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The DOE E3SM version 2.1: overview and assessment of the impacts of parameterized ocean submesoscales

The U.S. Department of Energy's Energy Exascale Earth System Model (E3SM) version 2.1 builds on E3SMv2 with several changes, with the most notable being the addition of the Fox-Kemper et al. (2011) mixed-layer eddy parameterization. This parameterization captures the effect of finite-amplitude, mixed-layer eddies as an overturning streamfunction and has the primary function of restratification. Herein, we outline the changes to the mean climate state of E3SM that were introduced by the addition of this parameterization. Overall, the presence of the submesoscale parameterization improves the fidelity of the v2.1 simulation by reducing the ocean surface biases in the North Atlantic present in v2, as illustrated by changes in the climatological sea surface temperature and salinity and the Arctic sea-ice extent. Other impacts include a slight shoaling of the mixed-layer depths in the North Atlantic and a small improvement in the Atlantic Meridional Overturning Circulation (AMOC). We note that the expected shoaling due to the parameterization is regionally dependent in our coupled configuration. In addition, we investigate why the parameterization and its impacts on mixed-layer depth have little impact on the simulated AMOC: despite increased dense-water formation in the Norwegian Sea, only a small fraction of the water formed makes its way south into the North Atlantic basin. Version 2.1 also exhibits small improvements in the atmospheric climatology, with smaller biases in many notable quantities and modes of variability.

54 ENVIRONMENTAL SCIENCES↗

Arctic Impact Identification with Less Data Using Variable Relationships: An Exploratory Express LDRD project.

Regional impacts from sea ice loss can be challenging to separate from internal climate variability, potentially requiring thousands of ensemble members. East Asian wintertime cooling has been linked to sea ice loss from present day conditions in the Polar Amplification Model Intercomparison Project with these large ensemble counts. This cooling is theorized to arise from a strengthened Siberian High and East Asian Jet response. The strengthened Siberian High can be detected with one fifth the ensemble members needed for the East Asian wintertime cooling in a single model. We thus hypothesize that leveraging relationships between multiple variables in a conditional pathways-based approach would reduce the number of required ensemble members to conclusively attribute East Asian wintertime cooling to future sea ice concentrations. In all analyzed cases, confidence was increased when evaluating sea ice loss’s responsibility for the joint effects of East Asian cooling, East Asian Jet strengthening, and Siberian High strengthening over just East Asian cooling. However, we were not able to confidently attribute future East Asian wintertime cooling to sea ice loss in a single model. We found that significant intra-ensemble variability within single Earth System Models (ESMs) produced highly uncertain forcing response models upon which attribution results were undermined. We were able to show that ensemble mean seasonally averaged metrics from multiple ESMs greatly improved the accuracy of the forcing response linear models and exposed the necessity of all three steps in the pathway (sea ice area, Siberian High pressure, and East Asian Jet speed) for accurate prediction of East Asian wintertime cooling. Although all three steps were necessary, East Asian wintertime cooling possesses a large dependence on the Siberian High pressure, which weakens the confidence associated with overall strong joint-attribution comparing present day and future scenarios. We believe transitioning the pathway nodes to relative changes between the Siberian High and Aleutian Low as well as between the midlatitude westerlies and subtropical jet in the East Asianj Jet region may be able to produce significant attribution more fully dependent upon all three steps. Ultimately, this research demonstrates the simple extensibility of conditional pathways-based attribution to sea ice loss forcing on the Earth system.

