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At least 37 records · Page 2

Plasma-gas interactions studies in a hybrid plume plasma rocket

Plasma-gas interaction was investigated and the basic mechanisms for energy and particle transport. The solution approach assumes cylindrical geometry and includes a multiplicity of atomic reactions, and the presence of a strong magnetic field is described. The principal reactions are electron and ion impact ionization, and charge exchange between hot ions and cold neutrals. Radial particle and energy transport is mainly by diffusion. A modified Bohm diffusion model for plasma in the core of the plume, and classical neutral particle diffusion in the cooler regions of the flow are presented. Neutrals are allowed to free stream in the low density regions, where the collision mean-free-path becomes comparable, or even larger than the characteristic dimensions of the system.

Chang, F. R.

A Survey of Xenon Ion Sputter Yield Data and Fits Relevant to Electric Propulsion Spacecraft Integration

A survey of low energy xenon ion impact sputter yields was conducted to provide a more coherent baseline set of sputter yield data and accompanying fits for electric propulsion integration. Data uncertainties are discussed and different available curve fit formulas are assessed for their general suitability. A Bayesian parameter fitting approach is used with a Markov chain Monte Carlo method to provide estimates for the fitting parameters while characterizing the uncertainties for the resulting yield curves.

xenon

Space radiation interaction mechanisms in materials

Models of charged-particle impact under conditions typical of the space environment are reported, with a focus on impact excitation and nuclear reactions, especially for heavy ions. Impact excitation is studied by using a global model for electronic excitation based on formal relations through the classical dielectric function to derive an approximation related to the local plasma (electron density distribution) within the atoms and molecules; and corrections to the model resulting from the nonfluid nature of this plasma are discussed. Nuclear reactions are studied by reducing quantum-mechanical treatment of this general N-body problem to an equivalent two-body problem that is solvable, and by comparing the results with experimental data. The equations for heavy-charged-particle transport are derived and solution techniques demonstrated. Finally, these methods of analysis are applied to study the change in the electrical properties of a GaAs semiconductor for photovoltaic applications; proton damage to GaAs crystals is found to arise from stable replacement defects and to be nonannealable, in contrast to electron-induced damage.

Wilson, J. W.

NSTAR Ion Thruster Plume Impact Assessments

Tests were performed to establish 30-cm ion thruster plume impacts, including plume characterizations via near and farfield ion current measurements, contamination, and sputtering assessments. Current density measurements show that 95% of the beam was enclosed within a 22 deg half-angle and that the thrust vector shifted by less than 0.3 deg during throttling from 2.3 to 0.5 kW. The beam flatness parameter was found to be 0.47, and the ratio of doubly charged to singly charged ion current density decreased from 15% at 2.3 kW to 5% at 0.5 kW. Quartz sample erosion measurements showed that the samples eroded at a rate of between 11 and 13 pm/khr at 25 deg from the thruster axis, and that the rate dropped by a factor of four at 40 deg. Good agreement was obtained between extrapolated current densities and those calculated from tantalum target erosion measurements. Quartz crystal microbalance and witness plate measurements showed that ion beam sputtering of the tank resulted in a facility material backflux rate of -10 A/hr in a large space simulation chamber.

Myers, Roger M.

Failure Mechanisms of Ni-H2 and Li-Ion Batteries Under Hypervelocity Impacts

Lithium-Ion (Li-Ion) batteries have yielded significant performance advantages for many industries, including the aerospace industry, and have been selected to replace nickel hydrogen (Ni-H2) batteries for the International Space Station (ISS) program to meet the energy storage demands. As the ISS uses its vast solar arrays to generate its power, the solar ar-rays meet their sunlit power demands and supply excess power to battery packs for power de-livery on the sun obscured phase of the approximate 90 minute low Earth orbit. These large battery packs are located on the exterior of the ISS, and as such, the battery packs are ex-posed to external environment threats like naturally occurring meteoroids and artificial orbital debris (MMOD). While the risks from these solid particle environments has been known and addressed to an acceptable risk of failure through shield design, it is not possible to completely eliminate the risk of loss of these assets on orbit due to MMOD, and as such, failure consequences to the ISS have been considered.

Miller, J. E.

