons in our solar system. The University of Rochester LA-ICP-MS system was used for analysis of samples. Analyses were conducted using an Agilent 7900 quadrupole mass spectrometer connected to a Photon Machines 193 nm G2 laser ablation (LA) system equipped with a HelEx 2-volume sample chamber. Spots used were 35 micrometers circles spaced at 65 micrometers intervals. Laser fluence was 7.81 J/cm^2 with a rep rate of 10 Hz. The iolite software package was used to reduce data collected from laser ablation analysis of experiments with Si-29 used as the internal standard isotope. Iolite's global fit module was used to simultaneously fit elements' diffusivities in each experiment while keeping the Matano interface constant. Elements analysed include V, Nb, W, Mo, La, Ce, Pr, Sm, Eu, Gd, Ta, and W. Figures

Szumila, Ian↗
NASA NTRSDate not supplied

Application of High-Spatial Resolution LA-MC-ICP-MS in Planetary Materials

High-precision stable and radiogenic isotopic measurements of planetary materials can help elucidate processes taking place during early Solar System formation, as well as during subsequent planetary differentiation. Laser Ablation Multi Collector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICP-MS) adds the valuable ability of preserving the spatial context of these isotopic measurements, by sampling small sample volumes (~10 – 60 um diameter) using a pulsed laser system. In the Center for Isotope Cosmochemistry and Geochronology (CICG) at NASA Johnson Space Center, these in-situ isotopic measurements are primarily made using the Applied SpectraTM iX-fs-Tandem LA-LIBS Instrument coupled to the Nu InstrumentsTM SP1700 MC-ICP-MS. The instrumental set-up also provides simultaneous Laser Induced Breakdown Spectroscopy (LIBS) measurements and the potential use of a low energy path with a collision/reaction cell for additional interference removal, though we focus here on the typical high-energy LA-MC-ICP-MS operation. We will provide examples of stable (e.g., Mg) and radiogenic (e.g., Lu-Hf) isotopic systems measured in planetary materials and their terrestrial analogs. The measurement of mass dependent Mg isotopic variations is an important tool for reconstructing processes such as evaporation and condensation of solids in the solar nebula. For early Solar System samples, Mg isotope measurements are also important for the short-lived (t1/2 = 0.7 Ma) Al-Mg chronometer. During laser ablation analyses, the measurement of the Al-Mg isotopic system is made in medium mass resolution (RP ~9500 at ~20% transmission) to limit interferences from 48Ti2+ and 48Ca2+ on 24Mg+, in addition to 52Cr2+ and 12C14N+ on 26Mg+. Measured in the mineral zircon, the 176Lu-176Hf decay system is often used for understanding the growth of continents on Earth, and is also a vital aid in deciphering early large-scale planetary differentiation processes, such as the crystallization of the lunar magma ocean, which is thought to be responsible for much of the Moon’s crust. Lu-Hf measurements are made in low resolution mode (RP <2000), with 10 ion masses (from 171Yb to 180Hf) measured simultaneously to facilitate corrections for isobaric interferences from 176Yb and 176Lu on 176Hf.

Jacob B Setera↗