54 ENVIRONMENTAL SCIENCES↗

The disproportionate impact of enhanced evaporation from melting arctic sea ice on cold-season land precipitation trends

Diminishing Arctic sea ice has led to enhanced evaporation from the Arctic marginal seas (AMS), which is expected to alter precipitation over land. In this work, AMS evaporation is numerically tracked to quantify its contribution to cold-season (October–March) precipitation over land in the Northern Hemisphere during 1980–2021. Results show a significant 32% increase in AMS moisture contribution to land precipitation, corresponding to a 16% increase per million square km loss of sea ice area. Especially over the high-latitude land, despite the fractional contribution of AMS to precipitation being relatively low (8%), the augmented AMS evaporation contributed disproportionately (42%) to the observed upward trend in precipitation. Notably, northern East Siberia exhibited a substantial rise in both the amount and fraction of extreme snowfall sourced from the AMS. Our findings underscore the importance of the progressively ice-free Arctic as an important contributor to the escalating levels of cold-season precipitation and snowfall over northern high-latitude land.

54 ENVIRONMENTAL SCIENCES↗

The two radiative states of the Arctic atmosphere and their impacts on the surface energy budget of sea ice

The surface energy budget (SEB) is a central regulator of Arctic climate and sea ice evolution, yet its processes remain poorly constrained due to sparse observations and complex, coupled surface-atmosphere interactions. This study leverages year-long measurements from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) to provide the most comprehensive assessment to date of the central Arctic SEB and its modulation by atmospheric variability. Ship- and ice-based observations from October 2019 to September 2020 were used to directly measure or tightly constrain each term of the SEB, leading to exceptional energetic closure with the seasonal snow and ice mass balance. The analysis reveals strong seasonal transitions in atmosphere-surface energy transfer that are modulated by the atmospheric state and constrained by the ability of the surface temperature to respond. Classification of the atmosphere into its two dominant radiative states—the semi-transparent (ST) and opaque (OP)—highlights the central role of synoptic-scale variability in clouds. The ST atmospheric state dominated the long winter ice growth season, with limited cloudiness supporting persistent surface radiative cooling and ice growth. The OP state, associated with liquid-containing or thick ice clouds, became dominant in spring, with the combination of increased solar heating and cloud surface longwave warming driving ice and snow melt. Eddy covariance versus bulk approaches for deriving surface turbulent heat fluxes provide vastly different perspectives on the role of turbulence in modulating the SEB. These results establish a high-quality benchmark dataset for Arctic SEB studies and demonstrate how the balance of atmospheric radiative states exerts a first-order control on the annual evolution of the sea ice. The findings have broad implications for advancing observing technologies, understanding Arctic amplification, improving climate models, and predicting future sea ice change.

54 ENVIRONMENTAL SCIENCES↗

Variability in Ice Nucleating Particles Across Greater Houston Texas

The concentration and cloud-forming potential of a region's ice nucleating particle (INP) population have uncertain impacts on deep convective clouds. Specifically, ice nucleating particles (INPs) may affect various cloud properties related to the formation, lifetime, and precipitation of deep convective clouds. As part of the U.S. Department of Energy's TRacking Aerosol and Convection interaction ExpeRiment (TRACER) campaign, researchers from Texas A&M University deployed three Davis Rotating-drum Universal-size-cut Monitoring (DRUM) samplers throughout Greater Houston, Texas from June through September 2022. Ambient particles, collected at the surface with the DRUM samplers in four aerodynamic diameter size ranges (>3, 3–1.2, 1.2–0.34, and 0.34–0.15 μm), were analyzed in offline cold-stage ice nucleation experiments. The INP population in Greater Houston is complex, varying by site and day, but can be generalized by a weak to moderately efficient mode of INPs at −24°C and an efficient mode at −15°C. Analysis reveals that supermicron particles are largely responsible for ice nucleation warmer than −20°C across the region while submicron particles dominate at temperatures colder than −20°C. Additionally, significant spatial diversity in the INP population was observed, with differences in mean nucleation temperature between sites for nearly every size cut. Although INP concentrations were typically ∼0.08 L −1 at −20°C throughout the campaign, a notable region-wide increase in INP concentration for particles freezing at temperatures warmer than −20°C occurred from mid-August to mid-September. This comprehensive characterization of Greater Houston's INP population, including spatial, temporal, and particle size variations, can help constrain ice microphysics parameterizations in weather and climate models.