Failure Mechanisms of Ni-H2 and Li-Ion Batteries Under Hypervelocity Impacts

Lithium-Ion (Li-Ion) batteries have yielded significant performance advantages for many industries, including the aerospace industry, and have been selected to replace nickel hydrogen (Ni-H2) batteries for the International Space Station (ISS) program to meet the energy storage demands. As the ISS uses its vast solar arrays to generate its power, the solar arrays meet their sunlit power demands and supply excess power to battery packs for power delivery on the sun obscured phase of the approximate 90 minute low Earth orbit. These large battery packs are located on the exterior of the ISS, and as such, the battery packs are exposed to external environment threats like naturally occurring meteoroids and artificial orbital debris (MMOD). While the risks from these solid particle environments has been known and addressed to an acceptable risk of failure through shield design, it is not possible to completely eliminate the risk of loss of these assets on orbit due to MMOD, and as such, failure consequences to the ISS have been considered.

Miller, J. E.

Coordinated Cation Transport in Ti 3 C 2 T x MXene Membranes

Membrane nanofiltration is an attractive strategy for the selective recovery of high-demand metals from wastewater and brine. Effective sieving of ions in aqueous environments will require precise control over membranes’ nanochannel size and chemistry. Ti 3 C 2 T x MXene is an environmentally stable 2D material that can be processed into laminar membranes containing nanoscale interlayer spaces. The MXene interlayer environment depends on the ion species and amount of water intercalated between MXene sheets, and it is the major factor governing permeation and selectivity through MXene membranes. Coordinated ion–ion and ion-interlayer dynamics in the presence of complex mixtures can impact ion permeability and selectivity. Herein, we observe strong competitive effects between different cations (Li + , Na + , and Ca 2+ ) in binary mixtures, resulting in reduced selectivity when compared with single-salt permeability ratios. X-ray diffraction, molecular dynamics, and density functional theory simulations support the conclusion that cations with stronger attraction to MXene flakes can preferentially occupy the MXene nanochannels and hinder other ions via charge or size exclusion. In conclusion, elucidation of ion transport behavior in MXene under complex conditions will allow for more rational design of efficient ion-sieving membranes.

2D Materials

Understanding the Quadrupole Mass Filter and Testing a High-Resolution QMS RGA for ITER

A common type of residual gas analyzer is the quadrupole mass spectrometer. One of the main components within this instrument is a mass filter known as the quadrupole. It is responsible for the selective throughput of the ionized gas particles - by ascending mass number - prior to ion impacts on the analyzer (or detector) surface from which the ion current signal is generated for processing. However, the quadrupole is not fully described in relation to the electric field characteristics and the function as an ion mass separator. This paper describes the basic origins of the electrical design, the intricate assembly criteria, and performance of the quadrupole within the spectrometer. A specialized quadrupole mass spectrometer is part of a configuration for a diagnostic gas analyzer system planned for ITER, a fusion research machine. It has a verified capability, essential as a diagnostic criterion for this reactor project, to successfully deconvolute the mass signals of Helium-4 and deuterium (reactor fuel exhaust gases, separated by only 0.026 atomic mass units), down to a relative three-percent concentration of the former gas. The associated preliminary testing, performed at the Oak Ridge National Laboratory, is also addressed. Finally, one of the key parameters used to express gas concentration, the relative sensitivity factor, will be explained, including an evaluation of dependency on other variables.

Marcus, Chris [ORNL] (ORCID:0000000190139636)

An experimental study of impingement-ion-production mechanisms

A simple model for the production of ions that impinge on and sputter erode the accelerator grid of an ion thruster is presented. Charge-exchange and electron-impact ion production processes are considered, but experimental results show the charge-exchange process dominates. Additional experimental results show the effects of changes in thruster operating conditions on the length of the region from which these ions are drawn upstream into the grid. Results which show erosion patterns and indicate molybdenum accelerator grids erode more rapidly than graphite ones are also presented.

Monheiser, Jeff M.

Advanced electric propulsion research, 1991

A simple model for the production of ions that impinge on and sputter erode the accelerator grid of an ion thruster is presented. Charge-exchange and electron-impact ion production processes are considered, but initial experimental results suggest the charge-exchange process dominates. Additional experimental results show the effects of changes in thruster operating conditions on the length of the region from which these ions are drawn upstream into the grid. Results which show erosion patterns and indicate molybdenum accelerator grids erode more rapidly than graphite ones are also presented.