Thompson, Seth A. [Texas A & M Univ., College Stat↗

Examining the Ice-Nucleating Particles from the North Slope of Alaska (ExINP-NSA) (Final Campaign Report)

The Examining the Ice-Nucleating Particles from the North Slope of Alaska (ExINP-NSA) campaign was conducted at the National Oceanic and Atmospheric Administration’s (NOAA) Barrow Atmospheric Baseline Observatory (71.3230° N, 156.6114° W, “BRW” hereafter), next to the Atmospheric Radiation Measurement (ARM) user facility NSA site and ~ 6 km northeast of the town of Utqiaġvik. The location of the NSA site is shown in Figure 1. Our observing period began in October 2021 and continued until May 2024. This campaign was funded by the U.S. Department of Energy (DOE) Office of Science Early Career Research Program through grant number DE-SC001879. This grant contains funding for three ARM field campaigns. The previous field campaigns were performed at ARM’s Southern Great Plains atmospheric observatory in Oklahoma (SGP; 36.6073° N, 97.4876° W) and the ARM’s Eastern North Atlantic atmospheric observatory on Graciosa Island, Azores (ENA; 39.0916° N, 28.0257° W). The ExINP-NSA campaign aims included: • Determining the number concentration of ice-nucleating particles (n INPs ) active at temperatures spanning the range of heterogeneous freezing processes (from ≈−30 °C to 0 °C) using a combination of online and offline measurements, • Determining whether local meteorological conditions and/or synoptic scale air mass transport impact INP abundance and/or ice nucleation efficiency, • Examining if the physicochemical properties of INPs relate to aerosol chemistry, and • Assessing if there is a similarity in INP properties across three ARM sites Multi-seasonal datasets of INP abundance in the NSA region were delivered from this campaign. This campaign also allowed researchers to perform a comprehensive analysis of atmospheric INPs based on long- term ground-based measurements in the Alaskan Arctic. Our data and results from the ExINP-NSA campaign will help refine current earth system models. One of the stated goals of ARM is to advance aerosol-cloud ice interaction, which will be a direct result of this campaign. Current earth system models poorly represent INPs, and the 15-minute time resolution data over several seasons generated during this campaign will provide an invaluable resource, especially combined with the datasets generated during two previous ARM ExINP campaigns. These datasets will allow for a greater understanding of ice nucleation processes as they may (or may not) relate to local meteorological processes and aerosol chemistry and will eventually help further the understanding of the Earth’s atmospheric processes and energy balance.

54 ENVIRONMENTAL SCIENCES↗

The correlation between Arctic sea ice, cloud phase and radiation using A-Train satellites

Abstract. Climate warming has a stronger impact on Arctic climate and sea ice cover (SIC) decline than previously thought. Better understanding and characterization of the relationship between sea ice and clouds and the implications for surface radiation is key to improving our confidence in Arctic climate projections. Here we analyze the relationship between sea ice, cloud phase and surface radiation over the Arctic, defined as north of 60° N, using active- and passive-sensor satellite observations from three different datasets. We find that all datasets agree on the climatology of and seasonal variability in total and liquid-bearing (liquid and mixed-phase) cloud covers. Similarly, our results show a robust relationship between decreased SIC and increased liquid-bearing clouds in the lowest levels (below 3 km) for all seasons (strongest in winter) but summer, while increased SIC and ice clouds are positively correlated in two of the three datasets. A refined map correlation analysis indicates that the relationship between SIC and liquid-bearing clouds can change sign over the Bering, Barents and Laptev seas, likely because of intrusions of warm air from low latitudes during winter and spring. Finally, the increase in liquid clouds resulting from decreasing SIC is associated with enhanced radiative cooling at the surface. Our findings indicate that the newly formed liquid clouds reflect more shortwave (SW) radiation back to space compared to the surface, generating a cooling effect of the surface, while their downward longwave (LW) radiation is similar to the upward LW surface emission, which has a negligible radiative impact on the surface. This overall cooling effect should contribute to dampening future Arctic surface warming as SIC continues to decline.

54 ENVIRONMENTAL SCIENCES↗

The role of local shipping emissions in aerosol-cloud interactions in the central Arctic

Arctic shipping is projected to increase as sea ice retreats, yet the impact of modern low-sulfur ship emissions on Arctic clouds and radiation remain poorly constrained. We use year-long in situ observations from the MOSAiC expedition to characterize ship-aerosol-cloud interactions for an icebreaker burning ultra-low sulfur fuel (0.1% mass per mass). Exhaust plumes were found to be strongly enriched in Aitken-mode particles, organic aerosol, and black carbon, but showed no detectable enhancement in particulate sulfate. Despite reduced hygroscopicity relative to ambient aerosols, ship emissions substantially increased local cloud condensation nuclei concentrations. A droplet activation parameterization was applied to quantify responses in cloud droplet number concentration ( N d ) to ship-induced perturbations in low-level Arctic clouds. In winter, abundant background accumulation-mode particles from Arctic haze supplied nearly all cloud droplets, while additional particles from ship emissions had little impact on N d . In contrast, during summer months, when unperturbed background aerosol concentrations are low, ship emissions nearly doubled N d compared to average background conditions and increased N d by a factor of five compared to very clean background conditions (25th percentile of background aerosol number concentrations). Longwave radiative transfer simulations for typical conditions of summer Arctic low-level clouds/fog suggest that these ship-induced increases in N d locally (i.e. <100 km downwind) lead to enhanced net surface longwave fluxes and consequent warming, primarily for optically thin clouds (liquid water path (LWP) ⩽ 30 g·m −2 ). For LWP = 10 g · m −2 , ship emissions lead to an increase of 1 W · m −2 in cloud longwave forcing at the surface compared to average unperturbed conditions (+7% relative increase), and up to 4 W · m −2 when compared to very clean background conditions (+22% relative increase). Even ultra-low sulfur fuel emissions can therefore locally and episodically modify Arctic cloud microphysics and radiative properties, especially during summer, implying that future increases in Arctic shipping could have non-negligible regional climate impacts.

Arctic↗

University of Miami G-band Vapor Radiometer Calibration (UMGVR_CAL) Field Campaign Report

Cold-air outbreak (CAO) clouds in the Arctic are commonly mixed-phase (MP); however, the partitioning of the amount of ice and water in CAO clouds and precipitation is not always well observed. Understanding how cloud phases partition as a function of cloud life cycle is important for predicting snowfall rates, convective life cycle, and intensity at weather timescales. The partitioning into liquid versus ice also has radiative impacts that are consequential for climate. These concerns motivated the incorporation of an airborne G-band vapor radiometer (GVR) into an National Science Foundation-supported aircraft campaign named the Cold Air outbreak Experiment in the Sub-Arctic Region (CAESAR). The GVR is an upward-pointing passive microwave radiometer using four frequencies centered around the 183.31 GHz water vapor absorption line, displaced by +- 1, 3, 7, and 14 GHz. For context, The U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) user facility operates a surface-based GVR at its North Slope of Alaska (NSA) site. The same GVR has been used previously for a field campaign in the southeast Pacific, where an offset was noticed between brightness temperatures (Tbs) measured under clear skies compared to those calculated from a radiative transfer model. To account for any calibration offsets to the Tbs, a request was made to DOE to allow the GVR to operate at ARM’s Southern Great Plains (SGP) observatory and enable comparisons between its measurements and those available at SGP. This request was granted, titled ‘UMGVR_CAL’, short for ‘UMGVR_Calibration’. From October 30 to November 10, 2023, the GVR was deployed to the ARM SGP site to take advantage of their regular, nearby radiosonde launches under clear-sky conditions. The latter were determined using the SGP total sky imagery data. The GVR brightness temperatures in these clear-sky conditions were compared to those calculated by a radiative transfer code (PAMTRA) based on the SGP radiosondes. During the campaign, four suitable clear-sky episodes could be used for the GVR calibration. While few in number, these proved to be enough to satisfy our goal.