Monheiser, Jeffery M.

Increasing the Life of a Xenon-Ion Spacecraft Thruster

A short document summarizes the redesign of a xenon-ion spacecraft thruster to increase its operational lifetime beyond a limit heretofore imposed by nonuniform ion-impact erosion of an accelerator electrode grid. A peak in the ion current density on the centerline of the thruster causes increased erosion in the center of the grid. The ion-current density in the NSTAR thruster that was the subject of this investigation was characterized by peak-to-average ratio of 2:1 and a peak-to-edge ratio of greater than 10:1. The redesign was directed toward distributing the same beam current more evenly over the entire grid andinvolved several modifications of the magnetic- field topography in the thruster to obtain more nearly uniform ionization. The net result of the redesign was to reduce the peak ion current density by nearly a factor of two, thereby halving the peak erosion rate and doubling the life of the thruster.

Goebel, Dan

A Semianalytical Ion Current Model for Radio Frequency Driven Collisionless Sheaths

We propose a semianalytical ion dynamics model for a collisionless radio frequency biased sheath. The model uses bulk plasma conditions and electrode boundary condition to predict ion impact energy distribution and electrical properties of the sheath. The proposed model accounts for ion inertia and ion current modulation at bias frequencies that are of the same order of magnitude as the ion plasma frequency. A relaxation equation for ion current oscillations is derived which is coupled with a damped potential equation in order to model ion inertia effects. We find that inclusion of ion current modulation in the sheath model shows marked improvements in the predictions of sheath electrical properties and ion energy distribution function.

Bose, Deepak

Alteration of the UV-visible reflectance spectra of H2O ice by ion bombardment

Satellite in the Jovian and Saturnian system exhibit differences in reflectivity between their 'leading' and 'trailing' surfaces which can affect the local vapor pressure. Since these differences are thought to be due to differences in the flux of bombarding magnetospheric ions, the influence of ion impact on the UV-visible reflectance of water ice surfaces (20-90 K) by keV ion bombardment was studied. An observed decrease in reflectance in the UV is attributed to rearrangement processes that affect the physical microstructure and surface 'roughness'. The ratio in reflectance of bombarded to freshly deposited films is compared to the ratio of the reflectance of the leading and trailing hemispheres for Europa and Ganymede.

Sack, N. J.

Material Interactions with Solar Wind Ion Environments

Solar wind composition is dominated by hydrogen (approx.96%) and helium (approx.3 to 4%) with a minor fraction (less than or equal to 1%) of heavy ions. Hydrogen (helium) ions impact spacecraft surfaces with energies from 0.5 to 5 keV (1.8 to 21 keV) due to variations in solar wind velocity from 300 km/s to 1000 km/sec with extremes of a few 10 s keV during periods of extremely high solar wind velocity exceeding 1000 km/sec. Mean impact energies are typically on the order of approximately 1 keV and 4 keV for hydrogen ions and helium ions, respectively. These energies are typically of the peak of the energy dependent light ion sputter yields for hydrogen and helium on many metals. In addition, light ions with kilovolt energies have been shown to produce blister (or exfoliation) damage to metal surfaces due to formation of high pressure gas bubbles within the materials when exposed to ion fluences on the order of 10(exp 16 to (10(exp 17 ions/sq cm. A number of spacecraft designs for current and future missions include gossamer polymer structures with thin metallic reflection coatings to shield instruments from the Sun or solar sail propulsion systems for use in a variety of locations in the inner solar system from 0.5 to 1 AU. In addition, there is interest in designing spacecraft for solar physics missions requiring operations as close to the Sun as 0.16 to 0.2 AU. Integrity of the metallic coatings is critical in many of these applications since degradation will result in modification of material thermal properties or exposure of polymers to solar UV photons which can compromise mission requirements. This paper will evaluate the relative contributions of sputtering and blister formation to material degradation in solar wind environments over a range of radial distances from the Sun to demonstrate where solar wind environments become important for materials selection. We will first review the physics and results from laboratory measurements of light ion sputtering, blistering, and exfoliation of metallic surfaces to establish the order of magnitude ion fluence required for significant surface damage. Solar wind ion fluence environments will then be evaluated due to variations in solar wind conditions as a function of solar cycle for varying distances from the Sun using models for radial variations in solar wind ion number density, temperature, and velocity to determine where sputtering and blistering is most likely to be an issue. Finally, ion fluence statistics for varying radial distances from the Sun will be shown to establish the mission duration and radial distances from the Sun where missions will encounter sufficient ion fluence to exhibit damage to metallic surfaces.