54 ENVIRONMENTAL SCIENCES↗

Brief communication: Decadal changes in topography, surface water and subsurface structure across an Arctic coastal tundra site

Abstract. In ice-rich polygonal tundra, spatiotemporal heterogeneity in ground-ice melt reshapes topography, impacting infrastructure, water and carbon cycles. This study evaluates changes in topography and subsurface structure at a coastal Arctic site by comparing data from two surveys conducted a decade apart. Each survey includes electrical resistivity tomography, active layer thickness, photogrammetry, and topographic data. Results reveal subsidence and decrease in permafrost table elevation with varying intensity and spatial distribution across polygons, alongside diverse thermal-hydrological responses, such as thermokarst pool formation in high-centered-polygons and more even subsidence in flat-centered-polygons. The study also underscores the value and limitations of sporadic surveys.

Bachman, Jonathan A↗

Arctic extreme precipitation changes from 1980 to 2022 in response to sea ice decline and enhanced atmospheric rivers

Arctic extreme precipitation (EP) broadly impacts permafrost degradation, glacier and snow cover changes, and ice sheet mass balance as well as ecosystems. However, investigation of EP spatiotemporal variations over the Arctic remains challenging, and their primary drivers are still poorly understood. Performance estimation of three state-of-the-art reanalysis products (Climate Forecast System Reanalysis (CFSR), European Centre for Medium-Range Weather Forecasts Reanalysis version 5 (ERA-5), and Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2)) against gauge-based precipitation observations reveals that MERRA-2 outperforms other reanalysis for Arctic EP changes. Based on MERRA-2 data, both annual EP amount and occurrence days averaged over the Arctic show statistically significant positive trends during 1980–2022 (3.37 ± 1.03 mm dec −1 and 0.42 ± 0.17 d dec −1 , respectively), with the most pronounced increase in the autumn. Spatial heterogeneity in annual and seasonal EP trends is found across the Arctic, with the largest positive annual trends of 30 mm dec −1 over the Bering Sea and the Denmark Strait. The significant EP increase is closely associated with intensified atmospheric rivers (ARs) and widespread decline in sea ice concentration (SIC). Specially, SIC and ARs are responsible for 12% and 50% of Arctic EP inter-annual variance, respectively, while ARs directly contribute 28.3% of the total annual EP amounts. These findings explain the mechanistic controls on Arctic EP, providing critical insights for projecting polar weather and climate extremes and their impacts on the Arctic environment.

atmospheric rivers↗

Influence of Atmospheric Rivers on Alaskan River Ice

Atmospheric rivers (ARs) transport vast amounts of moisture from low to high latitude regions. One region particularly impacted by ARs is Interior Alaska (AK). We analyze the impact of ARs on the annual river ice breakup date for 26 locations in AK. We investigate the AR-driven rise in local air temperatures and explore the relationship between ARs and precipitation, including extremes and interannual variability. We found that AR events lead to an increase in local air temperatures for over 1 week (by ≈ 1 °C). ARs account for 40% of total precipitation, explain 47% of precipitation variability, and make up 59% of extreme precipitation events, each year. By estimating the heat transfer between winter precipitation and the river ice surface, we conclude that increased precipitation during the coldest period of the year delays river ice breakup dates, while precipitation occurring close to the breakup date has little impact on breakup timing.

54 ENVIRONMENTAL SCIENCES↗

Air‐Ice‐Ocean Coupling During a Strong Mid‐Winter Cyclone: Observing Coupled Dynamic Interactions Across Scales

Abstract Arctic cyclones are key drivers of sea ice and ocean variability. During the 2019–2020 Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition, joint observations of the coupled air‐ice‐ocean system were collected at multiple spatial scales. Here, we present observations of a strong mid‐winter cyclone that impacted the MOSAiC site as it drifted in the central Arctic pack ice. The sea ice dynamical response showed spatial structure at the scale of the evolving and translating cyclonic wind field. Internal ice stress and ocean stress play significant roles, resulting in timing offsets between the atmospheric forcing and the ice response and post‐cyclone inertial ringing in the ice and ocean. Ice motion in response to the wind field then forces the upper ocean currents through frictional drag. The strongest impacts to the sea ice and ocean from the passing cyclone occur as a result of the surface impacts of a strong atmospheric low‐level jet (LLJ) behind the trailing cold front and changing wind directions between the warm‐sector LLJ and post cold‐frontal LLJ. Impacts of the cyclone are prolonged through the coupled ice‐ocean inertial response. Local impacts of the approximately 120 km wide LLJ occur over a 12 hr period or less and at scales of a kilometer to a few tens of kilometers, meaning that these impacts occur at combined smaller spatial scales and faster time scales than most satellite observations and coupled Earth system models can resolve.

Meteorology & Atmospheric Sciences↗

Reducing uncertainty of polar to midlatitude linkages using DOE’s E3SM in a coordinated model-experiment setting

This project brought DOE’s climate modeling effort with the Energy Exascale Earth System Model into the Polar Amplification Model Intercomparison Project (PAMIP), which is part of the sixth and latest Coupled Model Intercomparison Project, CMIP6. PAMIP examines the causes and consequences of polar amplification, when external forcing results in a larger temperature increase in high latitudes than the global average, in a coordinated set of model experiments with a common modeling protocol. Our teams from UC Irvine and the University of Toronto have designed, carried out, analyzed, and disseminated PAMIP output from the Energy Exascale Earth System Model (E3SM) and the Community Earth System Model (CESM). PAMIP’s ongoing stream of significant new results have advanced progress in the community’s understanding and led to new outstanding research questions that have motivated further work. PAMIP has led to improved consensus on the atmospheric response to sea ice loss. The important finding is that for a similar sea ice anomaly forcing, the simulated atmospheric response in the troposphere is remarkably consistent among the 16 models’ runs analyzed. The zonal-mean tropospheric response consists of a very robust equatorward shift of the westerly flow in mid-latitudes. However, while the multi-model mean response is robust, it has a weak amplitude relative to internal variability. We identified a weakness in the models (including E3SM) in terms of their response to sea-ice forcing that is related to eddy forcing (or nonlinear dynamical effects) at mid- to high latitudes. In fact, E3SM is an outlier in terms of the models participating, and in that sense, it turned out to be a vital participant model. We found that reductions in energy transport due sea-ice loss and involving dry air only are compensated by increases in moist energy transport from warmer sea surface temperature in midlatitudes. This leads to a large spread in energy transport into the Arctic and is a potential source of spread in Arctic amplification. We identified an important role that climate modes, including tropical modes of variability (El Nino and the Southern Oscillation (ENSO); the Quasi-biennial Oscillation (QBO)) play in the response to sea-ice anomalies, including in ocean coupled experiments. Similarly, we identified and quantified the contribution of sea-ice thickness to the atmospheric response compared to the response to sea-ice extent only. We found that it is important to run large ensembles and even with an ensemble size of 100 simulations the response is largely influenced by internal variability. We demonstrated convincingly that Ural blocking, not sea-ice loss, provides the weakening of the stratospheric polar vortex in fall/early winter and a negative phase of the North Atlantic Oscillation that can last for up to two months. However, sea-ice anomalies can influence the background flow so that the response to Ural blocking is more persistent under low sea-ice conditions in the Barents/Kara Sea than high sea ice Atmospheric model hierarchies that progressively add individual processes have a long history in providing dynamical insight for modeling the atmosphere. Similarly, coupled model hierarchies that progressively add individual ocean processes can provide insights into the workings of the coupled climate system, however such hierarchies have not been available except for a non-dynamical slab ocean model. Because of the missing processes, surface flux corrections must be added to produce a target climate. In this project, we managed to overcome this problem and develop a globally coupled ocean model hierarchy in CESM that can turn on and off the processes of mixed-layer entrainment and Ekman flow. We used the hierarchy to study the impact of Arctic sea-ice loss on the climate system. We find that the effect of mixed-layer entrainment on ocean heat uptake influences the atmospheric circulation by shifting the latitudinal positions of the mid-latitude westerly jet and the Intertropical Convergence Zone (ITCZ). In quadrupled CO 2 experiments, we studied how air-sea coupling affects the response of tropical rainfall under global warming. In order to identify the importance of individual ocean processes, we used the hierarchy of ocean models to separate the effects of seasonal mixed-layer entrainment, wind-driven Ekman flows, and frictional flows. We showed that including Ekman and frictional flows allows our simulation to produce the Pacific Ocean's enhanced equatorial warming pattern and equatorward ITCZ contraction noted in previous climate simulations. We also showed that the frictional flow, which has yet to receive much attention, is as important as the Ekman flow in generating equatorial heat convergence.