Minow, Joseph I.

General kinetic ion-induced electron emission model for metallic walls applied to biased Z-pinch electrodes

A kinetic ion-induced electron emission (IIEE) model for general applications is developed to obtain the emitted electron energy spectrum for a distribution of ion impacts on a metallic surface. We assume an ionization cascade mechanism and use empirical models for the ion and electron stopping powers. The emission spectrum and the secondary electron yield (SEY) are validated for a variety of materials. The IIEE model is used to study the effect of IIEE on the plasma-material interactions of Z-pinch electrodes. Un-magnetized Boltzmann-Poisson simulations are performed for a Z-pinch plasma doubly bounded by two biased copper electrodes with and without IIEE at bias potentials from 0 to 9 kV. At the anode, the SEY decreases from 0 to 1 kV, but then increases at higher bias potentials. At the cathode, the SEY is much larger due to higher energy ion bombardment and grows with bias potential. As the bias potential increases, the emitted cathode electrons are accelerated to higher energies into the domain, collisionally heating the plasma. Above 1 kV, the heating is strong enough to increase the plasma potential. Despite SEY greater than 1, only a classical sheath forms as opposed to a space-charge limited or inverse sheath due to the emitted electron flux not reaching the space charge current saturation limits. Furthermore, the current in the emissionless cases saturates to a value lower than experiment. With IIEE, the current does not saturate and continues to increase with the 4 kV case, matching most closely with the experiment.

Carbon based materials

Solar flare effects on the zodiacal light

Results are reported for an observational and theoretical study of possible solar-flare effects on the zodiacal light. A seven-year search for flare-induced brightness variations in the light is described which discovered no significant changes in either the level of brightness from night to night or the shape of the main zodiacal-light cone at elongations greater than 25 deg from the sun. Several possible dynamical effects of solar flares on the zodiacal dust cloud are investigated theoretically, including increased ion drag from a passing shock wave, possible rotational bursting of dust particles as a result of ion impacts, and fluorescence of the dust particles. It is found that the kinetic energy carried by shock-front ions is not sufficient to cause the dust to fluoresce, that increased ion drag may be significant only at heliocentric distances less than 0.1 AU, and that particles larger than 10 microns cannot attain bursting speeds at the appropriate distances. The question is considered of whether changes in the brightness of the polarized component as a result of variations in electron number density can be observed from earth or the Helios solar probe.

Misconi, N. Y.

Ion-Molecule Reactions and Ion Kinetics in DC Townsend Discharges in Dielectric Gases

In gas discharges the identify, transport, relative intensities, and kinetic energy distributions (KEDs) of ions may be dominated by ion-molecule reactions. In order to understand these discharges, there is a need for cross section data for various ion-molecule reactions, including symmetric and asymmetric charge-transfer, collisional detachment, and ion conversion reactions, especially for low to intermediate ion-impact energies. In view of the importance of dielectric gases, we have recently measured the KEDs of various positive and negative ions produced in DC Townsend discharges in SF6, CF4, CHF3, O2, and CO2. The relative abundance and mean energies of ions are obtained from the measured KEDs. The effective cross sections (Qeff) describing the KEDs of various ions can be derived by using the mean ion energies and the electric field-to-gas density ratios (E/N). In the case of SF6 and O2 discharges, the determined cross sections (Qeff) for the negative-ion molecule reactions are consistent with previously measured cross section data obtained by crossed-beam experiment. The availability of these cross section values enabled us to understand the ion data reasonably well. However, the lack of adequate cross section data for positive ions in all of the above gases is a major obstacle in understanding ion transport in these gas discharges.

Rao, M. V. V. S.