54 ENVIRONMENTAL SCIENCES↗

Partition between supercooled liquid droplets and ice crystals in mixed-phase clouds based on airborne in situ observations

Abstract. The onset of ice nucleation in mixed-phase clouds determines the lifetime and microphysical properties of ice clouds. In this work, we develop a novel method that differentiates between various phases of mixed-phase clouds, such as clouds dominated by pure liquid or pure ice segments, compared with those having ice crystals surrounded by supercooled liquid water droplets or vice versa. Using this method, we examine the relationship between the macrophysical and microphysical properties of Southern Ocean mixed-phase clouds at −40 to 0 °C (e.g. stratiform and cumuliform clouds) based on the in situ aircraft-based observations during the US National Science Foundation Southern Ocean Clouds, Radiation, Aerosol Transport Experimental Study (SOCRATES) flight campaign. The results show that the exchange between supercooled liquid water and ice crystals from a macrophysical perspective, represented by the increasing spatial ratio of regions containing ice crystals relative to the total in-cloud region (defined as ice spatial ratio), is positively correlated with the phase exchange from a microphysical perspective, represented by the increasing ice water content (IWC), decreasing liquid water content (LWC), increasing ice mass fraction, and increasing ice particle number fraction (IPNF). The mass exchange between liquid and ice becomes more significant during phase 3 when pure ice cloud regions (ICRs) start to appear. Occurrence frequencies of cloud thermodynamic phases show a significant phase change from liquid to ice at a similar temperature (i.e. −17.5 °C) among three types of definitions of mixed-phase clouds based on ice spatial ratio, ice mass fraction, or IPNF. Aerosol indirect effects are quantified for different phases using number concentrations of aerosols greater than 100 or 500 nm (N>100 and N>500, respectively). N>500 shows stronger positive correlations with ice spatial ratios compared with N>100. This result indicates that larger aerosols potentially contain ice-nucleating particles (INPs), which facilitate the formation of ice crystals in mixed-phase clouds. The impact of N>500 is also more significant in phase 2 when ice crystals just start to appear in the mixed phase compared with phase 3 when pure ICRs have formed, possibly due to the competing aerosol indirect effects on primary and secondary ice production in phase 3. The thermodynamic and dynamic conditions are quantified for each phase. The results show stronger in-cloud turbulence and higher updraughts in phases 2 and 3 when liquid and ice coexist compared with pure liquid or ice (phases 1 and 4, respectively). The highest updraughts and turbulence are seen in phase 3 when supercooled liquid droplets are surrounded by ice crystals. These results indicate both updraughts and turbulence support the maintenance of supercooled liquid water amongst ice crystals. Overall, these results illustrate the varying effects of aerosols, thermodynamics, and dynamics through various stages of mixed-phase cloud evolution based on this new method that categorizes cloud phases.

54 ENVIRONMENTAL SCIENCES↗

Electrifying Airport GSE: Monte Carlo Grid Impacts

Airports globally are shifting from ICE-powered to electric Ground Support Equipment (eGSE) to enhance efficiency, reduce operational costs, and improve operator health. Leveraging predictable routes, flat terrain, and low operational speeds, airports provide ideal conditions for electrification. This study evaluates freight GSE electrification at Dallas-Fort Worth International Airport (DFW), USA, using the Agile@ platform, which integrates three analytical methods: Freight Facility Model (FFM), Activity-Structure-Intensity-Fuel (ASIF), and Monte Carlo simulations. Results from 10,000 simulations indicate modest but critical increases in electricity demand and significant variability in GSE energy consumption. These insights emphasize the importance of data-driven scheduling, targeted maintenance, and strategic infrastructure planning. For high-uncertainty scenarios, airports are advised to deploy buffer energy storage systems (battery banks), implement demand-response charging strategies, schedule flexible workforce shifts, and prioritize proactive maintenance-particularly for equipment with higher operational uncertainty, such as tug tractors with trailers. Agile@ thus offers a robust, scalable, and data-driven framework to optimize long-term GSE planning and enhance reliability across diverse airport environments.

Bose, Ranjan [ORNL] (ORCID:0009000791026327)↗

Observation of a mixed close-packed structure in superionic water

The study of superionic (SI) water has been a highly active research area since its theoretical prediction. Despite significant experimental and computational efforts, its melting curve and the stability of different oxygen lattices remain debated, impacting our understanding of SI ice’s peculiar transport properties. Experimental results at lower pressures show disagreement, whereas data at higher pressures are scarce due to the extreme challenges of such experiments. In this work, we present ultrafast X-ray diffraction results of water compressed by multiple shocks to pressures up to ~ 180 GPa. At pressures exceeding 150 GPa and temperatures around 2500 K, our diffraction patterns challenge the pure FCC-SI phase model, providing experimental evidence of the mixed close-packed superionic phase predicted by advanced ab initio calculations. At lower pressures, we observe simultaneous signatures of BCC and FCC structures within a pressure-temperature range consistent with some static-compression experiments, helping to resolve contradictory results in literature. These insights offer new constraints on the stability domains of SI phases and reveal detailed structural features, such as stacking faults. Our results advance the structural understanding of high-pressure SI ice to a level approaching that of ice I polymorphs, with potential implications for water-rich interiors of giant planets.

Andriambariarijaona, Leon [Centre National de la R↗

Life-cycle cost-benefit analysis of a novel self-heating pavement made from coal-derived solid carbon

Winter weather events challenge the safety, efficiency, and sustainability of roadway networks, particularly road bridges vulnerable to climate impacts. Although effective, conventional de-icing methods incur high expenses and cause significant environmental contamination. To address these longstanding issues, a low-cost novel coal-derived carbon enabled smart pavement (CDC-SP) de-icing system was developed, aiming to alleviate traffic delays, severe corrosion, compromised safety, and environmental pollution. However, the economic performance of CDC-SP has not been quantified to guide decision-making. To this end, this paper presents a Life-Cycle Cost-Benefit Analysis (LCCBA) to assess the economic feasibility of the CDC-SP de-icing system for road bridges in five representative urban and rural areas across cool humid and cold humid climate zones. Given the variations and uncertainties of several factors that determine the costs and benefits, a sensitivity analysis was conducted to determine the system’s economic reliability. Additionally, a Monte Carlo simulation (MCS) was performed to quantify the impacts of important factors and identify the most beneficial scenarios. Furthermore, the CDC-SP de-icing systems have demonstrated substantial economic benefits and short payback periods, showing great applicability for rural and urban road bridges with different service levels across multiple climate zones as compared to conventional de-icing methods.

36 MATERIALS SCIENCE↗